A structural,magnetostrictive and Mössbauer study of Tb<Subscript>0.3</Subscript>Dy<Subscript>0.7</Subscript>(Fe<Subscript>0.9</Subscript><Emphasis Type="Italic">T</Emphasis><Subscript>0.1</Subscript>)<Subscript>1.95</Subscript> alloys

The effect of IIIA metal and transition metalT substitution for Fe on crystal structure, magnetostriction and spontaneous magnetostriction, anisotropy and spin reorientation of a series of polycrystalline Tb_0.3 Dy_0.7 (Fe_0.9 T _0.1)_1.95 (T=Mn, Fe, Co, B, Al, Ga) alloys at room temperature were investigated systematically. It was found that the primary phase of the Tb_0.3 Dy_0.7 (Fe_0.9 T _0.1)_1.95 alloys is the MgCu₂-type cubic Laves phase structure for different substitution. The magnetostrictionλ _s decrases greatly for the substitution of IIIA metal, B, Al and Ga, but is saturated more easily for Al and Ga substitution, showing that the Al and Ga substitution is beneficial to a decrease in the magnetocrystalline anisotropy of Tb_0.3 Dy_0.7 (Fe_0.9 T _0.1)_1.95 alloys. However, the substitution of transition metal Mn and Co decreases slightly the magnetostrictionλ _s . It was also found that the effect of different substitutions on the spontaneous magnetostrictionλ ₁₁₁ is distinct. The analysis of the Mössbauer spectra indicates that the easy magnetization direction in the {110} plane deviates slightly from the main axis of symmetry for Al and Ga substitution, namely spin reorientation, but it does not change evidently for B, Mn and Co substitution.     

Specific features of the three-electron <Emphasis Type="Italic">KL</Emphasis><Stack><Subscript>2, 3</Subscript><Superscript>2</Superscript></Stack> ionization of silicon atoms upon near-threshold photoabsorption

The shape and relative intensity of the group of the Kα_5–8 satellites (radiative transitions KL _{2, 3} ² )-L _{2, 3} ³ of Si atoms are experimentally studied upon photoabsorption near and far from the KL _{2, 3} ² ionization threshold. The satellites were excited near the ionization threshold by lines of the characteristic L spectrum and bremsstrahlung radiation from Nb and Mo anodes and far from the threshold by the L spectrum and bremsstrahlung radiation from an Ag anode and by monochromatized Kα_{1, 2} radiation from a Ti anode. It is established that the probability P(L _{2, 3} ² ) of formation of two additional 2p vacancies during KL _{2, 3} ² photoabsorption of Si atoms near the energy threshold is by a factor of 1.5 lower than that during photoionization in a more distant energy region beyond the threshold. At the same time, the P(L _{2, 3} ² )/P(L _{2, 3}) ratio remains invariable for the absorbed photons throughout the energy range studied. It is demonstrated that, as the KL _{2, 3} ² ionization threshold is approached, an intensity redistribution occurs among the components of the group of the Kα_5–8 lines, which reflects a decrease in the excitation cross section ratio σ(⁴ P)/σ(² P) of the ⁴ P and ² P terms of the KL _{2, 3} ² configuration. A conclusion is drawn that the effects of suppression of the generation of P terms of higher multiplicity during the KL _{2, 3} and KL _{2, 3} ² near-threshold photoionizations are of a common nature.     

VUV-luminescence and excitation spectra of the heavy trivalent rare-earth ions in fluoride matrices

VUV 4f ⁿ → 4f^n?15d transitions of Gd³⁺, Er³⁺, Tm³⁺, and Lu³⁺ in fluoride matrices have been analyzed with high-resolution luminescence and excitation spectroscopy. In trifluorides, strong electron-phonon coupling has been found. In the other matrices, the luminescence spectra clearly yield zero-phonon lines and phonon replica, indicating intermediate coupling. The energies of the zero-phonon lines observed are compared with theoretical predictions. Near the threshold of f → d excitations, some of the excitation spectra yield sharp structures which cannot be explained with phonon replica but will be discussed in terms of the energy levels of the 4f^n?15d configuration.     

4<Emphasis Type="Italic">p</Emphasis><Superscript>5</Superscript>4<Emphasis Type="Italic">d</Emphasis><Superscript>2</Superscript> configuration in the spectra of rubidium-like Ru VIII and Rh IX ions

The spectra of ruthenium and rhodium excited in a low-inductive vacuum spark have been obtained using a vacuum grazing-incidence spectrograph with a grating of 3600 lines/mm 3 m in radius in the range of 180–350 Å. The bidium-like spectra of Ru VIII and Rh IX were analyzed. Ten spectral lines of the 4p ⁶4d-4p ⁵4d ² transitions are identified and six energy levels in the 4p ⁵4d ² configuration with an excited internal electron were found for each ion for the first time.     

Kinetic freeze-out s pectra of identified particles produced in p–Pb collisions at $$\sqrt {s_{NN} }$$ = 5.02 TeV

We study the transverse momentum spectra of identified pions (π^– + π⁺), kaons ((K ^– + K ⁺), K ₀ ^s ), protons (p + p?) and lambda hyperons (Λ + Λ?) produced at mid-rapidity (0 < y _cm < 0.5) in most central (0?5)% p–Pb collisions at \(\sqrt {s_{NN} }\) = 5.02 TeV in comparison with a Unified Statistical Thermal Freeze-out Model (USTFM). The measurements for pions are reported upto p _T = 3 GeV, the kaons (K ^– + K ⁺) are reported upto p _T = 2.5 GeV, K ₀ ^s is reported upto p _T = 7 GeV, and the baryons (protons and lambda hyperons) are reported upto p _T = 3.5 GeV. A good agreement is seen between the calculated results and the experimental data points taken from the ALICE experiment. The transverse momentum spectra are found to be flatter for heavy particles than for light particles. Bulk freeze-out properties in terms of kinetic freeze-out temperature and the transverse collective flow velocity are extracted from the fits of the transverse momentum spectra of these hadrons. The effect of resonance decay contributions has also been taken care of.     

Spectra of rubidium-like Pd X-Sn XIV ions

Palladium, silver, and cadmium spectra excited in a low-inductive vacuum spark have been recorded on a vacuum grazing-incidence spectrograph with a grating of 3600 lines/mm and 3 m in radius, in the range 120–350 Å. The 4p ⁶4d-(4p ⁶5p + 4p ⁶4f + 4p ⁵4d ²) transitions in rubidium-like Pd X-Cd XII spectra have been investigated. Twenty two new spectral lines have been identified from the Dirac-Fock and Hartree-Fock calculations and the known lines were measured with high accuracy. The fine-structure intervals for the 4p ⁶4d ² D ground state and the energies of six, seven, and ten energy levels of excited configurations in Pd X, Ag XI, and Cd XII, respectively, were determined. On the basis of the analysis of isoelectronic regularities in the position of the energy levels, the previous identifications for the In XIII and Sn XIV spectra were refined.     

Searching for signatures around 1920 MeV of a N<Superscript>*</Superscript> state of three hadron nature

We provide a series of arguments which support the idea that the peak seen in the \( \gamma\) p \( \rightarrow\) K ⁺ \( \Lambda\) reaction around 1920MeV should correspond to the recently predicted state of J ^P = 1/2⁺ as a bound state of K \( \bar{{K}}\) N with a mixture of a ₀(980)N and f ₀(980)N components. At the same time we propose polarization experiments in that reaction as a further test of the prediction, as well as a study of the total cross-section for \( \gamma\) p \( \rightarrow\) K ⁺ K ^- p at energies close to threshold and of dσ/dM _inv for invariant masses close to the two-kaon threshold.     

Resonant Raman scattering in superconducting Ba<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>K<Subscript>x</Subscript>BiO<Subscript>3</Subscript>

The effect of the photon energy of the exciting laser radiation on the Raman spectra of Ba_1?xK_xBiO₃ with x=0.25, 0.40, and 0.50 is studied. An increase in the laser wavelength from 488 to 750 nm scarcely affects the amplitudes and frequencies of the spectral lines in the Raman spectra of the nonsuperconducting compound with x=0.25. For the optimally doped (x=0.40) and overdoped (x=0.50) superconducting compounds, a substantial increase in the line intensity and a considerable shift of the characteristic frequencies are observed. This result suggests that, in the whole range of superconducting compositions 0.37≤x≤0.50, the local symmetry of the Ba_1?xK_xBiO₃ crystal lattice differs from the perfect cubic symmetry, which should take place according to the literature data. The fact that resonance phenomena are observed when the laser photon energy is shifted toward the optical gap testifies to the presence of local electron pairs in the whole range of superconducting compositions 0.37≤x≤0.50 and is evidence in favor of the superconductivity mechanism proposed for Ba_1?xK_xBiO₃ on the basis of the X-ray absorption studies in our previous paper.     

X-ray spectra and electronic band structure of nitrogen in Al<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Ga<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>N solid solid solutions

The electronic energy structure of the valence band and the x-ray absorption near edge structure (XANES) region of nitrogen in Al _x Ga_1?x N solid solutions and binary crystals of gallium nitride GaN and aluminum nitride AlN are calculated using the local coherent potential method and the cluster version of the muffin-tin approximation within the framework of the multiple scattering theory. It is demonstrated that the calculated electron densities of states correlate with the nitrogen K x-ray emission and nitrogen K x-ray absorption spectra. The electronic energy structure of the top of the valence band and the XANES region in Al _x Ga_1?x N solid solutions are compared with those in the binary crystals of the GaN and AlN nitrides, and an interpretation of their specific features is proposed. An analogy is drawn between the evolution of the electronic energy structure of the valence band and the XANES region in the alloys under investigation and the evolution of the electronic band structure in the Al _x B_1?x N and B _x Ga_1?x N alloys. General trends in the transformation of the structure and variations in properties of these alloys are discussed.     

Population and current noise in semiconductor laser junctions

The population noise in a semiconductor laser is calculated by means of the quantum mechanical Langevin method. The resulting population noise is given by 〈δ N _c ² 〉=(T _c/2) (rate in+rate out)+K(¯n), whereN _c is the total number of electrons in the conduction band in the active region,T _c is a relaxation time. The first expression is the usual shot noise term. The transition rates are the sum of the rates due to the light field, the pumping and the spontaneous emission. The last termK(¯ n) is caused by the light field fluctuations;¯n is the mean number of photons in the laser mode.K(¯ n) consists of two parts: a) The main part is proportional to the intensity noise of the light field, which increases below but near threshold and gets constant above threshold. b) There is a second term due to the fact that parts of the fluctuations of the population and of the light field are correlated. — The noise spectrumS _I(ω) of the junction currentI is calculated for low frequencies. Beyond the usual shot noise termS _I(0)=2eI, additional noise is found in and above the threshold region, a) mainly because of the fluctuations of the light field in the laser mode and b) to a small amount, because the absorption processes due to the laser photons weaken the forward current, which is carried by emission processes, while the absorption noise adds to the emission noise.     

Effect of high doses on the Si <Emphasis Type="Italic">L</Emphasis><Subscript>2,3</Subscript> x-ray emission spectra of silicon implanted with iron ions under steady-state conditions

The effect of high doses on p-and n-type silicon samples implanted with Fe⁺ ions under steady-state conditions (implantation energy, 100 keV; ion current density, 0.6–0.8 μA/cm²; irradiation dose, 10¹⁴–10¹⁶ ions/cm²) is investigated using Si L _{2, 3} x-ray emission spectroscopy (the 3d3s → 2p electronic transition). An analysis of the Si L x-ray emission spectra of the silicon samples is performed by comparison with the spectra of reference materials and the spectra of silicon samples implanted with Fe⁺ ions in a pulsed mode. The Si L x-ray emission spectra are simulated by the molecular dynamics and full-potential linearized augmented-plane-wave (FLAPW) methods. It is revealed that the effect of high doses under steady-state conditions of Fe⁺ ion implantation into the semiconductor crystal matrix exhibits specific features: the disordering of the structure and partial amorphization of the sample from the surface deep into the bulk are more pronounced than those observed under conditions of pulsed ion implantation, although virtually no recrystallization of the sample at the threshold dose occurs. The most probable origins and mechanisms of the effect of high doses on the samples under investigation are discussed.     

On <Emphasis Type="Italic">K</Emphasis>β radiation of Ar<Superscript>16+</Superscript> ions in coronal plasma

The measured and calculated data obtained in this and earlier works for the intensity ratio G₃= I[Kβ₂]/I[Kβ₁] of the intercombination and resonance Kβ lines corresponding to the 1s3p³P₁→1s₂₁S₀ (Kβ₂) and 1s3p¹P₁→1s²¹S₀ (Kβ₁) transitions in the coronal plasma spectrum of Ar¹⁶⁺ ions were compared with each other. In this work, the G₃ ratio was measured on the TEXTOR (Julich, Germany) tokamak equipped with high-resolution Bragg spectrometers and other diagnostic instruments. The calculations carried out within the framework of the radiative-collision model using the ATOM, MZ, and GKU programs developed in the Lebedev Physical Institute, Russian Academy of Sciences, are in agreement, to the experimental accuracy, with all the data obtained on the PLT (Princeton, USA), ALCATOR-C (Cambridge, USA), and TEXTOR tokamaks. It is shown that the previously observed factor of 1.3–2 discrepancies between the measured and G₃ values calculated using the HULLAC code and appreciably exceeding the experimental error are caused by the use of inaccurate atomic data and simplified atomic kinetics in those works. The results presented in this work are evidence for the high accuracy of our atomic data (transition rates) and for the possibility of effectively using, on their basis, the K_β lines of multicharged ions in X-ray spectrum diagnostics of electron temperature and density in laboratory and astrophysical coronal plasma sources.     

Electronic energy structure and x-ray spectra of wide-gap AlN and BN crystals and B<Subscript>x</Subscript>Al<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>N solid solutions

The electronic energy structure of 2H and 3C AlN and BN crystals and B_xAl_1?xN solid solutions is calculated on the basis of the local coherent potential method using the cluster version of the MT approximation and the theory of multiple scattering. The features of the electronic structure of 2H-AlN crystals are compared with x-ray K and L absorption and emission spectra of aluminum and nitrogen. An interpretation of these features is given. The concentration dependences of the width of the upper subband of the valence band and the band gap in B_xAl_1?xN solid solutions (x = 0.25, 0.5, 0.75) are investigated. Charge transfer from aluminum to nitrogen atoms is shown to occur and increase with boron doping in both crystallographic modifications.     

Angular-anisotropy coefficients for fragment originating from the resonance-neutron-induced fission of <Superscript>235</Superscript>U oriented nuclei

Statistical distributions of the coefficients measured for the angular distribution of fragments originating from the fission of ²³⁵U oriented nuclei that was induced by resonance neutrons obtained by using booster targets at the electron accelerator in Harwell and at a pulsed reactor in Dubna were approximated by a curve that was calculated under the assumption of a normal distribution of partial-wave fission amplitudes. A cutoff from below at a level of one-half of the average partial-wave width was introduced in this distribution. The calculation was performed with allowance for the K = 0, 1 and 2 channels for J = 3 and the K = 1 and 2 channels for J =4. The contributions of the K channels to the total probability were in the ratio 0.15 : 0.53 : 0.32 for J = 3 and in the ratio 0.625 : 0.375 for J = 4. A strong suppression of the K = 0 channel in the J = 3 spin subsystem in contrast to the situation observed in photofission can be interpreted as an indication of the possible partial conservation of K in resonance states formed from the entrance channel, which features only maximum values of K equal to J and J ? 1.     

Atomic level energies in hafnium

The photo electron method for obtaining electron binding energies is described. The method has been applied to theL _I,L _II, andL _III levels in hafnium. The HfK α₁ and HfK α₂ x-ray emission lines have been measured with a crystal spectrometer. The electron binding energies of theK toO _III shells in hafnium are obtained from photo electron and x-ray emission data. A new type of Moseley diagram is described and is demonstrated for theK andL levels in theZ region 57 to 75. From these diagrams accurate binding energies for the element Pm (Z=61) have been obtained by interpolation.     

Manifestation of a strong quadrupole interaction and peculiarities in the SERS and SEHRS spectra of 4,4'-bipyridine

The paper analyzes Surface Enhanced Raman Scattering (SERS) and Surface Enhanced Hyper Raman Scattering (SEHRS) spectra of 4,4'-bypiridine molecule for two possible geometries, which are described by D ₂ and D _2h symmetry groups. It is pointed out on appearance of sufficiently strong lines, caused by vibrations with the unit irreducible representation for both possible configurations. Appearance of these lines in the SEHRS spectrum points out the existence of a strong quadrupole light-molecule interaction. In addition one observes the lines, caused by vibrations both with the unit irreducible representations A or A _g and the irreducible representation B ₁ or B _1u . The last ones describe transformational properties of the d _z component of the dipole moment, which is perpendicular to the surface. This property of the spectrum is caused by peculiarity of the geometry of the molecule, which consists of two benzene rings, which are weakly connected with each other. The linear combinations of the vibrations of the rings create two nearly degenerated symmetric and anti symmetrical states, which cannot be identified in the experimental spectra. The result is in a full agreement with the dipole-quadrupole theory of SERS and SEHRS.     

Experimental Study and Analysis of Absorption Spectra of Ni<Superscript>2+</Superscript> Ions in Nickel Orthoborate Ni<Subscript>3</Subscript>(BO<Subscript>3</Subscript>)<Subscript>2</Subscript>

The results of studies of the absorption spectra of nickel orthoborate Ni₃(BO₃)₂ in the range of electronic d–d-transitions are reported. The obtained data are analyzed in the framework of the crystal field theory. The Ni²⁺ ions are located in two crystallographically nonequivalent positions 2a and 4f with point symmetry groups C_2h and C₂, respectively, surrounded by six oxygen ions forming deformed octahedra. The absorption spectra exhibit three intense bands corresponding to spin-resolved transitions from the ground state of nickel ion ³A_2g (³F) to the sublevels of the ³T_2g (³F), ³T_1g (³F) and ³T_1g (³P) triplets split by the spinorbit interaction and the rhombic component of the crystal field. At temperatures below 100 K, the spectra exhibit a thin structure, in which phonon-free lines can be distinguished. Comparison of the calculated frequencies of the zero-phonon transitions with the experimental data allows estimating parameters of the crystal field acting on the nickel ions in the 2a- and 4f-positions, as well as the parameters of electrostatic interaction between the 3d electrons and spin-orbit interaction constants.     

Effect of photoions on the line shape of the Förster resonance lines and microwave transitions in cold rubidium Rydberg atoms

Experiments are carried out on the spectroscopy of the Förster resonance lines Rb(37P) + Rb(37P) → Rb(37S) + Rb(38S) and microwave transitions nP → n′S, n′D between Rydberg states of cold rubidium atoms in a magneto-optical trap (MOT). Under ordinary conditions, all spectra exhibit a linewidth of 2–3 MHz irrespective of the interaction time between atoms or between atoms and microwave radiation, although the limit resonance width should be determined by the inverse interaction time. The analysis of experimental conditions has shown that the main source of line broadening is the inhomogeneous electric field of cold photoions that are generated under the excitation of initial nP Rydberg states by broadband pulsed laser radiation. The application of an additional electric-field pulse that rapidly extracts photoions produced by a laser pulse leads to a considerable narrowing of lines of microwave resonances and the Förster resonance. Various sources of line broadening in cold Rydberg atoms are analyzed.     

Specific features of dielectric anomalies in Pb<Subscript>1 − <Emphasis Type="Italic">x</Emphasis></Subscript>Ge<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>Te(Ga) near a ferroelectric phase transition

The dielectric properties of Pb_{1 ? x} Ge _x Te(Ga) (x = 0.02, 0.03, 0.05) were studied in the temperature range 77–150 K at frequencies of 10⁴–10⁶ Hz. It is revealed that the ferroelectric phase transition temperature T _c and the permittivity ? of Pb_{1 ? x} Ge _x Te(Ga) increase substantially with the Ge content. The temperature dependence of the permittivity of Pb_{1 ? x} Ge _x Te shows two peaks; the main peak is at the ferroelectric phase transition temperature T _c , and an additional peak is at T ₁ > T _c .