Reaction of formaldehyde with hydrogen sulfide

Conclusions The reaction of CH₂O with H₂S gives a complex mixture of mercapto derivatives; the conversion of the latter to polymethylene sulfide is accomplished in the presence of a basic catalyst.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1631–1633, July, 1982.     

Reaction of thiourea with formaldehyde and simplest aliphatic diamines

N,N′-Bis(hydroxymethyl)thiourea reacted with propane-1,3-diamine at a molar ratio of 2 : 1 to give 5,5′-propane-1,3-diylbis(1,3,5-triazinane-2-thione), whereas 1,3,5,7,11,13,15,17-octaazatricyclo[15.3.1.1^7,11]-docosane-4,14-dithione was obtained in the reaction with equimolar amounts of the reactants. Tricyclic product was also formed in the three-component condensation of thiourea with formaldehyde and propane-1,3-diamine at a ratio of 1 : 3 : 1. The reactions of N,N′-bis(hydroxymethyl)thiourea with ethane-1,2-diamine (2 : 1) and of thiourea with formaldehyde and butane-1,4-diamine (1 : 2 : 1) afforded 5,5′-(ethane-1,2-diyl)bis(1,3,5-triazinane-2-thione) and 5,5′-(butane-1,4-diyl)bis(1,3,5-triazinane-2-thione), respectively.     

Reaction of ethyl acetoacetate with formaldehyde and primary amines

The condensation of ethyl acetoacetate with formaldehyde and primary amines in methanol at 65°C (Mannich reaction) gave up to 92% of hexahydropyrimidine derivatives containing ester and acetyl groups. Analogous reaction with aminopyridines stopped at the stage of formation of linear condensation products.     

Reaction of 2-vinylfuran with formaldehyde catalyzed by palladium complexes

Conclusion 5-Hydroxymethyl-2-vinylfuran is formed when 2-vinylfuran reacts with formaldehyde in the presence of Pd(acac)₂-PPh₃-Al(C₂H₅)₃ catalyst (1:3:4) in a 70% yield.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 693–695, March, 1976.     

Products of Reaction of NH with NO

The products of reaction of NO with breakdown products of NH₃ in an H₂/N₂/O₂ flame at 1500 K were investigated by mass spectrometric analysis of the hot gases. It is concluded that the major process involving NO and NH is NO + NH → N₂ + O + H and that not more than 10% of reactive collisions between these species lead to N₂O + H.     

Reaction of 3-methoxy-17-methylmorphinan-6-one with formaldehyde

Reaction of 3-methoxy-17-methylmorphinan-6-one ( 1 ) and formaldehyde with the presence of calcium hydroxide in aqueous dioxane gave 7,7-bis(hydroxymethyl)-3-methoxy-17-methyl-5-methylenemorphinan-6β-ol ( 2a ). Catalytic reduction of 2a yielded the 5α-methyl compound, 2b . Tosylation of 2a,b followed by lithium triethylborohydride reduction gave either 7α-methyl-6β,7β-oxetanes 4a,b or 7,7-dimethyl-6β-ols 5a,b , depending on reaction conditions. The C-6 ketones 6a,b were prepared by oxidation of 5a,b . One compound in this series, 6a , had antinociceptive activity.     

Reaction Products of Methylene Iodide with Tertiary Arsines

The reactions products of tertiary arsines with methylene iodide are (iodomethyl)trialkyl(aryl)-arsonium iodides. Treatment of the latter with lead(II) nitrate in aqueous ethanol solutions gives rise to an exchange reaction to form the corresponding nitrates in high yields.__________Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 2, 2005, pp. 268–271.Original Russian Text Copyright © 2005 by Gigauri, Arabuli, Machaidze, Rusiya.     

Reaction of Dimerized Fatty Acid with Aliphatic Diamines and Properties of Reaction Products

The reactions of dicarboxylic acids with di- and triamines were studied, and the properties of the resulting polyamides were examinated in relation to the structure and ratio of the starting reactants.     

Reaction of 1,3- hydroxylamino oximes with formaldehyde,acetaldehyde, and acetone

The products of condensation of 1,3-hydroxylamino oximes with formaldehyde have 1-hydroxy-1,2,5,6-tetrahydropyrimidine 3-oxide (cyclic form) structures, the products of condensation with acetone have N-(3-oximino-substituted)-,-dimethylnitrone (open form) structures, and the products of condensation with acetaldehyde exist in solution in the form of a tautomeric mixture of the open and cyclic forms. The products of condensation of alkyl-aromatic 1,3-hydroxylamino oximes with acetaldehyde have N-(3-oximino-substituted)--nitrone (open form) structures.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 252–258, February, 1977.     

Reaction of trialkyl-(3-aminopropyl)silanes with formaldehyde and elemental sulfur

Conclusions N-(3-Trialkylsilylpropyl)formamides (II) and N,N-bis(3-trialkylsilylpropyl)thioureas (III), together with a small amount of the trialkyl-(3-isothiocyanatopropyl)silane, are formed when trialkyl-(3-aminopropyl)silanes are reacted with formaldehyde and sulfur in aqueous-ethanol medium. 1,3,5-Tris(trialkylsilylpropyl)hexahydrotriazines are the intermediate products in these reactions.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 666–668, March, 1977.     

Reaction of γ-nitroketones and methyl 4-nitrobutanoates with formaldehyde and primary amines

5-Nitropentan-2-one reacts with methylamine and formaldehyde according to the Mannich reaction pattern to give 5-hexahydropyrimidinylcarbonyl-substituted 1-nitro-3,7-diazabicyclo[3.3.1]nonane in one experimental stage. When methyl 3-R-4-nitrobutanoates are used, the reaction stops after the formation of substituted 5-nitrohexahydropyrimidines in 40–98% yields. Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1687–1693, July, 2005.     

Cyclization of the Reaction Products of p-Phenylenediamine with Maleic Acid

Treatment of p-phenylenediamine with maleic acid and its diethyl ester gave di- and tetracarboxylic amino acids and their esters. A benzene derivative having an -alanine and an aspartic acid residue has been prepared. The cyclization of aminocarboxylic acids to imidazole and pyrimidine derivatives has been carried out.     

Methylchlorophosphanes and Their Reaction Products

Methyldichlorophosphane and dimethylchlorophosphane can be prepared only with considerable difficulty. The ease with which they yield numerous reaction products is an indication of the pronounced reactivity of these organohalophosphanes. Possible applications of such organophosphorus compounds exist inter alia in the fields of plant protection, corrosion prevention, and flame retardants, as well as in the catalysis of gas phase reactions, for instance the desulfurization of gas mixtures.     

Elucidation of the Reaction Products of Acetonitrile with Phosphorus Pentachloride

Abstract

The reaction of acetonitrile with PCl, results in the ionic compounds (1) to (4) containing the trichloro[2-chloro-2-[(trichlorophosphoranyli-dene)amino]ethenyl]phosphorus cations and not in the compounds [CH2?C?NPCl₃]PCl₆1 or trichloro[2-chloro-1 -[(trichlorophosphoranyli-dene)amino] ethenyl]phosphorus hexachlorophosphate (5) as assumed from ³¹P-NMR spectra [2, 3]. The crystal structures of the compounds (1) to (4) were determined with X-rays at 95K. As observed for the CI-C(NPCl₃); cation all the cations show cis-trans conformations with respect to their CI-C-X-P torsion angles. The wcl3 groups of the cations have two different orientations with one C?N?P?CI torsion angle of about 0° (cis) as in (1) or about 180° (trans) as in (3) and (4). In the salt (2) there are two formula units in the asymmetric unit with one cation showing the cis and the other showing the tram conformation.     

Reaction of carbazole with formaldehyde. Reactions of N-hydroxymethylcarbazole in the presence of acids

Formation of the reaction product from carbazole and formaldehyde (CF condensate) in the presence of hydrochloric acid takes place via a stage of equilibration between processes of formation and decomposition of N-hydroxymethylcarbazole.     

Reaction of formaldehyde with the Wilkinson complex in the presence of carboxylic acid amides

N,N-Dimethylacetamide and N, N-dimethyformamide react with RhCl(PPh₃)₃ with displacement of PPh₃ and the formation of a complex with the amide. Formamide and N-propylacetamide do not form similar complexes under similar conditions. In contrast to the reaction of RhCl(PPh₃)₃, which leads to the formation of RhCl(CO)(PPh₃)₂ due to decarbonylation of CH₂O, stabilization of the ₂-CH₂O form of the CH₂O coordinated with rhodium is likely in the reaction of formaldehyde with a rhodium complex containing an N-bonded amide. Under the conditions of hydroformylation of CH₂O in a solution of the Wilkinson complex in an unsubstituted amide the dominating pathway of the transformation of formaldehyde is its reaction with the solvent or the ammonia formed via decarbonylation of the unsubstituted amide.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2670–2673, December, 1989.