用偏光显微术研究聚合物分散液晶压光效应膜

制备出大液晶微滴的具有压光效应的聚合物分散液晶膜,给出样品按压前后偏光显微镜对比照片.提出压缩液晶微滴模型,采用Fortran软件模拟计算了压光效应液晶微滴双折射透光率分布,用Origin软件作图,计算结果绘图与偏光显微镜图片一致.定义按压后液晶微滴圆球变扁球的扁平度,计算按压后序参数与扁平度的关系,说明按压作用使液晶...     

聚合物分散液晶光栅的衍射特性的研究

报道了一种由聚合物分散液晶膜与具有周期性条状电极结构板结合的新型光栅器件，借助于聚合物分散液晶膜的电光特性，这种栅对入射光的散射或衍射取决于对其施加的电压，即它是电场可调的，实验结果显示出当驱动电压超过器件器件阈值电压时，衍射光的强度和衍射斑的可见级次被电场调制，而且它能入射光的线性偏振态变为椭圆偏振态。     

Diffraction Properties of Field-Adjustable Polymer Network Stabilized Liquid Crystal Grating

A new diffraction grating mode has been proposed. This grating is formed by applying of a spatially periodic electric field to a polymer network stabilized uniformly aligned liquid crystal layer. Due to the electro-optic properties of the polymer network stabilized liquid crystal layer, the grating type is electrically adjustable, i.e. it presents amplitude, phase or amplitude-phase type depending on the applied voltages. Experimental results show that the number of visible diffraction orders can be adjusted easily, and even be closed at the same time. The detail fabrication process and experimental results will be presented.     

天然Alboatisin电子结构和圆二色谱的密度泛函理论研究

采用蒙特卡罗MMFF94分子力学力场方法搜索一类新发现的生物活性分子Alboatisin A～C的稳定构象,用梯度校正的B3LYP方法,计算其稳定构象的旋光度、振动圆二色谱(VCD)、电子圆二色谱(ECD)等光学活性,并从微观的角度对VCD谱和ECD谱中强或弱的正或负康登效应进行归属．从分子结构、电子结构和分子振动分析了分子手性的微观起源．结果表明,计算与实验的旋光度值相吻合,OH的取代位置与数目可调控旋光度发生在手性骨架上的振动或电子跃迁转移是手性光谱产生的重要原因．Alboatisin的圆二色谱是手性骨架变形振动的光谱响应,是不对称电子跃迁的光谱响应结果．     

Diffraction Properties of Field Adjustable Polymer Network Stabilized Liquid Crystal Grating

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Far-Field Detection of Near-Field Circular Dichroism Enhancements Induced by a Nanoantenna

Nanophotonics can enhance the inherent weak signal exhibited by chiral molecules in circular dichroism (CD) spectroscopy experiments. One mechanism to achieve this CD enhancement is based on increasing the optical chirality produced by nanophotonics antennas in their near-field, where chiral molecules are placed. However, ascertaining whether this CD enhancement is reached presents significant experimental challenges due to the complexity of measuring near-field optical chirality. Here, it is demonstrated that a local and single measurement of the degree of circular polarization in the far-field enables quantifying near-field CD enhancements. Thereby, based on this far-field measurement, the optimal response of the antenna is predicted for enhanced chiral sensing. Experimental validation of this near-to-far-field relation is provided for silicon spherical nanoantennas. The experimental results, supported by analytical theory and exact numerical simulations, can be interesting for the experimental characterization of devices capable of enhancing CD from a single far-field Stokes measurement.     

S-和R-五味子丙素非对映异构体的圆二色谱研究

园二色谱(CD)是测定有机化合物绝对构型的常用方法。文章用圆二色谱仪对合成的4个联苯类化合物进行了表征(2个非桥键联苯化合物和2个桥键联苯化合物),得到两对几乎完全对称的圆二色谱谱图。根据其圆二色谱Cotton效应确定了4个化合物的联苯键的绝对构型。化合物3分别在256 nm出现负的Cotton效应,且在220 nm出现正的Cotton效应,表明这个化合物是S-构型;而化合物3’出现了相反的Cotton效应,表明这个化合物是S-构型。由化学相关法可以得知化合物2是R-构型, 化合物2’是R-构型。通过这些数据得出结论, 以S-噁唑啉为手性合成子的Ullmann反应得到的是S-构型联苯类化合物, 而以S-噁唑啉为手性合成子的Ullmann反应得到的是R-构型型联苯类化合物。     

聚合物网络稳定液晶膜的制备与研究

实验发现在液晶中添加少量的预聚物单体,利用光聚合诱导相分离的方法可以形成反型显示模式的聚合物网络稳定液晶膜。该膜在平时呈现透明态,在电场的调节下呈散射态。本文观察了在不同光照时间、不同光强下制得样品的聚合物网络织构,分析了在聚合过程中形成网络的形状、大小与致密程度,并对实验结果进行了相关的讨论。     

Janus Device Based on Liquid Crystal Regulation with a Large Incidence Angle: Analogous Quantum Optical Effect and Absorption

In this paper, a Janus metastructure device (JMD) is proposed. The JMD design introduces asymmetric structures, which leads to the generation of analogous quantum optical effects when light is incident at large angles. Specifically, forward electromagnetic-induced transparency (EIT) and backward narrowband absorption (NA) are achieved when light is incident along different directions, displaying Janus characteristics in the forward and backward directions. Additionally, the operating frequency of JMD can be controlled through the use of liquid crystal. Such features hold promising potential for various applications in photonic and optoelectronic fields. When the axial direction of the liquid crystal is oriented along the x-direction, the JMD achieves a transparent window over 90% within 0.46–0.51 THz at forward incidence, and an absorption peak of 84.1% appears at 0.331 THz at backward incidence. When the axial direction is oriented along the y-direction, the JMD achieves EIT in the range of 0.51–0.575 THz at forward incidence, and a backward absorption peak of 93.3% occurs at 0.305 THz. In addition, the performance changes at different polarization and incidence angles are presented. The mechanism of absorption generation, the method of suppressing excess absorption, and the parametric inversion of the electromagnetic characteristics of JMD are also discussed.     

胆甾相液晶散射光的特性研究

基于胆甾相液晶的电光特性,进行了液晶散射光相干性与不同外加电场之间关系的实验研究.利用反转剪切干涉仪具体测量了不同外加电压条件下液晶散射光的空间相干性,得出了液晶散射光相干性随外加电场变化的初步规律.结果表明,胆甾相液晶散射光的强度以及空间相干性可以由外加电场调制.     

液晶表面物理——挠曲电效应研究及进展

向列液晶的“挠曲电效应”在1969年由Meyer首先提出,30年后这一理论才被重视.文章回顾了挠曲电效应的研究历程,总结了已取得的成果,并就挠曲电研究中的基础问题、研究进展、研究现状及存在的问题进行了系统的介绍,为从事此方面研究的工作者提供参考.     

Bulk and Surface Effects in X-Ray Magnetic Circular Dichroism of Iron Clusters

General trends in x-ray magnetic circular dichroism (XMCD) spectra of iron clusters of different sizes are theoretically investigated using the fully-relativistic spin-polarized multiple-scattering formalism. Purely geometrical effects of clustering and cluster-size effects are explored separately from effects of various scattering potentials and/or treatment of the surface barrier. We found that a high portion of non-bulk atoms makes the XMCD spectra of iron clusters to appear significantly different from bulk spectrum, even for quite large clusters. If the vacuum surrounding the cluster is taken into account, XMCD spectra of iron clusters change essentially (in comparison with clusters cut out of the bulk or with clusters embedded in a sea of free electrons).     

Light Diffraction of Aligned Polymer Fibers Periodically Dispersed by Phase Separation of Liquid Crystal and Polymer

We have confirmed light diffraction of aligned polymer fibers obtained by a phase separation of an anisotropic-phase solution of liquid crystal and polymer. He—Ne laser light passing through the polymer fibers was scattered in the axis vertical to the fibers, and had two peaks of light intensity symmetrical to the center of the transmitting laser spot. The two peaks were found to be caused by light diffraction due to the periodic polymer-fiber dispersion because the peaks corresponded to values calculated by intervals between the fibers. The periodical fiber networks are considered to be formed by anisotropic spinodal decomposition. This effect can be used to measure the dispersion order of the polymer fibers. © 2004 The Optical Society of Japan     

用于电响应红外反射窗的液晶聚合物薄膜特性研究

提出了一种红外反射器件,通过载体液晶在电场下的转向控制胆甾型液晶聚合物粒子在器件中的排布方向,实现红外反射与透射之间切换.其中,胆甾型液晶聚合物粒子是实现红外反射关键.介绍了胆甾型液晶聚合物薄膜的制备方法,并采用超声波破碎的方法制备液晶粒子.研究了液晶混合物中不同比例的交联剂液晶1对液晶聚合物薄膜脆性和反射波段的影响,发现当液晶1占100%时,液晶聚合物薄膜的脆性最大,且其清亮点最高,并且薄膜的反射波段随着液晶1比例的增加而向短波方向偏移.同时,研究了薄膜厚度对液晶聚合物粒子的影响,发现液晶薄膜厚度越小,制备的液晶聚合物粒子越小且越均匀,其制成的器件电驱动性更好.该研究有利于帮助电响应红外反射窗的性能优化.     

聚合物LB膜定向铁电液晶的特性

利用新近合成的聚酰亚胺ＬＢ膜定向铁电液晶分子,通过原子力显微镜对经不同亚胺化温度处理的聚酰亚胺ＬＢ膜进行扫描探测,发现相应的ＬＢ膜具有不同的形貌结构,认为高温亚胺化的ＬＢ膜可以提高较高的势垒,这为铁电液晶双稳记忆性的出现提供了可能,而ＬＢ膜的超薄特性有利于开关过程中表面聚积电荷的中和与释放,保证了器件优良的双稳记忆性的最终获得以及微秒量级快速响应的实现。     

Low voltage transflective blue-phase liquid crystal display with a non-uniform etching substrate

A transflective polymer-stabilized blue-phase liquid crystal display(BP-LCD) with a non-uniform etching substrate is proposed.In-plane switching(IPS) electrodes on the bottom substrate are put on the different gaps,and the bottom substrate between the electrodes is etched into different depths in transmissive(T) and reflective(R) regions.This structure can balance the optical phase retardation in the two regions and is helpful to achieve well-matched voltag-dependent transmittance and reflectance curves.This transflective display has high optical efficiency,a wide viewing angle,and low operating voltage(approximately 6 V).     

新型聚合物分散液晶相位光栅的制备

把具有光敏特性的预聚物与向列相液晶按一定比例混合 ,注入表面经过取向处理的液晶盒中。以紫外灯为光源 ,通过光掩膜法 ,使混合物在光场的引发下发生相分离 ,形成液晶 /聚合物相位光栅。由于相分离后液晶在取向膜的作用下沿液晶盒面方向旋转 180° ,克服了传统液晶光栅器件对入射光偏振方向的依赖 ,提高了光的有效利用率。采用光学显微镜和He Ne激光器进行测试 ,结果表明所制样品具有较好的栅结构 ,其衍射效率不受入射光偏振方向的影响且具有电场可调性。该光栅制作方法简便 ,驱动电压低 ,在光通信器件、衍射光学、投影显示、光开关等领域有广泛的应用前景     

Dynamic d-symmetry Bose condensate of a planar-large-bipolaron liquid in cuprate superconductors

Abstract

Planar-large-bipolarons can form if the ratio of the surrounding mediums’ static to high-frequency dielectric constants is especially large, ε₀/ε_∞ >> 2. A large-bipolaron in p-doped La₂CuO₄ is modelled as two electrons being removed from the out-of-plane orbitals of four oxygen ions circumscribed by four copper ions of a CuO₂ layer. These oxygen dianions relax inwardly as they donate electrons to the surrounding outwardly relaxing copper cations. This charge transfer generates the strong in-plane electron–lattice interaction needed to stabilise a large-bipolaron with respect to decomposing into polarons. The lowest-energy radial in-plane optic vibration of a large-bipolaron’s four core oxygen ions with their associated electronic charges has d-symmetry. Electronic relaxation in response to multiple large-bipolarons’ atomic vibrations lowers their frequencies to generate a phonon-mediated attraction among them which fosters their condensation into a liquid. This liquid features distinctive transport and optical properties. A large-bipolaron liquid’s superconductivity can result when it undergoes a Bose condensation yielding macroscopic occupation of its ground state. The synchronised vibrations of large-bipolarons’ core-oxygen ions with their electronic charges generate this Bose condensate’s dynamic global d-symmetry.     

Structure and Properties of Glass Fiber Reinforced Polypropylene/Liquid Crystal Polymer Blends

A liquid crystal polymer (LCP) was used to improve the physical properties of glass fiber reinforced polypropylene (GFRPP). The LCP was beneficial to improve the mechanical and heat resistant properties of the GFRPP/LCP composite. Compared with the GFRPP with 30% (w%) glass fiber (GF), the yield strength and the impact strength for the GFRPP/LCP composites increased by 62.7% and 18.1%, respectively, with a 6.8°C increase in the Vicat softening temperature for a 5% LCP addition to the GFRPP composites. The crystallinity of the polypropylene (PP) matrix for the GFRPP/LCP composites increased for 5% LCP and then decreased with increasing the LCP content. The γ-phase crystals for the PP matrix occurred in the shear layer of the injection molded GFRPP/LCP samples. The improved adhesion interface between the GF and the PP matrix was beneficial to reinforce and toughen the GFRPP/LCP composites with a small addition of the LCP.