Formation of excited states of hydrogen atoms scattered from metal surfaces

The capture of electrons into excited states by protons scattered from a smooth metal surface at grazing incidence is treated using an Anderson hamiltonian with a degenerate atomic level. The shift of the metal Fermi sphere due to motion of the atom parallel to the surface brings some of the metal conduction electrons into resonance with excited hydrogen levels. This leads to formation of anisotropic atomic states. The calculated polarization characteristics of H_α light emitted from the scattered atoms agree well with experimental results.     

Capture of polarized electrons into excited atomic states in grazing scattering from a magnetized Ni(110) surface

The spin polarization of electrons captured into excited atomic levels of atoms during the scattering of fast ions from a magnetized Ni(110) surface under a grazing angle of incidence is deduced from the polarization of the fluorescence light. In our studies we have investigated the dependence of the spin polarization on projectile velocity and angle of incidence and observed generally small polarizations for captured electrons.     

Diffraction of fast atomic projectiles during grazing scattering from a LiF(001) surface

Light atoms and molecules with energies from 300 eV to 25 keV are scattered under a grazing angle of incidence from a LiF(001) surface. For impact of neutral projectiles along low index directions for strings of atoms in the surface plane we observe a defined pattern of intensity spots in the angular distribution of reflected particles which is consistently described using concepts of diffraction theory and specific features of grazing scattering of atoms from insulator surfaces. Experimental results for scattering of H, D, 3He, and 4He atoms as well as H2 and D2 molecules can be unequivocally referred to atom diffraction with de Broglie wavelengths as low as about 0.001 Angstroms.     

自旋—轨道耦合下冷原子的双反射

随着中性冷原子气体的人造自旋-轨道耦合的实验实现,近年来人们开始关注与之相关的可能应用,其中包括自旋-轨道耦合下原子反射镜的研究.本文在前人研究的基础上,考虑一束自旋-轨道耦合的冷原子气体入射到有限高势垒的情形,通过将部分反射和全反射情况进行对比,发现了与之前研究不同的性质.我们发现,在全反射条件下,反射原子的极化率随入射角变化较大,而随自旋-轨道耦合强度和原子入射能量的变化较小.但在发生部分反射的情况下,反射原子的极化率不仅随入射角变化较大,随自旋-轨道耦合强度和原子的入射能量变化也十分明显.我们仔细研究了自旋-轨道耦合原子气体的反射性质并讨论了其可能的应用.     

Energy and charge distributions of fast hydrogen ions and atoms reflected from Cu in the case of grazing incidence

The energy and charge distributions of protons and hydrogen atoms reflected from the Cu surface in the case of grazing incidence angles are measured at energies of incident particles (H⁺ and H⁰) of 200 and 250 keV. The charged fractions of reflected particles are analyzed. A weak dependence of the neutral fraction of reflected particles on the scattering angle is discovered for incidence angles of 1°–2° and an energy of scattered particles of 60 keV or less. It is shown that the neutral fraction of reflected particles with an energy of 60–80 keV or more is independent of the scattering angle and is determined by the ratio of the cross sections for the electron capture and loss by ions in the material.     

Modification of Classical SPM for Slightly Rough Surface Scattering with Low Grazing Angle Incidence

Based on the impedance/admittance rough boundaries, the reflection coefficients and the scattering cross section with low grazing angle incidence are obtained for both VV and HH polarizations. The error of the classical perturbation method at grazing angle is overcome for the vertical polarization at a rough Neumann boundary of infinite extent. The derivation of the formulae and the numerical results show that the backscattering cross section depends on the grazing angle to the fourth power for both Neumann and Dirichlet boundary conditions with low grazing angle incidence. Our results can reduce to that of the classical small perturbation method by neglecting the Neumann and Dirichlet boundary conditions.     

Modification of Classical SPM for Slightly Rough Surface Scattering with Low Grazing Angle Incidence

Based on the impedance/admittance rough boundaries, the reflection coefficients and the scattering cross section with low grazing angle incidence are obtained for both VV and HH polarizations. The error of the classical perturbation method at grazing angle is overcome for the vertical polarization at a rough Neumann boundary of infinite extent. The derivation of the formulae and the numerical results show that the backscattering cross section depends on the grazing angle to the fourth power for both Neumann and Dirichlet boundary conditions with low grazing angle incidence. Our results can reduce to that of the classical small perturbation method by neglecting the Neumann and Dirichlet boundary conditions.     

Dynamic Potential of Interaction between Nitrogen Atoms and Aluminum Crystal Surface

Specific features of the angular distributions of accelerated neutral nitrogen atoms at the grazing angles of incidence on the Al(001) crystal surface have been investigated by the computer simulation method. The N–Al pair interaction potential is approximated by the three-parameter Morse potential with the energydependent coefficients. The angular distributions of scattered atoms have been simulated taking into account the interaction between atoms and several atomic layers in the lattice and the atomic displacement during thermal oscillations. The parameters of the pair potential of accelerated neutral nitrogen atoms in the energy range from 10 to 70 keV have been determined according to the best agreement between the calculated dependence of the rainbow scattering angle on the energy of particles incident on the crystal surface and the available experimental data.

     

Theory of atomic diffraction from evanescent waves

We review recent theoretical models and experiments dealing with the diffraction of neutral atoms by a reflection grating, formed by a standing evanescent wave. We analyze diffraction mechanisms proposed for normal and grazing incidence, point out their scopes and confront the theory with experiment. Received: 12 June 1999 / Published online: 8 September 1999     

Surface‐sensitive reflection‐mode EXAFS from layered sample systems: the influence of surface and interface roughness

The calculation of reflection‐mode grazing‐incidence X‐ray absorption spectra from single surfaces and (multi‐)layered systems is studied here. In particular, the influence of the surface and interface roughness was investigated in detail. Simulations of grazing‐incidence reflection‐mode EXAFS spectra using a simple Fresnel theory neglecting any effect of roughness are compared with the Névot–Croce model and the elaborated distorted‐wave Born approximation which both include surface and interface roughness. Data are presented for clean gold surfaces, where the strong influence of the surface roughness on the resulting spectra is demonstrated. Furthermore, in the case of layered systems, the influence of both the outer (air or vacuum side) surface roughness and the inner interface roughness on the reflection‐mode EXAFS spectra is evaluated. The practical consequences of the observed correlations are discussed, and a quantitative data analysis of a copper sample that was oxidized in ambient air for several months is shown, including the evaluation of specular reflectivity profiles at fixed energy.     

Production of high circular polarization by ion surface scattering of ferromagnets

From a theoretical analysis we predict large fractions of circular polarization of light emitted by ions scattered from surfaces of ferromagnetic single crystals. Maximum enhancement of circular polarization as compared to surface ion scattering from non-magnetic materials is again expected at grazing incidence. A circular polarization of 89% was estimated for the case of Ar⁺ ions scattered from the (110) plane of a Ni single crystal.     

Temperature dependence of surface magnetization in local-moment systems

We present a theory to study the temperature-dependent behavior of surface magnetization in a ferromagnetic semi-infinite crystal. Our approach is based on the single-site approximation for the s-f model. The effect of the semi-infinite nature of the crystal is taken into account by a localized perturbation method. Using the mean-field theory for the layer-dependent magnetization, the local density of states and the electron-spin polarization are investigated at different temperatures for ordinary and surface transition cases. The results show that the surface magnetic properties may differ strongly from those in the bulk and the coupling constant of atoms plays a decisive role in the degree of spin polarization. In particular, for the case in which the exchange coupling constant on the surface and between atoms in the first and second layer is higher than the corresponding in the bulk, an enhancement of surface Curie temperature and hence the spin polarization can be obtained.     

Modeling of neutral-atom scattering at the surface of a crystal for the case of grazing incidence

The features of the angular distributions of accelerated neutral atoms at grazing angles of incidence on the Al(001) surface are studied using the mathematical modeling method. The interaction of accelerated atoms with crystal-lattice atoms and the electronic properties and atomic structure of the Al(001) surface are calculated using the electron-density-functional method. The angular distributions of scattered atoms are modeled by taking into account their interaction with several atomic layers in the crystal lattice and atomic displacements during thermal oscillations. The influence of crystal surface-layer relaxation on rainbow scattering, i.e., the difference between the distances of planes on the surface and in the volume, is established. The possibilities of using the effect of rainbow scattering to study the structural features of a crystal surface are discussed.     

A study of the electronic excitation of he from grazing incidence ion-surface interaction

The neutralization of He⁺ at grazing incidence from a Ni(111) surface leads to excited states. The light emission from the 3d ³ D and 3d ¹ D states is studied as a function of the beam energy and angular parameters. The observed circular polarization dependence on the crystallographic surface directions is interpreted in terms of the Brillouin zone of the solid.     

Nearly backward reflection of bulk acoustic waves at grazing incidence in a TeO2 crystal

Reflection of bulk acoustic waves in a TeO₂ acoustooptic single crystal is studied for the case of a grazing incidence on the free crystal-vacuum boundary. The propagation and reflection of elastic waves is considered in the XOY plane of the material cut out in the form of a rectangular prism. An extraordinary case of reflection at the grazing incidence, when the energy flow of one of the two reflected waves in the crystal is directed opposite to that of the incident wave, is studied. It is shown that the transformation of the incident elastic energy into the energy of the backward-reflected wave can occur with an efficiency close to 100% and can be observed in a wide range of crystal cut angles. An abrupt change of the reflection coefficients in the vicinity of the critical angle is predicted.     

Calculations on the effect of the surface potential barrier in LEED

The main effects of the surface potential barrier in LEED arise from strong internal reflection of diffraction beams for incidence conditions close to those for their grazing emergence. Near each grazing emergence condition, the details of LEED intensity profiles depend on the amplitude coefficient of internal reflection and hence on the shape of the surface potential barrier. Calculations of the amplitude coefficient for real one-dimensional barrier potentials with shapes specified by three parameters are reported. The calculations are done as a function of the energy associated with the surface-normal momentum component of the internally incident beam. The potential has the image form at large distances from the surface and joins smoothly to a quadratic at an intermediate distance. The results are tabulated and an interpolation formula is given so that the amplitude coefficient of reflection can be evaluated readily for potentials of the assumed form. Applications to the calculation of LEED intensity lineshapes are summarized.     

Survival of He+ ions during grazing scattering from a Ag(111) surface

He+ ions as well as neutral He atoms with keV energies are scattered under a grazing angle of incidence from a clean and atomically flat Ag(111) surface. From a comparison of ion fractions observed after scattering of He+ ions and He atoms we find for energies below some keV small but defined fractions of ions that have survived the complete scattering event with the surface. This feature allows us to clear up the microscopic interaction scenario for Auger neutralization of He+ ions at a Ag(111) surface. The Auger neutralization rates are 2 to 3 orders of magnitude smaller than conventional rates derived from experiments for He+-metal systems and agree with recent calculations.     

Brewster effect on amplitude and phase of reflectivity in the exciton spectral region

For the first time the exact Brewster effect has been identified in the exciton reflection spectrum. Experimentally, the amplitude and phase of the reflection coefficient for the ground exciton state in ZnTe at 2 K were studied versus the angle of incidence. It is shown that, in spite of strong excitonic absorption, the reflectivity can be zero either in p- or in s-components of polarization, including the case of normal incidence. The observation conditions for the effect are analysed within the framework of the spatial dispersion theory taking into account the presence of the exciton-free surface layer.     

Coherent reflection of he atom beams from rough surfaces at grazing incidence

We report coherent reflection of thermal He atom beams from various microscopically rough surfaces at grazing incidence. For a sufficiently small normal component k(z) of the incident wave vector of the atom the reflection probability is found to be a function of k(z) only. This behavior is explained by quantum reflection at the attractive branch of the Casimir-van der Waals interaction potential. For larger values of k(z) the overall reflection probability decreases rapidly and is found to also depend on the parallel component k(x) of the wave vector. The material specific k(x) dependence for this classic reflection at the repulsive branch of the potential is discussed in terms of an averaging out of the surface roughness under grazing incidence conditions.