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1.
Improved efficiencies of hybrid organic light‐emitting diodes using efficient electron injection layer
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Jayaraman Jayabharathi Pavadai Nethaji Venugopal Thanikachalam Palanivel Jeeva Ramaiyan Ramya 《Journal of Physical Organic Chemistry》2018,31(6)
Hybrid organic‐inorganic light‐emitting diodes were developed with pristine ZnO (2.0 wt%) and Cu‐doped ZnO (2.0 wt%) as electron injection layer and iridium(III)‐bis‐2‐(4‐fluorophenyl)‐1‐(naphthalen‐1‐yl)‐1H‐phenanthro[9,10‐d]imidazole (acetylacetonate) [Ir(fpnpi)2 (acac)] as green emissive layer (521 nm). The pristine ZnO and Cu‐doped ZnO are deposited at indium tin oxide cathode and emissive layer interface. The electroluminescent performances increased by electron injection layer–Cu‐doped ZnO compared with ZnO‐based device because Cu‐doped ZnO injects electron efficiently result in balanced h+ ? e? recombination in emissive layer than ZnO‐based device. The Cu‐doped ZnO (2.0 %) device shows luminance (L) of 10 982 cd/m2 at 23.0 V (ZnO, 1450 cd/m2 at 23.0 V). 相似文献
2.
Sy‐Hann Chen Cheng‐Liang Huang Bo‐Han Cheng Hao‐Jung Ku Hsin‐I Hsiao Po‐Ching Kao 《Particle & Particle Systems Characterization》2019,36(2)
Silver‐nanoicosahedron particles (AgNIPs) are produced by chemical reduction and photochemical methods and doped into the hole transport layer (HTL) or emissive layer (EML) of blue‐emitting polymer light‐emitting diodes (PLEDs) to improve their luminous efficiency. The optimal distributed‐densities of the AgNIPs are determined from current density–voltage–luminance measurements at different doping concentrations. The AgNIP dopant doses that maximize the average luminous efficiency of the proposed PLED are 6.71 µg cm?2 in EML (achieving 3.48 cd A?1) and 6.88 µg cm?2 in HTL (achieving 3.35 cd A?1). Although the luminous efficiencies of the blue‐emitting PLEDs fabricated by both doping methods are not significantly different, the maximum plasmonic enhancement (around 30‐fold) of the blue‐emitting PLED with AgNIPs in EML is red‐shifted to the green region (≈530 nm in the electroluminescence spectrum), seriously degrading the luminescent monochromaticity of the blue‐emitting PLED. The maximum plasmonic enhancement (around 33‐fold) of blue‐emitting PLED with AgNIPs in HTL occurred at 430 nm, overlapping the localized surface‐plasmon resonance extinctions of the AgNIPs in HTL (425 nm), thus favoring the enhancement of fluorescence emission. Therefore, to enhance the large‐area emission of blue‐emitting PLEDs, the AgNIPs should be doped in the HTL rather than the EML. 相似文献
3.
Zhifei Wang Shuang Zheng Neng Wan Liming Zhang Qilong Wang Nongyue He Yaji Huang 《Particle & Particle Systems Characterization》2013,30(10):905-910
The preparation of Au‐on‐Pd heteronanostructure (HNS) using citrate‐stabilized polycrystalline Pd nanoparticles (NPs) as the seeds is described. The resulting Au‐on‐Pd HNS is characterized and it is found that the formation of Au‐on‐Pd HNS depends greatly on a ratio between Pd seeds and AuCl4? ions added and the optimal molar ratio is 10:1. If fewer AuCl4? ions are added (Pd/Au ratio is 100:1), the growth of Au NPs only occurs on part of the Pd seeds’ surface. The addition of more AuCl4? ions (Pd/Au ratio is 5:1) hinders the growth of Au NPs on the Pd seeds’ surface. To demonstrate the catalytic performance, the electrochemistry oxidation of ethanol and the reduction of p‐nitrophenol by NaBH4 are chosen to examine the catalytic activity of Au‐on‐Pd HNS. Pd seeds, Au NPs, and poly(vinyl pyrrolidone) (PVP)‐stabilized PdAu nanoalloy are used as the references for comparison. In the first reaction, the catalytic reactivity of Au‐on‐Pd HNS is better than that of corresponding pure Pd or Au NPs, while the opposite occurs for the latter reaction. The catalytic activity of Au‐on‐Pd HNS is much higher than that of PVP‐stabilized PdAu nanoalloy. 相似文献
4.
Nondoped blue fluorescent OLED based on cyanophenanthrimidazole‐styryl‐triphenylamine/carbazole materials
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Thanikachalam Venugopal Jeeva Palanivel Jayabharathi Jayaraman 《Journal of Physical Organic Chemistry》2017,30(12)
New 2‐(4′‐9H‐carbazole‐9‐yl)‐styryl‐1H‐phenathro[9,10‐d]imidazole‐1‐yl)benzonitrile (SPICN‐Cz) and 4‐(2‐(4‐(diphenylamino)phenyl‐styryl‐1H‐phenathro[9,10‐d]imidazole‐1‐yl)benzonitrile (SPICN‐TPA) have been synthesised, and their photophysical, electrochemical, and electroluminescent properties were analysed in comparison with their cyano‐free parent compounds, SPI‐Cz, and SPI‐TPA. Solvatochromic effects show the transformation of an excited state character from locally excited (LE) state to charge transfer (CT) state. Using time‐dependent density functional theory calculation, the excited state properties of these donor‐acceptor blue emissive materials have been analysed. Their excited state properties have been tuned by replacing the strong donor triphenylamine to weak donor carbazole to achieve the combination of high photoluminance efficiency locally excited (LE) component and high exciton‐utilizing CT component in one excited state. Hybridization processes between LE and CT components of SPICN‐Cz and SPICN‐TPA in the emissive state have been discussed. The nondoped organic light emitting diode device based on SPICN‐Cz exhibit better electroluminescent performances than those of SPICN‐TPA–based device: high external quantum efficiency of 2.58 %, current efficiency of 2.90 cd A‐1, and power efficiency of 2.26 lm W‐1 with Commission Internationale de l'Éclairage (CIE) coordinates of (0.15, 0.12). The excited state modulation and the composition of LE and CT states in the donor‐acceptor system could be useful to design low‐cost, high‐efficiency fluorescent organic light emitting diode materials. 相似文献
5.
Fabrication of NIR‐Excitable SERS‐Active Composite Particles Composed of Densely Packed Au Nanoparticles on Polymer Microparticles
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Masaaki Kanahara Hiroki Satoh Takeshi Higuchi Atsushi Takahara Hiroshi Jinnai Koji Harano Satoshi Okada Eiichi Nakamura Yasutaka Matsuo Hiroshi Yabu 《Particle & Particle Systems Characterization》2015,32(4):441-447
A simple fabrication method is demonstrated for surface‐enhanced Raman scattering (SERS)‐active plasmonic nanoballs, which consisted of Au nanoparticles (NPs) and core–shell polystyrene and amino‐terminated poly(butadiene) particles, by heterocoagulation and Au NP diffusion. The amount of Au NPs introduced into the core–shell particles increases with the concentration of Au NPs added to the aqueous dispersion of the core–shell particles. When the amount of Au NPs increases, closely packed, three‐dimensionally arranged and close‐packed Au NPs arrays are formed in the shells. Strong SERS signals from para‐mercaptophenol adsorbed onto composite particles with multilayered Au NPs arrays are obtained by near‐infrared (NIR) light illumination. 相似文献
6.
The electroluminescence (EL) characteristics of phosphorescent organic light-emitting diodes (OLEDs) with an undoped bis(1,2-dipheny1-1H-benzoimidazole) iridium (acetylacetonate) [(pbi)2Ir(acac)] emissive layer (EML) of various film thicknesses were studied. The results showed that the intensity of green light emission decreased rapidly with the increasing thickness of (pbi)2Ir(acac), which was relevant to the triplet excimer emission. It suggested that the concentration quenching of monomer emission in the undoped (pbi)2Ir(acac) film was mainly due to the formation of triplet excimer and partly due to the triplet-triplet annihilation (TTA) and triplet-polaron annihilation (TPA). A green OLED with a maximum luminance of 26,531 cd/m2, a current efficiency of 36.2 cd/A, and a power efficiency of 32.4 lm/W was obtained, when the triplet excimer emission was eliminated. Moreover, the white OLED with low efficiency roll-off was realized due to the broadened recombination zone and reduced quenching effects in the EML when no electron blocking layer was employed. 相似文献
7.
Dual plasmonic‐enhanced bulk‐heterojunction solar cell incorporating gold nanoparticles into solution‐processed anode buffer layer and active layer
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Li Zhou Jinya Yang Ye Zhou Su‐Ting Han Longbiao Huang Yan Yan V. A. L. Roy 《固体物理学:研究快报》2015,9(2):115-119
A dual plasmonic resonance effect on the performance of poly(3‐hexylthiophene) (P3HT):phenyl C61‐butyricacid methyl ester (PC61BM) based polymer solar cells (PSCs) has been demonstrated by selectively incorporating 25 nm colloidal gold nanoparticles (Au NPs) in a solution‐processed molybdenum oxide (MoO3) anode buffer layer and 5 nm colloidal Au NPs in the active P3HT:PCBM layer. The devices exhibit up to ~20% improvement in power conversion efficiency which is attributed to the dual effect of localized surface plasmon resonance (LSPR) of Au NPs with enhanced light absorption and exciton generation. Our report shows a guideline on the usage of dual LSPR effect for the solution‐processed polymer solar cells to achieve high efficiencies. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
8.
Weidong Ruan Yinqiu Cui Feng Lin Tieli Zhou Ge Hui Ye Wang Yufeng Chen Fei Lu Jie Guo Bing Zhao 《Journal of Raman spectroscopy : JRS》2015,46(11):1117-1123
The Ag–Au compound nanostructure films with controllable patterns of Ag nanoparticle (NP) aggregates were fabricated. A strategy of two‐step synthesis was employed toward the target products. Firstly, the precursor Au NP (17 nm) films were synthesized as templates. Secondly, the Ag NPs (45 nm) were deposited on the precursor films. Three types of Ag NP aggregates were obtained including discrete Ag NPs (discrete type), necklace‐like Ag NP aggregates (necklace type), and huddle‐like Ag NP aggregates (huddle type). The surface‐enhanced Raman scattering (SERS) property was studied on these nanostructures by using the probing molecule of rhodamine 6G under the excitation laser of 514.5 nm. Interestingly, the different types of samples showed different enhancement abilities. A statistical method was employed to assess the enhancement. The relative enhancement factor for each Ag NP was estimated quantitatively under the ratio of 1 : 25 : 18 for the discrete‐type, necklace‐type, and huddle‐type samples at the given concentration of 10−8 mol/l. This research shows that the enhancement ability of each Ag NP is dependent on the aggregate morphology. Moreover, the different enhancement abilities displayed different limit detection concentrations up to 10−8, 10−11, and 10−9 mol/l, separately. The understanding of the relationship between the defined nanostructures and the SERS enhancement is very meaningful for the design of new SERS substrates with better performance. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
9.
Facile Synthesis of Gd(OH)3‐Doped Fe3O4 Nanoparticles for Dual‐Mode T1‐ and T2‐Weighted Magnetic Resonance Imaging Applications
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Hongdong Cai Xiao An Shihui Wen Jingchao Li Guixiang Zhang Xiangyang Shi Mingwu Shen 《Particle & Particle Systems Characterization》2015,32(10):934-943
The facile hydrothermal synthesis of polyethyleneimine (PEI)‐coated iron oxide (Fe3O4) nanoparticles (NPs) doped with Gd(OH)3 (Fe3O4‐Gd(OH)3‐PEI NPs) for dual mode T1‐ and T2‐weighted magnetic resonance (MR) imaging applications is reported. In this approach, Fe3O4‐Gd(OH)3‐PEI NPs are synthesized via a hydrothermal method in the presence of branched PEI and Gd(III) ions. The PEI coating onto the particle surfaces enables further modification of poly(ethylene glycol) (PEG) in order to render the particles with good water dispersibility and improved biocompatibility. The formed Fe3O4‐Gd(OH)3‐PEI‐PEG NPs have a Gd/Fe molar ratio of 0.25:1 and a mean particle size of 14.4 nm and display a relatively high r2 (151.37 × 10?3m ?1 s?1) and r1 (5.63 × 10?3m ?1 s?1) relaxivity, affording their uses as a unique contrast agent for T1‐ and T2‐weighted MR imaging of rat livers after mesenteric vein injection of the particles and the mouse liver after intravenous injection of the particles, respectively. The developed Fe3O4‐Gd(OH)3‐PEI‐PEG NPs may hold great promise to be used as a contrast agent for dual mode T1‐ and T2‐weighted self‐confirmation MR imaging of different biological systems. 相似文献
10.
High–Yield Production of Uniform Gold Nanoparticles with Sizes from 31 to 577 nm via One‐Pot Seeded Growth and Size‐Dependent SERS Property
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Peina Zhang Yijing Li Dayang Wang Haibing Xia 《Particle & Particle Systems Characterization》2016,33(12):924-932
In this work, uniform, quasi‐spherical gold nanoparticles (Au NPs) with sizes of 31–577 nm are prepared via one‐pot seeded growth with the aid of tris‐base (TB). Distinct from the seeded growth methods available in literature, the present method can be simply implemented by subsequently adding the aqueous dispersion of the 17 nm Au‐NP seeds and the aqueous solution of HAuCl4 into the boiling aqueous TB solution. It is found that at the optimal pH range, the sizes of the final Au NPs and their concentrations are simply controlled by either the particle number of the Au seed dispersion or the concentration of the HAuCl4 solution, while the latter enables us to produce large Au NPs at very high concentration. Moreover, as‐prepared Au NPs of various sizes are coated on glass substrates to test their surface‐enhanced Raman scattering (SERS) activities by using 4‐aminothiophenol (4‐ATP) molecules as probes, which exhibit “volcano type” dependence on the Au NP sizes at fixed excitation wavelength. Furthermore, the Au NPs with sizes of ≈97 and 408 nm exhibit the largest SERS enhancement at the excitation wavelength of 633 and 785 nm, respectively. 相似文献
11.
Measurement and interpretation of the excitation wavelength dependence of surface‐enhanced Raman scattering (SERS) spectra of molecules chemisorbed on plasmonic, e.g. Ag nanoparticle (NP) surfaces, are of principal importance for revealing the charge transfer (CT) mechanism contribution to the overall SERS enhancement. SERS spectra, their excitation wavelength dependence in the 445–780‐nm range and factor analysis (FA) were used for the identification of two Ag‐2,2′:6′,2″‐terpyridine (tpy) surface species, denoted Ag+–tpy and Ag(0)–tpy, on Ag NPs in systems with unmodified and/or purposefully modified Ag NPs originating from hydroxylamine hydrochloride‐reduced hydrosols. Ag+–tpy is a spectral analogue of [Ag(tpy)]+ complex cation, and its SERS shows virtually no excitation wavelength dependence. By contrast, SERS of Ag(0)–tpy surface complex generated upon chloride‐induced compact aggregate formation and/or in strongly reducing ambient shows a pronounced excitation wavelength dependence attributed to a CT resonance (the chemical mechanism) contribution to the overall SERS enhancement. Both the resonance (λexc = 532 nm) and off‐resonance (λexc = 780 nm) pure‐component spectra of Ag(0)–tpy obtained by FA are largely similar to surface‐enhanced resonance Raman scattering (λexc = 532 nm in resonance with singlet metal to ligand CT (1 MLCT) transition) and SERS (λexc = 780 nm) spectra of [Fe(tpy)2]2+ complex dication. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
12.
Efficient white electroluminescence has been obtained by using an electroluminescent layer comprising of a blue fluorescent bis (2-(2-hydroxyphenyl) benzoxazolate)zinc [Zn(hpb)2] doped with red phosphorescent bis (2-(2′-benzothienyl) pyridinato-N,C3′)iridium(acetylacetonate) [Ir(btp)2acac] molecules. The color coordinates of the white emission spectrum was controlled by optimizing the concentration of red dopant in the blue fluorescent emissive layer. Organic light-emitting diodes were fabricated in the configuration ITO/α-NPD/Zn(hpb)2:0.01 wt%Ir(btp)2acac/BCP/Alq3/LiF/Al. The J-V-L characteristic of the device shows a turn on voltage of 5 V. The electroluminescence (EL) spectra of the device cover a wide range of visible region of the electromagnetic spectrum with three peaks around 450, 485 and 610 nm. A maximum white luminance of 3500 cd/m2 with CIE coordinates of (x, y=0.34, 0.27) at 15 V has been achieved. The maximum current efficiency and power efficiency of the device was 5.2 cd/A and 1.43 lm/W respectively at 11.5 V. 相似文献
13.
Tanya Hutter Sumeet Mahajan Stephen R. Elliott 《Journal of Raman spectroscopy : JRS》2013,44(9):1292-1298
There is a growing interest in using quantum dots (QDs) and metallic nanoparticles (NPs), both for luminescence enhancement and surface‐enhanced Raman scattering (SERS). Here, we study the electromagnetic‐field enhancement that can be generated by lead‐sulfide (PbS) QDs using three‐dimensional finite‐element simulations. We investigate the field enhancement associated with combinations of PbS QDs with metallic NPs and substrates. The results show that high field enhancement can be achieved by combining PbS QDs with metallic NPs of larger sizes. The ideal size for Ag NPs is 25 nm, providing a SERS enhancement factor of ~5*108 for light polarization parallel to the NP dimer axis and a gap of 0.6 nm. For Au NPs, the bigger the size, the higher is the field for the studied diameters, up to 50 nm. The near‐field values for PbS QDs above metallic substrates were found to be lower compared to the case of PbS QD‐metal NP dimers. This study provides the understanding for the design and application of QDs for the enhancement of near‐field phenomena. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
14.
Richard S. Agnes Mark D. Schluchter Seunghee Margevicius Xinning Wang Malcolm E. Kenney Clemens Burda James P. Basilion 《Particle & Particle Systems Characterization》2015,32(4):448-457
Targeted drug delivery using epidermal growth factor peptide‐targeted gold nanoparticles (EGFpep‐Au NPs) is investigated as a novel approach for delivery of photodynamic therapy (PDT) agents, specifically Pc 4, to cancer. In vitro studies of PDT show that EGFpep‐Au NP‐Pc 4 is twofold better at killing tumor cells than free Pc 4 after increasing localization in early endosomes. In vivo studies show that targeting with EGFpep‐Au NP‐Pc 4 improves accumulation of fluorescence of Pc 4 in subcutaneous tumors by greater than threefold compared with untargeted Au NPs. Targeted drug delivery and treatment success can be imaged via the intrinsic fluorescence of the PDT drug Pc 4. Using Pc 4 fluorescence, it is demonstrated in vivo that EGFpep‐Au NP‐Pc 4 impacts biodistribution of the NPs by decreasing the initial uptake by the reticuloendothelial system (RES) and by increasing the amount of Au NPs circulating in the blood 4 h after IV injection. Interestingly, in vivo PDT with EGFpep‐Au NP‐Pc 4 results in interrupted tumor growth when compared with EGFpep‐Au NP control mice when selectively activated with light. These data demonstrate that EGFpep‐Au NP‐Pc 4 utilizes cancer‐specific biomarkers to improve drug delivery and therapeutic efficacy over untargeted drug delivery. 相似文献
15.
Luca Guerrini Jos V. Garcia‐Ramos Concepcin Domingo Santiago Sanchez‐Cortes 《Journal of Raman spectroscopy : JRS》2010,41(5):508-515
Surface‐enhanced Raman scattering (SERS) is an extremely powerful tool for the analysis of the composition of bimetallic nanoparticle (BNP) surfaces because of the different adsorption schemes adopted by several molecules on different metals, such as Au and Ag. The preparation of BNPs normally implies a change in the plasmonic properties of the core metal. However, for technological applications it could be interesting to synthesize core–shell structures preserving these original plasmonic properties. In this work, we present a facile method for coating colloidal gold nanoparticles (NPs) in solution with a very thin shell of silver. The resulting bimetallic Au@Ag system maintains the optical properties of gold but shows the chemical surface affinity of silver. The effectiveness of the coating method, as well as the progressive silver enrichment of the outermost part of the Au NPs, has been monitored through the SERS spectra of several species (chloride, luteolin, thiophenol and lucigenin), which show different behaviors on gold and silver surfaces. A growth mechanism of the Ag shell is proposed on the basis of the spectroscopic and microscopic data consisting in the formation and deposit of Ag clusters on the Au NP surface. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
16.
《Current Applied Physics》2007,7(4):380-383
Several iridium-based complexes were investigated as phosphorescent dopants. They achieved about 100% internal quantum efficiency, due to utilization of both singlet and triplet excitons in the radiative processes. We have fabricated phosphorescent OLEDs with 8% Ir(ppz)3 as a triplet emissive dopant in various host materials. CBP, which has an efficiency of 0.20 cd/A, is the best host material. Furthermore, we synthesized metal-organic phosphor complexes based on Ir with different ligands as to (Im)2Ir(acac), (Im-R)2Ir(acac), and Ir(ppz)2(acac). 相似文献
17.
Xiang‐Dong Tian Bi‐Ju Liu Jian‐Feng Li Zhi‐Lin Yang Bin Ren Zhong‐Qun Tian 《Journal of Raman spectroscopy : JRS》2013,44(7):994-998
Shell‐isolated nanoparticles (NPs)‐enhanced Raman spectroscopy (SHINERS) can be potentially applied to virtually any substrate type and morphology. How to take a step forward to prepare SHINERS NPs (SHINs) with superior performance is critical for the practical applications of surface‐enhanced Raman scattering (SERS) in the breadth and depth. Here, we present a method to obtain 120 nm diameter gold NPs coated with ultrathin silica shells (1–4 nm). The silica shell can be controlled growth through carefully tuning a series of parameters, such as amount of 3‐aminopropyl triethoxysilane used, pH, reaction time, and reaction temperature. We compare the enhancement factor of the obtained 120 nm Au with a 4 nm silica shell NPs to the 55 nm Au with a 4 nm silica shell NPs, and the activity of a 120 nm SHINs is nearly 24 times that the 55 nm SHIN from a single particle view. We also compare the enhancement factor of 1 nm silica shell Au@SiO2 NPs with the bare Au NPs. The enhancement factor of 1 nm silica shell Au@SiO2 NPs was found to be about twice that of the bare particles. For a deeper understanding of the source of the giant enhanced electrical field of the 1 nm silica shell Au@SiO2 NPs, we study the plasmonic property of single 1 nm silica shell Au@SiO2 NP on a gold film substrate through correlation of the structure of single NP using SEM with its SPR spectroscopy. We find that the multipolar interaction between the single Au@SiO2 NP and gold film substrate is important for the SERS. Our studies on the performance of 120 nm SHINs and the plasmonic property of these particles can significantly expand the applications of SHINERS technique and improve the understanding of physical nature of SHINs. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
18.
Comparing the Contribution of Visible‐Light Irradiation,Gold Nanoparticles,and Titania Supports in Photocatalytic Nitroaromatic Coupling and Aromatic Alcohol Oxidation
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Jian Zhao Xuebin Ke Hongwei Liu Yiming Huang Chao Chen Arixin Bo Xianliang Sheng Huaiyong Zhu 《Particle & Particle Systems Characterization》2016,33(9):628-634
Under visible‐light irradiation, gold nanoparticles (Au NPs) supported by titania (TiO2) nanofibers show excellent activity and high selectivity for both reductive coupling of nitroaromatics to corresponding azobenzene or azoxylbenzene and selective oxidation of aromatic alcohols to corresponding aldehydes. The Au NPs act as active centers mainly due to their localized surface plasmon resonance (LSPR) effect. They can effectively couple the photonic energy and thermal energy to enhance reaction efficiency. Visible‐light irradiation has more influence on the reduction than on the oxidation, lowering the activation energy by 24.7 kJ mol?1 and increasing the conversion rate by 88% for the reductive coupling, compared to merely 8.7 kJ mol?1 and 46% for the oxidation. Furthermore, it is found that the conversion of nitroaromatics significantly depends on the particle size and specific surface area of supported Au NPs; and the catalyst on TiO2(B) support outperforms that on anatase phase with preferable ability to activate oxygen. In contrast, for the selective oxidation, the effect of surface area is less prominent and Au NPs on anatase exhibit higher photo‐catalytic activity than other TiO2 phases. The catalysts can be recovered efficiently because the Au NPs stably attach to TiO2 supports by forming a well‐matched coherent interface observed via high‐resolution TEM. 相似文献
19.
通过对一种新型贵金属铱的配合物磷光材料(pbi)2Ir(acac)与咔唑共聚物进行物理掺杂, 制备了结构为indium-tin oxide(ITO)/poly(N-vinylcarbazole)(PVK): (pbi)2Ir(acac)(x)/2,9-dimethyl-4,7-diphenyl-1,10-phenan throline(BCP)(20nm)/8-Hydroxyquinoline aluminum(Alq3)(10nm)/Mg:Ag的聚合物电致磷光器件,研究了磷光聚合物掺杂体系在低掺杂浓度时(0.1%和0.5%(质量百分数,全文同))的光致发光(PL)和电致发光(EL)特性. 结果表明, 该掺杂体系的PL光谱和EL光谱中均同时存在主体材料PVK与磷光客体(pbi)2Ir(acac)的发光光谱, 但主客体的发射强度不同,推测该掺杂体系在电致发光条件下, 同时存在主体材料到客体的不完全的能量传递和载流子直接俘获过程. 磷光掺杂浓度为0.1%的器件在19V电压下实现了白光发射, 色坐标为(0.32, 0.38), 掺杂浓度为0.5%的器件在20.6V电压下的最大发光亮度为11827 cd·m-2, 而在13.4V电压下的最大流明效率为4.13 cd·A-1.
关键词:
有机电致发光器件
铱配合物磷光
聚合物掺杂 相似文献
20.
Physical processes involved in laser ablation in liquid (LAL) are studied using a gold target irradiated through transparent water. During and after irradiation, the heated material from the surface of a target produces a plume that expands into liquid‐forming nanoparticles (NPs). The LAL method of NP production is ecologically much cleaner than others. A better understanding of the processes associated with complicated hydrodynamic phenomena leading to LAL is important for controlled manufacturing. We consider laser pulses with different durations τL covering fifth orders of magnitudes ranging from 0.1 ps to 0.5 ns and large absorbed fluences Fabs near optical breakdown of liquid. It is shown that the trajectory of the contact boundary with liquid at the middle and late stages after passing the maximum intensity of the longest pulse is rather similar for very different pulse durations if energies Fabs are comparable. We trace how hot (in a few eV range) dense gold plasma expands, cools down, intersects a saturation curve, and condenses into NPs appearing first inside the water‐gold diffusively mixed intermediate layer where gold vapour has the lowest temperature. Later, the pressure around the gold‐water contact drops down below the critical pressure for water. As a result, the nanoparticles find themselves in gaseous water bubble where density of water gradually decreases to 10?4 ? 10?5 g/cm3 at maximum bubble expansion. 相似文献