Mechanisms of inelastic scattering of low-energy protons by C6H6, C60, C6F12, and C60F48 molecules

The mechanisms of inelastic scattering of low-energy protons with a kinetic energy of 2–7 eV by C₆H₆, C₆F₁₂, C₆₀, and C₆₀F₄₈ molecules are studied using the methods of quantum chemistry and nonempirical molecular dynamics. It is shown that, for the C₆H₆ + proton and C₆₀ + proton systems, starting from a distance of 6 Å from the carbon skeleton, the electronic charge transfer from the aromatic molecule to H⁺ occurs with a probability close to unity and transforms the H⁺ ion into a hydrogen atom and the neutral C₆H₆ and C₆₀ molecules into cation radicals. The mechanism of interaction of low-energy protons with C₆F₁₂ and C₆₀F₄₈ molecules has a substantially different character and can be considered qualitatively as the interaction between a neutral molecule and a point charge. The Coulomb perturbation of the system arising from the interaction of the noncompensated proton charge with the Mulliken charges of fluorine atoms results in an inversion of the energies of the electronic states localized, on the one hand, on the positively charged hydrogen ion and, on the other hand, on the C₆F₁₂ and C₆₀F₄₈ molecules. As a result, the neutral molecule + proton state becomes the ground state. In turn, this inversion makes the electronic charge transfer energetically unfavorable. Quantum-chemical and molecular-dynamics calculations on different levels of theory showed that, for fluorine derivatives of some aromatic structures (C₆F₁₂, C₆₀F₄₈), the barriers to proton penetration through carbon hexagons are two to four times lower than for the corresponding parent systems (C₆H₆, C₆₀). This effect is explained by the absence of active π-electrons in the case of fluorinated molecules.     

Light emission from a-Si:C:O:H films fabricated by C2F6 and O2/C2F6 plasma treating silicone oil liquid

Amorphous Si:C:O:H films were fabricated at low temperature by C₂F₆ and O₂/C₂F₆ plasma treating silicone oil liquid. The a-Si:C:O:H films fabricated by C₂F₆ plasma treatment exhibited white photoluminescence at room temperature, while that by O₂/C₂F₆ plasma treatment exhibited blue photoluminescence. Fourier transformed infrared spectroscopy and Raman spectroscopy studies showed that the sp³ and sp² hybridized carbons, SiC bond, SiO bond and carbon-related defects in a-Si:C:O:H films correlated with photoluminescence. It is suggested that the blue emission at 469 nm was related to the sp³ and sp² hybridized carbons, SiC bond, carbon dangling bonds as well as SiO short chains and small clusters, while the light emitting at 554 nm was related to the carbon-related defects.     

Infrared emission of 12C16O, 13C16O,and 12C18O

The combination of a new high-resolution grating spectrometer and a spontaneous emission source has made it possible to measure precisely the 1 → 0, 2 → 1, and 2 → 0 transitions of ¹²C¹⁶O relative to the accurately known ¹²C¹⁶O laser lines which have been referred to pure frequency standards by Eng et al. The 1 → 0 and 2 → 0 band centers agree to within 0.0002 cm^?1 with those measured relative to wavelength standards by Fourier transform spectroscopy (FTS). From a weighted simultaneous fit to the FTS-absorption, FTS-flame, our grating-emission, and microwave results, a set of calculated line positions was obtained for the 1 → 0, 2 → 1, and 2 → 0 transitions of ¹²C¹⁶O. The absolute accuracy of these line positions is believed to be ±0.0005 cm^?1 and we propose that the lines can be used as secondary wavenumber standards in the infrared.The spontaneous emission sequences v′ → (v′ ? 1) were measured for ¹²C¹⁶O up to v′ = 20, for ¹³C¹⁶O up to v′ = 11 (using a ¹³C-enriched sample), and for ¹²C¹⁸O up to v′ = 4 (in natural abundance). Internally consistent sets of Dunham coefficients were calculated from the best available data for the molecules of ¹²C¹⁶O, ¹³C¹⁶O, and ¹²C¹⁸O.     

Resonances and fluctuations in the 16O + 15N and 12C + 19F collisions

The search and study of quasi-molecular resonances in the ³¹P composite system populated via two entrance channels are performed with two different experimental techniques. The ¹⁶O + ¹⁵N reaction products have been studied by the γ-ray detection method at cm. energies ranging from 15.5 MeV to 36.1 MeV. Binary channels of the ¹⁶O + ¹⁵N and ¹²C + ¹⁹F collisions have been studied by using the kinematical coincidence method at 26 incident energies ranging from E_c.m. = 20.6MeV to 33.5MeV for the first system, and at energies corresponding to the same excitation energies of the composite system for the second system. The ¹⁶O + ¹⁵N reaction exhibits two prominent gross structures in the large angle elastic scattering excitation function correlated with the resonant structures observed in inelastic channel γ-ray yield measurements. Spin assignments were tentatively made for the two resonances. On the contrary, no such structures can be clearly established in the ¹²C + ¹⁹F system where only indications of non-correlated structures in various channels have been observed.     

Reactions induced by 35 MeV 6He beam on 12C and 14C

The ⁶He+^12,14C scattering and reactions have been studied using a 35 MeV ⁶He radioactive beam and preliminary results are presented. The three-body reaction ⁶He+¹²C ↦ ¹⁰Be+2 α has been clearly identified and sequential decay of intermediate states in ¹⁴C has been studied. Search for an analog reaction on ¹⁴C, ⁶He+¹⁴C ↦ ¹²Be+2 α, has not given conclusive results yet. Other interesting reactions with this entrance channel are discussed.     

A resonant interpretation of gross structure in 12C + 12C and16O + 16O inelastic scattering

A barrier-top-resonance model calculation is found adequate to describe the gross structure behavior thus far observed in ${}^{12}\text{C}\text{+}{}^{12}\text{C and}{}^{16}\text{O}\text{+}{}^{16}\text{O}$ inelastic scattering excitation functions.     

Fusion oscillations for 16O with 12C

We explain qualitatively the oscillations seen in the total fusion excitation function of ¹⁶O on ¹²C by using an optical model potential containing a parity dependence which accounts for elastic α-particle transfer. We show that it is possible to achieve this while simultaneously obtaining a reasonable fit to the elastic angular distributions. In particular the anomalous large angle scattering is consistent with the parity dependence required to fit the fusion oscillations.     

Selectivity of the 12C(18O, 16O)14C reaction

A study about the ¹²C(¹⁸O, ¹⁶O)¹⁴C two-neutron transfer reaction was performed at the Catania INFN-LNS laboratory at 84 MeV incident energy. The ¹⁶O ejectiles produced in the reactions were momentum analyzed and identified by the MAGNEX spectrometer. The Q-value spectrum of ¹⁴C shows several known bound and resonant states, in particular states with 2p-4h configuration respect to the ¹⁶O core. The integrated cross sections show an enhanced yield for the two-neutron transfer compared to the one-neutron transfer. These results are some experimental evidences that the (¹⁸O, ¹⁶O) reaction proceeds mainly by the direct transfer of the neutron pair, instead of a second order process.     

Application of the incoming wave boundary condition to16O+16O and12C+12C elastic scattering

The elastic scattering of¹²C+¹²C and¹⁶O+¹⁶O has been studied in the framework of an incoming wave boundary condition model. Different logarithmic derivatives for the incoming waves have been tested and their effects investigated with the help of Fourier analyses. It is shown that a logarithmic derivative obtained from a JWKB approximation leads to strong absorption of the low partial waves while a logarithmic derivative constant for all partial waves causes reflections. These reflections are necessary to describe the high energy elastic scattering of¹²C+¹²C. The fits thus obtained with shallow real potentials are comparable to those obtained with deep folding potentials. It is shown that not the lowest partial waves, but those within a window just below the grazing angular momentum are most important for the higher energy¹²C+¹²C angular distributions.     

12C6+离子辐照小鼠Lewis肿瘤的研究

研究了HIRFL提供的12C6+离子辐照C57BL/6J小鼠右后腿移植的Lewis肿瘤的生长延迟和碳离子辐照对Lewis肿瘤小鼠寿命的延长.结果表明,碳离子照射的小鼠肿瘤生长体积明显地小于对照的体积.在剂量相同、分次数辐照越多时,肿瘤生长就越缓慢,肿瘤抑制就越高.在辐照分次数相同时,不同剂量对受照肿瘤生长体积未产生差异.在4Gy×3,8Gy×3和12Gy×2组3种辐照剂量下,小鼠寿命的P值小于0.05;可知小鼠的寿命延长具有统计学意义. Growth delay of the transplantable Lewis tumors growing in right hind legs of C(57) BL/6J mice and life prolongation of the mice with Lewis tumors were investigated after()~(12)C~(6+) ion radiation at HIRFL. The results show that growth volumes of the mouse tumors following carbon radiation are distinctly less than control during 21 days; the more fractions of radiation with same doses, the slower growth of tumors and the higher inhibition of tumors; different doses with the same fractions of radiation ...     

Quantum phase transition in quasi-one-dimensional BaRu6O12

We report the first systematic study of the electrical transport and magnetic properties of BaRu6O12, which has a quasi-one-dimensional (quasi-1D) hollandite structure. We show that BaRu6O12 is quasi-1D electronically as well. Its physical properties were found to be extremely sensitive to disorder. Furthermore, a transition from being metallic with a resistance drop around 2 K to being weakly insulating as the applied magnetic field was increased was also found. We propose that these two features are related to the possible presence of a quantum phase transition in this material system.     

Oscillations in the excitation function for complete fusion of 6O+12C at low energies

The excitation function of the complete fusion of ¹⁶O + ¹²C has been measured in the range E_c.m.=8.5?12.9 MeV. It contains oscillations which have already been observed at higher energies. Some of these oscillations are tentatively in terms of a rotational band.     

Laser-induced chemistry in silane-hexafluoroacetone mixtures for production of novel Si/C/F/O and C/F/O materials

Chemical reactions induced by CO₂-laser radiation in mixtures of silane and hexafluoroacetone afford various gaseous silicon- and carbon-containing compounds and result in deposition of microstructures of carbon, C/F/O and Si/C/O/F materials. These products are suggested to be formed by a variety of exothermic reactions initiated through SiH₄-photosensitized decomposition of hexafluoroacetone. Silane is shown to be a very potent reagent for the reduction of C-F bonds.     

Proton decay of spin isospin modes excited by the12C(6Li,6He)12N reaction

First investigations of the reaction¹²C(⁶Li,⁶He)-¹²N(p)¹¹C were used to study spin-isospin strength in the nucleus¹²N at E_Li=156 MeV. While the⁶He ejectiles were detected at _He=0° using a magnetic spectrograph, the decay protons were analysed in a wide range of backward angles (100°_p<170°) with=" an=" arrangement=" of=" semiconductor=" strip=" detectors.=" singles=" spectra=" were=" extracted=" as=" well=" as=" coincident=" excitation=" strength=" for=" the=" decay=" to=" low=" lying=" levels=">¹¹C. For the decay to the¹¹C ground state angular correlations were evaluated for six different energy regions in¹²N^*.The authors wish to thank the staff of the Karlsruhe Cyclotron Laboratory for their cooperation. This work has been funded by the German Federal Minister for Research and Technology (BMFT) under contract no. 06ER262I and by the Kernforschungs-zentrum Karlsruhe.     

Delta-isobar configurations in 12C and 16O nuclei

The differential yield of the reaction ¹⁶O(γ, π ⁺ p) at the maximum photon energy of 450 MeV was measured in the region of high momentum transfers to the residual nuclear system. The experimental results obtained for the ¹⁶O nucleus and the cross section measured earlier for the reaction ¹²C(γ, π ⁺ p) were analyzed on the basis of a model that takes into account the admixture of isobar states in the nuclear wave function. The probabilities for the delta-isobar configurations in the ground states of the carbon and oxygen nuclei per nucleon were estimated empirically at 0.012 ± 0.003 ± 0.002 and 0.019 ± 0.003 ± 0.003, respectively.     

Tensor polarization of 12C[2+ 1] in the 16O(13C,12C)17O reaction at 50 MeV

The ¹⁶O(¹³C,¹²C)¹⁷O reaction at 50 MeV has been investigated using the kinematical coincidence method. Polarization tensors t ₂₀ and t ₄₀ of ¹²C[2⁺ ₁] for the quantization axis taken along the direction of propagation have been measured by analyzing the energy spectrum of ¹²C[2⁺ ₁], modulated by the effect of γ ray emission. The deduced t ₄₀ values significantly deviate from zero, contrary to the prediction of the distorted-wave Born approximation theory based on one-step p shell neutron stripping without spin-dependent interactions. The phenomenological spin–orbit interaction necessary to reproduce the magnitude of measured t ₄₀ is found to be much larger than the folding model prediction. It is shown that the experimental polarization tensors as well as the cross sections can be reproduced by introducing multi-step processes involving excitations in ¹²C and ¹³C without introducing spin-dependent interactions. Received: 2 August 1999 / Revised version: 3 February 2000     

Geometric and electronic structures of B12C6N6 fullerene

An electron deficient fullerene B₁₂C₆N₆ is studied by using ab initio calculations. The structure is generated by replacing N with C in the B₁₂N₁₂ cage to ensure only B–C and B–N bonds are formed. All the possible isomers are optimized and the low energy structures are determined. C and N atoms in the low energy isomers are inclined to segregate and form B₂C₂ and B₂N₂ squares. Natural bond analysis shows that the atomic orbitals of B, C and N in this cage hybrid approximately in sp^2.3 and then form B–C and B–N bonds. The 2p orbitals perpendicular to the cage surface are partially occupied and the molecular orbitals formed by these orbitals are highly delocalized. The natural charge on N is about −1.17 in both B₁₂N₁₂ and B₁₂C₆N₆, and the charge on C is −0.72 to −0.60. The molecular orbital compositions show that the B–N bonds are the same in B₁₂N₁₂ and B₁₂C₆N₆, and the B–C bonds possess stronger covalent character. The HOMO of B₁₂C₆N₆ is formed by 2p of B and C, and the LUMO is formed by 2p of C. The energy gap of C₂₄, B₁₂N₁₂ and B₁₂C₆N₆ is 2.52, 6.84 and 3.22 eV, respectively.