Inelastic x-ray scattering in correlated Mott insulators

We calculate the inelastic light scattering from x rays, which allows the photon to transfer both energy and momentum to the strongly correlated charge excitations. We find that the charge-transfer peak and the low-energy peak both broaden and disperse through the Brillouin zone similar to what is seen in experiments in materials such as Ca2CuO2Cl2.     

Inelastic neutron scattering spectroscopy of C60@calix[8]arene

The vibrational dynamics of the p-rert-butylcalix[8]arene and the 1:1 inclusion complex C₆₀@p-tert-butylcalix[8]arene are investigated by a combination of inelastic neutron scattering (INS) and MM3 molecular mechanics calculations. The results show that the isolated, single molecule approximation breaks down and is not sufficient to explain the features observed experimentally. The origin of the line broadening in the low energy region is discussed in terms of intermolecular interactions: this effect is sharper in the case of the complex with the C₆₀ molecule, due to the high number of co-conformers allowed by the mismatch between the circumferences of the host and the guest. The successful interpretation of the INS spectra validates the use of the model adopted.     

Inelastic neutron scattering measurements and Ab initio calculations of hydrogen in single-crystal palladium

Using a single-crystal sample of PdH, we have measured the inelastic form factor for exciting the proton from its ground state to various excited states as a function of crystal orientation. Because of the anharmonicity of the potential well which splits otherwise degenerate states, each inelastic form factor could be measured individually. Agreement between theory and experiment is excellent, both with regard to the transition energies and to the modulation of the intensity, giving confidence in the quantum treatment of the proton and hence in the use of the model to predict other properties of the system.     

Raman spectra of single-crystal C60

We have analysed the Raman spectra of C₆₀ single crystals between room temperature and 10K and studied the temperature-induced phase transition in this material. The spectra show crystal field splitting of the internal Raman modes but no evidence for a line shift near the phase transition. The photo-induced transformation of the crystals and its implication on the interpretation of the Raman spectra is discussed. In the low temperature phase we observed two lines at 30 cm^–1 and 41 cm^–1 which we assign to the librational modes of the crystal.     

Elastic moduli of single-crystal C60

The matrix of elastic constants of the fcc phase of solid C₆₀ has been determined experimentally from measurements of the the velocity of 5 MHz ultrasound in single-crystal samples with different crystallographic orientations. The following values were obtained for the elastic moduli: C ₁₁=14.9±0.9 GPa, C ₁₂=8.8±1.0 GPa, and C ₄₄=6.6±0.18 GPa. The results are compared with theoretical estimates of the elastic moduli and data obtained in previous measurements of the elastic characteristics of solid C₆₀. Fiz. Tverd. Tela (St. Petersburg) 40, 173–175 (January 1998)     

Inelastic x-ray scattering study of exciton properties in an organic molecular crystal

Excitons in a complex organic molecular crystal were studied by inelastic x-ray scattering (IXS) for the first time. The dynamic dielectric response function is measured over a large momentum transfer region, from which an exciton dispersion of 130 meV is observed. Semiempirical quantum chemical calculations reproduce well the momentum dependence of the measured dynamic dielectric responses, and thus unambiguously indicate that the lowest Frenkel exciton is confined within a fraction of the complex molecule. Our results demonstrate that IXS is a powerful tool for studying excitons in complex organic molecular systems. Besides the energy position, the IXS spectra provide a stringent test on the validity of the theoretically calculated exciton wave functions.     

High-temperature conductivity study on single-crystal C60

We report about dc, ac (100Hzv100kHz) and contactless microwave (10 GHz) conductivity studies on C₆₀ crystalline bulk material from room temperature to 850 K. The high temperature regime is governed by an activated behavior with a frequency and sample independent activation energy of about 0.9 eV. The low temperature regime exhibits a frequency dependent and weakly temperature dependent conductivity due to extrinsic properties.Anomalies in the heating curves of virgin samples (dynamical vacuum conditions) in the temperature ranges 560 K and 740 K are ascribed to the desorption of oxygen.     

Inelastic electron scattering from hydrogen at 50° and 60°

Inelastic electron scattering cross sections have been measured for four-momentum transfers between 4.1 GeV² and 30.5 GeV². At the large scattering angles of this experiment, the dominant contribution to the cross section comes from the W₁ structure function. In the conventional scaling variables, x and x′, this structure function does not exhibit scaling behavior, and at fixed x or x′ it is found to decrease with increasing four-momentum transfer.     

Inelastic electron scattering at 180° from 14C

Inelastic scattering of 37, 50, and 60 MeV electrons at 180° from ¹⁴C has been studied. Cross sections for the excitation of eight states in ¹⁴C with excitation energy less than 16 MeV have been observed. Most of the strength is observed to be concentrated in one transition at 11.31 MeV which is assigned a spin and parity of 1⁺. The total width of this state is observed to be 207 ± 13 keV, while the electromagnetic transition width is determined to be 6.8 ± 1.4 eV.     

Inelastic electron-photon scattering

It is suggested that colliding e⁺e⁻ beam machines may be used to study inelastic electron-photon scattering.