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1.
Liang Chen Shaoming Yu Lingli Huang Gang Wang 《Journal of Radioanalytical and Nuclear Chemistry》2012,292(3):1181-1191
The sorption of radionuclide 63Ni(II) on bentonite/iron oxide magnetic composites was investigated by batch technique under ambient conditions. The effect
of contact time, solid content, pH, coexistent electrolyte ions, fulvic acid, and temperature on Ni(II) sorption to bentonite/iron
oxide magnetic composites was examined. The results demonstrated that the sorption of Ni(II) was strongly dependent on pH
and ionic strength at pH <8.0, and was independent of pH and ionic strength at high pH values. The sorption of Ni(II) was
dominated by outer-sphere surface complexation or ion exchange at low pH, whereas inner-sphere surface complexation was the
main sorption mechanism at high pH. The experimental data were well fitted by Langmuir model. The thermodynamic parameters
(∆G°, ∆S°, ∆H°) calculated from the temperature-dependent sorption isotherms indicated that the sorption of Ni(II) on bentonite/iron oxide
magnetic composites was an endothermic and spontaneous processes. The results show that bentonite/iron oxide magnetic composites
are promising magnetic materials for the preconcentration and separation of radionickel from aqueous solutions in environmental
pollution. 相似文献
2.
The sorption of Pb(II) from aqueous solution using NKF-5 zeolite was investigated by batch technique under ambient conditions.
The NKF-5 zeolite sample was characterized by using FTIR and X-ray powder diffraction in detail. The sorption of Pb(II) was
investigated as a function of pH, ionic strength, foreign ions, and humic substances. The results indicated that the sorption
of Pb(II) on NKF-5 zeolite was strongly dependent on pH. The sorption was dependent on ionic strength at low pH, but independent
of ionic strength at high pH. At low pH, the sorption of Pb(II) was dominated by outer-sphere surface complexation and ion
exchange with H+ on NKF-5 zeolite surfaces, whereas inner-sphere surface complexation was the main sorption mechanism at high pH. From the
experimental results, one can conclude that NKF-5 zeolite has good potentialities for cost-effective preconcentration of Pb(II)
from large volumes of aqueous solutions. 相似文献
3.
Liang Chen Shaoming Yu Liming Zuo Bin Liu Lingli Huang 《Journal of Radioanalytical and Nuclear Chemistry》2011,289(2):511-520
In this study, a local bentonite from Gaomiaozi county (Inner Mongolia, China) was converted to Na-bentonite and was characterized
by FTIR and XRD to determine its chemical constituents and micro-structure. The removal of cobalt from aqueous solutions by
Na-bentonite was investigated as a function of contact time, pH, ionic strength, foreign ions and temperature by batch technique
under ambient conditions. The results indicated that the sorption of Co(II) was strongly dependent on pH. At low pH, the sorption
of Co(II) was dominated by outer-sphere surface complexation or ion exchange whereas inner-sphere surface complexation was
the main sorption mechanism at high pH. The Langmuir, Freundlich, and D-R models were used to simulate the sorption isotherms
of Co(II) at the temperatures of 293.15, 313.15 and 333.15 K, respectively. The thermodynamic parameters (∆G°, ∆S°, ∆H°) of Co(II) sorption on GMZ bentonite calculated from the temperature-dependent sorption isotherms indicated that the sorption
of Co(II) on GMZ bentonite was an exothermic and spontaneous process. The Na-bentonite is a suitable material for the preconcentration
and solidification of Co(II) from aqueous solutions. 相似文献
4.
Liu Xia Chen Yuantao Chi Yaling Guo Zhijun Cai Linsen 《Journal of Radioanalytical and Nuclear Chemistry》2012,292(3):1357-1366
In this article, a series of batch experiments were carried out to investigate the effect of various environmental factors
such as contact time, solid content, pH, ionic strength, foreign ions, temperature and coexisting humic acid on the sorption
behavior radionuclide 60Co(II) on illite. The results indicated that the sorption of Co(II) was strongly dependent on pH, ionic strength and temperature.
At low pH, the sorption was dominated by outer-sphere surface complexation and ion exchange on illite surfaces, whereas inner-sphere
surface complexation was the main sorption mechanism at high pH. The Langmuir, Freundlich and Dubinin-Radushkevich (D-R) models
were used to simulate the sorption isotherms at three different temperatures of 303.15, 323.15 and 343.15 K. The thermodynamic
data (∆G
0, ∆S
0, ∆H
0) were calculated from the temperature dependent sorption isotherms and the results suggested that the sorption process of
Co(II) on illite was an endothermic and spontaneous process. The sorption test revealed that the illite can be as a cost-effective
adsorbent suitable for pre-concentration of Co(II) from large volumes of aqueous solutions. 相似文献
5.
MX-80 bentonite was detected using acid-based titration, XRD and FTIR in detail. The sorption behavior of 63Ni(Ⅱ) from aqueous solution to MX-80 bentonite was investigated as a function of solid content, ionic strength and pH by using batch technique. The experimental data of 63Ni(Ⅱ) sorption on MX-80 bentonite was obtained using the diffuse layer model (DLM) with the aid of FITEQL 3.1 program. The results indicated that the sorption of 63Ni(Ⅱ) on MX-80 bentonite was mainly dominated by surface complexation... 相似文献
6.
The development of nuclear power releases large amounts of radionuclides into the natural environment. Herein, the sorption of radionuclide 63Ni on bentonite from Gaomiaozi county (Inner Mongolia, China) at different experimental conditions such as pH, contact time, ionic strength, foreign cations and anions, and temperatures were investigated by using batch technique. The results indicated that the sorption of 63Ni on the bentonite was quickly at first contact time and then increased slowly with increasing contact time. The sorption of 63Ni was strongly dependent on ionic strength at low pH values and independent of ionic strength at high pH values. The sorption of 63Ni on bentonite was mainly dominated by outer-sphere surface complexation or ion exchange at low pH values, whereas inner-sphere surface complexation was the main sorption mechanism at high pH values. The Langmuir, Freundlich, and D–R models were applied to simulate the sorption isotherms of 63Ni at three different temperatures, and the thermodynamic parameters (i.e., ΔH°, ΔS° and ΔG°) calculated from the temperature-dependent sorption isotherms indicated that the sorption of 63Ni on bentonite was an endothermic and spontaneous process. Experimental results indicate that the bentonite is a suitable material for the preconcentration and solidification of 63Ni from large volume of solutions in radionickel pollution cleanup. 相似文献
7.
Yunhui Dong Zhengjie Liu Yueyun Li 《Journal of Radioanalytical and Nuclear Chemistry》2011,289(1):257-265
Bentonite has been studied extensively because of its strong sorption and complexation ability. Herein, GMZ bentonite from
Gaomiaozi county (Inner Mongolia, China) was investigated as the candidate of backfill material for the removal of Th(IV)
ions from aqueous solutions. The results indicate that the sorption of Th(IV) is strongly dependent on pH and ionic strength
at pH < 5, and independent of ionic strength at pH > 5. Outer-sphere surface complexation or ion-exchange are the main mechanism
of Th(IV) sorption on GMZ bentonite at low pH values, whereas the sorption of Th(IV) at pH > 5 is mainly dominated by inner-sphere
surface complexation or surface precipitation. Soil fulvic acid (FA) and humic acid (HA) have a positive influence on the
sorption of Th(IV) on bentonite at pH < 5. The different addition sequences of HA and Th(IV) to GMZ bentonite suspensions
have no obvious effect on Th(IV) sorption to HA-bentonite hybrids. The high sorption capacity of Th(IV) on GMZ bentonite suggests
that the GMZ bentonite can remove Th(IV) ions from large volumes of aqueous solutions in real work. 相似文献
8.
Hui Zhang Xianjin Yu Lei Chen Jiaqiang Geng 《Journal of Radioanalytical and Nuclear Chemistry》2010,286(1):249-258
The sorption of 63Ni(II) from aqueous solution using ZSM-5 zeolite was investigated by batch technique under ambient conditions. ZSM-5 zeolite
was characterized by point of zero net proton charge (PZNPC) titration. The sorption was investigated as a function of shaking
time, pH, ionic strength, foreign ions, humic acid (HA), fulvic acid (FA) and temperature. The results indicate that the sorption
of 63Ni(II) on ZSM-5 zeolite is strongly dependent on pH. The sorption is dependent on ionic strength at low pH, but independent
of ionic strength at high pH values. The presence of HA/FA enhances 63Ni(II) sorption at low pH values, whereas reduces 63Ni(II) sorption at high pH values. The sorption isotherms are simulated by Langmuir model very well. The thermodynamic parameters
(i.e., ∆H
0, ∆S
0 and ∆G
0) for the sorption of 63Ni(II) are determined from the temperature dependent sorption isotherms at 293.15, 313.15 and 333.15 K, respectively, and
the results indicate that the sorption process of 63Ni(II) on ZSM-5 zeolite is spontaneous and endothermic. 相似文献
9.
Yaling Chi Yuantao Chen Xia Liu Zhijun Guo Linsen Cai 《Journal of Radioanalytical and Nuclear Chemistry》2012,292(3):1349-1355
The sorption of UO2 2+ from aqueous solution on attapulgite was investigated as a function of contact time, solid content, pH, ionic strength, foreign ions, humic acid (HA), and fulvic acid (FA) under ambient conditions by using batch technique. The attapulgite sample was characterized by XRD and FTIR in detail. The results indicated that the sorption of UO2 2+ was strongly dependent on pH and ionic strength. The sorption of UO2 2+ on attapulgite increased quickly with rising pH at pH < 6.5, and decreased with increasing pH at pH > 6.5. The presence of HA or FA enhanced the sorption of UO2 2+ on attapulgite obviously at low pH because of the strong complexation of surface adsorbed HA/FA with UO2 2+ on attapulgite surface. Sorption of UO2 2+ on attapulgite was mainly dominated by ion-exchange or outer-sphere surface complexation at low pH values, but by inner-sphere surface complexation at high pH values. The results indicate that attapulgite is a very suitable adsorbent for the preconcentration and solidification of UO2 2+ from large volumes of aqueous solutions because of its negative surface charge and large surface areas. 相似文献
10.
Different kinds of clay minerals have been studied extensively in the removal of radionuclides from large volumes of aqueous solutions because of their high sorption capacity. Herein, the Na-montmorillonite was characterized by using XRD and FTIR in detail. The sorption of 63Ni(II) from aqueous solution to montmorillonite as a function of pH, ionic strength, foreign ions, humic substances and temperature was studied by batch technique. The sorption of 63Ni(II) on montmorillonite achieved equilibration quickly. The sorption of 63Ni(II) to montmorillonite was strongly dependent on pH, and dependent on ionic strength at low pH and independent of ionic strength at high pH values. The sorption of 63Ni(II) on montmorillonite was enhanced at low pH in the presence of humic acid (HA), while a negative effect of HA on 63Ni(II) sorption was found at high pH values. At low pH values, the sorption of 63Ni(II) was attributed to outer-sphere surface complexation or ion exchange, whereas the sorption was dominated by inner-sphere surface complexation at high pH values. The montmorillonite sample is a suitable material in the preconcentration of radionuclides from large volumes and the material can be used as backfill material in nuclear waste repository. 相似文献
11.
Lipeng Zhang Hui Zhang Zhiwei Ge Xianjin Yu 《Journal of Radioanalytical and Nuclear Chemistry》2011,288(2):537-546
The fate and transport of toxic metal ions and radionuclides in the environment is generally controlled by sorption reactions.
The removal of 60Co(II) from wastewaters by MnO2 was studied as a function of various environmental parameters such as shaking time, pH, ionic strength, foreign ions, and
humic substances under ambient conditions. The results indicated that the sorption of 60Co(II) on MnO2 was strongly dependent on pH and ionic strength. At low pH, the sorption of 60Co(II) was dominated by outer-sphere surface complexation and ion exchange with Na+/H+ on MnO2 surfaces, whereas inner-sphere surface complexation was the main sorption mechanism at high pH. The presence of HA/FA enhances
60Co(II) sorption at low pH values, whereas reduces 60Co(II) sorption at high pH values. The Langmuir and Freundlich models were used to simulate the sorption isotherms of 60Co(II) at three different temperatures of 298.15, 318.15 and 338.15 K. The thermodynamic parameters (ΔH
0, ΔS
0 and ΔG
0) calculated from the temperature dependent sorption isotherms indicated that the sorption process of 60Co(II) on MnO2 was endothermic and spontaneous. 相似文献
12.
N. M. Alandis O. A. Aldayel W. K. Mekhemer J. A. Hefne H. A. Jokhab 《Journal of Dispersion Science and Technology》2013,34(11):1526-1534
In this study, the adsorption behavior of natural bentonite with respect to Fe(III) and Ni(II) has been studied in order to consider its application to purity metal finishing wastewaters. During the adsorption process, batch technique is used, and the effects of pH, bentoite amount, temperature, heavy metal concentration, bentonite treatment (calcinations of natural bentonite at 700°C, washing by deionized water to remove the excess salt from bentonite surface), and agitation time on adsorption efficiency are studied. The washed and calcined bentonite samples were labeled by WB and CB, respectively. The pH-dependence of Fe(III) and Ni(II) sorption on the bentonite is significantly more noticeable, indicating a major contribution of surface complexation at the edge sites. It was determined that adsorption of Fe(III) and Ni(II) is well fitted by the second order reaction kinetic. Furthermore, the sorption rate of Fe(III) was higher than the sorption rate of Ni(II). Adsorption of Fe(III) and Ni(II) on NB appeared to follow Langmuir isotherm. In addition, calculated and experimental adsorbed amounts of Fe(III) by the unit NB mass are very higher than Ni(II). The paper also discusses the thermodynamic parameters of the adsorption (the Gibbs free energy, entropy, and enthalpy). Our results demonstrate that the adsorption process was spontaneous and endothermic under natural conditions. Also the adsorption capacity of bentonite for Fe(III) Ni(II) and increases with increased bentonite dose. According to the equilibrium studies, the selectivity sequence can be given as Fe(III) > Ni(II). The adsorbed amount of Fe(III) and Ni(II) on washed bentonite (WB) were very higher compared to NB and CB. Our results show that bentonite could especially WB be considered as a potential adsorbent for Fe(III) and Ni(II) removal from aqueous solutions. 相似文献
13.
R. Kandlbinder V. Geißler R. Schupfner O. Wolfbeis B. Zinka 《Journal of Radioanalytical and Nuclear Chemistry》2009,280(1):113-119
The adsorption of Cs on clayey materials such as bentonite and Na-montmorillonite was studied in various electrolytic conditions
(concentration and composition), various solid to liquid ratios and various pH conditions. The results obtained for these
different conditions were modeled considering an exchange model associated to the surface complexation concept. Then, the
same approach was considered to model the sorption of Rb, which have the same chemical behavior than Cs. Experiments were
carried out for various electrolyte, pH, and Rb concentrations. The stoichiometries corresponding to the sorption of Rb on
bentonite and montmorillonite were then deduced from the experimental results. 相似文献
14.
Investigation of sequestration mechanisms of radionuclide 63Ni(II) on kaolinite in aqueous solutions
Pengfei Zong Hui Pan Hai Wang Chaohui He 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(1):405-413
To better understand the application of kaolinite as an adsorbent for the decontamination of Ni(II) from radionuclide contaminated aqueous systems, herein, the sorption behavior of radionuclide 63Ni(II) on kaolinite as a function of contacting time, pH, coexistent electrolyte ions, adsorbent concentration, fulvic acid and humic acid was investigated using batch technique. At low pH values, ion exchange and/or outer-sphere surface complexation was the main mechanism of Ni(II) sorption on kaolinite, whereas, the sorption of Ni(II) was dominated by inner-sphere surface complexation at high pH values. The presence of different electrolyte ions can enhance or inhibit the sorption of Ni(II) on kaolinite to some extent. The Langmuir and Freundlich models were used to simulate the sorption isotherms of Ni(II) at three different temperatures of 288, 313 and 338 K. The thermodynamic parameters (i.e., ΔS°, ΔH°, and ΔG°) calculated from the temperature-dependent sorption isotherms indicated that the sorption reaction of Ni(II) on kaolinite was endothermic and spontaneous. The findings in this present study demonstrates that the kaolinite can be used as a cost-effective adsorbent for the solidification and pre-concentration of Ni(II) from large volumes of aqueous systems. 相似文献
15.
Xue Wang 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(3):2301-2308
Sequestration of Ni(II) on diatomite as a function of reaction time, pH, ionic strength, foreign ions and temperature were investigated by batch sorption technique. The results indicated that the sorption of Ni(II) on diatomite was quickly in the first contact time of 2 h and then slowly with increasing contact time. The interaction of Ni(II) with diatomite was strongly pH- and ionic strength-dependent at low pH values (i.e., which was dominated by ion exchange or outer-sphere surface complexation), while the pH-dependent and ionic strength-independent sorption at high pH suggested that inner-sphere or multinuclear surface complexation was the main sorption mechanism. With increasing temperature, the sorption of Ni(II) on diatomite increased and the experimental data were well fitted by Langmuir model. The sorption samples at pH 6.8 and 10.0 were also characterized by XPS spectroscopy, and the results suggested that Si atoms also participated in Ni(II) sorption on diatomite. The results are important to evaluate the physicochemical behavior of Ni(II) and other similar radionuclides and heavy metal ions in the environment. 相似文献
16.
Lei Chen Bin Gao Songsheng Lu Yunhui Dong 《Journal of Radioanalytical and Nuclear Chemistry》2011,288(3):851-858
Sorption of radionickel on attapulgite is studied as a function of contact time, ionic strength, pH and temperature. The results indicate that the sorption of Ni(II) on attapulgite is strongly ionic strength-dependent at pH <8, and independent of ionic strength at pH >8. Outer-sphere surface complexation or ion exchange contributes to Ni(II) sorption on attapulgite at pH <8, whereas the sorption of Ni(II) is mainly dominated by inner-sphere surface complexation at pH >8. The sorption of Ni(II) on attapulgite increases with increasing temperature, and the thermodynamic parameters (??H 0, ??G 0 and ??S 0) calculated from the temperature dependent sorption isotherms suggest that the sorption of Ni(II) on attapulgite is a spontaneous and endothermic process. The high sorption capacity of attapulgite suggests that attapulgite is a suitable material for the preconcentration and solidification of radionickel from large volumes of aqueous solutions. 相似文献
17.
Yan Huang Liang Chen Hualin Wang 《Journal of Radioanalytical and Nuclear Chemistry》2012,291(3):777-785
Herein, hydroxyapatite (HAP) was prepared by aqueous precipitation technique and was characterized by using FT-IR and XRD
to determine its chemical functional groups and micro-structure. The removal of cobalt from aqueous solution to HAP was studied
by batch technique as a function of various environmental parameters such as contact time, pH, ionic strength, foreign ions,
fulvic acid (FA), and temperature under ambient conditions. The results indicated that the sorption of Co(II) on HAP was strongly
dependent on pH and ionic strength. The presence of FA enhanced the sorption of Co(II) on HAP at low pH, whereas reduced Co(II)
sorption on HAP at high pH. The Langmuir, Freundlich and D-R models were used to simulate the sorption isotherms at three
different temperatures of 303.15, 323.15 and 343.15 K. The thermodynamic parameters (ΔH°, ΔS° and ΔG°) calculated from the temperature dependent sorption isotherms indicated that the sorption process of Co(II) on HAP was spontaneous
and endothermic. The sorption of Co(II) was dominated by outer-sphere surface complexation and ion exchange at low pH, whereas
inner-sphere surface complexation or surface precipitation was the main sorption mechanism at high pH values. The results
suggest that the HAP is a suitable material in the preconcentration and solidification of Co(II) from large volumes of aqueous
solutions. 相似文献
18.
Yong Qiu Shaoming Yu Leilei Cheng Feifei Lu 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(3):1673-1681
The acid-activated sepiolite (ASEP) was prepared by physical purification and acid activation of natural sepiolite, and was characterized by XRD, FT-IR, SEM and N2 adsorption–desorption. The prepared ASEP was applied for the sorption of 60Co(II) from aqueous solutions. The sorption of 60Co(II) from aqueous solutions by ASEP was investigated as a function of contact time, solid content, pH, ionic strength, foreign ions, humic acid (HA) and temperature. The results indicated that the sorption of 60Co(II) on ASEP was strongly dependent on pH values. At low pH, the sorption of 60Co(II) was dominated by outer-sphere surface complexation or ion exchange, whereas inner-sphere surface complexation or surface precipitation was the main sorption mechanism at high pH. The presence of HA increased the sorption of 60Co(II) on ASEP at low pH values, and reduced the sorption at high pH values. The Langmuir and Freundlich models were applied to simulate the sorption of 60Co(II) at three temperatures of 298, 318 and 338 K. The thermodynamic parameters ( $ \Updelta G^\circ ,\,\;\Updelta S^\circ $ and $ \Updelta H^\circ $ ) calculated from the temperature dependent sorption isotherms indicated that the sorption of 60Co(II) on ASEP was an endothermic and spontaneous process. ASEP has a great application potential for cost-effective disposal of 60Co(II) from large volumes of aqueous solutions. 相似文献
19.
Chen Lei Xiangping Tian Baohua Ma 《Journal of Radioanalytical and Nuclear Chemistry》2013,298(2):1127-1135
In this paper, the attapulgite-iron oxide magnetic composites were synthesized by coprecipitation method and were characterized by SEM, XRD and FTIR in detail. The characterization results indicated that the iron oxide was successfully formed on the surface of attapulgite. The prepared attapulgite-iron oxide magnetic composites were applied as adsorbents to remove Eu(III) from aqueous solutions by using batch sorption experiments under different experimental conditions. The sorption properties of Eu(III) on bare attapulgite were also performed as comparison. The results indicated that the sorption of Eu(III) on attapulgite-iron oxide magnetic composites was strongly dependent on pH and temperature. The attapulgite-iron oxide magnetic composites can be separated from aqueous solutions using magnetic separation method in large scale. At low pH values, the sorption of Eu(III) was influenced by ionic strength and pH obviously, while the sorption of Eu(III) was not affected by ionic strength at high pH values. The sorption of Eu(III) was dominated by ion exchange or outer-sphere surface complexation at low pH values, and mainly by inner-sphere surface complexation at high pH values. The thermodynamic parameters (i.e., ?G °, ?S °, ?H °) calculated from the temperature dependent sorption isotherms indicated that the sorption of Eu(III) on attapulgite-iron oxide magnetic composites was an endothermic and spontaneous process. Although the sorption capacities of Eu(III) on attapulgite-iron oxide magnetic composites were a little lower than those of Eu(III) on bare attapulgite, the magnetic separation in large scale is suitable for the application of the magnetic composites in the preconcentration of Eu(III) from large volumes of aqueous solutions in possible real applications. 相似文献
20.
Xiaoping Song Yajie Wang Jingjing Cai 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(2):991-1000
Bentonite has been studied extensively because of its strong sorption and complexation ability. In this study, GMZ bentonite (China) was studied as a potential sorbent for the removal of Th(IV) from aqueous solutions. The results indicate that the sorption of Th(IV) is strongly dependent on pH and ionic strength at pH <5, and is independent of ionic strength at pH >5. Outer-sphere surface complexation or ion exchange in inter-layer sites of the montmorillonite fraction of the GMZ bentonite may be the main sorption mechanism of Th(IV) onto GMZ bentonite at low pH values, whereas the sorption of Th(IV) at pH >5 is mainly dominated by inner-sphere surface complexation or surface precipitation. The presence of soil fulvic acid has a positive influence on the sorption of Th(IV) on GMZ bentonite at pH <5. The competition between Th(IV) with aqueous or surface adsorbed cation ions (e.g., herein Li+, Na+ and K+) and surface functional groups of GMZ bentonite is important for Th(IV) sorption on GMZ bentonite. The results of high sorption of Th(IV) suggest that the GMZ bentonite is a suitable backfill material in nuclear waste management. 相似文献