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1.
邻香兰素对甲苯胺Schiff碱稀土配合物的制备和表征 总被引:4,自引:0,他引:4
前文曾报道了香兰素(3-甲氧基-4-羟基苯甲醛)与对甲基苯胺的Schiff碱稀土配合物。本文讨论邻香兰素(2-羟基-3-甲氧基苯甲醛)与对甲基苯胺的Schiff碱稀土配合物[LnL_2Cl·2H_2O]Cl_2(Ln:ce,Pr,Nd,Sm,Eu,Gd,Dy;L:Schiff碱)的制备和表征。 1 实验 1.1 配合物的制备 按文献方法,用等摩尔比的邻香兰素与对甲基苯胺在无水乙醇中先制成Schiff碱,然后按摩尔比1:2将稀土氯化物LnCl_3·nH_2O的无水乙醇溶液滴加到 相似文献
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Elena Labisbal Laura Rodríguez Araceli Vizoso Mnica Alonso Jaime Romero Jos‐Arturo García‐Vzquez Antonio Sousa‐Pedrares Antonio Sousa 《无机化学与普通化学杂志》2005,631(11):2107-2114
Tin(IV) complexes of the series of dianionic terdentate Schiff bases N‐[(2‐pyrroyl)methylidene]‐N′‐tosylbenzene‐1,2‐diamine, (H2L1), N‐[(2‐hydroxyphenyl)methylidene]‐N′‐tosylbenzene‐1,2‐diamine (H2L2) and some R substituted 2‐{[(2‐hydroxyphenyl)imino]methyl}phenols [R = H (H2L3), 4,6‐(OCH3)2 (H2L4), 3‐(OC2H5) (H2L5) and 3,5‐Br2 (H2L6)] have been synthesized. The compounds were obtained by the electrochemical oxidation of a tin anode in a cell containing an acetonitrile solution of the corresponding ligand. The complex [SnL12] was also obtained by reaction of SnCl2·2H2O and H2L1 in methanol in the presence of triethylamine. The crystal structure of the ligand [H2L6] and the complexes [SnL12] (1) , [SnL22] (2) , [SnL32] (3) and [SnL62] (6) were determined by X‐ray diffraction. In the complexes, the tin atom is in an octahedral environment coordinated by two dianionic terdentate ligands. Spectroscopic data for the complexes (IR, 1H and 119Sn NMR and mass spectra) are discussed and related to structural information. 相似文献
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The oxovanadium(IV) complexes of the Schiff base hydrazones, synthesized from 3‐hydrazinoquinoxaline‐2‐one (HQO) with salicylaldehyde (HSHQO), o‐hydroxyacetophenone (HHAHQO), dehydroacetic acid (HDHAHQO) and o‐nitrobenzaldehyde (NBHQO) were synthesized and characterized on the basis of analytical, conductance, magnetic moment, infrared, NMR, ESR and electronic spectral data. The ligands HSHQO, HDHAHQO behaved as monobasic tridentate ONN donors through phenolic oxygen, azomethine nitrogens. The ligand HAHQO acted as a monobasic bidentate ON donor through the phenolic oxygen, azomethine (free) nitrogen and the ligand NBHQO acted as neutral bidentate ON donor through oxygen of the nitro group and azomethine (free) nitrogen. 相似文献
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合成了一个新的L-酪氨酸萘酚醛希夫碱及邻菲咯啉混配氧钒配合物[VO(Naph-L-Tyr)(Phen)]•CH3OH (Naph-L-Tyr=2-羟基-1-萘甲醛与L-酪氨酸形成的希夫碱, Phen=1,10-邻菲咯啉). 利用元素分析、红外光谱和X射线单晶衍射进行了表征. 晶体结构测定表明, 该晶体属于三斜晶系, P-1空间群, 其晶体学数据: a=1.00023(11) nm, b=1.13478(12) nm, c=1.34076(15) nm, a=108.118(2)o, b=96.3920(10)o, g=92.4010(10)o, V=1.4326(3) nm3, Z=2, Dc=1.420 g/cm3, F(000)=634, 最终的偏差因子为R1=0.0670, wR2=0.1324 [I>2s (I)]. 以钒原子为中心形成了六配位变形的八面体构型, 晶体中相邻分子之间通过氢键和π-π相互作用形成一维链状结构. 利用紫外吸收光谱、荧光光谱、圆二色光谱和粘度测量等研究了配合物与小牛胸腺DNA (CT-DNA)的作用, 结果表明配合物以插入方式与CT-DNA作用. 琼脂糖凝胶电泳法研究表明, 配合物对质粒pBR322 DNA分子具有切割作用. 相似文献
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Nandu Bala Sharma Anirudh Singh Ram C. Mehrotra† 《Phosphorus, sulfur, and silicon and the related elements》2013,188(7):1527-1539
The interaction of Bu2Sn(OPri)2 with a trifunctional tetradentate Schiff base (LH3) (where H3L = HOC6H4CH═NCH3C(CH2OH)2) yields the precursor complex Bu2Sn(LH) 1, which, on equimolar reactions with different metal alkoxides [Al(OPri)3, Bu3Sn(OPri), Ge(OEt)4]; Al(Medea)(OPri) (where Medea = CH3N- (CH2CH2O)2); and Me3SiCl in the presence of Et3N], affords, respectively, the complexes Bu2Sn(L)Al(OPri)2 2, Bu2Sn(L)Al(Medea) 3, Bu2Sn(L)Bu3Sn 4, Bu2Sn(L)Ge(OEt)3 5, and Bu2Sn(L)SiMe3 6. The reactions of 2 with 2,5-dimethyl-2,5-hexanediol in a 1:1 ratio and with acetylacetone (acacH) in a 1:2 molar ratio afforded derivatives Bu2Sn(L)Al(OC(CH3)2CH2CH2C(CH3)2 O) 7 and Bu2Sn(L)Al(acac)2 8, respectively. All of the derivatives 1– 8 have been characterized by elemental analyses, molecular weight measurements, and spectroscopic [IR and NMR (1H, 119Sn, 29Si, and 27Al)] studies. 相似文献
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1 INTRODUCTION The insulin-mimetic property of vanadium complexes is the most noteworthy finding and the relationship between vanadium and diabetes mellitus has been extensively studied in the past decades[1~5]. Vanadium complexes are capable of increa… 相似文献
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M. I. Fernndez García M. Fondo A. M. García Deibe M. B. Fernndez Fernndez A. M. Gonzlez 《无机化学与普通化学杂志》2000,626(9):1985-1991
New copper(II) complexes of asymmetrical tetradentate Schiff bases containing pyrazine have been prepared and thoroughly characterised by elemental analysis, IR and electronic spectroscopy, mass spectrometry and magnetic measurements. Two alternative methods were used in the isolation of the complexes: template synthesis in the preparation of Cu(SalDpyz)ClO4 (HSalDPyz = derived from the condensation of salicylaldehyde, acetylpyrazine and 1,2‐ethylendiamine, 2‐methyl‐1,2‐propylendiamine, 1,2‐phenylendiamine) and direct interaction between copper perchlorate and the corresponding Schiff base, as in the isolation of Cu(AEPyz)(ClO4) (HAEPyz = (Z)‐4‐[2‐{[2‐{[(E)‐1‐(pyrazinyl)ethylidene]amino} ethyl)amino]‐3‐penten‐2‐one)]. [Cu(SalEn)(py)(OClO3)][Cu(SalEn)(py)]ClO4 ( 1 ) (SalEn = 4‐(2‐hydroxyphenyl)‐3‐aza‐3‐buten‐1‐amino, py = pyridine), metal precursor in the preparation of Cu(SalEnpyz)(ClO4) (HSalEnpyz = 2‐{E(2‐{[(E)‐1‐(2‐pyrazinyl)ethylidene]amino}ethyl)imino]methyl}phenol), was crystallographically characterised. The crystal structure of [Cu(AEpyz)]ClO4 ( 2 ) is also reported. 相似文献
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基于TiO2光催化性能的染料敏化改性,采用2-噻吩甲醛缩合乙二胺合成了席夫碱配体L,并与金属配合得到了金属配合物[ZnLCl2](1),[NiL'(NO3)2](2)(L'为单噻吩醛缩乙二胺),对配体L、配合物1 和2进行了X射线单晶衍射结构分析。 用合成的配体和配合物修饰TiO2得到相应的复合光催化剂L-TiO2、1-TiO2和2-TiO2,并进行了红外光谱、紫外-可见漫反射光谱、粉末X射线衍射图谱等表征,研究了这3种光催化剂降解水中有机污染物4-硝基酚(4-NP)和罗丹明B(RhB)的催化活性。 结果表明,1-TiO2、2-TiO2可以有效的降解4-NP和RhB,降解率可达90%以上。 相似文献
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混合二烃基二氯化锡与水杨醛缩苯胺类Schiff碱配合物的合成和表征 总被引:1,自引:0,他引:1
由混合二烃基二氯化锡与水杨醛缩苯胺类Schiff碱反应,合成了24种新的有机锡配合物。经元素分析、NMR、TG-DSC测定和X射线粉末衍射分析,确定有14种是有机锡与Schiff碱的1:1配合物,10种是1:2配合物。配体是以酚羟基氧原子与锡原子配位,摩尔电导率测定表明这些配合物均为非电解质。 相似文献
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Dr. Angelo Frei Dr. A. Paden King Gabrielle J. Lowe Dr. Amy K. Cain Dr. Francesca L. Short Hue Dinh Dr. Alysha G. Elliott Dr. Johannes Zuegg Prof. Justin J. Wilson Assoc. Prof. Mark A. T. Blaskovich 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(6):2021-2029
Resistance to currently available antifungal drugs has quietly been on the rise but overshadowed by the alarming spread of antibacterial resistance. There is a striking lack of attention to the threat of drug-resistant fungal infections, with only a handful of new drugs currently in development. Given that metal complexes have proven to be useful new chemotypes in the fight against diseases such as cancer, malaria, and bacterial infections, it is reasonable to explore their possible utility in treating fungal infections. Herein we report a series of cobalt(III) Schiff base complexes with broad-spectrum antifungal activity. Some of these complexes show minimum inhibitory concentrations (MIC) in the low micro- to nanomolar range against a series of Candida and Cryptococcus yeasts. Additionally, we demonstrate that these compounds show no cytotoxicity against both bacterial and human cells. Finally, we report the first in vivo toxicity data on these compounds in Galleria mellonella, showing that doses as high as 266 mg kg−1 are tolerated without adverse effects, paving the way for further in vivo studies of these complexes. 相似文献
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Qingdao Zeng Shaohua Gou Jianglin Zhu Junjie Zhu Xiaozeng You 《Journal of inclusion phenomena and macrocyclic chemistry》1999,35(1-2):299-309
A series of pendant-arm Schiff base macrocycles have been obtained via the cyclocondensation reaction between sodium 2,6-diformyl-4-substitutedphenolates and tris-(2-aminoethyl)- amine derivatives followed by transmetallation with Cu(ClO4)2·6H2O. The resulting dinuclear copper(II) complexes have been characterized by elemental analysis, infrared and mass spectra as well as magnetic moments at room temperature. All complexes have been electrochemically investigated, and two typical compounds have been studied with ESR spectra as well. 相似文献
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3-醛基水杨酸-1,3-丙二胺Schiff碱过渡金属异双核配合物的合成及表征 总被引:7,自引:0,他引:7
3-醛基水杨酸与二胺类形成的Schiff碱是有效的双核配体,其配合物的合成和表征已有一些报道,但二胺为1,3-丙二胺的Schiff碱与过渡金属形成的异双核配合物的研究至今未见报道。我们用二(3-羧基水杨醛叉)缩丙撑二胺与过渡金属合成了一些异双核配合物,并用元素分析、IR、UV-Vis,室温磁矩及氧化还原半波电位对配合物的组成和结构进行了表征。 相似文献
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新型双核席夫碱配合物的合成及谱学性质 总被引:1,自引:0,他引:1
Eight novel binuclear tetradentate Schiff base complexes (M=Cu(Ⅱ),Ni(Ⅱ),Zn(Ⅱ)) are synthesized. The structure of complexes is two discrete Schiff base unit bridged. The complexes were condensed from series sub-stituent Ketones (5-chloro-2-hydroxybenzophenone, 5-methyl-2-hydroxy-benzophenone, 5-Bromo-2-hydroxybenzop- henone) and dialdehydes (5,5′-methylene-disalicylaldehyde) with the amino group of 1,2-diaminobenzene, and by Metal ion as template. The compounds were characterized by elemental analyses, FT-infrared spectra, Raman, 1H NMR, UV-vis electronic spectra, EPR spectra. The FT-infrared spectra and Raman spectra of complexes were compared and discussed. The UV-vis election spectra, 1H NMR and EPR spectra of complexes have also been attributed and minutely analyzed. 相似文献
17.
Y. Sindhu C. J. Athira M. S. Sujamol K. Mohanan 《Phosphorus, sulfur, and silicon and the related elements》2013,188(9):1955-1963
Oxovanadium(IV) complexes of Schiff bases, derived from 2-amino-4-phenyl thiazole/substituted 2-amino-4-phenyl thiazoles and thiophene-2-aldehyde have been synthesized and characterized on the basis of elemental analysis, molar conductance measurements, magnetic susceptibility data, and UV-visible, and IR spectral studies. All the complexes are monomeric possessing a 1:2 (metal:ligand) stoichiometry. On the basis of these data, a square pyramidal geometry has been assigned for the complexes. A few complexes have been subjected to thermal decomposition studies. The ligands and their metal complexes have been screened for their antibacterial activities. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. 相似文献
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描述了一种新颖、简便的合成含五齿配位基的大环席夫碱配体的方法,制备和表征了该席夫碱的1∶1包合物。用化学和光谱学方法测定了标题配合物的组成,认为在所有配合物中配位金属原子取八面体结构。数据表明:配体起O2N4六齿结构而每个环绕金属原子在八面体环境中。配合物的红外和1H NMR光谱符合中心金属原子的配位结果。用分光光度法测定了配合物的稳定常数。用共轭余量法(CR method)计算了在热分解的不同阶段配合物活化的动力学和热力学参数。此外,用抑菌圈直径法筛选了配体及其金属配合物抑制细菌和真菌的能力。用回收率试验研究了天然螯合配体在不同天然水体中对Fe(Ⅲ)离子配合作用的影响。 相似文献
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《Journal of Coordination Chemistry》2012,65(1-3):197-207
Bimetallic and trimetallic complexes of stoichiometry [M(acacen)M′Y2], [M(sacacen)M′Y2], and {[M(acacen)]2M′Y2} have been prepared by reaction of the appropriate square-planar Schiff base metal complex with various secondary metal salts in toluene and/or absolute ethanol. Systems which are reported here include those where M = Cu(II); M′ = Cu(II), Ni(II), Co(II), Mn(lI) and Zn(II); Y? = Cl?, Br?, and NO3 ?. Trinuclear complexes have been isolated only for {[Cu(acacen)]2M′(NO3)2} where M′ = Cu(lI) or Mn(II); binuclear complexes result from all other combinations. The geometry of the chelated Cu(II) ion is square-planar in the bimetallic complexes and possibly square-pyramidal in the trimetallic compounds, while that of the secondary metal ion depends on the coordination preference of M′, the nature of Y? and whether the bridging donor atoms are oxygen or sulfur. Probable structures of the new polynuclear complexes have been deduced from spectral, conductivity and magnetic measurements. 相似文献