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1.
Activated carbons are produced from wastes of Algerian date stones by pyrolysis and physical activation in the presence of water vapor into a heated fixed-bed reactor. The effect of pyrolysis temperature and activation hold time on textural and chemical surface properties of raw date stones and carbon materials produced are studied. As expected, the percentage yield decreases with increase of activation temperature and hold time. The characterization of carbon materials is performed by scanning electron microscopy (SEM). X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and nitrogen adsorption (BET). Results show the presence of cellulose and hemicellulose in the raw material, and the predominance of carbon and graphite after pyrolysis. Different oxygen-containing functional groups are found in the raw material while aromatic structures are developed after pyrolysis and activation. The best specific surface area (635 m 2 g −1) and microporous volume (0.716 cm 3 g −1) are obtained when the date stones are grinded, pyrolysed at 700 °C under a 100 cm 3 min −1 nitrogen flow and then activated under water vapor at 700 °C for 6 h. 相似文献
2.
Activated carbons from bagasse fly ash (BFA) were prepared by one step chemical activation using ZnCl 2 as activating agent, or combination method of chemical with CO 2 physical activation (physicochemical activation). The development of porosity was studied in correlation with the method of activation, activation temperature, and also the chemical weight ratio. A typical sample by the combination method at 600 °C and weight ratio of ZnCl 2:BFA = 2 exhibited micropore volume of 0.528 cc/g, mesopore volume of 0.106 cc/g and surface area of 1200 m 2/g. For determining the adsorption capacity of the carbon samples in solutions, phenol and methylene blue equilibrium adsorption experiments were conducted. The properties and adsorption capacity of the synthesized activated carbons has been compared to commercial activated carbon (Norit ® SX Plus). 相似文献
3.
Cotton stalks, an agricultural waste, were chemically activated in a batch process using H 3PO 4 in a locally designed carbonizer at 420 °C in the absence of any purging gases. Mechanically cut short sticks were soaked in diluted H 3PO 4 for a short duration (Batch 1) and an extended period (Batch 2) prior to thermal treatment. The derived carbons contained both coarse and fine grains with acidic effect. Porosity was characterized by N 2 adsorption at −196 °C and the isotherms analyzed by the α-method to estimate total and microporous surface areas in addition to total and microporous volumes. The produced carbons exhibited well-developed porosity that was essentially microporous in composition. Several key performance parameters were altered considerably as a result of impregnation with H 3PO 4 and the extended chemical activation period (Batch 2). Most of the internal porosity of both carbons was accessible to adsorption of iodine, whereas the uptake of methylene blue dye was proportional to the average size of micropores which were larger for the batch with a longer acid soaking time. SEM and FTIR investigations revealed the presence of a developed honeycomb structure and different oxygen functionalities on surfaces of the activated products which are advantageous in liquid-phase applications. Preliminary laboratory-scale experiments with Pb(II) indicate that adsorption capacity of target heavy metals compares favorably with commercially available activated carbons. The raw material, pre-processing, and activation process prove feasible for the production of activated carbon on a large scale, thereby providing a sustainable strategy for treatment of toxic waste streams. 相似文献
4.
Five different cellulose-based fabrics were used to prepare activated carbon cloths (ACCs) by phosphoric acid activation at pre-established experimental conditions, in an attempt to explore the effect of the precursor's nature on properties of the resulting ACCs. Characterization by elemental analysis, nitrogen (77 K) adsorption, and scanning electron microscopy was carried out. Electrical properties of the developed ACCs were investigated to examine the possibility of regenerating the ACCs by direct electrical heating. Thermal behavior of the raw precursor and of one of the acid-treated fabrics was also studied by thermogravimetric analysis and noticeable differences due to the precursors’ characteristics and acid impregnation were detected, respectively. The ACCs derived from a denim precursor showed BET surface area (784 m 2 g −1) and total pore volume (0.40 cm 3 g −1) lower than those obtained from the four other precursors (1058–1183 m 2 g −1, 0.55–0.67 cm 3 g −1), whereas carbon content and yield for the former were higher. Morphology and physical appearance of the ACCs were dependent on the raw fabric employed, with most of the samples presenting well-preserved fibres integrity. Besides, the denim-derived ACCs also showed the lowest electrical resistivity (8.10 −3 Ωm). It was properly correlated with the elemental carbon content and total pore volume of the developed ACCs. 相似文献
5.
Activated carbons with well-developed pore structures were prepared from pistachio-nut shells by chemical activation using zinc chloride under both nitrogen atmosphere and vacuum conditions. The effects of preparation parameters on the carbon pore structure were studied in order to optimize these parameters. It was found that under vacuum conditions, the characteristics of the activated carbons produced are better than those under nitrogen atmosphere. The impregnation ratio, the activation temperature, and the activation hold time are the important parameters that influence the characteristics of the activated carbons. The optimum experimental conditions for preparing predominantly microporous activated carbons with high pore surface area and micropore volume are an impregnation ratio of 0.75, an activation temperature of 400 degrees C, and a hold time of 1 h. Under these conditions, the BET surface areas of the carbons activated under nitrogen atmosphere and vacuum conditions were 1635.37 and 1647.16 m2/g, respectively. However, at a ZnCl2 impregnation ratio of 1.5, a furnace temperature of 500 degrees C, and a hold time of 2 h, the predominantly mesoporous activated carbon prepared under vacuum condition had a BET surface area of 2527 m2/g. Fourier transform infrared spectra were used to detect changes in the surface functional groups of the samples during the different preparation stages. 相似文献
6.
Nutshells of Sterculia alata, a forest waste, were used to prepare activated carbons by zinc chloride activation under four different activation atmospheres,
to develop carbons with substantial capability, and to adsorb phenol from wastewater. Experiments were carried out at different
chemical ratios (activating agent/precursor). Effect of carbonization temperature and time are the important variables, which
had significant effect on the pore structure of carbon. Developed activated carbon was characterized by SEM analysis. Pore
volume and surface area were estimated by Hg porosimetry and BET surface area analyses. The carbons showed surface area and
micropore volumes of around 712 m 2/g and 0.542 cm 3/g, respectively. The activated carbon developed shows substantial capability to adsorb phenol from wastewater. The kinetic
data were fitted to the models of intraparticle diffusion, pseudo-second order, and Lagergren model and followed more closely
the pseudo-second-order chemisorption model. The isotherm equilibrium data were well-fitted by the Langmuir and Freundlich
models. The maximum uptake of phenol was found at pH 3.5. 相似文献
7.
Chicken waste and chicken waste blended samples with selected high sulfur coal were used as raw materials for activated carbon preparation. Raw materials were subjected to the preparation procedures of carbonization in a nitrogen atmosphere and activation in a steam atmosphere. The basic properties of the raw materials, chars and activated carbons were investigated by components analysis, surface porosity and thermogravimetric analysis. Two activated carbon samples were selected for elemental mercury capture tests in a lab-scale drop tube reactor with air flow. The current results show that chicken waste is not a suitable raw material for activated carbon production due to its higher contents of volatile matter and ash. Coal can be used as a carbon carrier for improving the carbon content of products. A low-cost activated carbon was prepared by a co-process of chicken waste and coal, and examining the high capture efficiency for elemental mercury. It suggests that the coal provides a carbon carrier or trap for some active species, such as chlorine released from the chicken waste. These active species would likely provide or create the adsorptive sites on the surface of activated carbon for elemental mercury. 相似文献
8.
The goal of this work was the development of a methodology based on solid phase extraction (SPE) to characterize nitrogen compounds and phthalates from landfill leachate samples. Activated carbon (AC) was used to extract all the organic compounds from the samples. The samples were collected in Porto Alegre-South Brazil. As the AC used had small particle size, it was impossible to use it in the form of packed cartridges; hence, it had to be applied in a batch mode. The desorption of the organic compounds from the AC was made by sonication with dichloromethane. The extract was analyzed by gas chromatography with mass spectrometric detection (GC-MSD). Some aspects of the validation of the methodology were also established. Several nitrogen compounds and phthalates were identified in the samples, proving the efficiency of this method with regard to the selectiveness for these substances. 相似文献
9.
Three activated carbons have been prepared, two from oil-palm shell and one from coconut shell, by the phosphoric acid activation process. Adsorption isotherms of copper(II) were determined to evaluate and compare the performance of experimental carbons. The obtained data are fitted very well to Langmuir and Freundlich adsorption models. All prepared activated carbons show 4–7-fold high adsorption capacity (q max 19.5–23/18.6–21?mg?g ?1) than that of the commercial ones (q max 5.6/2.9?mg?g ?1) under the conducted experimental conditions. The mechanism of adsorption was evaluated from the competitive adsorption of copper(II) and calcium(II) in a binary solution depending on their behaviour as Lewis acid and assessed as inner-sphere complexation. The competitive adsorption of copper(II) with other borderline and soft metal ions was evaluated by the best scavenger using a solution of ternary solute of copper(II), nickel(II) and lead(II). The adsorption selectivity order is determined as follows: Pb?>?Cu???Ni. 相似文献
10.
Global attention is increasingly focused on the adverse health and environmental impacts of textile dyes, marking the necessity for effective and sustainable dye remediation strategies in industrial wastewater. This study introduces a novel, eco-friendly activated carbon produced from olive stones (OLS), a readily available by-product of the olive oil industry. The OLS was chemically activated with H 3PO 4 and KOH, creating two materials: OLS-P and OLS-K, respectively. These were then utilized as cost-effective adsorbents for the removal of methylene blue (MB) dye. The activated materials were characterized via X-ray diffraction (XRD), Fourier transform infra-red spectroscopy (FTIR), iodine number, and pHpzc analysis, with the zero-point charge determined as approximately pH 1 for OLS-P and pH 8 for OLS-K. Batch adsorption experiments conducted at various temperatures revealed that adsorption process followed the pseudo-second-order kinetic model and the Langmuir isotherm model. Temperature was found to significantly impact adsorption performance, with OLS-K demonstrating a substantial increase in adsorption capacity (q e) from 6.27 mg/g at 23˚C to 94.7 mg/g at 32 ˚C. Conversely, OLS-P displayed a decrease in q e from 16.78 mg/g at 23 ˚C to 3.67 mg/g at 32 ˚C as temperature increased. The study highlights the potential of KOH-treated olive stones as a promising, cost-efficient adsorbent for methylene blue remediation from wastewater. 相似文献
11.
In this work, Sterculia foetida fruit shells were used for the preparation of activated carbon and utilized for the removal of industrial effluent methylene blue is described. The carbon materials were prepared by washing the shells with water, dried in sunlight and subjected to heating at 700 °C in a muffle furnace to get the carbon material. This is divided into three portions, one is used as pristine and two portions were subjected to physical activation using steam and chemical activation using K 2CO 3. The impurities were removed by treatment with NaOH (0.1 M) and subsequently with HCl (0.1 M). Turbostatic structure was determined by XRD and the specific surface area was determined using BET showed 4, 1017 and 596 m 2/g as the surface areas. Using these activated carbon materials, we have achieved 93% removal of methylene blue, found in industrial effluents. 相似文献
12.
The main objective of this study was to evaluate the feasibility of pistachio shell as a biomass feedstock for the production of fungicidal oil and a precursor for the production of activated carbon by physical activation. For this purpose, pistachio shell was pyrolyzed in a fixed bed reactor at the different temperatures (300-600 °C). The pyrolysis products were identified as gas, bio-oil, aqueous solution and char. The product distribution from pyrolysis process did not significantly change when the pyrolysis temperature was above 300 °C. The pyrolysis gas product had low calorific value since it contained the high proportion of carbon oxides. Because of their high oxygen content, the bio-oils were found not to be used as a fuel. Thus, the bio-oil was tested again four different types of fungi (pathogenetic, wood decaying and saprophyting). It was shown fungicidal activity again all tested fungi at the concentration of 10-50 mg ml −1. The pyrolysis char was evaluated as a precursor for the production of activated carbon. The surface area and micropore volume of the activated carbon produced from the char by CO 2 activation at 900 °C were found to be 708 m 2 g −1 and 0.280 cm 3 g −1, respectively. 相似文献
13.
In this work, carbon xerogels with a high pore volume and surface area (up to 2.58 cm 3/g and 3200 m 2/g respectively) have been synthesized using the sol-gel polycondensation of resorcinol (R) with formaldehyde (F) in a basic
medium of monoethanolamine (MEA), followed by drying and pyrolysis. This medium (MEA) has not been used in previous investigations.
The effect of activation with CO 2 on the pore size distribution and the chemical functional groups has been investigated using N 2 (77 K) adsorption, FTIR and elemental analysis techniques. A series of experiments has been conducted to investigate the
effect of activation time and activation temperature. Activation of the samples was carried out at 850, 900 and 980 °C for
times ranging from one to three hours. Within the range of activation conditions, an increase in activation time at 850 °C
results in a continuous steady rise of the BET surface area and total pore volume. However, at the two higher temperatures,
the surface area shows a maximum when plotted against activation time. FT-IR results show that the use of MEA as a catalyst
leads to the formation of nitrogen functional groups in the surface of the resin. 相似文献
14.
Two series of activated carbons have been prepared from date pits; series C, using carbon dioxide as activating agent, and series S, prepared by activation with steam under the same experimental conditions. The obtained samples were oxidized with nitric acid in order to introduce more oxygen surface groups. The surface area and porosity of the parent and oxidized activated carbons were studied by N 2 adsorption at 77 K and CO 2 adsorption at 273 K. The oxygen surface complexes were characterized by temperature-programmed decomposition (TPD). The results show that carbon dioxide and steam activations produce microporous carbons with an increasing amount of CO evolving groups when increasing the burn-off. On the other hand, oxidation with nitric acid increases the amount of CO and CO 2 evolved by the decomposition of surface oxygen groups, this increase being related to the development of porosity in the carbon with the degree of activation and to the activating agent used (CO 2 versus steam). 相似文献
15.
A novel corn grain precursor was used for the preparation of activated carbon by chemical activation. The detailed investigation of the porosity development in the prepared activated carbon was done by altering the various activation conditions such as the activation temperature, activation time and ratio between the powdered form of carbonized corn grain char and KOH. The surface characteristics including the surface roughness of all the activated carbon samples were evaluated from the analysis of nitrogen (N 2) adsorption isotherm data. At the maximum of 2978 m 2/g, a super surface area having the corn grain‐based activated carbon (CG‐AC) was synthesized by using the following conditions: 1/4 ratio of powdered form of carbonized corn grain char/KOH; 800 °C; and 4 h. The possibility of preparing highly porous activated carbons with controlled porosity by varying different activation conditions was found from the pore size distribution results. In particular, the domination of the ratio between the powdered form of carbonized corn grain char and KOH on the porosity development was high compared to the activation temperature and activation time. In addition, the surface roughness calculated from the surface fractal dimension indicates the decrease of surface roughness with increasing activation conditions. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
16.
This study assesses the performance of optimized acacia wood-based activated carbon (AWAC) as an adsorbent for methylene blue (MB) dye removal in aqueous solution. AWAC was prepared via a physicochemical activation process that consists of potassium hydroxide (KOH) treatment, followed by carbon dioxide (CO 2) gasification under microwave heating. By using response surface methodology (RSM), the optimum preparation conditions of radiation power, radiation time, and KOH-impregnation ratio (IR) were determined to be 360 W, 4.50 min, and 0.90 g/g respectively, which resulted in 81.20 mg/g of MB dye removal and 27.96% of AWAC’s yield. Radiation power and IR had a major effect on MB dye removal while radiation power and radiation time caused the greatest impact on AWAC’s yield. BET surface area, mesopore surface area, and pore volume of optimized AWAC were found to be 1045.56 m 2/g, 689.77 m 2/g, and 0.54 cm 3/g, respectively. Adsorption of MB onto AWAC followed Langmuir and pseudo-second order for isotherm and kinetic studies respectively, with a Langmuir monolayer adsorption capacity of 338.29 mg/g. Mechanism studies revealed that the adsorption process was controlled by film diffusion mechanism and indicated to be thermodynamically exothermic in nature. 相似文献
17.
Activated carbon (AC) derived from gasified Glyricidia sepium woodchip (GGSWAC) was prepared using KOH and CO 2 activation via microwave radiation technique to remove atenolol (ATN) from aqueous solution. The surface area (S BET) and total pore volume (TPV) of GGSWAC were 483.07 m 2/g and 0.255 cm 3, respectively. The n-BET model fits well with the isothermal data indicating a multilayer adsorption with the saturation capacity of 121, 143 and 163 mg/g at 30, 45 and 60 °C, respectively. The kinetic study showed that ATN adsorption followed Avrami model equation (R 2 ≅ 0.99). Based on the thermodynamic parameters, the adsorption of ATN onto GGSWAC was endothermic (ΔH S = 234.17 kJ/mol) in the first layer of adsorption and exothermic in the subsequent layer (ΔH L = −165.62 kJ/mol). The ATN adsorption was controlled by both diffusion and chemisorption. In continuous operation, the Thomas (R 2 = 0.9822) and Yoon–Nelson (R 2 = 0.9817) models successfully predicted the ATN adsorption. 相似文献
18.
A variety of alkylarenes such as fluorenes, xanthenes, and anthrone were effectively oxygenated to the corresponding carbonyl compounds with molecular oxygen as oxidant in the presence of activated carbon. 相似文献
19.
High specific capacitance and low cost are the critical requirements for a practical supercapacitor. In this paper, a new activated carbon with high specific capacitance and low cost was prepared, employing cotton stalk as the raw material, by using the phosphoric acid (H 3PO 4) chemical activation method. The optimized conditions were as follows: the cotton stalk and activating agent with a mass ratio of 1:4 at an activation temperature of 800 °C for 2 h. The samples were characterized by nitrogen adsorption isotherms at 77 K. The specific surface area and pore volume of activated carbon were calculated by Brunauer–Emmett–Teller (BET) and t-plot methods. With these experimental conditions, an activated carbon with a BET surface area of 1,481 cm 2?g ?1 and micropore volume of 0.0377 cm 3?g ?1 was obtained. The capacitance of the prepared activated carbon was as high as 114 F?g ?1.The results indicate that cotton stalk can produce activated carbon electrode materials with low cost and high performance for electric double-layer capacitor. 相似文献
20.
Co-pyrolysis at relatively low temperature (673 K) and high pressure (10 MPa), using three organic compounds, was used to
modify the porosity of the two ACs. The co-pyrolysis is effective for the modification of the porosity of an AC, and the efficiency
depends on the organic compound used. The differences found are consequence of the chemical composition of the organic precursor.
High pressure pyrolysis produces beneficial results when an organic compound that volatilizes during the preparation is used.
Conducting pyrolysis at low temperature permits improved control of the porosity because the rate of gasification can be more
tightly controlled. 相似文献
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