UV laser photofragment GaCH3 detected by far UV laser mass spectrometry

The GaCH₃ radical has been directly detected by far UV laser mass spectrometry for the first time, as a UV laser photofragment from gaseous trimethylgallium Ga(CH₃)₃, but not from triethylgallium, Ga(C₂H₅)₃. The relative yield Y() of GaCH₃ was measured, at various UV photolysis laser wavelengths =193, 210 and 245 nm, and follows the absorption spectrum of the Ga(CH₃)₃ precursor molecules.     

Orange,red and deep-red flashlamp-pumped Pr3+:LiYF4 laser with improved output energy and efficiency

Three laser transitions (607.2 nm, 639.5 nm, 720.9 nm) in a flashlamp-pumped Pr³⁺:LiYF₄ laser at room temperature are investigated. Cerium ions (Ce³⁺) doped into the fused-quartz envelope of the flashlamp efficiently transfer strong UV radiation from pumping light into the absorption region of Pr³⁺ ions ( = 420–480 nm), so that the slope efficiency of all three laser emissions could be increased by almost 100% compared to excitation with a pure quartz flashlamp. At a pump energy of 30 J the output energy of these three laser emissions reached 4.7 mJ, 87 mJ and 30 mJ.     

XeCl laser controlled chemical etching of aluminum in chlorine gas

The 308 nm XeCl laser assisted etching process of thin Al metal films on Si substrate in Cl₂ gas was investigated. Etch rates were measured versus the laser fluence on the sample, the laser repetition rate, the Cl₂ pressure and the sample temperature. Irradiation experiments under vacuum of films which were previously exposed to Cl₂, and laser assisted etching in rare gases, nitrogen and air mixtures with Cl₂ were also performed to elucidate the mechanism of the etching process. The surface morphology was investigated by scanning electron microscopy. The results show that a) Etch rates of up to about 1.5 m per pulse are obtained which are strongly dependent on the Cl₂ pressure and sample temperature. b) The etching mechanism is essentially a chemical chlorination of the Al in between the laser pulses which is followed by photo-ablation of the reaction products, c) AlCl₃ evaporation and redeposition processes can explain the observed results. d) The Al films can be etched fully and cleanly without damage to the smooth Si substrate. e) Etching through adjacent or imaged mask on the Al film yielded relatively smooth and well defined Al walls with structures of the order of 1 m.     

Morphology and composition on Al surface irradiated by femtosecond laser pulses

We study the surface chemicals and structures of aluminum plates irradiated by scanning femtosecond laser pulses in air for a wide range of laser fluence from 0.38 to 33.6 J/cm². X-ray photoelectron spectroscopy and X-ray diffraction analyses indicate clearly that crystalline anorthic Al(OH)₃ is formed under femtosecond laser pulse irradiation. Besides aluminum hydroxide, crystalline Al₂O₃ is also found in the samples irradiated at high laser fluence. Field emission scanning electron microscopy demonstrates that the surfaces of the samples irradiated with low laser fluence are colloidal-like and that nanoparticles with a few nanometers in size are embedded in glue-like substances. For high laser fluence irradiated samples, the surfaces are highly porous and covered by nanoparticles with uniform size of less than 20 nm.     

Matrix assisted pulsed laser deposition of light emitting polymer thin films

Matrix assisted laser processing allows for the deposition of functional and fragile materials with a minimum of breakdown and decomposition. In this communication we report on light emitting thin films of ruthenium tris(bipyridine)-centered star-shaped poly(methyl methacrylate), Ru(bpyPMMA₂)₃(PF₆)₂, grown by matrix assisted pulsed laser deposition. A pulsed excimer laser (KrF) operating at 248 nm was used for all experiments. Due to the absorption at 248 nm and the solubility characteristics of [Ru(bpyPMMA₂)₃](PF₆)₂, dimethoxy-ethane (DME) was used as a solvent [1]. Dilute solutions (2 wt.%) of [Ru(bpyPMMA₂)₃](PF₆)₂ and DME were flash frozen in liquid nitrogen producing a solid target. Thin films ranging from 20 to 100 nm were grown on Si in an Ar atmosphere at 200 mTorr at a laser fluence of 0.04 J/cm². The deposited materials were characterized by proton nuclear magnetic resonance (¹H NMR) and gel permeation chromatography (GPC) equipped with refractive index (RI), and ultraviolet/visible (UV/vis) detection. PACS 81.15.Fg; 79.20.Ds; 78.66.Qn; 42.70.Jk     

Excimer laser projection-patterned deposition of Al via photolytically driven decomposition of trialkylamine alane as adsorbate precursor

Aluminum films have been deposited from trimethylamine alane (CH₃)₃N · AlH₃ and triethylamine alane (C₂H₅)₃N · AlH₃ precursors on Al₂O₃, GaAs and quartz substrates using XeCl (=308 mn) and KrF (=248 nm) excimer lasers. Substrate surface irradiation induces the decomposition of the precursor in the adsorbed phase. The technique allows projection patterned deposition of Al at room temperature. Al deposition proceeds in two steps: surface nucleation, which is a pure photolytic process, and the succesive Al growth, which is photolytically driven but is thermally activated at low laser energy densities (<60 mJ/cm²). The nucleation process strongly depends on the substrate and laser wavelength. Mirror like Al films are deposited at rates up to about one Al monolayer per pulse which corresponds to rates up to 2 m/min when photolyzing at 100 Hz. Al films with good adhesion and resistivities down to 7.5 cm (2.5 times bulk), were deposited. The process has good spatial selectivity. Patterns with 1 m resolution have been generated.     

Upconversion CW laser at 284 nm in a Nd:YAG-pumped double-cladding thulium-doped ZBLAN fiber laser

A successful continuous-wave (CW) ultraviolet (UV) laser in a Tm⁺³-doped ZBLAN fiber, operated at 284 nm (¹ I ₆ → ³ H ₆ transition of Tm⁺³) is demonstrated. The excitation uses a four-step upconversion scheme. The pump source is a Nd:YAG laser operated at 1.064 μm. A laser output power of 42 μW continuous wave was obtained for 590 mW of the launched pump power. The slope efficiency with respect to the launched pump power was measured to be 9%. Ultraviolet (at 365 nm) and visible (at 453 and 480 nm) radiation was also observed.     

Photoabsorption of BCl3 Gas under pulsed ArF excimer laser irradiation

The gas immersion laser doping (GILD) technique requires the measurement of the fraction of incident light absorbed in the gas phase during the irradiation with a pulsed laser. Here we report the absorption of boron trichloride (BCl₃) gas at the wavelength of a pulsed ArF excimer laser (=193 nm). We have determined the one-photon (₁) and two-photon () absorption cross sections of this dopant gas for 193 nm. The values of ₁ and are 3.6×10^–20 cm² and 9×10^–45 cm⁴·s, respectively. However, the distinction between simultaneous and sequential absorption has not been possible. Based on these results, we have established a relationship which allows the calculation of the fraction of incident light absorbed as a function of incident intensity and gas pressure.     

All-solid-state CW Nd:LuVO<Subscript>4</Subscript>-LBO laser at 533 nm under direct 888 nm pumping

We report an efficient laser emission on the 1066 nm ⁴ F _3/2 to ⁴ I _11/2 transition in Nd:LuVO₄ under the pump with diode laser at 888 nm. Continuous wave (CW) 11.2 W output power at 1066 nm is obtained under 18.3 W of incident pump power; the slope efficiency with respect to the incident pump power was 71.9%. Moreover, intracavity frequency doubling with LiB₃O₅ (LBO) nonlinear crystal yielded 4.2 W of green light at 533 nm. An optical-to-optical efficiency with respect to the incident pump power was 23.0%.     

Tunable UV radiation at short wavelengths (188–240 nm) generated by sum-frequency mixing in lithium borate

Sum-frequency mixing (₃=₁+₂) of UV laser radiation (₁=266 nm and 213 nm) and tunable coherent infrared light (₂=1.2–2.6 m) in lithium borate (LBO) generates radiation at short wavelengths (₃=188–242 nm). The UV radiation at ₁ is produced by the fourth and fifth harmonic of a pulsed Nd-YAG laser. The infrared light is generated with an optical parametric oscillator of beta barium borate. The phase-matching angle is measured as function of ₃ and compared with calculated values. For UV laser radiation at shorter wavelengths (173 nm₁213 nm) the calculations predict an extension of the tuning range of the sum-frequency generated at ₃ to wavelengths as short as the LBO transmission cutoff at 160 nm.     

Laser-ionization mass-spectrometric studies on laser ablation of a nitrogen-rich polymer at 532 nm and 1064 nm

Laser-ionization Time-Of-Flight (TOF) mass-spectrometric studies have been carried out on the 532 nm and 1064 nm laser ablation products from a nitrogen-rich polymer. The polymer used had an elemental composition of C_6.0N_8.9H_3.4 and consisted of C=N, C-N, and N-H chemical bonds. The TOF mass spectra observed were composed of various peaks (150 amu) depending on the ablation laser wavelength. The primary peaks were assigned to C⁺, CN⁺, CHnN⁺ ₂ (n=1–3) and C₂H₂N⁺ ₃ for 532 nm ablation, and C⁺, C⁺ ₃, HCN⁺, HCCN⁺, CH₂NH⁺, HNCN⁺, H₃NCN⁺, and C₄H₄N⁺ ₇ for 1064 nm ablation. The flight velocity distributions with peak velocities ranging from 8.6×10³ cm/s to 3.8×10⁴ cm/s were measured for these products. The distinct velocity distributions observed between small and large products indicate the presence of two origins in the fragment ejection process from the polymer for both 532 nm and 1064 nm ablation. Furthermore, we suggest an importance of the translational energy of the fragments for the product generation in the laser plume.     

Continuous wave laser operation of Yb<Superscript>3+</Superscript>:YVO<Subscript>4</Subscript>

We have demonstrated the continuous wave laser operation of Yb³⁺:YVO₄. For Ti:Al₂O₃ laser pumping at 985 nm, a maximum slope efficiency of 41.1% and a threshold pump power of 76 mW were obtained. The maximum output power was 433 mW at a laser wavelength of 1037 nm.Using a cw diode laser around 974 nm as a pump source, a slope efficiency of 10.9% and a maximum output power of 152 mW were achieved at a laser wavelength of 1039 nm. The laser threshold pump power was 608 mW with respect to the absorbed pump power. The effective emission cross-sections for the ²F_5/2²F_7/2 transition were determined using the Füchtbauer–Ladenburg equation. The maxima of the effective absorption and emission cross-sections were found at 984.5 nm (6.74×10^-20 cm²) in -po larization and 985.5 nm (4.28×10^-20 cm²) also in -p olarization. The upper laser level lifetime was measured with suppression of radiation trapping and is around 318 s. PACS 42.55.Rz; 42.55.Xi; 42.70.Hj     

Observation of new laser transitions and saturation effects in optically pumped NO

We report investigations of an NO laser employing specially profiled magnetic fields of up to 3.4T, and F₂ pump laser intensities as great as 20 MW cm^–2. We have observed laser oscillation at 226 nm on a rotational branch of the B'-X/it(3–11) band of NO for the first time, in addition to the previously reported oscillation at 218 nm on the B'-X/it(3–10) band. We have also observed visible laser emission on a rotational branch of the B ²-B ² II(3–1) band of NO. Saturation of the NO laser pulse energy with pump intensity has been observed, the total NO laser pulse energy having been increased to 490 J. The possibility of increasing the NO laser pulse energy towards 1 mJ per transition is discussed.     

Dual excimer and CO2 laser etching studies of polyethylene terephthalate

Polyethylene terephthalate (PET) films preheated with a pulsed CO₂ laser have been ablatively etched with an XeCl laser. The observed reduction in ablation threshold, from 170 to 140 mJ cm^–2, is consistent with a thermal mechanism for XeCl laser ablation of PET. Transient changes in the UV absorption coefficient of PET caused by heating with pulsed CO₂ laser radiation have also been studied and a significant increase in absorption observed at 308 nm. Permanent changes in the ultraviolet absorption of PET following exposure to low fluence XeCl laser radiation are also reported.     

Effects of 1064 nm laser on the structural and optical properties of nanostructured TiO2 thin film

TiO₂ thin film has been widely used as photoelectrode in dye-sensitized solar cells. It can also be used in quantum dot synthesized solar cells. Study of its effects in different spectrum of light is important for its use in solar cells. We have reported effects of 1064 nm laser on the surface morphology, structural and optical properties of nanostructured TiO₂ thin film deposited on glass substrates using sol-gel spin coating technique. Q-Switched Nd:YAG pulsed laser at various power densities is used in this study. Surface morphology of the film is investigated using X-ray diffraction (XRD) and atomic force microscopy technique. The XRD pattern of as deposited TiO₂ thin film is amorphous and after laser exposure it became TiO₂ anatase structure. Atomic force microscopy of the crystalline TiO₂ thin film shows that the grain size increases by increasing laser power density. The calculations of the band gap are carried out from UV/Visible spectroscopy measurements with JASCO spectrometer. For laser power density of 25 MW/cm² there is an increase in the transmission and it decreases at the value of 38 MW/cm² and band gap decreases with increasing laser power density. Photoluminescence spectra of the crystalline TiO₂ thin film indicate two broad peaks in the range of 415 and 463 nm, one for band gap peak (415 nm) and other for oxygen defect during film deposition process.     

Frequency doubling of laser light in an isotropic medium with electrically destroyed centre of inversion

The non-zero non-linear susceptibility tensor components ² (E ⁰)which account for frequency doubling of laser light in a naturally isotropic medium immersed in a DC efectric field (E ⁰) are discussed. The conditions for extremal second harmonic generation (SHG) are derived, which depend onE ⁰ and on the incident laser intensity but primarily on the microstructure of the medium. With growingE ⁰, the susceptibilities ² (E ⁰) increase for cigar-like microsystems but decrease for disc-shaped ones, according to whether the induced dipole helps or hinders the permanent dipole in reorienting the microsystem along (E ⁰). Non-linear electronic distortion alone is insufficient for explaining the anomalous experimental results.Generally, upon the electrically induced anisotropy, an anisotropy self-induced by the laser beam is superimposed, with optical axis along the propagation direction if the beam is circularly polarised or unpolarised, or along the oscillation direction of the light vector if it is linearly polarised.Extremal anisotropy of the medium occurs at saturation of electric or optical reorientation. This is experimentally inachievable in molecular substances even with very strong fields but is easy to obtain in solutions of macromolecules or colloid particles, where yet other opto-electronic processes intervene significantly.     

Synthesis of Ultrafine γ-Al2O3 Powders by Pulsed Laser Ablation

Ultrafine -alumina (-Al₂O₃) powders have been successfully produced by laser ablation (aluminum target, Nd:YAG laser, 1.06 m, 7 ns, filter-target distance 6 cm, oxygen flow rate 1 l/min, pressure 200 Torr, fluence 16 J/cm²). The structural properties of the Al₂O₃ powders have been studied by X-ray diffraction, transmission electron microscopy and Brunauer, Emmet, Teller analysis. The behavior of luminous plume in background oxygen has been investigated by streak and fast photography, and emission spectroscopy. Stoichiometric -Al₂O₃ powder has been obtained at an oxygen pressure of 200 Torr, with a diameter of 11.8 nm and a specific surface area of 160 m²/g. At lower oxygen pressures the average diameter decreased to 6.1 nm, and the surface particle area increased to over 300 m²/g, but the powder composition was altered by the presence of some unreacted aluminum. The measurements on plume expansion revealed initial plume velocities of 0.04–0.18 cm/s, slowing down with pressure and distance. Emission spectroscopy indicates the presence of both neutral and ionized species, the most prominent lines being Al(I) 394.4 and 396.1 nm, Al(I) 358.7 nm, Al(III) 360.1 and 361.2 nm and Al(II) 466.7 nm; in time, only Al(I) 394.4 and 396.1 nm lines persisted for more than 2 s. Much weaker lines could be observed for O(II) ions. -Al₂O₃ (0.9 g) powders have been obtained for 1 kWh (laser output energy), with a powder collection efficiency of 75%.     

A photolyticallyQ-switched photolytic iodine laser

A novel, repetitively pulsed, photolyticQ-switching scheme has been demonstrated on a 1.315 m (² P _1/2² P _3/2) cw photolytic iodine laser using an intracavity cell containing either IBr or ICl. When the cell is irradiated with a KrF laser (=248 nm), I(² P _3/2) atoms are produced and lasing ceases due to the introduction of loss into the laser cavity. Lasing resumes, however, following recombination of the atoms into the parent molecule. Experimental evidence is presented which indicates that the laser's shut-off time is a function of excimer laser energy and the pressure of buffer gas in the cell.     

Spectroscopic evidence of positive clusters in Ag colloids obtained by laser ablation in aqueous solutions

We have found evidence of positive cluster formation during the laser ablation process of a silver target in aqueous solutions. In particular, by employing in situ shot-by-shot UV–vis spectroscopy in the early stages of the ablation, we observed a weak and unstable absorption band around 266 nm and a more stable one around 290 nm, which could be assigned to charged clusters like Ag ₃ ²⁺ and Ag ₄ ²⁺ , respectively. Surface-enhanced Raman scattering experiments performed with a test molecule adsorbed on a silver colloid obtained in pure water were compatible with the presence of Ag ₄ ²⁺ active sites on the surface of the Ag nanoparticles.     

Ultra-violet excited laser emission in Na2

Laser emission at different wavelengths in the range of 903–914 nm and around 2.5 m has been observed upon excitation of Na₂ by uv radiation from an excimer laser at 351 nm and an excimer pumped dye laser in this wavelength range. The emission is attributed to a cascade emission followed by . In addition, coupled with the laser emission around 910 nm, broad-band fluorescence peaking around 855.5 nm is observed which, eventually, may be the first observation of the bound-free transition in Na₂.