Spherical silicon optical resonators: Possible applications to biosensing

We observed whispering gallery modes in the 90^° elastic light scattering and 0^° transmission spectra of a 500 μm silicon microsphere in the near-infrared telecommunication wavelengths. The whispering gallery modes have quality factors on the order of 10⁵. An autocorrelation function analysis of the 90^° elastic light scattering and 0^° transmission spectra is performed. The differential autocorrelation of the 90^° elastic light scattering and 0^° transmission spectra reveal a spectral mode spacing 0.23 nm of the whispering gallery modes, which can be used for spectral calibration as well as the calibration of the microsphere size. The spectral shift of the whispering gallery modes can be measured for biosensing applications. An estimation analysis is performed for the adsorption of 30 DNA base pairs on the microsphere results in a wavelength shift of 0.57 nm, which is approximately 40 times the linewidth of the whispering gallery modes. This high sensitivity heralds silicon microspheres as possible candidates for biosensing applications.     

Dynamics of helical-wave emission in a fiber-coupled diode end-pumped solid-state laser

We have generated TEM_0,l ^* modes in an end-pumped microchip laser using a standard fiber-coupled diode. A rich set of dynamic behaviors, such as periodic and quasi-periodic self-modulation, chaotic pulsing and frequency locking was observed in the generated TEM_0,l ^* modes. Experimental results confirm the theoretical predictions that the locking occurs as a subcritical bifurcation and that a region of coexisting locked and unlocked states exists. Received: 14 November 2000 / Revised version: 22 January 2001 / Published online: 23 May 2001     

Optical Fiber Excitation of Fano Resonances in a Silicon Microsphere

In this article, Fano lineshape whispering gallery modes were observed in the light scattering spectrum of a silicon microsphere in near-infrared telecommunication wavelengths. A simple model is presented to explain the transition from Lorentzian lineshape to the Fano lineshape resonances with the coupled-mode theory of multiple whispering gallery modes. Polar mode spacing of 0.23 nm is observed in the spectra, which correlates well with the calculated value. The quality factor of the Lorentzian and Fano resonances are on the order of 10⁵. By using an appropriate interface design for the microsphere coupling geometries, Fano lineshape optical resonances herald novel device applications for silicon volumetric lightwave circuits.     

Additive-pulse mode locking of a diode-pumped Nd3+:YVO4 laser

We demonstrate self-starting additive-pulse mode locking of a diode-pumped Nd³⁺:YVO₄ laser. Pulse durations of 2.7 ps are measured at a repetition frequency of 90.7 MHz and at an average output power of 1.1 W. This corresponds to a peak power of 4.5 kW. Received: 27 June 2001 / Revised version: 10 October 2001 / Published online: 29 November 2001     

Spectral line broadening mechanism of Er3+ transitions in Er:Ti:LiNbO3 channel waveguides

In order to elucidate the interaction effects among the various defects present in a LiNbO₃-based integrated optical device, we investigated the change of the optical properties of Er³⁺ ions under the application of an external electric field and hydrostatic pressure. We obtained for stoichiometric bulk material a complete picture of the field-induced spectral shifts as a function of transition and site. As a first important application of these results we were able to clarify the mechanism of spectral broadening of the Er³⁺ transitions in Ti:Er:LiNbO₃ channel waveguides. By selecting different waveguide modes for excitation and using highly selective double-resonance excitation with two lasers, we found that the [Ti⁴⁺] concentration gradient caused by the indiffusion results in an internal E-field gradient. This translates, due to the averaging within the guided mode, into mode-dependent spectral line broadening. Received: 24 May 2001 / Published online: 23 October 2001     

Photoacoustic characteristics of dynamical adhesion of films on a metallic substrate

In this communication, we report a numerical model that predicts the mechanical deformations associated with the pulsed laser irradiation of a film surface, based on thermal diffusion theory. The model is consequently advanced to produce a method for evaluating film adhesion strength. The epicenter surface displacements within the irradiated fields have been measured using a heterodyne interferometer. The comparison of the experimental data and the displacements calculated by the model shows good agreement. By investigating the propagating acoustic modes under non-destructive and destructive modes, we reveal that, with or without interface delamination, the phase structure of the longitudinal waves will be altered due to the change of reflection mode at the interface. Applying shock dynamics theory, we evaluate the adhesion strength of the TiN/stainless interface. We also indicate the strain rate can be up to 10⁵∼10⁶ s^-1 during film interface delamination. Received: 5 April 2002 / Accepted: 24 June 2002 / Published online: 26 February 2003 RID="*" ID="*"Corresponding author. Fax: +86-511/879-1919, E-mail: mzhou@ujs.edu.cn     

Influence of a sharp fiber tip on high-Q modes of a microsphere resonator

We investigate the degradation of the Q factor of a fundamental whispering-gallery mode of a microsphere resonator when a fiber tip is placed in the evanescent field of the mode. With a tip diameter of 80 nm it is possible to maintain a Q factor exceeding 10(8), even when the tip is as close as 10 nm to the sphere surface. This result demonstrates the possibility of using such a tip as a "nanotool" to actively place a single nanoparticle in a single high- Q mode with great precision to achieve well-controlled coupling.     

Fiber Optic Excitation of Silicon Microspheres in Amorphous and Crystalline Fluids

ABSTRACT

This study investigates the optical resonance spectra of free-standing monolithic single crystal silicon microspheres immersed in various amorphous fluids, such as air, water, ethylene glycol, and 4-Cyano-4’-pentylbiphenyl nematic liquid crystal. For the various amorphous fluids, morphology-dependent resonances with quality factors on the order of 10⁵ are observed at 1428 nm. The mode spacing is always on the order of 0.23 nm. The immersion in various amorphous fluids affects the spectral response of the silicon microsphere and heralds this technique for use in novel optofluidics applications. Even though the nematic liquid crystal is a highly birefringent, scattering, and high-index optical medium, morphology-dependent resonances with quality factors on the order of 10⁵ are observed at 1300 nm in the elastic scattering spectra of the silicon microsphere, realizing a liquid-crystal-on-silicon geometry. The relative refractive index and the size parameter of the silicon microsphere are the parameters that affect the resonance structure. The more 4-Cyano-4’-pentylbiphenyl interacting with the silicon microsphere, the lower the quality factor of the resonances is. The more 4-Cyano-4’-pentylbiphenyl is interacting with the silicon microsphere, the lower the mode spacing Δλ of the resonances is. The silicon microspheres wetted with nematic liquid crystal can be used for optically addressed liquid-crystal-on-silicon displays, light valve applications, or reconfigurable optical networks.     

Pigtailing the high-Q microsphere cavity: a simple fiber coupler for optical whispering-gallery modes

We demonstrate a simple method for efficient coupling of standard single-mode optical fibers to a high- Q optical microsphere cavity. Phase-matched excitation of whispering-gallery modes is provided by an angle-polished fiber tip in which the core-guided wave undergoes total internal reflection. In the experimental setup, which included a microsphere with both an input and an output coupler, the total fiber-to-fiber transmission at resonance reached 23% (total insertion loss, 6.3 dB), with loaded quality factor Q>/=3x10(7) and unloaded Q approximately 1.2x10(8) at 1550 nm. A simple pigtailing method for microspheres permits their wider use in fiber optics and photonics devices.     

Deposition of mass-selected cluster ions using a pulsed arc cluster-ion source

A PACIS (pulsed arc cluster-ion source) developed for high average cluster-ion currents is presented. The performance of the PACIS at different operational modes is described, and the suitability for cluster-deposition experiments is discussed in comparison with other cluster-ion sources. Maximum currents of mass-selected cluster ions of 3–6 nA of small Si_n ^- (n=4–10) clusters and 0.3–0.5 nA of large Al_n ^+/- (n=20–70) clusters are achieved. The mass-selected cluster ions are soft-landed on a substrate at residual kinetic energies lower than 1 eV/atom, and the samples are characterized by X-ray photoelectron spectroscopy and scanning tunneling microscopy. First results on the soft landing of “magic” Si₄ ^- clusters on graphite are presented. Received: 30 May 2001 / Accepted: 14 June 2001 / Published online: 2 October 2001     

Detection of NO in a spark-ignition research engine using degenerate four-wave mixing

We report the first application of degenerate four-wave mixing (DFWM) to combustion diagnostics in a methane-fuelled internal combustion research engine. Combustion-generated NO in the spark-ignited engine was detected using scanning narrowband DFWM in a modified forward folded BOXCARS geometry. The resulting spectra of the X²Π-A²Σ⁺(0,0) band at 226 nm display an excellent signal-to-noise ratio. Extension of the technique to different engine operating conditions and to time-resolved multiplex DFWM is discussed. Received: 3 May 2001 / Revised version: 1 October 2001 / Published online: 29 November 2001     

A laser system providing tunable, narrow-band radiation from 35 nm to 2 μm

We describe a laser system that readily provides radiation tunable from 2 μm in the infra-red to 35 nm in the extreme ultraviolet spectral range. The broad spectral range is covered through a range of non-linear processes such as Raman shifting and high-order harmonic generation. Pulses with duration of tens of picoseconds are obtained. The relative bandwidth of the radiation is δλ/λ=10^-4, comparable with what can be achieved by using high-resolution monochromators at state-of-the-art synchrotron beamlines. We discuss different methods for characterising the radiation in this wide wavelength regime. We also discuss the capabilities of the system from the measured parameters. Received: 12 December 2000 / Revised version: 8 March 2001 / Published online: 27 April 2001     

Observation of microlaser with Er-doped phosphate glass coated microsphere pumped by 780 nm

The silica microspheres coated with a thin layer of Er-doped phosphate glass are fabricated and whispering-gallery modes (WGMs) with quality factor of 8 × 10⁶ in the 780 nm band are obtained. We demonstrate that the microsphere can form single-mode and multi-mode microlaser in communication-band with a pumping laser of wavelength 780 nm band. Moreover, the representative lateral emission distributed modes in the microsphere can be directly observed via the upconverted photoluminescence.     

Effects of tunneling coupling on plasmon modes in asymmetric double-quantum-well structures

The collective charge density excitations in asymmetric double-quantum-well (DQW) structures with different tunneling strengths are systematically studied. In particular, the damping properties of the plasmon modes in various tunneling strengths are investigated in detail. It is shown that plasmon modes in asymmetric DQW structures are quite different from those in symmetric DQW systems. In weak tunneling regime, an intra-subband mode ω _- with an acoustic-like dispersion relation which is damped in symmetric DQW structures arises and coexists with the optical-like mode ω ₊ while the inter-subband mode ω ₁₀ is highly damped. With the tunneling strength being increased, the ω ₁₀ branch gradually becomes undamped and emerges out of the (1-0) single-particle continuum, whereas the ω _- branch gradually approaches the (0-0) single-particle continuum. In intermediate coupling regime, these three branches of modes coexist undamped. In strong tunneling regime, ω _- enters the (0-0) single-particle continuum and becomes damped. Consequently, only the ω ₊ and ω ₁₀ modes exist in this regime. Received 10 July 2001 and Received in final form 17 September 2001     

Photorefractive tuning of whispering gallery modes of a spherical resonator integrated inside a microstructured optical fibre

We demonstrate the photorefractive tuning of the whispering gallery modes of a single BaTiO₃ microsphere resonator integrated inside a grapefruit-shaped microstructured optical fibre, upon CW laser irradiation at 532 nm while using irradiation intensities up to 5.5 W/cm². Temporal evolution results of the WGM spectra are provided with respect to the illumination and relaxation conditions applied.     

Structural change of radiation defects in graphite crystals induced by STM probing

It was found that STM (scanning tunneling microscopy) images of defects in highly oriented pyrolytic graphite introduced by bombardment of 400 eV Ar⁺ ions in ultra-high vacuum exhibit substantial changes in the course of STM probing. Detailed examination of abrupt changes in the tunneling current measured at defect sites during voltage scans shows that the primary cause of the defect-image change was found to be neither the injected current nor the injected power but the absolute value of the voltage applied between the probe tip and the sample. We propose that an electric polarization induced force attracting the sample surface toward the probe tip widens the layer spacing of the graphite surface, leading to an acceleration of the lateral diffusion of interstitial atoms introduced by the ion irradiation, which results in a change in the defect structures and the accompanying electronic structures sensible in the STMimaging. Received: 14 June 2001 / Accepted: 7 September 2001 / Published online: 20 December 2001     

Elastic scattering from a sapphire microsphere placed on a silica optical fiber coupler: Possible applications to biosensing

Elastic light scattering is performed in the original band of optical fiber communication at 1300 nm for a 500 μm sapphire microsphere placed on a silica optical fiber half coupler. The morphology dependent resonances (MDRs) are observed in the transverse magnetically (TM) polarized and transverse electrically (TE) polarized 0^° transmission and 90^° elastic scattering obtained from the sapphire microsphere. The TE and TM MDRs can be detected selectively with the use of a Glan polarizer. The TE and TM polarization selectivity provides the ability to select relative MDR to BG levels. The TM polarization provides higher MDR signal to background ratio (SBR) and is suitable for optical monitoring, biological sensing or any other optoelectronic application that requires a high resolution optical filter. The polar angular mode spacing of 0.36 nm of the resonances correlates well with the optical size of the sapphire microsphere. The autocorrelation of the 90^° elastic scattering spectra also shows peaks at 0.36 nm. The spectral linewidths of the resonances are on the order of 0.1 nm, which corresponds to quality factors on the order of 10⁴. A sapphire sphere with a radius of 500 μm and relative refractive index of 1.31, resonances will red-shift by 1.01 nm (0.077%). This shift is on the order of 10 linewidths, making sapphire biophotonic sensors an interesting alternative to silica biophotonic sensors.     

Calculation of optimal fiber radius and whispering-gallery mode spectra for a fiber-coupled microsphere

Coupled-mode theory is used to numerically calculate the coupling coefficients between the modes of a tapered fiber and those of a fused-silica microsphere. In the visible and near-infrared wavelength ranges, typical tapered fibers are multimode. To maximize the photon tunneling from the fundamental fiber mode to the microsphere whispering-gallery mode and to minimize the tunneling from the sphere to higher-order fiber modes, the optimal fiber radius is found to be somewhat smaller than that for phase matching. Also calculated are whispering-gallery mode spectra that take into account the eccentricity of the microsphere and the fact that in an experiment the tapered fiber is not necessarily perfectly aligned with the equatorial plane of the microsphere.     

Dynamic light scattering and <Superscript>31</Superscript>P NMR spectroscopy study of the self-assembly of deoxyguanosine 5'-monophosphate

Self-assembling properties of deoxyguanosine 5'-monophosphate in isotropic solutions of concentrations from 0.5 wt% to 15 wt% were investigated by dynamic light scattering (DLS) and ³¹P NMR spectroscopy. A slow diffusive mode with a diffusion coefficient D _slow∼ 10^-12 m²/s was detected by DLS for the whole concentration range. This mode is assigned to the translational motion of large globular aggregates, similar to those observed in DNA and other polyelectrolyte solutions. The existence of such aggregates was confirmed by freeze fracture electron microscopy. Close to the isotropic-cholesteric phase transition, at 4 wt% c 10 wt%, also a faster diffusive mode is observed in the polarized DLS response and a very fast mode is detected by depolarized DLS. These modes are related to translational and rotational diffusion of the columnar stacks of guanosine molecules, which are favorably formed in the relatively narrow pretransitional region. The stacking was also revealed from the appearance of a secondary resonance line in the ³¹P NMR spectra. Using the hydrodynamic theory of Tirado and Garcia de la Torre, the length of the cylindrical stacks was found to be L = 364±78 ?, which is significantly larger than the values reported for other guanosine derivatives. Received 13 July 2001 and Received in final form 17 October 2001     

Two-color pump-probe ionization spectroscopy of gaseous water enhanced by preliminary impulsive Raman excitation

We use sub-10-fs pulses at 400 nm and 15-fs pulses at 800 nm to ionize water molecules and their isotopomers HDO and D₂O in a pump–probe scheme. Pulses are generated via spectral broadening of 25-fs pulses of a 1-kHz Ti:sapphire amplifier system by self-phase modulation in a noble-gas-filled hollow waveguide and subsequent compression using chirped mirrors. At this time scale vibronic excitation of the first bending mode of water in the electronic ground state by impulsive Raman scattering is possible (e.g. the fundamental bending mode of H₂O: t_vib=20 fs). The effect of this pre-excitation on the ionization rate is shown. Received: 14 May 2001 / Revised version: 24 August 2001 / Published online: 19 September 2001