Simultaneous electrochemical and electron paramagnetic resonance studies of fullerene anion radicals C 60 1− and C 60 3−

Simultaneous electrochemical and electron paramagnetic resonance experiments have been carried out on the reduced C₆₀ fullerene to examine theg-factor assignment of the radical species. C ₆₀ ^1? and C ₆₀ ^3? show the following EPR characteristics at room temperature: C ₆₀ ^1? :g _1?=2.0002±0.0001, 2ΔB _1s=0.17 mT, and C ₆₀ ^3? :g _{3?=2.0008±0.0002}, 2ΔB _1s=0.07 mT. EPR linewidths are apparently narrower compared to those in most of the spectra previously reported. Variable temperature EPR study on solution containing C ₆₀ ^1? has shown thatg _1? value is not while the linewidth is only slightly temperature dependent.     

Electron paramagnetic resonance study of S− and S− 3

Abstract

Two new sulphur are reported in monocristalline rubidiumchloride doped with rubidium and sulphur, and irradiated with X-rays at room temperature. By an extensive comparison with other experimental data on chalcogen centres in alkali halides an interstitial RbCl:S^? and a substitutional RbCl:S^? ₃ model is proposed for these paramagnetic defects. Theoretical calculations confirm the S^? ion model for the former.     

Stochastic resonance in a bias linear system with multiplicative and additive noise

In this paper, the stochastic resonance in a bias linear system subjected multiplicative and additive dichotomous noise is investigated. Using the linear-response theory and the properties of the dichotomous noise, this paper finds the exact expressions for the first two moments and the signal-to-noise ratio (SNR). It is shown that the SNR is a non-monotonic function of the correlation time of the multiplicative and additive noise, and it varies non-monotonously with the intensity and asymmetry of the multiplicative noise as well as the external field frequency. Moreover, the SNR depends on the system bias, the intensity of the cross noise between the multiplicative and additive noise, and the strength and asymmetry of the additive noise.     

High-field electron paramagnetic resonance study of the polymerization in Na2Rb1−x Cs x C60

We report on the study of the magnetic properties of the low-temperature polymer phases in N₂Rb_1?xCs_xC₆₀ at 110 GHz microwave frequency withx varying between 0 and 1. The magnetic and structural properties of the polymer phase strongly depend on the Cs content and its electronic structure progressively becomes quasi-one-dimensional asx is increased. While the electronic properties of the polymeric Na₂RbC₆₀ appear to be close to three-dimensional metal, Na₂Rb_0.3Cs_0.7C₆₀ shows characteristics of quasi-one-dimensional metal where instability in the electronic structure was found as detected by the sudden disappearance of the ESR intensity due to the opening of the gap at the Fermi surface. The observation of an additional resonance line below 15 K, which could be attributed to antiferromagnetic resonance, suggests that the low-temperature polymeric phase in Na₂Rb_0.3Cs_0.7C₆₀ has a well-defined magnetic ground state.     

Theoretical investigation of electron paramagnetic resonance parameters and lattice distortion in α-Al2O3 crystal doped with V3+ ions

The electron paramagnetic resonance parameters D, g _∥ and g _⊥ for V³⁺ ions in α-Al₂O₃ crystals are calculated on the basis of the complete diagonalization method and the superposition model. In the calculation, the contributions of the variation of the cation–ligand bond lengths and bond angles are taken into consideration. The calculated results agree well with the experimental data. Our investigation shows that the local structure around the V³⁺ ions possesses a compressed trigonal distortion above the O^2?-triangle and an elongated trigonal distortion in the lower one.     

Stochastic resonance of a tri-stable system with α stable noise

A tri-stable system excited by weak periodic signal is taken as a model and the stochastic resonance phenomenon is investigated by additive α stable noise in this paper. The laws for the resonance system parameters q, p, skewness parameter r and intensity amplification factor Q of α stable noise to act on the resonant output are explored under different stability indicies α and asymmetric skewness β of α stable noise. The results indicate that a weak signal can be realized by tuning the system parameters q, p and r under the joint action of additive α stable noise, and the interval of q and p which can induce stochastic resonance does not change with α or β. Moreover, a certain rule is found in which adjusting the intensity amplification factor Q of α stable noise can also realize a synergistic effect when studying the noise-induced stochastic resonance, and the interval of Q does not change with α or β; the best value of the characteristic index is $\alpha =1$ under any system parameter, and the best value of the symmetry parameter is $\beta =1$ under any system parameter. So, the system performance is best when $\alpha =1$ and $\beta =1$. The results will contribute to a reasonable selection of parameter-induced stochastic resonance system parameters and noise intensity of noise-induced stochastic resonance under α stable noise.     

The phenomenon of stochastic resonance in a single-mode laser system with an input periodical signal

Using the linear approximation method, we study a single-mode laser system driven by colored pump noise and quantum noise with coupling between the real and imaginary parts when the laser is operated well above threshold. The steady state mean intensity fluctuation C(0) and signal-to-noise ratio (SNR) are calculated. It is found that there is a maximum in SNR when there is a minimum in the fluctuation of laser system if the coupling coefficient between real and imaginary parts of the quantum noise equals zero.     

Dark periods in the resonance fluorescence of a single Λ system

We use the quantum jump method to study the photon statistics of a single laser-driven atom in the configuration where both lower levels are strongly coupled to the common upper level. Under certain conditions we show that, for almost degenerate lower levels, light and dark periods occur which are similar to those of the well-known Dehmelt V system. Analytic results for their mean lengths and other statistical properties are given. For large separation of the lower levels we prove an interesting bunching property by the photons in the resonance fluorescence near the dark resonance. We propose a realistic system for which these effects may be observed.     

Rapid scan electron paramagnetic resonance at 1.0 GHz of defect centers in γ-irradiated organic solids

The radicals in six ⁶⁰Co γ-irradiated solids: malonic acid, glycylglycine, 2,6 di-t-butyl 4-methyl phenol, l-alanine, dimethyl malonic acid, and 2-amino isobutyric acid, were studied by rapid scan electron paramagnetic resonance at L-band (1.04 GHz) using a customized Bruker Elexsys spectrometer and a locally-designed dielectric resonator. Sinusoidal scans with widths up to 18.2 mT were generated with the recently described coil driver and Litz wire coils. Power saturation curves showed that the rapid scan signals saturated at higher powers than did conventional continuous wave signals. The rapid scan data were deconvolved and background subtracted to obtain absorption spectra. For the same data acquisition time the signal-to-noise for the absorption spectra obtained in rapid scans were 23–37 times higher than for first-derivative spectra obtained by conventional continuous wave electron paramagnetic resonance.     

Superposition model in electron magnetic resonance spectroscopy – a primer for experimentalists with illustrative applications and literature database

We review applications of the superposition model (SPM) in EMR area, which enables semi-empirical modeling of zero-field splitting (ZFS) parameters (ZFSPs) for transition ions in crystals by separation of geometrical and physical information. Nomenclature used for ZFS and crystal field (CF) Hamiltonians is presented to expose common framework underlying two independent implementations: SPM/ZFS and SPM/CF, which require distinct model parameters. SPM/ZFSP applications in EMR area for S-state 3d⁵ (4f⁷) ions and 3d^N ions with orbital singlet ground state are reviewed. SPM/ZFS methodology for ML_n complexes [central metal (M) ion surrounded by n ligands (L)] with specific symmetry is presented. SPM-related computer packages combined with other methods, role of axis systems in SPM analysis, and structural models for several ion-host systems, are discussed. Extensive survey of SPM/ZFS applications is provided to elucidate usefulness of SPM modeling for interpretation of ZFSPs. This review is geared for EMR practitioners interested in practical utilization of SPM/ZFS (or SPM/CFP) analysis. Database of SPM/ZFS references is compiled for studies of single molecule magnets and single ion magnets based on transition ions. Due to its comprehensiveness, suitable sets of model parameters required for practical utilization SPM/ZFS may be easily located using source references as pointers.     

An algebraic geometry study of theb−c system with arbitrary twist fields and arbitrary statistics

We present an analysis of the generalb–c system (including the – system) on a compact Riemann surface of arbitrary genusg0 by postulating that its correlation functions should only have the singularities imposed by the operator product expansion (OPE) of the system. Studying a very (in fact optimally) general form of theb–c system, we prove rigorously that the standard practice of eliminating zero modes, and even the standard lagrangian, follow from the analyticity structure dictated by the OPE alone. We extend the analysis to consider the most general case of the presence of twist (e.g. spin) fields. We then determine all the possible correlation functions of theb–c system, with statistics unspecified, compatible with the OPE. On imposing Fermi and Bose statistics, we obtain the correlation functions of the fermionicb–c and – systems, respectively.     

Persistent current and the existence of a metallic phase flanked by two insulating phases in a quantum ring with both electron–electron and electron–phonon interactions

The persistent current in the ground state of a quantum ring threaded by a magnetic flux is calculated within the framework of the Holstein-Hubbard model. It is found that the persistent current is suppressed by both the electron–electron and electron–phonon interactions. Calculation of Drude weight reveals that the persistent current is diamagnetic in nature. It is observed that as the number of atoms in the quantum ring increases, the persistent current decays in a continuous way. It is finally predicted that there exists an intervening metallic phase flanked in real time by two insulating phases, the SDW phase and the CDW phase.     

Modeling and design of a magnetic resonance mass spectrometer with a resolution of ∼ 106

The equations of motion for a charged particle in crossed magnetic and electric fields are used to make a numerical simulation of the operation of a magnetic resonance mass spectrometer for which the ion trajectory in the analyzer is divided into various sections. The calculations take into account the real structural dimensions and the parameters of the main components and systems and also allow for its operating characteristics in various regimes, as obtained by investigating a prototype. The calculation s yield the optimum geometric, electrical, frequency, phase, and magnetic parameters of the device, for which one can achieve a resolution R ₅₀₉₆≈1.35×10⁶ and a current efficiency K _I ≈0.006. Zh. Tekh. Fiz. 69, 89–96 (April 1999)     

High-resolution electron microscopy and X-ray diffraction study of intergrowth structures in α- and β-type YbAlB4 single crystals

Structural features of layered boride YbAlB₄ single crystals with YCrB₄-type (α-type) and ThMoB₄-type (β-type) phases derived from a hexagonal AlB₂-type structure were investigated by electron diffraction, high-resolution electron microscopy and X-ray diffraction. X-ray diffraction experiments indicate the existence of some structural motifs. High-resolution images clearly show that the structural motifs build the intergrown lamellar structures in the matrix. The lamellar structures can be characterized by a coherent tiling of deformed Yb hexagons, which are a common structure unit in the α- and β-type structures. The characteristic intergrown nanostructure is similar to that observed in the β-type TmAlB₄ polycrystalline sample.     

Experimental study of nuclear fusion reactions in a ptμ system

By means of muon catalysis we study the phenomena in a pt-fusion, which have been previously investigated in the only experiment and now are at the frontier of nuclear few-body physics. The experiment is aimed at measuring the yields of the reaction products: ??-quanta, conversion muons and e ⁺ e ^? pairs. As a result we plan to measure the pt-fusion partial product yields (first time for e ⁺ e ^? pairs) with accuracy not worse than 10%, and this will enable us to obtain the nuclear reaction rates in M1 and E0 transitions in A = 4 system.     

Influence of the net gain on characteristic of stochastic resonance in a single-mode laser system

The phenomenon of stochastic resonance (SR) is found in a single-mode laser system driven by the colored pump noise with signal modulation and the quantum noise with cross-correlation between the real and imaginary parts. When the net gain a0 changes, it is found that, 1) the shape of the curve of the signal-to-noise ratio (SNR) versus the pump noise self-correlation time τ exhibits a changing process of multiform SR, from single-peak SR, to simultaneous existence of resonances and suppressions; 2) the curve of SNR. versus signal frequency Ω experiences a complicated changing process from the monotonous descending to the simultaneous appearances of a maximum and a minimum, and finally to monotonous descending; 3) the curve of SNR versus cross-correlation coefficient between the real and imaginary parts of the quantum noise λq appears an acute single-peak SR. Therefore, the net gain ao greatly influences the characteristic of SR of laser system.