带有分数阶阻尼的压电能量采集系统相干共振

研究了含分数阶阻尼的双稳态能量采集系统的相干共振. 建立了带有分数阶阻尼的轴向受压梁压电能量采集系统动力学模型. 对于分数阶方程, 采用Euler-Maruyama-Leipnik方法进行求解, 计算了不同阻尼阶数下的能量采集系统的信噪比、响应均值、跃迁数目等统计物理量. 结果表明: 此压电能量采集系统在随机激励下可以实现相干共振, 阻尼阶数对相干共振的临界噪声强度和相干共振幅值有很大影响. 关键词： 分数阶阻尼 随机激励 能量采集系统 相干共振     

随机激励下双稳态压电俘能系统的相干共振及实验验证

随着压电晶体材料的迅速发展, 基于压电效应的能量采集系统是俘获环境中的宽带随机振动能量的一种有效途径. 研究了有限宽带随机激励作用下, 磁斥力双稳态压电俘能系统的相干共振俘能机理, 并进行了实验验证. 运用Euler-Maruyama方法求解了随机非线性压电振动耦合方程, 比较分析了相干共振发生前后系统的动力学特性和俘能效率, 然后基于Kramers逃逸速率解释了相干共振. 最后的随机振动实验结果验证了双稳态压电俘能系统的相干共振俘能机理. 并且观察到: 当相干共振发生时, 系统会在两个势能阱之间剧烈运动, 此时宽带随机振动能量会被转化为大幅值窄带低频振动响应, 从而极大地提高了宽带随机振动能量的俘获效率.     

CdTe量子点-铜酞菁复合体系荧光共振能量转移的研究

以波长为780 nm、重复频率为76 MHz、脉宽为130 fs的飞秒激光作为激发光源, 采用超快时间分辨光谱技术研究了CdTe量子点-铜酞菁复合体系的荧光共振能量转移. 实验结果表明, 在780 nm的双光子激发条件下, 复合体系中CdTe量子点的荧光寿命随着铜酞菁溶液浓度的增加而减少, 荧光共振能量转移效率增加. 同时也研究了激发功率对荧光共振能量转移效率的影响. 结果表明, 随着激发光功率的增加, 复合体系溶液中CdTe量子点的荧光寿命增加, 荧光共振能量转移效率减小, 其物理机理是因为高激发功率下的热效应和由双光子诱导的高阶激发态的跃迁. 当激发光功率为200 mW时, 双光子荧光共振能量转移效率为43.8%. 研究表明CdTe量子点-铜酞菁复合体系是非常有潜力的第三代光敏剂.     

聚二甲基硅氧烷微流道中光流控荧光共振能量转移激光

将单一折射率的石英裸光纤植入由聚二甲基硅氧烷构成的基片微流道中,以低折射率的罗丹明B(RhB)和吡啶821(LDS821)乙醇溶液构成的供体和受体对作为激光增益介质.采用沿光纤轴向消逝波抽运方式,首先以波长为532nm的连续波激光器作为激励光,对荧光共振能量转移特性参数进行了研究.然后以波长为532nm的脉冲激光器作为抽运光,通过直接激励供体分子RhB,并将其能量转移给临近的受体分子LDS821,在不改变抽运光波长的条件下,实现了较低阈值(1.26μJ/mm~2)的受体LDS821激光辐射.     

The influence of collision energy on magnetically tuned 6Li-6Li Feshbach resonance

The effect of collision energy on the magnetically tuned $^{6}$Li-$^{6}$Li Feshbach resonance (FR) is investigated theoretically by using the coupled-channel (CC) method for the collision energy ranging from 1 μ$ {\rm K} \cdot {k}_{\rm B}$ to 100 μ$ {\rm K} \cdot {k}_{\rm B}$. At the collision energy of 1 μ$ {\rm K} \cdot {k}_{\rm B}$, the resonance positions calculated are 543.152 Gs (s wave, the unit $1 {\rm Gs}=10^{-4} {\rm T}$), 185.109 Gs (p wave $|m_{l}| = 0$), and 185.113 Gs (p wave $|m_{l}| = 1$), respectively. The p-wave FR near 185 Gs exibits a doublet structure of 4 mGs, associated with dipole-dipole interaction. With the increase of the collision energy, it is found that the splitting width remains the same (4 mGs), and that the resonance positions of s and p waves are shifted to higher magnetic fields with the increase of collision energy. The variations of the other quantities including the resonance width and the amplitude of the total scattering section are also discussed in detail. The thermally averaged elastic rate coefficients at $T=10$, 15, 20, 25 K are calculated and compared.     

悬臂梁压电振子宽带低频振动能量俘获的随机共振机理研究

研究了利用系统非线性来提高悬臂梁压电振子宽带低频振动能量俘获效率的随机共振机理,通过增加一对矩形永磁铁对传统线性悬臂梁压电振子结构进行了改进,结果揭示:在外部非线性磁力作用以及合适的磁铁间距条件下,这种外加磁力悬臂梁压电振子会构成一个双稳系统,在外部宽带低频随机振动源激励下发生随机共振现象,且发生随机共振时的输出电压明显增大,从而可以扩展悬臂梁压电振子的共振频率范围、提高低频振动能量的转化输出. 关键词： 压电悬臂粱 振动能量俘获 宽带低频 随机共振     

Fluorescence resonance energy transfer: FRET studies of ligand binding to cell surface receptors

We describe a simple optical system employing fluorescence resonance energy transfer (FRET) to identify potential binding domains on the macrophage scavenger receptor for the ligand maleylated bovine serum albumin (mal-BSA). Using a plasma membrane vesicle system, we placed donor probes on the ligand and acceptor probes in the membrane to determine the distance of bound ligand from the cell surface. Two donors and three acceptors were employed. Transfer between ligand covalently modified with multiple dansyl molecules and hexadecanoylaminoeosin in the membrane yielded a distance of 46.5 ± 7.5 å; transfer from the same type of donors to octadecylrhodamine B in the membrane gave a distance of 58.5 ± 3.0 å. No transfer was observed between ligand mono-labeled with fluorescein and l,l′-dioctadecyl-3,3,3′,3′-tetramethylindocarbocyanineperchlorate in the membrane. This suggests that the orientation of mal-BSA bound to the receptor places the fluorescein probe too far from the lipid surface to experience energy transfer. The distance information identifies a potential location for the binding site, which can be compared to structural information about the receptor and used to extract a binding sequence.     

两原子相干共振能量传递的单次与N次能量提取

两原子间隔一定距离且两原子跃迁频率接近时,两原子之间可发生能量传递.理论研究了供能原子和受能原子两共振原子的能量传递.求解薛定谔方程得出两原子共振能量传递效率.结果表明,供能原子在真空场中的激发态寿命在能量传递效率中起到十分重要的作用.能量传递效率与两原子间距离的负三次幂的正弦值的平方成正比,在一阶近似条件下,与两原子间距离的6次方成反比.以供能原子处于激发态时为初始时刻,能量从初始时刻随时间由供能原子向受能原子传递,对受能原子的单次能量提取的最大值大约在供能原子寿命的2/3时刻;对受能原子的连续N次能量提取的最大值,每次提取时间大约在供能原子寿命的1/2时刻.     

Generalized energy detector for weak random signals via vibrational resonance

In this paper, the generalized energy (GE) detector is investigated for detecting weak random signals via vibrational resonance (VR). By artificially injecting the high-frequency sinusoidal interferences into an array of GE statistics formed for the detector, we show that the normalized asymptotic efficacy can be maximized when the interference intensity takes an appropriate non-zero value. It is demonstrated that the normalized asymptotic efficacy of the dead-zone-limiter detector, aided by the VR mechanism, outperforms that of the GE detector without the help of high-frequency interferences. Moreover, the maximum normalized asymptotic efficacy of dead-zone-limiter detectors can approach a quarter of the second-order Fisher information for a wide range of non-Gaussian noise types.     

Search for singlet-triplet bistability or biradicaloid properties in polycyclic conjugated hydrocarbons: a valence-bond analysis

Two classes of molecules displaying singlet-triplet biradical bistability (i.e. species having significant biradicaloid properties) can be designed as follows. Alternant conjugated polycyclic hydrocarbons with numerous fixed double bonds (double bonds that remain unchanged in all its Kekulé resonance structures), a large number of Dewar resonance structures which measures the corresponding diradical resonance, and a small HOMO-LUMO band gap which measures the ease of thermal spin inversion are candidates for singlet triplet biradical bistability. Chichibabin's hydrocarbon ( 1 ) is an example. In addition, in the search for candidate molecules having singlet triplet bistability, one should also examine polycyclic conjugated systems having nonalternant induced spin frustration. Spin frustrated nonalternant polycyclic conjugated hydrocarbons will display singlet-triplet bistability (biradicaloid properties) and are generated from alternant valence-bond diradicals or Hückel molecular orbital diradicals having classical Kekulé structures by appropriate intramolecular joining of two starred or nonstarred positions with bonds, respectively.     

四稳系统的双重随机共振特性

提出了一类8次势函数并讨论了其分岔特性,得到由左、右2个小尺度双稳势和中间势垒构成的对称四稳系统.建立了在周期力和随机力共同作用下四稳系统输出响应的近似解析表达式,并从能量角度引入功这一过程量来刻画大、小不同尺度双稳势之间的作功能力,发现四稳势中存在着双重随机共振现象.理论分析与数值仿真结果表明,当中间势垒高度大于左右2个小尺度双稳势的势垒高度时,四稳系统的响应随着噪声强度的变化由束缚在小尺度双稳系统中做小幅振动转变为跨越中间势垒的大幅振动,功随噪声强度的变化出现了双峰曲线,存在着双重随机共振,且小尺度随机共振能增强大尺度随机共振的效应.     

Thermal effects on parallel resonance energy of whistler mode wave

In this short communication, we have evaluated the effect of thermal velocity of the plasma particles on the energy of resonantly interacting energetic electrons with the propagating whistler mode waves as a function of wave frequency and L-value for the normal and disturbed magnetospheric conditions. During the disturbed conditions when the magnetosphere is depleted in electron density, the resonance energy of the electron enhances by an order of magnitude at higher latitudes, whereas the effect is small at low latitudes. An attempt is made to explain the enhanced wave activity observed during magnetic storm periods.     

Eigenvectors of the multichannel scattering matrix at resonance energy values

Explicit representations for the T matrix and the scattering matrix analytically continued to unphysical energy sheets in a multichannel problem featuring binary channels are discussed. From these representations, it follows that a resonance on a given unphysical sheet arises at the (complex) energy value for which the appropriately truncated scattering matrix considered on the physical sheet has zero eigenvalue. It is shown that the channel components of that eigenvector of the truncated scattering matrix which corresponds to zero eigenvalue at a resonance energy value have the meaning of breakup amplitudes for the respective resonance state of the multichannel system being considered.     

An application of stochastic resonance for energy harvesting in a bistable vibrating system

The application of stochastic resonance to mechanical energy harvesting is currently of topical interest, and this paper concentrates on an analytical and experimental investigation in which stochastic resonance is deliberately exploited within a bistable mechanical system for optimised energy harvesting. The condition for the occurrence of stochastic resonance is defined conventionally by the Kramers rate, and the modelling of a theoretical nonlinear oscillator driven by a small periodic modulating excitation and a harvestable noise source, which, together satisfy this condition, is developed in the paper. A novel experiment is also discussed which validates this particular form of stochastic resonance, showing that the response can indeed be amplified when the frequency of the weak periodic modulating excitation fulfills the correct occurrence condition. The experimental results indicate that the available power generated under this condition of stochastic resonance is noticeably higher than the power that can be collected under other harvesting conditions.     

Fluorescence resonance energy transfer from TX-100 to 3-acetyl-4-oxo-6,7-dihydro-12H-indolo-[2,3-a]quinolizine in premicellar and micellar environments

Fluorescence (Förster) resonance energy transfer (FRET) from the phenyl groups of the non-ionic triton X-100 (TX-100) micelles to a potent bioactive molecule 3-acetyl-4-oxo-6,7-dihydro-12H-indolo-[2,3-a] quinolizine (AODIQ) has been studied using steady state absorption and fluorescence techniques. High values of Stern–Volmer constants (K_SV) suggest that a long-range dipole–dipole interaction is operative for the energy transfer mechanism. From the analysis of the quenching of the donor fluorescence the energy transfer efficiency (E) has been determined in both premicellar and micellar environments. Experimental results reveal that the energy transfer process is more efficient in the micellar environment compared to the premicellar situation.     

Diffusion-enhanced resonance energy transfer shows that linker-DNA accessibility decreases during salt-induced chromatin condensation

Accessibility of linker-DNA chromatin during salt-induced condensation of chicken erythrocytes chromatin was studied by diffusion-enhanced resonance energy transfer. A terbium complex was covalently bound to linker-DNA and fluorescein molecules bound to latex particles with diameters ranging from 14 to 2470 nm were used as acceptor. The accessibility of linker-DNA to molecules with a diameter superior to 14 nm diminished during condensation, but for an acceptor diameter of 14 nm or less, no accessibility variation was observed. It can be concluded that (1) linker-DNA is located inside the fiber when chromatin is in the condensed state, (2) chromatin condensation can prevent the approach to DNA due to steric hindrance, (3) salt-induced chromatin condensation is a gradual process, and (4) condensed chromatin models containing a central cavity are more likely.Abbreviations DTPA diethylene tetramine pentacetic acid - FDL-DERET fast diffusion limit of diffusion-enhanced resonance energy transfer - Pso-Tb psoralen-terbium complex - PAS paraamino salicylic acid - TREF time-resolved emission of fluorescence     

双稳随机共振参数特性的研究

以双稳系统为研究对象，探讨了影响和产生双稳随机共振的参数选择特性.双稳系统参数和二次采样频率参数有着内在的物理联系，它们的改变都会引起势垒、势阱间距和粒子跃迁速率的改变，并使噪声能量相对重新分配，进而影响随机共振效果.根据随机共振的参数选择规律，可通过适当的参数选择来得到最佳的随机共振状态，为后续数据处理奠定基础.     

Dependence of resonance energy transfer on exciton dimensionality

We investigate the dependence of resonance energy transfer from Wannier-Mott excitons to an organic overlayer on exciton dimensionality. We exploit the excitonic potential disorder in a single quantum well to tune the balance between localized and free excitons by scaling the Boltzmann distribution of excitons through temperature. Theoretical calculations predict the experimentally observed temperature dependence of resonance energy transfer and allow us to quantify the contribution of localized and free excitons. We show that free excitons can undergo resonance energy transfer with an order of magnitude higher rate compared to localized excitons, emphasizing the potential of hybrid optoelectronic devices utilizing resonance energy transfer as a means to overcome charge transfer related limitations.     

Effects of energy spread on brightness and coherence of undulator sources

The (spectral) brightness for partially transverse coherent sources such as synchrotron radiation and free‐electron laser sources can be defined as the maximum of the Wigner distribution. Then, the brightness includes information on both coherence and wavefront characteristics of the radiation field. For undulator sources, it is customary to approximate the single‐electron electric field at resonance with a Gaussian beam, leading to great simplifications. Attempts to account for the modified spatial and angular profile of the undulator radiation in the presence of detuning due to energy spread, currently build on the simplified brightness expression derived under the assumption of Gaussian beams. The influence of energy spread on undulator radiation properties is becoming important in view of diffraction‐limited rings with ultralow emittance coming on‐line. Here the effects of energy spread on the brightness of undulator radiation at resonance are discussed, as well as relevant relations with coherence properties.     

Pyrene excitation via resonance energy transfer from protein tryptophan reveals a fluidity gradient in liver microsomes

Membrane fluidity measurements based on excimer formation of pyrene and pyrene derivatives as a measure of lateral diffusion yield a decreased fluidity in the presence of proteins [1,2]. It was the aim of our study to investigate whether the reduced excimer formation is due to a rigidifying effect of proteins on the whole membrane or if the fluorophore mobility is hindered mainly in the immediate protein environment. Resonance energy transfer in microsomal membranes between intrinsic tryptophan residues and pyrene was used to study the excimer formation rate in the vicinity of proteins. The excimer-to-monomer fluorescence ratio after excitation via resonance energy transfer decreased compared to that observed for the direct excitation. The results suggest that, because of the reduced fluidity in the neighborhood of proteins, pyrene and pyrenedodecanoic acid do not diffuse homogeneously in the membrane plane.