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1.
V. R. Galakhov M. Neumann D. G. Kellerman 《Applied Physics A: Materials Science & Processing》2009,94(3):497-500
X-ray absorption, resonant X-ray emission, and X-ray photoelectron spectroscopical methods have been applied for the study
of the electronic structure of defective lithium cobaltites Li
x
CoO2 (0.6≤x≤1.0). Resonant O K
α X-ray emission spectra of LiCoO2 showed localized excitonic states due to a dd transition between occupied and unoccupied Co 3d states. On the base of measurements of Co 3s X-ray photoelectron, Co 2p, and O 1s X-ray absorption spectra, it was established that in defective cobaltites the electronic holes are localized mainly in O
2p states. An evidence of phase separation in Li
x
CoO2 has been found. It was shown that the semiconductor-to-metal transition in Li
x
CoO2 (x<0.76) at about 160 K is not accompanied by changes in the Co 3d electronic configuration which remains 3d
6. 相似文献
2.
The exciton absorption spectra of thin films of (Cs1 − x
Rb
x
)2CdI4 solid solutions have been investigated and the refractive index n(λ) in their transparency window in the concentration range of 0 ≤ x ≤ 1 has been measured. The exciton-band parameters and optical permittivity ɛ∞(x) have been found to linearly depend on the concentration. It is established that excitons are incorporated into the CdI2 sublattice of the solid solutions and belong to intermediate-coupling ones. The characteristics of excitons in ferroelastics
are compared with the corresponding parameters for CdI2, RbI, and CsI, which are used as components to synthesize ternary compounds. 相似文献
3.
The preparation of (La9.33−2x/3Sr
x
□0.67−x/3)Si6O24O2 (0 ≤ x ≤ 2) samples with different amounts of cation vacancies is reported. Structure and unit-cell parameters were deduced by Rietveld
analysis of XRD patterns. Structural features that enhance oxygen conductivity in Sr-doped apatites are discussed. Up to three
components were detected in 29Si MAS-NMR spectra which change with the amount and distribution of cation vacancies. In general, oxygen conductivity increases
with the amount of vacancies at La1 (6h) sites, passing through a maximum for x = 0.4. In the case of activation energy, a minimum is detected near x = 1.2, indicating that entropic and enthalpic change in different ways. The presence of cation vacancies should enhance oxygen
hopping along c-axis; however, the analysis of the frequency dependence of conductivity suggests that oxygen motions are produced along three
axes. 相似文献
4.
The Raman spectra of the (GaN)129, (SiO2)86, and (GaN)54(SiO2)50 nanoparticles were calculated using the molecular dynamics method. The spectrum of (SiO2)86 had three broad bands only, whereas the Raman spectrum of (GaN)129 contained a large number of overlapping bands. The form of the Raman spectrum of (GaN)54(SiO2)50 was determined by the arrangement of the GaN and SiO2 components in it. The nanoparticle with a GaN nucleus had a continuous fairly smooth spectrum over the frequency range 0 ≤ ω ≤ 600 cm−1, whereas the spectrum of the nanoparticle with a SiO2 nucleus contained well-defined bands caused by vibrations of groups of atoms of different kinds and atoms of the same kind. 相似文献
5.
We have investigated a set of sodium cobaltates (Na
x
CoO2) samples with various sodium content (0.67 ≤ x ≤ 0.75) using Nuclear Quadrupole Resonance (NQR). The four different stable phases and an intermediate one have been recognized.
The NQR spectra of 59Co allowed us to clearly differentiate the pure phase samples which could be easily distinguished from multi-phase samples.
Moreover, we have found that keeping samples at room temperature in contact with humid air leads to destruction of the phase
purity and loss of sodium content. The high sodium content sample evolves progressively into a mixture of the detected stable
phases until it reaches the x = 2/3 composition which appears to be the most stable phase in this part of phase diagram. 相似文献
6.
A comparative investigation of the magnetic properties of amorphous nanogranular composites (Co41Fe39B20)
x
(SiO
n
)100 − x
and (Co86Nb12Ta2)
x
(SiO
n
)100 − x
has been performed in the subpercolation region at temperatures in the range 4.2–300 K. The thermomagnetic dependences in
the range 4.2–300 K and the processes of magnetization reversal and remanent magnetization relaxation at liquid-helium temperatures
have been studied. It has been established that the average anisotropy constants of amorphous nanograins are equal to 3.6–7.0
kJ/m3 for the (Co41Fe39B20)
x
(SiO
n
)100 − x
composites and 5–8 kJ/m3 for the (Co86Nb12Ta2)
x
(SiO
n
)100 − x
composites. The fundamental differences in the concentration dependences of the anisotropy constant K
eff and the coercive force H
C
have been revealed for the two systems under investigation. It has been demonstrated that, as the concentration of the metal
phase increases, the quantities K
eff and H
C
increase for the (Co86Nb12Ta2)
x
(SiO
n
)100 − x
composites and decrease for the (Co41Fe39B20)
x
(SiO
n
)100 − x
composites. 相似文献
7.
A. V. Okotrub L. G. Bulusheva A. G. Kudashov V. V. Belavin D. V. Vyalikh S. L. Molodtsov 《Applied Physics A: Materials Science & Processing》2009,94(3):437-443
Arrays of vertically aligned nitrogen-doped carbon (CN
x
) nanotubes have been synthesized by decomposition of aerosol mixture of acetonitrile and ferrocene at 850°C. Nitrogen concentration
in the outer shells of the CN
x
nanotubes was found from X-ray photoelectron spectroscopy (XPS) data to reach ∼6%. The XPS N 1s spectra and N 1s near-edge X-ray absorption fine structure (NEXAFS) spectra identified three chemical forms of nitrogen in the CN
x
nanotube arrays: pyridine-like, graphitic, and molecular nitrogen. The π
* resonance of molecular nitrogen showed clear polarization dependence that indicates predominant orientation of N2 molecules along the nanotubes axis. The estimated range of the polar angle distribution of the N2 molecules orientation in the CN
x
nanotube array amounts to 15°. 相似文献
8.
A. V. Boryakov S. I. Surodin D. E. Nikolichev A. V. Ershov 《Physics of the Solid State》2017,59(6):1206-1214
The chemical and the phase compositions of multilayer nanoperiodic SiO x /ZrO2 structures prepared by vacuum evaporation from separated sources and subjected to high-temperature annealing have been studied by X-ray photoelectron spectroscopy with a layer-by-layer etching. It is found that, under deposition conditions used, the silicon suboxide layers had the stoichiometric coefficient x ~1.8 and the zirconium-containing layers were the stoichiometric zirconium dioxide. It was found, using X-ray photoelectron spectroscopy, that annealing of the multilayer structures at 1000°C leads to mutual diffusion of the components and chemical interaction between ZrO2 and SiO x with predominant formation of zirconium silicate at heteroboundaries of the structures. The SiO x layers of the annealed nanostructures contained ~5 at % elemental silicon as a result of the phase separation and the formation of fine silicon nanocrystals. 相似文献
9.
Lei Shi Jiang Yin Kuibo Yin Feng Gao Yidong Xia Zhiguo Liu 《Applied Physics A: Materials Science & Processing》2008,90(2):379-384
As potential gate dielectric materials, pseudobinary oxide (TiO2)x(Al2O3)1-x (0.1≤x≤0.6) films (TAO) were deposited on Si (100) substrates by pulsed-laser deposition method and studied systematically
via various measurements. By a special deposition process, including two separate steps, the TAO films were deposited in the
form of two layers. The first layer was deposited at room temperature and the second layer was completed at the substrate
temperature of 400 °C. Detailed data show that the properties of the TAO films are closely related to the ratio between TiO2 and Al2O3. The existence of the first layer deposited at room temperature can effectively restrain the formation of the interfacial
layer. And according to the results of X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy
performed on the films, no other information belonging to the silicon oxide could be observed. For the (TiO2)0.4(Al2O3)0.6 film, the best result has been achieved among all samples and its dielectric constant is evaluated to be about 38. It is
valuable for the amorphous TAO film as one of the promising dielectric materials for high-k gate dielectric applications.
PACS 77.55.+f; 73.40.Qv; 81.15.Fg 相似文献
10.
Ruiting Sun Xiaoli Wang Jing Shi Le Wang 《Applied Physics A: Materials Science & Processing》2011,104(1):129-133
New perovskite solid solution ceramics of (1−x)BaTiO3-xBi(Mg1/2Ti1/2)O3 ((1−x)BT-xBMT, x≤0.09) were synthesized by the solid-state reaction technique. X-ray diffraction studies have revealed a stable single perovskite
structure for all samples. Dielectric measurements were carried out at different frequencies and temperatures. The polarization
evolutions with temperatures were measured to investigate the ferroelectric properties. All the compositions show features
of ferroelectrics with diffuse phase transition, though the temperature T
m
of their dielectric constant maximum ε
m
is frequency dependent. The dielectric constant peak ε(T) of (1−x)BT-xBMT ceramics become broad with increasing BMT content. During the temperature range of ε(T) peak summit, (1−x)BT-xBMT ceramics present quasi-linear dielectric phenomenon under high electric field with very high dielectric constant. 相似文献
11.
S.-A. Ku C.-W. Luo H.-L. Lio K.-H. Wu J.-Y. Juang A. I. Potekaev O. P. Tolbanov S. Yu. Sarkisov Yu. М. Andreev G. V. Lanskii 《Russian Physics Journal》2008,51(10):1083-1089
Transmission spectra and phase matching conditions for second harmonic generation in GaSe1–x
S
x
(0 < x ≤ 0.4) solid solution crystals are experimentally investigated. An algorithm is suggested and dispersion equations are derived
that allow the phase matching angles describing best the available experimental data to be estimated as a function of the
mixing ratio x.
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 80–85, October, 2008. 相似文献
12.
Magnetic and kinetic properties as well as transmission and absorption spectra of Hg
1−x−y
Mn
x
Fe
ySe (0.09 ≤ x ≤ 0.099 and 0.001 ≤ y ≤ 0.01) crystals are investigated at H ≈ 0.5–6 kOe in the temperature range T = 77–300
K. The band parameters are determined on the basis of experimental data. It is found that in the crystals under study at T
≈ 300 K, electron scattering by polar optical phonons dominates, direct optical band-to-band transitions occur, and replacement
of a part of Mn atoms by Fe for x + y = 0.1 results in an increase in Eg
op with Fe content.
__________
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 35–39, March, 2007. 相似文献
13.
A. M. Pashaev B. G. Tagiev O. B. Tagiev Kh. B. Ganbarova 《Journal of Applied Spectroscopy》2011,78(2):266-271
We have ground bulk samples to obtain nanoparticles of (Ga2S3)1–x
(Eu2O3)
x
solid solutions, the sizes of which were determined using an atomic force microscope. The photoluminescence spectra of the
nanoparticles were studied in the temperature interval 77–300 K. We have established the mechanisms for emission and transfer
of energy from the matrix to the rare-earth ion, and we determined the Stokes shift (ΔS = 0.7 eV), the Huang–Rhys parameter
(S = 16), and the optical phonon energy (ħ−ω = 23 meV). 相似文献
14.
A. N. Veis 《Russian Physics Journal》2008,51(7):714-717
Spectra of optical absorption in Bi0.5Sb1.5Te3 films grown on mica and KBr substrates have been investigated for T = 145 and 300 K. The data obtained have been analyzed
together with the data of investigations on the fundamental absorption edge for Bi2Te3 available in the scientific literature. It has been revealed that the interband absorption spectra for both Bi0.5Sb1.5Te3 and Bi2Te3 represent a superposition of two components corresponding to direct and indirect allowed optical transitions. In this case,
the least energy gap separating the valence band and the conduction band is direct for Bi2−xSbxTe3 (x ≤ 1.5, T = 300 K). For Bi0.5Sb1.5Te3 the temperature variation rates have been estimated for the thresholds of direct and indirect interband transitions. It has
been shown that this solid solution is direct gap solution at T ≥ 145 K.
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 50–52, July, 2008. 相似文献
15.
V. A. Kulbachinskii V. G. Kytin P. M. Tarasov N. A. Yuzeeva 《Physics of the Solid State》2010,52(9):1830-1835
The effect of Ga doping on the temperature dependences (5 K ≤ T ≤ 300 K) of the Seebeck coefficient α, electrical conductivity σ, thermal conductivity coefficient κ, and thermoelectric
figure of merit Z of p-(Bi0.5Sb0.5)2Te3 single crystals has been investigated. It has been shown that, upon Ga doping, the hole concentration decreases, the Seebeck
coefficient increases, the electrical conductivity decreases, and the thermoelectric figure of merit increases. The observed
variations in the Seebeck coefficient cannot be completely explained by the decrease in the hole concentration and indicate
a noticeable variation in the density of states due to the Ga doping. 相似文献
16.
J. R. Suárez F. Estrada O. Navarro M. Avignon 《The European Physical Journal B - Condensed Matter and Complex Systems》2011,84(1):53-58
We have studied the effect of cationic disorder on the spin polarization of the double
perovskite system
Sr2Fe1+x
Mo1−x
O6
with −1 ≤ x ≤ 1/3. The composition x = 0 corresponds
to the well-known double-perovskite Sr2FeMoO6, which is expected to
have complete spin polarization, however all samples present some degree of Fe/Mo disorder
which reduces the tunneling magnetoresistance in granular samples. We consider an
electronic model within the renormalized perturbation expansion Green’s functions,
consisting in a correlated electron picture with localized Fe-ions and itinerant electrons
interacting with the local spins via a double-exchange type mechanism. Our results show
the influence of disorder on the density of states and the ground-state properties,
particularly on the spin polarization over the whole range of x. 相似文献
17.
R. M. Shymkiv S. A. Sveleba I. V. Karpa I. N. Katerynchuk I. M. Kunyo E. I. Phitsych 《Journal of Applied Spectroscopy》2012,78(6):823-828
Optical absorption spectra in thin [N(CH3)4]2CuCl4 crystals in the thickness range 10 μm ≤ d < 100 μm have been studied. Strengthening of the crystal field has been found with
a decrease in the [N(CH3)4]2CuCl4 crystal size. The reasons for absorption band shifts in the visible region depending on the [N(CH3)4]2CuCl4 crystal thickness and the manifestation of a size effect in crystals with an incommensurate superstructure are discussed. 相似文献
18.
Pramod Bhatt E. Carlegrim A. Kanciurzewska M. P. de Jong M. Fahlman 《Applied Physics A: Materials Science & Processing》2009,95(1):131-138
Thin film iron-tetracyanoethylene Fe(TCNE)
x
, x∼2, as determined by photoelectron spectroscopy, was grown in situ under ultra-high vacuum conditions using a recently developed
physical vapor deposition-based technique for fabrication of oxygen- and precursor-free organic-based molecular magnets. Photoelectron
spectroscopy results show no spurious trace elements in the films, and the iron is of Fe2+ valency. The highest occupied molecular orbital of Fe(TCNE)
x
is located at ∼1.7 eV vs. Fermi level and is derived mainly from the TCNE− singly occupied molecular orbital according to photoelectron spectroscopy and resonant photoelectron spectroscopy results.
The Fe(3d)-derived states appear at higher binding energy, ∼4.5 eV, which is in contrast to V(TCNE)2 where the highest occupied molecular orbital is mainly derived from V(3d) states. Fitting ligand field multiplet and charge
transfer multiplet calculations to the Fe L-edge near edge X-ray absorption fine structure spectrum yields a high-spin Fe2+ (3d6) configuration with a crystal field parameter 10Dq∼0.6 eV for the Fe(TCNE)
x
system. We propose that the significantly weaker Fe-TCNE ligand interaction as compared to the room temperature magnet V(TCNE)2 (10Dq∼2.3 eV) is a strongly contributing factor to the substantially lower magnetic ordering temperature (T
C
) seen for Fe(TCNE)
x
-type magnets. 相似文献
19.
A series of solid solutions with a general formula of Ca2(1-x)Sr2xAl2SiO7:Eu2+ were synthesized by a high temperature solid state reaction. The structure, diffuse reflection spectra, photoluminescence
spectra, color-coordinate parameters and lifetimes of phosphors were investigated. XRD results show that Ca2Al2SiO7 is totally miscible with Sr2Al2SiO7. These solid solution phosphors show a broad excitation band of 350–450 nm that matches well with the output lights of near-UV
LEDs and tunable emission from bluish green to yellowish green. These optical properties originate from the 4f7–4f65d transition of Eu2+ ions. The crystal field strength was considered to be tailed by controlling the host composition, which leads to the shift
of absorption band and emission band, and the varying of color coordinates.
PACS 78.55.-m; 42.70.-a; 61.05.C- 相似文献
20.
K. P. Andryushin A. A. Pavelko I. A. Verbenko O. N. Razumovskaya L. A. Shilkina V. A. Aleshin L. A. Reznichenko 《Bulletin of the Russian Academy of Sciences: Physics》2011,75(8):1082-1084
Ceramic samples of bismuth ferrite and solid solutions of Bi1 − x
A
x
FeO3 type (where A = Lu, Yb, Tm, Er, Ho, Dy, Tb, Gb, Eu, Sm, Nd, Pr, La; 0.05 ≤ x ≤ 0.20; Δx = 0.05) were prepared. Spectra of the real part of electrical conductivity were studied within the range 10−4–10−6 Hz. The dependence of the samples’ thermal stability and electrical conductivity on the size of the substituting ions was
established. 相似文献