Isotopic shift in the3P1-3P0 Mg transition

High precision frequency measurements of the³ P ₁-³ P ₀ transitions have been performed for the three natural abundant Mg-isotopes in a metastable atomic beam. A second order hyperfine theory for two-electron atoms allows the determination of the centre-of-gravity for²⁵Mg and then the evaluation of the isotopic shift displacements. The high resolution frequency measurements (10^?8) show a noticeable departure of the total shift from a linear dependence with respect to the atomic mass.     

Atomic beam measurement of the lifetime of the3 P 1 metastable states of Mg and Ca

The lifetime of the metastable level³ P ₁ of Mg and Ca have been measured in an atomic beam experiment. We excite the atoms to the³ P ₁ state by electron collisions and we measure the decay length of the light emitted by the beam. The velocity distribution of the atoms is also measured by a time-of-flight technique. The decay length and the velocity measurements are then combined to compute the required lifetimes. The results are (2.4±0.2)×10^?3 sec for Mg and (0.55±0.04)×10^?3 sec for Ca.     

Fine structure and isotope shift of the 3s4d 3 D-3s3p 3 P, 3s5d 3 D-3s3p 3 P and 3p 2 3 P-3s3p 3 P Transitions of MgI

Summary We report the measurements of the³ D(3s4d)-³ P(3s3p)³ D(3s5d)-³ P(3s3p), and³ P(3p ²)-³ P(3s3p) transition frequency of MgI, the fine-structure separation and isotope shift between²⁴Mg and²⁶Mg. The measurements have been performed in a metastable atomic beam; a good agreement is found for data already existing in the literature. The accuracy of the measurements reported in this paper is mainly limited by the Doppler broadening of theI ₂ transitions used as a reference and by the precision in the knowledge of the related wavelengths.     

Extended measurements of isotope shifts in Mg I

The isotope shifts in the Mg I transitionsλ 2,852 Å (3s ^{2 1} S ₀-3s3p ¹ p ¹ P ₁) andλλ 3,829, 3,832 and 3,838 Å (3s3p ³ P-3s3d ³ D) have been measured for²⁴Mg,²⁵Mg and²⁶Mg. The measurements were carried out using a pressure scanned Fabry-Perot interferometer and separated isotopes excited in hollow cathode discharge tubes. The results are compared to theoretical predictions and an attempt is made to convert measured line shifts into level shifts.     

Di-urethanesil hybrid electrolytes doped with Mg(CF3SO3)2

Two siloxane-based di-urethanesil frameworks incorporating poly(oxyethylene) (POE) chains have been synthesized by the sol–gel process and doped with magnesium triflate (Mg(CF₃SO₃)₂) with the goal of developing electrolytes for the fabrication of solid-state rechargeable magnesium batteries. In these matrices, short POE chains are covalently bonded to the siloxane network via urethane linkages. The xerogels have been represented by the notation d-Ut(Y) _n Mg(CF₃SO₃)₂, where Y?=?300 and 600 represents the average molecular weight of the POE chains and n stands for salt composition (molar ratio of OCH₂CH₂ units per Mg²⁺). Xerogels with compositions ranging from 2?≤?n?<?∞ were prepared. A crystalline POE/Mg(CF₃SO₃)₂ complex of unknown stoichiometry is formed in the d-Ut(300) _n Mg(CF₃SO₃)₂ materials with n?≤?6 and in the d-Ut(600) _n Mg(CF₃SO₃)₂ materials with n?≤?5. The organically modified silicate electrolytes with the highest conductivity of the d-Ut(300) _n Mg(CF₃SO₃)₂ and d-Ut(600) _n Mg(CF₃SO₃)₂ series are the samples with n?=?6 (3.9?×?10^?8 S cm^?1 at 26 °C and 8.7?×?10^?5 S cm^?1 at 97 °C) and n?=?100 (2.63?×?10^?7 S cm^?1 at 20 °C and 1.4?×?10^?5 S cm^?1 at 85 °C), respectively. Since the electrolytes for Mg batteries that have been proposed up to now have many intrinsic problems and although the room temperature conductivity values exhibited by the systems developed in the present study are still low in view of practical application, this work opens new directions for the development of solid-state Mg ion electrolytes.     

Ab-initio interpretation of 〈r−3〉 electronic quantities in the hfs of Mg I 3s 3p 3 P and1 P

It has been known for a long time that, in a two-electron arc spectrum, the properties of the³ P and¹ P terms of the lowests p configuration cannot be interpreted correctly in a pure-configuration model. Following the experimental determination of the hyperfine constantA(3s 3p ¹ P ₁) in Mg I by Kluge and Otten, this paper presents the ab-initio interpretation of the 〈r ^?3〉_3p hyperfine electronic quantities in 3s 3p through the use of the multiconfigurational Hartree-Fock method. It appears that taking into account the effects of the monoelectronic excitations 3s→nd, 2p→np and 3p→np leads to ab-initio evaluations in very good agreement with experiment. The case of the 3p→np excitation, to which Brillouin's theorem should apply in principle, is discussed. Using the same method, a refined evaluation is proposed for the nuclear electric-quadrupole moment of Mg²⁵ (Q=0.200 ± 0.01 barn).     

Lifetime measurements in the triplet system of Mg I

In an atomic beam the metastable 3s3p ³ P-states of Mg I were populated by electron impact. A pulsed tunable dye laser was used to excite the metastable atoms to the 3snd³ D-(n=3–7) and to the 3sns³ S ₁-states (n=4and 6). Observing the time dependence of the reemitted resonance light the lifetimes of these states were measured.     

Levelcrossing experiments in the first excited1 P 1 states of the alkaline earths

The hyperfine structure of the lowest¹P₁ state of²⁵Mg,⁴³Ca,⁸⁷Sr,¹³⁵Ba and¹³⁷Ba have been measured by the level-crossing and anticrossing technique. The magnetic dipole and electric quadrupole coupling constants determined by these measurements are²⁵Mg(3s3p¹P₁):A=? 7.7(5) MHz; 16 MHz>B>0 MHz,⁴³Ca(4s4p¹P₁):A=? 15.3(4) MHz; ¦B¦<12 MHz,⁸⁷Sr (5s5p¹P₁:A=? 3.4(4) MHz;B=39(4) MHz,¹³⁵Ba(6s6p¹P₁):A=? 97.5(1.0) MHz;B=31(9)MHz,¹³⁷Ba(6s6p¹P₁):A=?109.2(1.2) MHz;B=51(12)MHz. The results have been compared with the predictions of the Breit-Wills theory of the two-electron hyperfine structure using the experimental data on the³P states. Large discrepancies have been observed which are due to different radial wave functions of thes andp electron in the triplet and singlet system. This effect has been taken into account by fitting the data with the aid of two additional parameters. That this procedure is justified is shown by an analysis of the fine structure splitting, the life times, and the isotopic shifts in thesp configurations of group II elements.     

Experimental determination of isotope shifts in Mg I

The isotope shift in the Mg l transitionsλλ 5167, 5172 and 5183Å (3s3p ³ P-3s4s ³ S) andλ 5528 Å (3s3p ¹ P 3s4d ¹ D) has been measured for the isotopes²⁴Mg,²⁵Mg and²⁶Mg. The hyperfine structure of theλ 5167 Å line has been studied and theA andB factors for the 3s4s ³ S ¹ level in²⁵Mg determined. The measurements were made with separated isotopes using a scanning Fabry-Perot interferometer.     

Near-UV sub-Doppler spectroscopy on a metastable Mg beam by a frequency-doubled diode laser

Near-UV radiation is generated by doubling the frequency of a semiconductor laser in a nonlinear crystal. The crystal is contained in a resonant cavity in order to improve the conversion efficiency. The cavity increases the efficiency by about three orders of magnitude. This radiation has been used to perform spectroscopy of metastable magnesium in an atomic beam. We observed the (3s3p)³ P–(3s3d)³ D transition multiplet, which is of interest for metrological applications. The isotopic shift between²⁴Mg and²⁶Mg was measured and new information on the hyperfine structure of²⁵Mg was obtained. This radiation source is promising also in order to improve the Mg frequency standard.     

Dye laser saturation spectroscopy of the 23 S 1-23 P transition in6, 7Li+ ions

The metastable 2³ S ₁ state and the short lived 2³ P states of the helium-like^{6, 7}Li⁺ ion spectra have been investigated by dye laser saturation spectroscopy in a low-energy Li⁺ ion-beam and fluorescence light detection. The hyperfine structure splittings of all the levels, the 2³ P fine structure intervals and the isotope shift of the 2³ S ₁-2³ P transitions have been measured. These measurements were made by application of a specially constructed tunable dye laser system capable of single-mode laser scans over more than 60 GHz.     

High resolution spectroscopy of prompt and metastable decaying levels in highly ionized argon,especially of the metastable3 P 2-state of Ar16+ and the4 P 5/2-state of Ar15+

Besides the prompt x-ray emission of Ar-ions, the metastable decay of the heliumlike³ P ₂- and the lithiumlike⁴ P _5/2-levels of highly ionized Ar¹⁶⁺ and Ar¹⁵⁺ atoms has been observed in a foil-excited beam using a flat-crystal spectrometer. Due to the highx-ray energy resolution of the spectrometer the two³ P ₂ →¹ S ₀ and⁴ P _5/2 →² S _1/2 transitions could be resolved. The experiment yielded (3128 ±2) eV for the³P₂ → and (3091 ± 2)eV for the⁴ P _5/2 →² S _1/2 transition energy respectively. Using a time of flight technique the lifetimes of the³ P ₂- and the⁴ P _5/2-states were determined to be (1.44 ±0.09)ns and (0.66 ± 0.05) ns.     

Lifetime measurements of the3 P 2 and4 P 5 2/0 states in He- and Li-like titanium and chromium

Ti and Cr ions at specific energies of 3.6 MeV/N and 5.0 MeV/N have been excited by passing them through thinC foils. The emission ofK-x rays andK-Auger electrons have been investigated using a flat crystal spectrometer and an electrostatic cyclindrical mirror analyzer. The lifetimes of the (1s2p)³ P ₂ and (1s2s2p)⁴ P _5/2 states have been determined by applying the time-of-flight technique. The experimental resultsτ(Ti²⁰⁺,³ P ₂)=(404±40)ps,τ(Cr²²⁺,³ P ₂)=(215±35)ps,τ(Ti¹⁹⁺,⁴ P _5/2)=(236±12)ps, andτ(Cr²¹⁺,⁴ P _5/2)=(140±8)ps are compared with calculated lifetimes.     

The structure of25Mg

Gamma-decay modes and spin(-parity) assignments of levels in²⁵Mg have been systematically investigated up to 10 MeV excitation energy by particle-γ-ray angularcorrelation measurements with the²⁴Mg(d, pγ) reaction at 6.5 MeV bombarding energy and with the²²Ne(α,nγ) reaction at 11.8, 12.5, 14.4 and 15.5 MeV bombarding energy. A level scheme has been established which is comprehensive up to 8.3 MeV excitation energy forI≦9/2 and up to 10 MeV for 9/2O d _5/2 — 1s _1/2-O d _3/2 shell and the unifieds-d shell Hamiltonian. The agreement is good to excellent. The first intruder states are located near 6.8 MeV excitation energy. The collective properties of²⁵Mg beyond the well established rotational bands are investigated using both the new experimental information and theB(E2)'s obtained from the shell model. The spectrum of²⁵Mg is completely rotational for the first five to six MeV above the yrast line. Shell modelB (M 1)'s reflect the Nilsson model structure of²⁵Mg in great detail. The prospectiveI ^π=9/2^?, 13/2^?, and 15/2^? members of the established negative-parity,K=1/2 band are found in levels atE _x=7801, 9410, and 8896 keV.     

Measurement of the lifetime of the3 P 2 and4 P 5/2 states in Ar16+ and Ar15+

Promptly decaying levels in Li- and Be-like Ar could be identified in the delayed x-ray and electron spectrum in addition to the four known metastable (1s2s)¹ S ₀, (1s2s)³ S ₁, (1s2p)³ P ₂, and (1s2s2p)⁴ P _5/2 states in He- and Li-like systems. The states having lifetimes of about 10^?14s still contribute to the spectrum observed 10^?9s after the ions have passed a foil. This observation is explained by cascading processes from states of high principal quantum numbern≧14. The measured lifetime of the⁴ P _5/2 state subtracting the contribution of cascades is (0.594±0.016) ns and slightly larger than the theoretically predicted value of 0.563 ns. The³ P ₂ state is depopulated at short distances behind the foil by cascading processes. Its measured lifetime of (1.44±0.08) ns compares to a theoretical value of 1.48 ns.     

Spectroscopic study of the production of magnesium ions from the atomic metastable states 3s3p 3 P 0, 2 by electron impact

Spectroscopic studies of the production of MgII ions from atomic metastable states by electron impact in crossed atomic and electron beams were made. Cross sections for excitation of the strongest spectral transitions and their energy dependences were determined. The maximum value of the cross section for ionization with excitation of the 3² S _1/2–3² P _3/2 transition reached 2.4×10^?16 cm². Possible mechanisms of production of excited ions from metastable states and their contribution to the total ionization process are discussed.     

Isomer shift in BaSnO3 under a pressure up to 15 GPa

The dependence of the unit cell volume of BaSnO₃ on the pressure up to 15 GPa has been investigated and the constants of the Murnaghan equation of state B ₀ = 178.39 ± 4.09 GPa and B′₀ = 4.68 ± 0.56 have been obtained using the X-ray diffraction method. The change of the isomer shift (IS) in BaSnO₃ with a variation in the pressure P has been examined using the gamma resonance method. This quantity is ?IS(P)/?P = ?(0.00474 ± 0.0002) mm s^?1 GPa^?1 or, taking into account the measurements of the unit cell parameter under pressure, ?IS/?L = 1.42 mm s^?1Å^?1, where L is the tin-oxygen distance.     

A measurement of the 3P1 metastable state in Ca

A dye-laser excitation technique has been used to measure the lifetime of the ³P₁ metastable state in Ca. The lifetime is 0.39±0.04 msec.     

Level-crossing-Untersuchung der Hyperfeinstruktur des angeregten 32 P 3/2- und 42 P 3/2-Zustands von Na23

The hyperfine structure of the excited 3² P _3/2- and 4² P _3/2-state of Na²³ has been investigated in a level-crossing-experiment by means of a detailed analysis of the dependence of the scattered resonance light as a function of the magnetic field. From the experimental curves the following results for the hyperfine structure constantsA andB and for the lifetimesΤ were deduced 3² P _3/2-state: 4² P _3/2-state:A=18.65(10)Mc/sA=6.006(30)g _j/1.334Mc/sB=2.82(30)Mc/sB=0.86 (9)g _j/1.334Mc/sΤ=1.60 (3) · 10^?8sΤ=6.56 (25)1.334/g_j·10^?8 s. The nuclear electric quadrupolemoment of Na²³ derived from these values isQ=0,097 · 10^?24 cm², where the Sternheimer-correction has been applied.     

Isotopic shift of the ground state of neon from the experimental results concerning the absorption of 0.63-μm laser radiation

Isotopic shifts of the 3s[3/2] ₁ ⁰ –2р ⁶(¹ S ₀) and 3s'–2р ⁶(¹ S ₀) transitions, equal, respectively, to 417 ± 20 and–98 ± 20 MHz, have been measured using the 0.63-μm radiation of a helium–neon laser and opto-magnetic resonances induced by the interference of the reactive components of fields in overlapping areas of the emissions of isotopic atoms. Combining these results with the absolute specific mass shift of the 3p[5/2]₂ level (–647 MHz), the isotopic mass shift of the ground state of neon equal to 3223 ± 30 MHz, and its specific mass shift equal to–9782 ± 30 MHz have been determined.