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1.
A microcomputer program based on the Beierbeck-Saunders approach for estimating 13C-NMR chemical shifts in acyclic hydrocarbons is described. It is shown to be applicable in cases of asymmetric alkanes with diastereotopic carbon atoms induced by chirality, side-chains attached to fixed rings, and solid-state analyses of hydrocarbons, for which rules based on conformationally-averaged solution data are unsatisfactory.  相似文献   

2.
Abstract

The idea (Hancock, 1992) that the dominant architectural feature in controlling metal ion selectivity in both open-chain and macro-cyclic ligands is the size of the chelate ring is pursued further. It is shown that when more than one or two six-membered chelate rings are present in the complex of a nitrogen donor macrocycle, the steric requirements of the six-membered chelate ring of a M-N bond length of 1.6 Å and N-M-N angle of 109.5° become particularly severe, and can only be met by a small tetrahedral metal ion. Thus, the ligand 16-aneN4 (1,5,9,13-tetraazacyclohexadecane) forms complexes of low stability with all metal ions studied to date, but a conformer of 16-aneN4 is identified by MM calculation which is predicted to form complexes of high stability with very small tetrahedral metal ions. The question of the M-O bond length and O-M-O angles that will produce minimum strain in chelate rings containing neutral oxygen donor is addressed. The observation (Hay, 1993) that the geometry around an ethereal oxygen coordinated to a metal ion approximates to trigonal planar rather than tetrahedral leads to ideal M-O-C angles of about 126°, which leads to minimum strain energy with much longer M-L lengths in chelate rings containing neutral oxygen donors than neutral nitrogen donors. It is suggested that this fact accounts for the general tendency of crown ethers to form their most stable complexes with potassium out of the alkali metal ions, and also accounts for the very small macrocyclic effect observed in complexes of macrocycles containing mixed nitrogen and oxygen donor groups. The preferred geometry of four-membered chelate rings is discussed, and it is shown that higher coordination numbers of metal ions are associated with four membered chelate rings, and that four membered chelate rings may be used to engineer preference for larger metal ions. Very rigid reinforced chelate rings are discussed, and it is shown that open-chain ligands with reinforced bridges between the donor atoms can display all the thermodynamic and kinetic aspects associated with macrocyclic ligands.  相似文献   

3.
The hydrothermal reactions of metal precursors with aminotri(methylenephosphonic acid) yielded a series of similar structural coordination polymers of general formula {M[HN(CH2PO3H)3](H2O)3}n [M = Mg(II) (1), Mn(II) (2), Co(II) (3), Zn(II) (4) and Cd(II) (5)]. Compounds 15 were characterized by X-ray single crystal diffraction, elemental analyses, and thermogravimetric analyses. Compounds 15 all reveal the wave-like 1D chain structures and the structures are constructed by two types of eight-membered, square-like rings linked alternatively via the phosphonate oxygen atoms, generating double-channel systems. The magnetic studies of 2 and 3 reveal that antiferromagnetic interactions are mediated between the metal ions.  相似文献   

4.
In the title compound, C30H50O3, the three six‐membered rings adopt chair, twist and twist‐boat conformations. The five‐membered ring is in a slightly distorted envelope conformation. The substituent on the five‐membered ring is in an extended conformation, with its two hydroxyl O atoms forming an intramolecular hydrogen bond. One of these O atoms also forms an intermolecular hydrogen bond with the oxy­gen of the carbonyl group in a neighbouring mol­ecule.  相似文献   

5.
Abstract

This review continues the previous articles (I. Haiduc, J. Coord. Chem., 71, 3139 (2018) and J. Coord. Chem., 72, 35 (2019)), which discussed the structures with nitrogen-donor species (atoms and molecules) acting as centers in inverse coordination complexes. i.e. metal compounds which display an arrangement of acceptor and donor sites opposite to that occurring in conventional coordination complexes. This review is Part 1 of a work which introduces the topology of inverse coordination complexes with organic nitrogen heterocycles, and presents a panorama of five-membered rings and covers pyrazole, imidazole, triazoles, tetrazole, pyrrole, oxadiazole, thiadiazole, azaphospholes, and smaller rings.  相似文献   

6.
The molecular and crystal structures of the two 2,3-dihydrobilatrienes-abc1 and2, representing model compounds for the phytochrome chromophore, were determined by X-ray crystallography at 97 K. Crystals of the racemate1 contain disordered regions. Both molecules are found to be ofall-(Z) configuration, assuming a helical conformation. The acidic hydrogen atoms are localized at the nitrogen atoms of rings A, C and D. A summary of the geometries of unsaturated five-membered rings as observed in four accurate low-temperature crystal structures of bilatrienes-abc is given.Herrn Prof.Josef Schurz zum 60. Geburtstag gewidmet.  相似文献   

7.
Formation of fullerenes — spherical carbon clusters C60 and clusters of other sizes — during condensation of carbon vapors has not yet received theoretical explanation. Recent experimental works concerned with cluster formation in carbon vapors have established that during condensation carbon atoms form rings and then polycyclic clusters, which are precursors of fullerenes. Theoretical investigation of the spontaneous formation of fullerenes from polycyclic rings calls for a simple model of the potential of interatomic interaction of carbon, which would allow fast calculations of bond energies and statistical sums of the clusters. We use the modified Brenner potential, which was developed for hydrocarbon molecules. The parameters of the potential are refitted according to the results of quantum chemical calculations. Institute of Theoretical and Applied Mechanics, Siberian Branch, Russian Academy of Sciences. Institute of Computation Technologies, Siberian Branch, Russian Academy of Sciences. Translated fromZhurnal Struktumoi Khimii, Vol. 37, No.4, pp. 664–670, July–August, 1996. Translated by I. Izvekova  相似文献   

8.
In as-hydrolyzed amorphous precursors of Pb(Zr,Ti)O3 (PZT) ceramics with various Zr/Ti ratios prepared from lead acetate and transition metal n-butoxides in parent alcohol medium the local environment of constituent metal atoms has been determined by EXAFS. The local zirconium atom environment in high-Zr precursors consists of distorted octahedra of oxygen atoms with all the bonds made up of Zr–O–Zr links. For low-Zr precursors a smaller distortion of the oxygen octahedra is observed, and two Ti atoms are found in the second shell. The titanium local environment is almost independent of the Zr/Ti ratio, with five oxygen atoms in the first and two titanium atoms in the second shell of neighbors. Lead atoms contain two oxygen atoms in the first coordination shell. Pb–O–M (M = Zr, Ti) links are identified in all precursors: the former at Zr/Ti 75/25 and the latter at lower Zr/Ti ratios. Although a pronounced tendency for the homocondensation of zirconium species is found down to a Zr/Ti 50/50 ratio, heterometallic links (Pb–O–M) are determined in PZT precursors.  相似文献   

9.
New phosphites 1–4 were synthesized from phosphorus trichloride and an appropriate diphenol followed by the addition of trifluoroethanol in the presence of triethylamine. These phosphites are to serve as precursors in the syntheses of biorelated hypervalent phosphoranes. 1H, 19F, and 31P NMR spectra were recorded. X-ray analysis of 3 and 4 revealed that the sulfur-containing eight-membered ring was in a syn conformation that a allowed a sulfur donor interaction to the phosphorus atom, whereas for phosphite 2, the eight membered sulfonyl containing ring was in an anti conformation that did not allow a donor interaction to phosphorus from the oxygen atom of the sulfonyl group. Structural comparisons are made with related cyclic phosphites and phosphates having donor atoms in eight-membered rings.  相似文献   

10.
The first five-membered rings of metal atoms connected by M–M or M-H-M bonds only have been obtained by a Re2+Re3 condensation in which a polyhydride acts as a bridging bidentate ligand toward a coordinatively unsaturated fragment (see scheme below). In spite of the octahedral coordination of the Re centers, the Re5 rings display conformations (twisted and envelope) comparable with those observed for organic five-membered rings of tetrahedral carbon atoms.  相似文献   

11.
Two complexes of a thiosemicarbazone ligand, namely N-(2-hydroxyethyl)-2-(thiophene-2-ylmethylene)-hydrazinecarbothioamide (HL), have been synthesized. The complexes have been characterized by physico-chemical and spectroscopic methods. The crystal and molecular structures of [CoL3]·2MeOH (1) and [NiL2] (2) have been determined by X-ray diffraction studies. For both complexes, the metal is coordinated through the sulfur and azomethine nitrogen atoms of the thiosemicarbazone. The ligand exists in its thiolate tautomeric form, and the central Co(III) and Ni(II) atoms have distorted octahedral and square planar geometries, respectively, with five-membered chelate rings formed by the ligand. The lattice of 1 shows infinite oxygen donor/acceptor hydrogen bonds in the ab plane and weak interactions between rings along the c axis, respectively, giving a supramolecular network. The molecular units in 2 are linked together by hydrogen bonds between the hydroxyl oxygen and hydrazone N proton, giving rise to an infinite ribbon extended along the c-axis. These chains are connected by N3–H3···O1 interactions that form a sheet within the ac plane.  相似文献   

12.
Abstract

The conformation in solution of eight-membered 12H-dibenzo[d,g][1,3,2]-dioxametallocin rings containing phosphorus and titanium, respectively, were studied by the NMR spectroscopy using ring substituents containing diastereotopic protons as a probe for conformational bias. The results of this study suggest that in addition to steric effects, an electronic effect due to donation of the lone pair of electrons on the ring oxygen atoms to the metal center influences the preferred conformation in solution.  相似文献   

13.
 Network formation of gelatin gel is known to consist of three-dimensionally cross-linked triple helices among polypeptide chains. The effects of added low molecular weight mono-ols, diols and polyols on the higher-order structure formation of gelatin chains were investigated using the following measurements: melting temperature, viscoelasticity and spin-lattice relaxation time (T 1) of H17 2O of gels, and circular dichroism spectra of diluted gelatin solutions. Furthermore, hydration behaviors of these hydroxy compounds were evaluated from the dynamic hydration numbers (n DHN) derived from T 1 of H17 2O in the solutions. It was found that network structures of gelatin gels containing hydoxy compounds were influenced by the number and position of hydroxyl groups as well as the number of carbon atoms of these coexisting compounds. The effect of hydroxyl groups of hydroxy compounds was considered to stabilize the helices among gelatin chains. Especially, the addition of polyols with large number of hydroxyl groups increased the number of cross-linking junctions in the gel networks, which consist of the aggregation among the helices. On the contrary, the effect of carbon atoms of hydroxy compounds is to disturb the formation of the helices and the aggregation among the helices. Received: 18 April 1996/Accepted: 23 July 1996  相似文献   

14.
Abstract

Copper(II) complexes of various optically active di- and tripeptides have been studied with the aid of optical rotatory dispersion (ORD) and circular dichroism (CD) techniques. The magnitudes of the molecular rotations related to the d-d transitions of the complexes fall into three different ranges, depending on the positions of asymmetric carbon atoms of the ligands. The molecular rotations of GAG and GLG complexes are greater than those of GGA, GGL, and GGV complexes, which are again greater than those of AGG, LGG, and VGG complexes (G, A, L, and V are glycine, alanine, leucine, and valine residues, respectively, in the tripeptides investigated, the N-terminal residue being the first residue in each abbreviation). The structures of these complexes, deduced from their potentiometric equilibrium curves and from the known crystal structure of the copper(II)-triglycine complex, show that the asymmetric carbon atoms of the second and third amino acid residues (counting from the N-terminal amino acid residue) are in the plane composed of the central metal ion, the nitrogen atoms of the amino and peptide groups, and the oxygen atom of the carboxylate group. The magnitude of the Cotton effect increases with the planarity of the chelate rings which include the asymmetric carbon atom and the metal ion, and with increasing strength of the coordinate bonds that form these chelate rings. Further support for this interpretation is found in the CD spectra of the copper(II) and nickel(II) complexes of AGG, GAG, GGA, and AAA. Analysis of the CD spectra of LL and DL alanylalanine complexes also demonstrate the influence of planarity and coordinate bond strength on the magnitude of the Cotton effect. Schiff base formation of aldehydes and ketones with dialanines causes fundamental changes in the geometries of the copper(II) complexes and reverses the relative contributions of the chelate rings to the total CD absorption intensities of the complexes.  相似文献   

15.
A new bidisplaced acetate functionalized pendant arm derivative, 1,4-diacetate-1,4,7-triazacyclodecane (L) and its corresponding Co(III), Fe(III) complexes [CoLCl] (1) and [FeLCl]2 · 3H2O (2) were synthesized and characterized by elemental analysis, IR spectra,UV–Vis spectra, HNMR, MS, XPRD, TGA and single-crystal X-ray diffraction analysis. The crystal structure shows the metal ions in the complexes have similar coordination six-coordinate, by three nitrogens and two oxygens of the chelate ligand, and a chloride. Through calculation of the twist angle, we discover 1 forms a distorted octahedral geometry while 2 forms a distorted-prismatic geometry. In 2, there are abundant hydrogen bonds between the oxygen atoms of water and the nitrogens and oxygens of the ligand, resulting in a two-dimensional supramolecular network with a regular triatomic water cluster. The thermal gravimetric analyses of the two complexes are also given.  相似文献   

16.
Abstract

Reported are synthetic routes to inorganic heterocycles of different ring size, containing phosphorus, hydrazine, silicon and other elements as ring components. Steric effects that cause saturated sixmembered rings to adopt an unusual twist conformation are discussed (temperature dependent NMR-spectra, X-ray structures).  相似文献   

17.
The composition of solid saturated hydrocarbons from slack-wax after reaction with urea has been investigated by electron-attachment (EA) mass spectrography with negative ions. From the spectra of the samples the content of paraffin hydrocarbons, monocyclic, dicyclic and other polycyclic naphthenes was calculated. The presence of n-paraffins up to C46, isoparaffins and cycloalkanes up to C52 has been confirmed. In the paraffin series the concentration of normal paraffin hydrocarbons containing one and two 13C atoms was determined. On the basis of the results obtained the constitution of the samples and the possible structures of the hydrocarbons were discussed. The results obtained have shown that the solid hydrocarbons which react with urea not only consist of one- or two-ring systems, but also of systems with up to five and six rings.  相似文献   

18.

The bis (4-chloro-2-methylphenoxy)acetato lead (II) monohydrate infinite polymer was synthesized and characterized by elemental analysis and infrared spectroscopy. The crystal and molecular structure has been determined and the bond valences were computed. Molecules of the monomer, each occupying an asymmetric unit, are connected by the inversion center and a polymer chain is created by Pb(2O)Pb rings in spiro arrangement. The lead atom is seven coordinate by four oxygen atoms from two chelating carboxyl groups, one water molecule, and two oxygen atoms provided by symmetry generated carboxyl groups. Each carboxyl group acts as a bidentate ligand toward one metal atom and as a monodentate ligand with respect to a second. The lead-oxygen distances are spread over a wide range of values. One molecule of (4-chloro-2-methylphenoxy)acetate in the monomer is close to planarity, and the second is bent. All 4-chloro-2-methylphenoxy groups are almost parallel. The polymer infinite chains are assembled by weak hydrogen bonds to a layered structure.  相似文献   

19.
The synthesis and purification of novel bi(silacyclohexyls) C5H10SiX-XSiC5H10 with X = H (1), Ph (2), F (3), Cl (4), Br (5), and I (6), which are composed of two silacyclohexyl rings connected by a silicon–silicon single bond, is described. Molecular structures for 2, 4, 5, and 6 were determined employing X-ray crystallography. Surprisingly, the SiSi bond lengths increase in the order I < Br < Cl, contrary to what is observed for methylated disilanes Me2XSiSiXMe2. The bond lengthening can be traced back to 1, 3 nonbonded interactions between the halogen atoms and the axial hydrogen atoms in the SiC5 ring, which also cause a decrease of the SiSiX bond angles with increasing size of the halogen atom. Both rings substitute each other in the equatorial position for 4, 5, and 6, but in the axial position for 2.  相似文献   

20.
《Analytical letters》2012,45(4):539-552
Abstract

Solid polycyclic aromatic hydrocarbons with 4–7 rings on metal, glass, ceramic, and plastic substrates were desorbed and ionized in air with a quadrupled Nd-YAG laser. Gaseous product ions were analyzed at ambient conditions in air directly using ion mobility spectrometry. Ablation rates for perylene on borosilicate glass were estimated as 0.01 ng/mm2 per pulse and standard deviation for peak heights with roughly 1 ug/mm2 was 34 %. Substrate interference was avoided by using an unfocused laser beam at 0.5–1 mJ/pulse although gaseous ions also could be generated from substrates with a focused beam at 1 mJ/pulse.  相似文献   

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