Dynamics of liquid silane

Neutron scattering of cold neutrons from liquid silane at 137° K and 98°K is explained on the basis of a simple model. The rotational diffusion constant,D _r, and the delay time,τ ₀, after which rotational diffusion may be said to occur are derived on the basis of this model. At 137° K we getD _r=0.22×10¹³ sec⁻¹ andτ ₀=0.68×10⁻¹³ sec. At 98°KD _r (=0.06×10¹³ sec⁻¹) is down by a factor of more than three butτ ₀=(0.54×10⁻¹³ sec) shows only a small change. By comparison with data on liquid CH₄ it is concluded that the law of corresponding states is not applicable for describing rotational dynamics of CH₄ and SiH₄. Rotational motions in SiH₄ are more hindered than in CH₄ at the same reduced temperature.     

Dynamics of a supercooled liquid

The theory of collective motion in liquids suggested by the authors has been found to explain successfully the recent experimental results of temperature dependent disorder in supercooled liquid gallium. Metastability limit is exhibited through a singularity of S(k, ω = 0) and corresponds to a critical value of correlation between different particles beyond which the supercooled liquid goes to the thermodynamically stable solid state.     

Control over parameters of photonic nanojets of dielectric microspheres

We report on the results of theoretical investigation of the parameters of photonic nanojets formed near the shadow surface of micron-sized dielectric spheres irradiated by a laser radiation. The longitudinal and transversal dimensions of the photonic nanojet and its peak intensity also are calculated as the functions of particle size, index of absorption, and optical contrast of the particulate material. The photonic nano-flux was simulated numerically in composite particles made of a core and a shell with different refractive indices and variable shell thickness. Some practical conclusions are drawn concerning the possible ways to gain the control over the nanojet parameters in micron-sized spherical particles.     

Dynamics of freezing and liquid instability

A theoretical analysis of the dynamic stability of a supercooled simple liquid to finite amplitude periodic density waves is presented. The theory predicts absence of a classical spinodal point for a simple one component liquid. A dynamical constraint on the formation of the bcc phase is revealed.     

Dynamics of laser-induced cavitation in liquid

This paper presents an analysis of the rate of bubble expansion and an estimate of maximum bubble diameter and bubble lifetime prior to collapse. Such data are needed for the optimization of system parameters for elemental analysis in water by laser-induced breakdown spectroscopy (LIBS). Two techniques were used for this study: pump-probe beam deflection and high-speed photography. Plasma in the water bulk was generated by a focussed laser pulse with energy of 140 mJ and pulse duration of 10 ns, operating at the fundamental Nd:YAG laser wavelength (1064 nm). Reasonable agreement on the value of maximum bubble diameter was obtained between the photographic and probe beam deflection results. Reasonable agreement for the total duration of the oscillating cavitation bubble was also obtained for the two techniques, with a mean value of ∼800 μs. A comparison between empirical results and predictions based on the Rayleigh equation is also presented.     

Liquids: Dynamics of liquid structure

The study of the liquid state is predominately an experimental subject so any useful definition of “dynamical structure” in liquids should be closely related to the types of experiments employed in these studies. Most studies of the liquid state have been carried out for fluids lying on or near the liquid-vapor coexistence curve, the line connecting the triple point (T.P.) and the critical point (C.P.). The shaded portion of Figure 1 indicates this region. The term dynamical structure suggests measurements on systems which are not in thermodynamic equilibrium. Even so, equilibrium properties are determined through the application of the fluctuation dissipation theorem. Before we present a heuristic definition of dynamical structure, let us first consider an example which illustrates this definition.     

Controlling the parameters of photon nanojets of composite microspheres

We consider the spatial and amplitude characteristics of PNJ forming in the neighborhood of the shadow surface of micron-sized composite particles consisting of a nucleus and a shell with various refraction indices when laser radiation scatters on them. We study the longitudinal and transverse dimensions of a photon flux and its peak intensity depending on the microparticle shell thickness. We show that a certain choice of the refraction index of the shell relative to the nucleus in two-layer composite spherical microparticles can significantly lengthen the forming PNJ or increase their peak intensity. The width of the photon flux during this changes insignificantly.     

Experimental observation of nanojets formed by heating PbO-coated Pb clusters

We are reporting the first experimental observation of nanojets formed by heating PbO-coated Pb clusters, which has been predicted theoretically by Moseler and Landman. During heating, the hot liquid is ejected through the broken orifice into a vacuum and forms a condensed trail in the shape of a tadpole, as shown in the transmission electron micrographs. The temperature-variable Raman spectra indicate that nanojet formation is closely related to the heating temperature and thus essentially to the pressure in the coated clusters. The pressure inside the shell rises from the inner core's melting and its confined volume expansion. It then drops after the final explosion, dominating the whole nanojetting process.     

Dynamics of liquid 4He in vycor

Using inelastic neutron scattering, we have observed well-defined phonon-roton ( p-r) excitations in superfluid 4He in Vycor over a wide wave-vector range, 0.3相似文献   

Dynamics of nanoparticles in a supercooled liquid

The dynamic properties of nanoparticles suspended in a supercooled glass forming liquid are studied by x-ray photon correlation spectroscopy. While at high temperatures the particles undergo Brownian motion the measurements closer to the glass transition indicate hyperdiffusive behavior. In this state the dynamics is independent of the local structural arrangement of nanoparticles, suggesting a cooperative behavior governed by the near-vitreous solvent.     

Dynamics of a circular array of liquid columns

We report on an experimental study of an array of liquid columns, hanging below an overflowing circular dish fed at a constant flow-rate. This one-dimensional pattern exhibits spatio-temporal chaos as well as a host of ordered dynamical regimes, depending on flow-rate, initial positions, number of columns, and liquid properties. In this paper, we present stability diagrams obtained with liquids of different properties and an extensive quantitative study of the ordered, predictable dynamical states. Some destabilization mechanisms of these regimes are also presented.     

Dynamics of liquid ammonia from cold neutron scattering

The scattering of 4.1 Å neutrons by liquid ammonia has been measured at 218 K in the angular range of 30–90° using the Trombay rotating crystal spectrometer. The experimental data, after correcting for multiple scattering, have been compared with model calculations, and it is shown that it is possible to get detailed information about the rotational correlation function on the basis of neutron experiments alone. The model assumes Langevin diffusion for translational motions. Rotational motions are described by means of an orientational correlation function which has a gaseous behaviour for times up toτ ₀ and then changes over to a diffusive character with a rotational diffusion constantD _r. Within the framework of the model the correlation function can be described withD _r=0.28×10¹³sec^?1 andτ ₀=0.57×10^?18sec. Corrections for multiple scattering and their dependence on model parameters are discussed.     

Dynamics of excitations in a one-dimensional bose liquid

We show that the dynamic structure factor of a one-dimensional Bose liquid has a power-law singularity defining the main mode of collective excitations. Using the Lieb-Liniger model, we evaluate the corresponding exponent as a function of the wave vector and the interaction strength.     

Dynamics and hydrogen bonding in liquid ethanol

Molecular dynamics simulations of liquid ethanol at three temperatures have been carried out. The hydrogen bonding states of ethanol molecules have been characterized by the number of hydrogen bonds in which the molecules participate. It is observed that the mean lifetimes of molecules in each hydrogen bonding state are markedly dependent on the temperature. Moreover, molecules with one hydrogen bond are more stable when they are donors than when they are acceptors. The dependence of the reorientational correlation functions on the hydrogen bonding state of molecules has been studied carefully. The decay of these functions is slower for molecules with higher numbers of hydrogen bonds and also becomes slower as temperature decreases. The relaxation for molecules with only one hydrogen bond is faster for those acting as proton donors than for those acting as proton acceptors. Finally, the results obtained by computer simulation are compared with those from recent measurements of the frequency-dependent dielectric permittivity of liquid ethanol.     

Photonic nanojets as three-dimensional optical atom traps: A theoretical study

We show that an efficient three-dimensional optical atom trap can be achieved by light scattered off a dielectric microsphere. Namely, under suitable conditions, a plane wave incident on a polymer sphere produces a focal point in the forward scattering direction known as photonic nanojet. The photonic nanojet is formed at a distance of a few micrometers away from the surface of the sphere wherein the Casimir–Polder interaction felt by an atom is negligible compared to the optical and gravitational potentials. When many polymer spheres are brought together so as to form a linear chain, a one-dimensional periodic optical lattice filled with cold atoms is possible since interference between the incident and scattered beams is minimal when the spheres are not too close.     

Formation of microbumps and nanojets on gold targets by femtosecond laser pulses

Femtosecond laser-induced sub-wavelength microstructuring of a thin gold layer coated onto a quartz glass substrate is investigated. Formation of microbumps (microbubbles) and nanojets under single pulse laser irradiation is observed. Discussion of these effects and demonstration of their dependencies on the laser pulse energy and gold layer thickness are presented. PACS 42.62-b; 42.65.Re; 52.38.Mf