Doppler-free two-photon laser spectroscopy of barium I: Hyperfine splitting and isotope shift of high lying levels

The Doppler-free two-photon absorption method performed with a narrowbandc w dye laser permitted high resolution measurements of transitions from the Ba I ground state 6s ^{2 1} S ₀ to several highly excited states. The lifetimes and hyperfine splittings of these states as well as the isotope shifts of the transitions have been determined accurately. The lifetime values are in agreement with transition probability data; the hyperfine splitting results show considerable configuration interaction effects. A detailed discussion of the isotope shifts is given.     

Influence of the Stark effect on multiphoton ionization of atoms when the dynamic polarizability depends strongly on the laser frequency

The influence of the Stark effect on multiphoton ionization of Ba atoms under conditions when the dynamic polarizability depends strongly on the frequency of the laser radiation is investigated. It is found that for some electric field strengths ε of the laser radiation this effect gives rise to resonance peaks in the Ba⁺ ion yield as a function of the laser radiation frequency at frequencies corresponding to single-photon transitions between the excited states. These frequencies can differ substantially from the frequencies corresponding to the conventional multiphoton excitation of these states from the ground states of the atoms. Peaks in the ion yield as a function of ε behave differently from the conventional Stark effect—their position on the frequency scale does not depend strongly on ε. The conditions under which such an induced resonance structure appears are determined. Zh. éksp. Teor. Fiz. 113, 499–512 (February 1998)     

Superlong pulses of laser oscillation on the 6 1P1-5 1D2 transition of the barium atom

A possibility of CW laser oscillation on atomic transitions between a resonance energy level and a metastable one under conditions when lower laser states are deactivated by electron impacts has been theoretically shown. We determined the plasma parameters so that CW laser action on such transitions of Cu, Au, Ca and Ba atoms may be possible. Superlong laser pulses of 6 μs duration were obtained on the 6 ¹P₁-5 ¹D₂ transition of the barium atom.     

Investigation of <Superscript>138</Superscript>Ba in the (<Emphasis Type="Italic">n</Emphasis>, <Emphasis Type="Italic">n′γ</Emphasis>) reaction

For the reaction ¹³⁸Ba(n, n′γ) induced by a beam of fast reactor neutrinos, the gamma spectrum, the angular distributions of gamma radiation, and its linear polarizations are measured, along with the half-lives of the excited states involved. The known diagram of energy levels and gamma transitions is supplemented. The multipole-mixture ratios δ are found for many transitions between the energy levels in question, and half-lives are determined for some excited states.     

Hyperfine structure in the 6p5d configuration and isotope shifts in transitions between the 6s5d and the 6p5d configurations in Ba I

High-resolution laser fluorescence spectroscopy, using a single-mode dye laser acting on a collimated atomic beam, has been performed to determine the hyperfine-structure (hfs) constants in six states of the 6p 5d configuration of¹³⁵Ba and¹³⁷Ba. Isotope shifts (IS) for eleven transitions between the 6s 5d and the 6p 5d configurations have also been measured. From an analysis of the energy levels, intermediate angular wavefunctions have been deduced. The wavefunctions are used to evaluate experimental hyperfine parameters from the experimental hfs constants. The parameters are, for the magnetic-dipole interaction compared with theoretical values, and for the electricquadrupole interaction used to estimate the nuclear quadrupole moments for the odd isotopes. The IS in the measured transitions are analysed using a King-plot, with the first resonance line in Ba II as the reference. Specific mass and field shifts are evaluated for the measured transitions. The field shifts have been used to determine the change in mean-square radius between the natural abundant Ba-isotopes.     

Multi-photon resonance enhanced super high-order harmonic generation

This paper proposes highly charged ions pumped by intense laser to produce very high order harmonics.Numerical simulations and full quantum theory of Ne 9+ ions driven by laser pulses at 1064 nm in the power range of 10 9 W/cm 2 ～ 10 15 W/cm 2 show that the emission spectrum corresponds to the electronic transitions from the excited states to the ground state,which is very different from the spectrum of general high-order harmonic generation.In such situation,harmonic order as high as 1000 can be obtained without producing lower order harmonics and the energy conversion efficiency is close to general high order harmonic generation of hydrogen atom in the same laser field.     

Spectroscopic diagnostics of the laser erosion plasma of an AgGaS<Subscript>2</Subscript> polycrystalline target

Results are presented from experimental studies of the radiation emitted from a plasma produced in vacuum after irradiating a polycrystalline target by 1.06-μm laser radiation with an intensity of (3–5)×10⁸ W/cm². Plasma radiation from regions located at distances of 1 and 7 mm from the target is analyzed. It is shown that the main contribution to the plasma radiation in the 220–600 nm spectral range is made by transitions from the excited states of single-charged Ag⁺ and S⁺ ions. The atomic component of plasma radiation is represented by intense spectral lines corresponding to transitions from the Rydberg states of Ag and Ga atoms, whereas no resonance lines of these atoms are observed.     

Absorption spectrum of H<Stack><Subscript>3</Subscript><Superscript>+</Superscript></Stack> near 1.06 μm

The absorption spectra of molecular hydrogen plasma excited by electric hollow-cathode and high-frequency discharges are measured. The spectra in the region of 1.06 μm were recorded using a neodymium intracavity laser spectrometer with a resolution of 0.03 cm^?1 and an absorption sensitivity of 10^?8 cm^?1. The absorption lines that can be attributed to the transitions to vibrational states in the molecule are recorded.     

Photoionization cross-section measurements from the 2p, 3d and 3s excited states of lithium

The photoionization cross-sections from the 2p²P_{1/2, 3/2}, 3d²D_{3/2, 5/2} and 3s²S_1/2 excited states of lithium have been measured at different ionizing laser wavelengths, above the first ionization threshold. The experiments are performed by using a thermionic diode working in the space charge limited mode and the cross-sections are measured by employing the saturation technique. By changing the ionization photon energy, a smooth frequency dependence of the cross-sections has been observed for the 2p and 3d states. The cross-section from the 3s excited state has been measured at a single photon energy. The measured values of the photoionization cross are compared with the available data.     

A mechanism for excitation of metastable levels by(γ,γ') reactions

The analysis of the cross-section of ⁷⁷Se and ⁸⁷Sr isomeric states excitation in the (γ, γ′) reaction, was carried out using neutron pick-up and stripping reaction results. It allows the shell configurations of the transitions to the activation states to be determined. To check thus obtained conclusions the energies of Jπ=1^- excited states for ⁹⁰Zr and ¹³⁸Ba were calculated, which are in good agreement with the resonance structure at the γ-quanta elastic scattering in the 5 to 10 MeV energy range. This revised version was published online in August 2006 with corrections to the Cover Date.     

Radiative and non-radiative decays from the excited state of Ti3+ ions in oxide crystals

The fluorescence spectra of Ti³⁺ in Y₃Al₅O₁₂ (YAG), Al₂O₃ (sapphire), YAlO₃ (YAP) observed at 10 K are composed of zero-phonon lines accompanied by the broad vibronic sidebands. The temperature dependence of the fluorescence lifetime and of the total intensity of the broadband measured in YAG and Al₂O₃ indicate that the radiative decay times from the excited states are nearly constant in the range 10–300 K. This demonstrates that the broadband radiative emissions in Ti³⁺:YAG and Ti³⁺:Al₂O₃ are due to magnetic dipole transitions or to electric dipole transitions induced by static odd-parity distortion, respectively. The decrease of the fluorescence lifetime with increasing temperature in Ti³⁺:YAG and Ti³⁺:Al₂O₃ is due to non-radiative decay from the excited state which occurs through phonon-assisted tunnelling between the excited and ground states. The radiative decay of Ti³⁺:YAP is enhanced with increasing temperature, indicating that radiative decay rate contains a term associated with odd-parity phonons. Nevertheless, a non-radiative decay rate of 3.6 × 10⁴ s^–1 observed in the temperature range 10–300 K is due to excited state absorption, which depopulates the excited state and quenches the fluorescence at the laser wavelength.     

High resolution spectroscopy of rydberg states in indium I

Two-photon laser spectroscopy in a dense indium vapour allowed to investigatenp ² P _{1/2, 3/2} states (n=27–35) for^{113, 115}In with a thermionic diode. Precise data on the fine structure splitting of these states and the isotope shift of the two photon transitions have been obtained. The fine structure splitting shows a hydrogenic behaviour. By using the result of our isotope shift measurement in combination with literature values, level isotope shifts with reference to the ionization limit are deduced and analysed with respect to the different contributions.     

High resolution measurements of hyperfine structure and isotope shifts in 9 spectral lines of Nd I

Nine transitions in Nd I, originating from various levels belonging to the 4f ⁴6s ² ground state configuration, have been studied with high resolution using an actively stabilized C.W. ring dye laser in a crossed laser-atomic-beam set-up. Accurate values for the isotope shifts in all transitions as well as for the hyperfine structure constants of 7 excited states have been obtained.     

Excited-state laser spectroscopy of the impurities in III–V and II–VI semiconductors

At temperatures where the shallow donors become occupied, weak impurity lines appear on sweeping the field with laser wavelenghts where photon energy is insufficient to cause transitions from the ground state ti any of the excited states if the impurities. With all the materials investigated, the two most prominent of these lines, which are attributed to transitions between excited states, lie on the same two curves on a dimensionless diagram of excitation energy against cyclotron energy. One of these lines is identified as arising from the 2p⁻ to 2s transition. The other probably also originates from the 2p⁻ state. The photon energy for the 311μ laser line is just sufficient to cause transitions from the 1s to 2p⁻ state in n-GaAs. Because of this almost exact coincidence, fine structure due to the central cell corrections for individual impurities is particularly well resolved in magnetic field.     

109Cd → 109Ag and 107Cd → 107Ag β decays

The energies, magnetic dipole and electric quadrupole moments, spectroscopic factors of the ground and excited states of ¹⁰⁹Ag and ¹⁰⁷Ag, the reduced probabilities of electromagnetic transitions between them, and the reduced probabilities of β transitions from the ground states of ¹⁰⁹Cd and ¹⁰⁷Cd to the excited states of ¹⁰⁹Ag and ¹⁰⁷Ag were calculated on the basis of the dynamic collective model. The vacuum fluctuations of quasiparticles and multiphonon (up to 10 phonons) states of the main band of the even-even core were taken into account. The calculation results show good agreement with the experimental data.     

Effects of electron relaxation on multiple harmonic generation from metal surfaces with femtosecond laser pulses

Calculations are presented for the first four (odd and even) harmonics of an 800 nm laser from a gold surface, with pulse widths ranging from 100 down to 14 fs. For peak laser intensities above 1 GW/cm² the harmonics are enhanced because of a partial depletion of the initial electron states. At 10¹¹ W/cm² of peak laser intensity the calculated conversion efficiency for 2nd-harmonic generation is 3 × 10⁻⁹, while for the 5th-harmonic it is 10⁻¹⁰. The generated harmonic pulses are broadened and delayed relative to the laser pulse because of the finite relaxation times of the excited electronic states. The finite electron relaxation times cause also the broadening of the autocorrelations of the laser pulses obtained from surface harmonic generation by two time-delayed identical pulses. Comparison with recent experimental results shows that the response time of an autocorrelator using nonlinear optical processes in a gold surface is shorter than the electron relaxation times. This seems to indicate that for laser pulses shorter than ∼30 fs, the fast nonresonant channel for multiphoton excitation via continuum-continuum transitions in metals becomes important as the resonant channel becomes slow (relative to the laser pulse) and less efficient.     

Excited-state absorption and energy output of laser ruby

The laser performance, luminescence intensity and absorption in excited state of rubies annealed in reducing or oxidizing atmosphere is given. Rubies doped with Mg, Ti or Fe were compared to those containing Cr only. The decrease of energy output is caused by the non-radiative transitions from the excited states to the ground⁴A₂ state. O^– centre developed by the presence of the large ions facilitate the transitions from the upper excited states only, whereas Fe and to a less extent Ti ions make the non-radiative transition from the metastable²E level to the⁴A₂ level possible. Ti³⁺ ions filter also the UV content of the flashlight and prevent the transition from the²E to the higher states.     

Emission of excited copper atoms in laser-produced erosion plasmas

The distribution of emission from excited states of a copper atom in erosion plasmas formed in vacuum by the action of neodymium laser pulses with a power density of (3–5)×10⁸ W/cm² on a copper target is studied. Averaged spectra and oscillograms of emission of Cu I lines were recorded in a region of 210–600 nm. Resonant lines of Cu I, lines of cascade transitions to resonant levels of Cu I, and lines from shifted levels of a copper atom are shown to possess the highest intensity. Oscillograms of emission at Cu I transitions have two peaks, which may be associated with two phases of surface evaporation of copper: under the action of a Nd³⁺:YAG laser pulse and radiation of the core of an erosion plasma plume. The relationship between the intensities of peaks in oscillograms of emission of Cu I lines points to the presence of a considerable cascade contribution to the population of the resonant states of Cu I and self-absorption of resonant lines of a copper atom at the first stage of evaporation of a copper target.     

Study of shallow impurity states in compound semiconductors using high resolution photoluminescence spectroscopy

In this paper we review briefly the use of high resolution photoluminescence to study the behavior of shallow impurity states in compound semiconductors. As an illustration we focus our review on GaAs. The binding energies of the ground state and of several low-lying excited states of the impurity centers are determined by studying the radiative transitions associated with excitons bound to neutral donors or acceptors. The difference between the binding energies of different donors in GaAs is rather small. Thus to resolve transitions associated with different chemical donors a magnetic field is used. This has the effect of sharpening the transitions as well as increasing the separation between them. One can identify donors in samples with total impurity concentrations as high as 5X10¹⁵/cm³. The binding energies of different chemical acceptors in GaAs are much higher. Thus the radiative transitions associated with excitons bound to neutral acceptors can be resolved in zero magnetic field. Energy levels of shallow donors and acceptors in GaAs are reviewed.     

Microwave spectrum of the vibrational excited states ν6 and ν8 of formic acid: Contribution to the assignment of the Formic Acid Submillimeter Laser

The microwave spectrum of the ν₆ and ν₈ vibrationally excited states of H¹²COOH has been reinvestigated in the 10–200-GHz region, and 23 new transitions, essentially of the b type, were measured. The transitions allowed us to obtain a set of improved parameters for each of these two states which contribute to the assignment of the Formic Acid Submillimeter Laser. The vibrational energies of the ν₆ and ν₈ states have been derived from the assignment of infrared pump transitions and the corresponding submillimeter transition of the optically pumped submillimeter laser.