Rotationally resolved spectra of two van der Waals states of I + Cl

Three-step optical resonance is used to execute state-selected transitions from the ground state of ICl to two van der Waals states, $\text{b(}\text{Ω}\text{= 1)}$ and $\text{b′(}\text{Ω}\text{= 2)}$, both of which correlate with the second dissociation limit, $\text{I}\text{(}{}^2\text{P}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}\text{) +}\text{Cl}\text{(}{}^2\text{P}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{)}$, of ICl. Since the B(0⁺) state also belongs to this limit, three out of five states converging to I + Cl¹ are now accounted for. Principal constants of these states are: b′(2): T_e = 18275.84, ω_e = 31.093, ω_ex_e = 1.672, ω_ey_e = 0.0070, B_e = 0.034834, α_e = .001587, and D_e = 164.09 cm^?1; b(1): T_e = 18273.30, ω_e = 26.75, ω_ex_e = 0.882, B_e = 0.03579, q = 0.00084, and D_e = 166.63 cm^?1. In both states the equilibrium distance is near 4.2 Å, slightly greater than the sum of van der Waals contact radii, $\text{r}{}_{\mathrm{<mtext>I</mtext>}}\text{+ r}{}_{\mathrm{<mtext>Cl</mtext>}}\text{= 3.95}\text{A}\text{?}$. The large value of q in the b(1) state indicates that, in the basis set $\text{|j}{}_{\mathrm{a}}\text{j}{}_{\mathrm{b}}\text{j}\text{Ω}\text{〉}$ (a = I, b = Cl, j = j_a + j_b) the b(1) and b′(2) states belong to j = 1 and j = 2 “complexes,” respectively.     

Polarization and polarization transfer in the 2H(d,n)3He reaction at 10 MeV

Angular distributions of six polarization transfer coefficients $\text{K}{}_{\mathrm{x}}{}^{\mathrm{x\prime }}\text{(θ), k}{}_{\mathrm{x}}{}^{\mathrm{z\prime }}\text{(θ), K}{}_{\mathrm{z}}{}^{\mathrm{<mtext>x</mtext><mtext>?</mtext>}}\text{(θ), K}{}_{\mathrm{z}}{}^{\mathrm{<mtext>z</mtext><mtext>?</mtext>}}\text{(θ),}\text{and}\text{K}{}_{\mathrm{yy}}{}^{\mathrm{<mtext>y</mtext><mtext>?</mtext>}}\text{(θ)}$; of the four analyzing powers A_y(θ), A_xx(θ), A_yy(θ), and A_zz(θ); and of the polarization function P^ý(θ), have been measured atE_d = 10.00 MeV for the reaction ²H(d, n)³He. Measurements were made for neutron lab angles between 0° and 80° in 10° steps. Additionally the y-axis associated quantities were measured at θ_1ab = 99°. Most of the measured coefficients are large at some angles and all show considerable variation with angle.     

The external field problem for QCD

In lattice gauge theory, many computations such as the strong coupling expansions, mean field theory, or the few plaquette models require the evaluation of the one-link integral in the presence of an arbitrary N × N complex matrix source (J). For SU(N) gauge theories, we express our general solution to the external field problem as an integral over the maximal abelian subgroup [U(1)]^N?1

where S₀ = 2Σ_kz_k cos(φ_k ? θ), z_j are eigenvalues of √JJ⁺, e^2iNθ=detJ/detJ⁺, and G is an appropriate jacobian determinant. Our explicit solution follows from differential Schwinger-Dyson equations cast in a separable form by using fermionic variables, and the special cases of N = 2, 3 and ∞ agree with earlier derivations.     

“Forbidden” rotational spectra of symmetric-top molecules: PH3 and PD3

A millimeter-wave spectrometer having a sensitivity of 4 × 10^?10 cm^?1 in the 2-mm region has been constructed for observation of extremely weak millimeter-wave spectra of gases. It has been used to measure J → J, K = 0 ← 3 transitions in PH₃ and J → J, K = 0 ← 3 as well as K = ±1 ← ±4 transitions in PD₃. The B₀ and C₀ spectral constants (in MHz) are: for PH₃, B₀ = 133 480.15 ± 0.12 and C₀ = 117 488.85 ± 0.16; for PD₃, B₀ = 69 471.10 ± 0.03 and C₀ = 58 974.37 ± 0.05. The effective ground-state values obtained for the bond angle and bond length are: for PH₃, $\text{r}{}_0\text{(}\text{A}\text{?}\text{) = 1.420}{}_0$ and $\text{α}{}_0\text{(}{}^{\mathrm{o}}\text{) = 93.34}{}_5$; for PD₃, $\text{r}{}_0\text{(}\text{A}\text{?}\text{) = 1.417}{}_6$ and $\text{α}{}_0\text{(}{}^{\mathrm{o}}\text{) = 93.35}{}_9$. The corresponding zero-point-average values were calculated to be: for PH₃, $\text{r}{}_{\mathrm{z}}\text{(}\text{A}\text{?}\text{) = 1.4269}{}_9\text{± 0.0002}$ and $\text{α}{}_{\mathrm{z}}\text{(}{}^{\mathrm{o}}\text{) = 93.228}{}_7$; for PD₃, $\text{r}{}_{\mathrm{z}}\text{(}\text{A}\text{?}\text{) = 1.4226}{}_5\text{± 0.0001}$ and $\text{α}{}_{\mathrm{z}}\text{(}{}^{\mathrm{o}}\text{) = 93.256}{}_7\text{± 0.004}$. For both species, the equilibrium values are $\text{r}{}_{\mathrm{e}}\text{(}\text{A}\text{?}\text{) = 1.4115}{}_9\text{± 0.0006}$ and $\text{α}{}_{\mathrm{e}}\text{(}{}^{\mathrm{o}}\text{) = 93.32}{}_8\text{± 0.02}$.     

Analysis of the 2770-Å emission system in I2

A weak emission spectrum of I₂ near 2770 Å is reanalyzed and found to to minate on the A(1u³Π) state. The assigned bands span v″ levels 5–19 and v′ levels 0–8. The new assignment is corroborated by isotope shifts, band profile simulations, and Franck-Condon calculations. The excited state is an ion-pair state, probably the 1g state which tends toward $\text{I}{}^{\mathrm{?}}\text{(}{}^1\text{S) +}\text{I}{}^{\mathrm{+}}\text{(}{}^3\text{P}{}_1\text{)}$. In combination with other results for the A state, the analysis yields the following spectroscopic constants: T″_e = 10 907 cm^?1, $\text{D}$″_e = 1640 cm^?1, ω″_e = 95 cm^?1, $\text{R″}{}_{\mathrm{e}}\text{= 3.06}\text{A}\text{?}$; T′_e = 47 559.1 cm^?1, ω′_e = 106.60 cm^?1, $\text{R′}{}_{\mathrm{e}}\text{= 3.53}\text{A}\text{?}$.     

Molecular structure of phosgene as studied by gas electron diffraction and microwave spectroscopy: The rz structure and isotope effect

The r_z structure of phosgene has been determined by a joint analysis of the electron diffraction intensity and the rotational constants as follows: $\text{r}{}_{\mathrm{z}}\text{(}\text{CO}\text{) = 1.1785 ± 0.0026}\text{A}\text{?}$, $\text{r}{}_{\mathrm{z}}\text{(}\text{CCl}\text{) = 1.7424 ± 0.0013}\text{A}\text{?}$, ∠_z;ClCCl = 111.83 ± 0.11°, where uncertainties represent estimated limits of experimental error. The effective constants representing bond-stretching anharmonicity have been obtained from an analysis of the isotopic differences in the r_z structure: $\text{a}{}_3\text{(}\text{CO}\text{) = 2.9 ± 0.9}\text{A}\text{?}{}^{\mathrm{?1}}$, $\text{a}{}_3\text{(}\text{CCl}\text{) = 1.6 ± 0.4}\text{A}\text{?}{}^{\mathrm{?1}}$. The equilibrium bond distances have been estimated from the r_z structure for the normal species and from the anharmonic constants to be $\text{r}{}_{\mathrm{e}}\text{(}\text{CO}\text{) = 1.1756 ± 0.0032}\text{A}\text{?}$, $\text{r}{}_{\mathrm{e}}\text{(}\text{CCl}\text{) = 1.7381 ± 0.0019}\text{A}\text{?}$.     

Deviation from scaling in the triple-regge region of pp→ pX and fP universality

By generalizing $\text{f}\text{P}$ universality to Regge-particle “scattering” we obtain $\text{s}\text{d}\text{σ}\text{d}\text{t}\text{d}\text{M}{}^2\text{= F(}\text{s}\text{M}{}^2\text{,t)}$$\text{[1 +}\text{M}{}^{\mathrm{?1}}\text{b}{}_{\mathrm{<mtext>f</mtext>}}\text{(0)}\text{b}{}_{\mathrm{<mtext>P</mtext>}}\text{(0)}\text{]}$ for pp → pX, where b_f(t) and b_P(t) are the f and P Regge residues for, say, pp → pp. This agrees with the recent NAL data.     

Lorentz contracted geometrical model

The model assumes that when two high energy particles collide each behaves as a geometrical object which has a Gaussian density and is spherically symmetric except for the Lorentz-contraction in the incident direction. Folding the two spatial distribution together we obtain the slope (b) of the elastic diffraction peak in terms of the c.m. velocities (β_i and β_j) and the sizes (A_i and A_j) of the two incident particles. These sizes are assumed to have the experimental s-dependence of σ_tot ∝ πA² for each reaction. The combined s-dependence of the σ_tot's and the β's gives the s-dependence of the elastic slope $\text{b}{}_{\mathrm{ij}}\text{(s) =}\text{1}\text{2}\text{(A}{}_{\mathrm{i}}{}^2\text{β}{}_{\mathrm{i}}{}^2\text{+ A}{}_{\mathrm{j}}{}^2\text{β}{}_{\mathrm{j}}{}^2\text{)}\text{σ}{}^{\mathrm{ij}}{}_{\mathrm{<mtext>tot</mtext>}}\text{(s)}\text{σ}{}^{\mathrm{ij}}{}_{\mathrm{<mtext>tot</mtext>}}\text{(∞)}$. This formula agrees with the experimental slope for p-p, $\text{p}$-p, K⁺-p, K^?-p and π^±-p elastic scattering from 3 to 1500 GeV/c, with only 3 parameters: A_π² = 6.1, A_K² = 3.3 and A_p² = 10.5 (GeV/c)^?2.     

Microwave spectra of deuterated ethylenes: Dipole moment and rz structure

The pure rotational spectra of three deuterated ethylenes, CH₂CD₂, CH₂CHD, and cis-CHDCHD, were observed by microwave spectroscopy, and the rotational and centrifugal distortion constants were determined precisely. The dipole moment of CH₂CD₂ was calculated from the Stark effects to be 0.0091 ± 0.0004 D. From the observed rotational constants the average structure was calculated to be $\text{r}{}_{\mathrm{z}}\text{(CC)}\text{= 1.3391 ± 0.0013}\text{A}\text{?}$, $\text{r}{}_{\mathrm{z}}\text{(CH)}\text{= 1.0869 ± 0.0013}\text{A}\text{?}$, θ_z(CCH) = 121.28 ± 0.10°, and $\text{r}{}_{\mathrm{z}}\text{(CH)}\text{- r}{}_{\mathrm{z}}\text{(CD)}\text{= 0.00137 ± 0.00037}\text{A}\text{?}$, where the errors include one standard deviation in the fitting and errors due to an uncertainty (±0.03°) in θ_z(CCH) - θ_z(CCD).     

Centrifugal distortion in weakly bound linear triatomic molecules

A simple formula is derived for the centrifugal distortion constant of a linear triatomic molecule in which one of the chemical bonds is much weaker than the other. The derivation is in complete analogy with the standard semiclassical diatomic derivation and results in the equation $\text{D}{}_{\mathrm{J}}\text{= [}\text{4B}{}_{\mathrm{e}}{}^3\text{(hv)}{}^2\text{][1 ? (}\text{B}{}_{\mathrm{e}}\text{b}{}_{\mathrm{e}}\text{)]}$, where B_e, ν, and b_e are, respectively, the triatomic rotational constant, the low stretching frequency, and the rotational constant of the strongly bound diatomic part of the triatomic molecule.     

Conditions for static balance for the post-Newtonian two-body problem with electric charge in general relativity

The usual condition for static balance, for two bodies with masses and charges m_i and e_i (i = 1, 2), is $\text{e}{}_{\mathrm{i}}\text{=±G}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{m}{}_{\mathrm{i}}$. From a post-Newtonian analysis of the two-body problem, an alternate condition for static balance $\text{e}{}_{\mathrm{i}}\text{=±(Gm}{}_1\text{m}{}_2\text{)}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ has been found. We do not know if this condition is exact beyond the post-Newtonian approximation.     

Electron-hole interaction in the presence of excitons

We calculate the effective electron-hole interaction V_re in the presence of an exciton gas, which reads in real space:

$\text{V}{}_{\mathrm{re}}\text{(r)=}\text{?e}{}^2\text{r}\text{{1+}\text{∑}\text{i=1}\text{4}\text{(?1)}{}^{\mathrm{i}}\text{C}{}_{\mathrm{i}}\text{exp}\text{(?Z}{}_{\mathrm{i}}\text{r}\text{a}\text{}}$

The parameters C_i and Z_i are given explicitly for GaAs. For this material, we show the binding energy of the exciton is weakly modified so long as $\text{8πR}{}_0\text{?}{}_{\mathrm{ex}}\text{a}{}_0{}^3\text{kT?1}$. (R₀, exciton Rydberg, a₀ exciyon radius, ?_ex exciton density, T temperature).     

Rotational constants of the E O+g state of I2 determined by polarization spectroscopy

The resonant 2-photon E(O⁺_g) ← B(O⁺_g) ← X(O⁺_g) transition of I₂ vapor has been studied by polarization spectroscopy, leading to a rotational analysis of the ν = 0–15 vibrational levels of the E state. The principal constants determined are $\text{B}{}_{\mathrm{e}}\text{= 19.9738(42) × 10}{}^{-3}\text{, α}{}_{\mathrm{e}}\text{= 5.602(84) × 10}{}^{-5}\text{, γ}{}_{\mathrm{e}}\text{= 1.02(41) × 10}{}^{-7}\text{, D}{}^{\mathrm{e}}{}_{\mathrm{J}}\text{= 3.040(74) × 10}{}^{-9}\text{cm}{}^{-1}\text{, and r}{}_{\mathrm{e}}\text{= 3.6470(5)}\text{A}\text{?}$.     

Activation energy of field emission flicker noise power due to adsorbed potassium on tungsten

The temperature dependence of the field emission flicker noise spectral density functions has been investigated for potassium adsorbed on tungsten (112) planes by a probe hole technique. By integration of the spectral density functions $\text{W(?) = B}{}_{\mathrm{i}}\text{?}{}^{\mathrm{?ge}}\text{i}$ the noise power $\text{(δn}{}^2{}_{\mathrm{\Delta ?}}$ for different frequency intervals Δ? is obtained. From the exponential temperature dependence of $\text{(δn}{}^2{}_{\mathrm{\Delta ?}}$ noise power “activation energies” q_Δ? are determined. Plots of these energies versus coverage show a similar “oscillating” behaviour as recently found for $\text{W(?}{}_{\mathrm{j}}\text{)}$ or which indicates phase transitions of the adsorbed potassium submonolayers. The noise activation energies are discussed in terms of existing models and a comparison is made between the experimental q values and surface diffusion energies E_d as determined by conventional methods.     

Relativistic correction to the deuteron magnetic moment and angular condition

The relativistic correction (RC) to the deuteron magnetic moment is calculated using the light-cone dynamics. The restrictions imposed by the angular condition on the electromagnetic current operator of the deuteron are discussed in detail. It is shown that the additive model for the current operator of interacting constituents is consistent with the angular condition only for the two first terms of the expansion of the “good” current component $\text{j}{}_{\mathrm{+}}\text{=}\text{1}\text{2}\text{(j}{}_0\text{+ j}{}_{\mathrm{<mtext>z</mtext>}}\text{)}$ in powers of the momentum transfer q. The RC to μ_d is expressed through the matrix element of the “good” component j₊ and is found to be equal to $\text{(0.6–0.8) × 10}{}^{\mathrm{?2}}\text{e}\text{h}\text{?}\text{/2m}{}_{\mathrm{<mtext>p</mtext>}}\text{c}$ for realistic NN potentials. Taking account of RC decreases essentially the discrepancy between the theoretical and experimental values of μ_d. Possible solutions of the angular condition for squared q-terms of the j₊ current component are also discussed.     

Electron-muon mass ratio,neutrino masses and Weinberg angle in an approximate SU(4)+ ⊗ SU(4)− symmetry for leptons

Assuming an SU(4) group for leptons together with the dynamical equation $\text{P}{}_{\mathrm{z}}\text{{z ? z} = 0}$ ($\text{P}{}_{\mathrm{z}}$ is the projection of the representation z from the direct product z ? z) for the symmetry breaking, we predict: and a Weinberg angle $\text{sin}{}^2\text{θ}{}_{\mathrm{<mtext>w</mtext>}}\text{=}\text{1}\text{4}$.     

Can the optical excitations of surface plasmons be used to study (liquid) metal surfaces?

The surface plasmon dispersion relation is obtained for a metal with a free electron density given by N(z) = N_b + (N_s ? N_b) exp $\text{(}\text{?z}\text{a}\text{)}$ for z ? 0 and N = 0 for z < 0. We have used a local theory which includes the effects of retarded fields and found the dispersion relation to be sensitive to the parameters $\text{(N}{}_{\mathrm{s}}\text{? N}{}_{\mathrm{b}}\text{)}\text{N}{}_{\mathrm{b}}$ and a, which characterize our density profile.     

Quantitative evidence of weak isospin mixing in the low-lying isobaric analog resonances in 209Bi

The excitation functions of ${}^{208}\text{Pb}\text{(}\text{p}\text{,}\text{p}{}_0\text{)}{}^{208}\text{Pb}$ have been measured in the energy range E_p = 14.2 to 17.4 MeV in 50 keV steps at θ_lab = 120°, 140° and 160°. The isobaric analog resonances of the parent states in ²⁰⁹Pb up to E_x = 2.5 MeV and the optical-model background were fit simultaneously at all energies and angles. The spreading widths and the values of a parameter β², which measures the isospin purity of the IAR, were determined for the $\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{,}\text{i}{}_{\mathrm{<mtext>11</mtext><mtext>2</mtext>}}\text{,}\text{j}{}_{\mathrm{<mtext>15</mtext><mtext>2</mtext>}}\text{,}\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$, and $\text{s}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ resonances. An average value of the isospin purity of β² = 66% was found.     

The electronic isotope shift in the A2Π-X2Σ+ bands of BeH,BeD and BeT

The 0-0, 1-1, 2-2, and 3-3 bands of the A²Π-X²Σ⁺ transition of the tritiated beryllium monohydride molecule have been observed at 5000 Å in emission using a beryllium hollow-cathode discharge in a He + T₂ mixture. The rotational analysis of these bands yields the following principal molecular constants.

$\text{A}{}^2\text{Π:}\text{B}{}_{\mathrm{e}}\text{= 4.192}\text{cm}{}^{\mathrm{?1}}\text{; r}{}_{\mathrm{e}}\text{= 1.333}\text{A}\text{?}$

$\text{X}{}^2\text{Σ:}\text{B}{}_{\mathrm{e}}\text{= 4.142}\text{cm}{}^{\mathrm{?1}}\text{; r}{}_{\mathrm{e}}\text{= 1.341}\text{A}\text{?}$

$\text{ω}{}_{\mathrm{e}}\text{′ ? ω}{}_{\mathrm{e}}\text{″ = 16.36}\text{cm}{}^{\mathrm{?1}}\text{; ω}{}_{\mathrm{e}}\text{′X}{}_{\mathrm{e}}\text{′ ? ω}{}_{\mathrm{e}}\text{″X}{}_{\mathrm{e}}\text{″ = 0.84}\text{cm}{}^{\mathrm{?1}}$

From the pure electronic energy difference (E_Π - E_Σ)_BeT = 20 037.91 ± 1.5 cm^?1 and the corresponding previously known values for BeH and BeD, the following electronic isotope shifts are derived

$\text{ΔE}{}_{\mathrm{e}}{}^{\mathrm{i}}\text{(}\text{BeH}\text{?}\text{BeT}\text{) = ?4.7 ≠ 1.5}\text{cm}{}^1\text{, ΔE}{}_{\mathrm{e}}{}^{\mathrm{i}}\text{(}\text{BeH}\text{?}\text{BeT}\text{) = ?1.8 ≠ 1.5}\text{cm}{}^1$

and related to the theoretical approach given by Bunker to the problem of the breakdown of the Born-Oppenheimer approximation.     

A study of 3He capture in light nuclei

Excitation functions at θ = 90° have been measured for ${}^{16}\text{O}\text{(}{}^3\text{He}\text{, γ}{}_{\mathrm{0?2,\; 3?5,\; 6}}\text{)}{}^{19}\text{Ne}$, ${}^{15}\text{N}\text{(}{}^3\text{He}\text{, γ}{}_{\mathrm{0,\; 1?4}}\text{)}{}^{18}\text{F}\text{,}{}^{14}\text{N}\text{(}{}^3\text{He}\text{, γ}{}_{\mathrm{0,\; 1,2,3}}\text{)}{}^{17}\text{F}$, and ${}^{20}\text{Ne}\text{(}{}^3\text{He}\text{, γ}{}_{\mathrm{0\; +\; 1}}\text{)}{}^{23}\text{Mg}$, in the range E_{3He = 3–19 MeV}. The first reaction has also been studied at θ = 40°. Excitation functions at 90° have also been measured for and ${}^4\text{He}\text{(}{}^3\text{He}\text{, γ}{}_{\mathrm{0\; +\; 1}}\text{)}{}^7\text{Be}$ for E_3He = 19–26 MeV. Angular distributions have been measured for the first four reactions.For the most excitation functions, a broad peak is observed, several MeV wide, centred at about E_x≈ 20 MeV. Superimposed on this, in some cases, are narrower peaks, with width ≈ 1 MeV. Energies and widths have been extracted for all resonances.Cluster-model calculations have been carried out, using methods similar to those which have proved successful for low-lying states in A= 18–19 nuclei. No satisfactory correspondence with the present results was found. The shell model has been used to calculate Γ_3He and Γ_γ for 1?ω excitations in the final nuclei. These generally show good agreement with the trends of the experimental data. The results are consistent with the excitation of the giant dipole resonance in ³He capture, but much more weakly than in proton capture.