Vibration analysis of a new polymer quartz piezoelectric crystal sensor for detecting characteristic materials of volatility liquid

We present a new polymer quartz piezoelectric crystal sensor that takes a quartz piezoelectric crystal as the basal material and a nanometer nonmetallic polymer thin film as the surface coating based on the principle of quartz crystal microbalance (QCM). The new sensor can be used to detect the characteristic materials of a volatile liquid. A mechanical model of the new sensor was built, whose structure was a thin circle plate composing of polytef/quartz piezoelectric/polytef. The mechanical model had a diameter of 8 mm and a thickness of 170 μ. The vibration state of the model was simulated by software ANSYS after the physical parameters and the boundary condition of the new sensor were set. According to the results of experiments, we set up a frequency range from 9.995850 MHz to 9.997225 MHz, 17 kinds of frequencies and modes of vibration were obtained within this range. We found a special frequency f_sp of 9.996358 MHz. When the resonant frequency of the new sensor’s mechanical model reached the special frequency, a special phenomenon occurred. In this case, the amplitude of the center point O on the mechanical model reached the maximum value. At the same time, the minimum absolute difference between the simulated frequency based on the ANSYS software and the experimental measured stable frequency was reached. The research showed that the design of the new polymer quartz piezoelectric crystal sensor perfectly conforms to the principle of QCM. A special frequency value f_sp was found and subsequently became one of the most important parameters in the new sensor design.     

Preparation and characterization of PTFE coating in new polymer quartz piezoelectric crystal sensor for testing liquor products

A new method was developed based on the electron beam vacuum dispersion(EBVD) technology to prepare the PTFE polymer coating of the new polymer quartz piezoelectric crystal sensor for testing liquor products. The new method was applied in the new EBVD equipment which we designed. A real-time system monitoring the polymer coating's thickness was designed for the new EBVD equipment according to the quartz crystal microbalance(QCM) principle, playing an important role in preparing stable and uniform PTFE polymer coatings of the same thickness. 30 pieces of PTFE polymer coatings on the surface of the quartz crystal basis were prepared with the PTFE polymer ultrafine powder(purity ≥ 99.99%)as the starting material. We obtained 30 pieces of new PTFE polymer sensors. By using scanning electron microscopy(SEM), the structure of the PTFE polymer coating's column clusters was studied. One sample from the 30 pieces of new PTFE polymer sensors was analysed by SEM in four scales, i.e., 400×, 1000×, 10000×, and 25000×. It was shown that under the condition of high bias voltage and low bias current, uniformly PTFE polymer coating could be achieved, which indicates that the new EBVD equipment is suitable for mass production of stable and uniform polymer coating.     

Evaluation of new single crystal piezoelectric materials for surface acoustic-wave applications

Surface acoustic waves (SAW), or Rayleigh waves, bound to the surfaces of piezoelectric materials are becoming rapidly significant in electronic device applications, particularly as VHF-UHF frequency filters and versatile time-domain processors. The majority of available devices utilize either signle crystalline quartz or lithium niobate as the piezoelectric medium. This paper describes briefly the growth and critical evaluation of SAW impedance and propagation properties for certain new single crystal piezoelectric materials. Crystals discussed are Czochralski-grown bismuth germanium oxide, films of zinc oxide and aluminum nitride both epitaxially grown on single crystal sapphire, and flux-grown beryllium oxide. It is concluded that bismuth germanium oxide may prove an important cost-effective alternative to both quartz and lithium niobate, and that either zinc oxide or aluminum nitride is destined to prove invaluable in the realization of monolithic circuits such as programmable tapped delay lines, in which SAW will be interfaced with metal-oxide semiconductor (large scale integrated) technology, and active SAW elements employing functional integration.     

介观压电石英晶体等效电路的量子化

借鉴阻尼谐振子作量子力学处理的研究思想,将介观压电石英晶体等效电路量子化,在此基础上研究了真空态和压缩真空态下,各支路电流和电压的量子涨落. 关键词： 介观压电石英晶体 等效电路 阻尼谐振子 量子涨落     

The conversion efficiency of a piezoelectric quartz crystal: Relation between input electrical power and frequency

The dependence of the conversion efficiency of a piezoelectric transducer on its frequency and the input electrical power has been examined and it is found that the efficiency is dependent not on the input power but on frequency and the nature of the liquid     

一种新型混合双包层光子晶体光纤的色散特性研究

以多极法理论为基础,设计了一种混合双包层结构的光子晶体光纤.通过改变其五层空气孔的四个结构参数（内层空气孔直径、外层空气孔直径、六边形孔间距和八边形孔间距）,理论上实现了色散绝对值在144—20 μm的波段内变化仅为125 ps·km^-1·nm^-1的平坦色散特性.在此情况下对其损耗进行了数值模拟,使所设计的光纤在144—20 μm的宽波段范围内具有小于0005 dB/km的低限制损耗特性. 关键词： 光子晶体光纤 多极法 平坦色散 限制损耗     

一种新型混合双包层光子晶体光纤的色散特性研究

以多极法理论为基础,设计了一种混合双包层结构的光子晶体光纤.通过改变其五层空气孔的四个结构参数（内层空气孔直径、外层空气孔直径、六边形孔间距和八边形孔间距）,理论上实现了色散绝对值在144—20 μm的波段内变化仅为125 ps·km^-1·nm^-1的平坦色散特性.在此情况下对其损耗进行了数值模拟,使所设计的光纤在144—20 μm的宽波段范围内具有小于0005 dB/km的低限制损耗特性.     

Possible lattice formation of new materials within a piezoelectric semiconductor plasma

The possible lattice formation of grains of chosen material in a magnetized current carrying n-type piezoelectric semiconductor plasma has been examined. In addition to the repulsive Coulomb potential, there appears a non-Coulombic oscillatory potential among the highly charged grains due to the strong resonant collective interaction of the grains and the electron-acoustic mode of the host semiconductor giving rise to the possibility of the lattice formation of grains of new materials.     

Effect of background materials in photonic crystal fiber sensor

Optical Review - In this study, an automobile wheel type photonic crystal fiber (PCF) has been designed to investigate the effect of the background material on analyte sensing. The designed PCF has...     

The kinetics of hydrogen (deuterium) sorption by thin palladium layers studied with a piezoelectric quartz crystal microbalance

The kinetics of the hydrogen (deuterium) Sorption processes in the α-phase region of a thin electrodeposited Pd layer (thickness 3 × 10^?5 cm) are reported. Measurements have been performed with a piezoelectric quartz crystal microbalance using an AT-cut crystal with a resonance frequency f⁰_q = 5.27 MHz and a sensitivity of ～10¹⁰ digits g^?1, at a constant temperature 80.3 ± 0.05 °C and different pressures. Both the absorption and the desorption of H₂(D₂) on Pd layers are controlled successively by a chemisorption step (second order kinetics) in the early stage of the processes and by a surface migration step (first order kinetics), in the subsequent stage of the processes. Consistent with the reported piezoelectric quartz crystal microbalance measurements, thermal desorption and electrochemical desorption studies, a mechanism is suggested which takes into account the adsorption ofH(D) atoms on two different surface states: (a) a “pre-dissolved” state which does not depend on the surface nature; (b) and adsorption state, the density of which depends upon the structure and nature of the Pd sample. The kinetic control of the entire processes (sorption and desorption) depends on the ratio of the density of sites (a) to (b).     

An erosion sensor based on a quartz crystal microbalance for quantitative determination of the cleaning efficiency in an ultrasonic vessel

The efficiency of ultrasonic cleaning vessels cannot be measured directly in an easy way. In the presented work, a sensor is developed which quantitatively measures the ablation of a test layer. The sensor element is a quartz crystal which is coated with a sacrificial layer. Small changes in mass of this layer can be measured by a frequency shift of the crystal oscillation. For measurements, a 10 MHz AT-cut quartz crystal was used in a cleaning vessel working at 44.9 kHz. To determine the frequency shift by the ablation of the test layer, the quartz crystal was driven by a frequency generator sweeping the frequency in the range of the resonance frequency and a characteristic frequency was determined. The test layer which was applied to the quartz crystal consisted of silica microparticles suspended in varnish. In a preliminary experiment using a commercial cleaner it could be shown that significant changes in resonance frequency by cavitation effect could be detected. The initial frequency shift of the sacrificial layer is reproducible within 10%. The test layer can be adapted to the conditions of the cleaning vessel. By changing the electrical input power of the vessel, a threshold in the cavitation erosion was found.     

A new technology for studying multicomponent liquids using a quartz crystal resonator: Theory and applications

A new technique for analyzing multicomponent liquids is suggested. It is based on recording “electronic autographs” of liquids and thereby allows one to identify and certify them. In this technique, information comes from the dynamics of the complex process of self-organization in drying drops, this dynamics being dependent on the composition and structure of the liquid. Detecting the self-organization dynamics as acoustomechanical impedance, one can reveal quantitative distinctions between liquids and thereby test their quality by comparing with a reference.     

Coupling analysis of a matched piezoelectric sensor and actuator pair for vibration control of a smart beam

This paper presents a theoretical and experimental study of the in-plane and out-of-plane coupling of a matched piezoelectric sensor/actuator pair bonded on a beam. Both the sensor and actuator are triangularly shaped polyvinylidene fluoride (PVDF) transducers and are intended to provide a compact sensor/actuator system for beam vibration control. The measured sensor-actuator frequency response function has shown an unpredicted increase in magnitude with frequency, which was found, to be due to in-plane vibration coupling. An analytical model has been developed to decompose the sensor-actuator response function into an in-plane contribution and an out-of-plane contribution. This in-plane coupling can limit the feedback control gains when a direct velocity feedback control is applied. A method called the j omega s compensation method is proposed to identify the effect of the in-plane vibration coupling at low frequencies. Even after this compensation, however, there was unexpected strong out-of-plane coupling at even modes, which may have been caused by a lack of accuracy in the shaping of the PVDF sensor and actuator. Numerical simulations have confirmed the sensitivity of the matched sensor/actuator pair with shaping errors.     

Light switching at a prism-liquid crystal interface. A new sensor for magnetic fields

Light beam propagation at a prisms-liquid crystal interface is studied both theoretically and experimentally. Our results suggest the possibility of employing such an interface as an element while designing optical sensors for magnetic fields. A comparison between the data of a theoretical model based on the Berreman formalism and the experimental results is presented.     

Investigation of a pulsed waveguide piezoelectric pressure sensor

The problem of pulsed mechanical action on a stepped acoustic waveguide with a sensitive piezoceramic element in the presence of a perfectly rigid boundary is considered. The dependence of the stress generated by the piezoelectric element on time, measuring circuit parameters, and external perturbing action is obtained analytically. A calibration of the waveguide piezoceramic sensor of the proposed design, which is intended for measuring the pressure of shock waves incident on a solid obstacle, is performed by the thumper method.     

A new method for the absolute measurement of piezoelectric coefficients on thin polymer films

A new quasistatic method to measure piezoelectric coefficients on thin polymer films is presented. This method is based on a combined experimental/analytical approach, where small polymer samples (6 mm x 3 mm x 110 microm) are encapsulated in a soft silicone rubber and an electric field is applied across their thickness (3-direction). Strains are measured optically along three perpendicular directions using a laser Doppler vibrometer, and the experimental measurements are used in a Rayleigh-Ritz energy minimization procedure implemented symbolically in MATHCAD, which yields the absolute piezoelectric coefficients d(3ii). These measured coefficients are material properties of the polymer and do not depend on the specific boundary conditions of the problem. The validity of the method is established using the ATILA finite element code. Experimental values of d(311), d(322), and d(333) obtained for polyvinylidene fluoride (PVDF) at room temperature, in the frequency range 500-2000 Hz, are presented and compared with existing data; excellent agreement is found. The extension of the method to the determination of electrostrictive coefficients on soft polyurethane materials is introduced.     

Parameter optimization and characteristic analysis of a polymer microring resonant wavelength multiplexer

Novel formulas of transmission functions are presented, some parameters are optimized, and transmission characteristics are analyzed for a polymer microring resonant wavelength multiplexer around the central wavelength of 1.55 μm with the wavelength spacing of 5.6 nm and with eight vertical output channels. The computed results show that the designed device possesses some excellent features including the 3 dB bandwidth of 0.25 μm, weaker background light of 3.8×10⁻⁴, smaller inserted loss of less than 0.6 dB, and lower crosstalk below −20 dB for every vertical output channel.     

Spectroscopic studies of optical materials in the far infrared: The case of crystal quartz

Spectroscopic studies using far infrared reflectivity and transmissivity measurements between 10 and 600 cm⁻¹, were performed on plane parallel quartz crystal plates, in the temperature range 10–300 K. The temperature dependence of the optical mode parameters is reporeted for both polarizations parallel and perpendicular to the c-axis. The extraordinary optical constants of quartz are determined at 10 and 300 K, from the A₂ transmissivity channeled spectrum, between 10 and 300 cm⁻¹.