空气热储存、光合作用和土壤垂直水分运动对黄土高原地表能量平衡的影响

地表能量不平衡问题一直是陆面过程研究的一个重要科学难题. 本文利用黄土高原陆面过程试验(LOPEX)资料, 在将垂直感热平流项引入地表能量平衡方程的基础上, 估算了空气热储存和光合作用储存的大小, 并分别用水分守恒关系和两层土壤温度方法计算了浅层土壤水分垂直通量, 考察了空气热储存、光合作用储存和水分垂直运动热量输送对地表能量平衡的影响.结果表明: 黄土高原区自然植被下垫面的空气热储存、光合作用储存和土壤水分垂直运动热量输送平均日变化峰值分别达到1.5, 2.0和7.9 W·m^-2; 在能量平衡方程中引入这三项后, 地表能量闭合度由88.1%提高到89.6%. 空气热储存、光合作用储存和水分垂直运动热量输送对于改善黄土高原地表能量不平衡状况有一定作用, 研究区域的半干旱气候背景和植被状况是导致各热储存量与其他试验区存在差异的根本原因.     

Water at the interface modified silica filler-polydimethylsiloxane: quantum-chemical modelling

Intermolecular interactions determine the reinforcement of polydimethylsiloxane (PDMS) elastomers by fumed silica, and a water interlayer on the fumed silica/PDMS interface may act as a lubricant, decreasing the interaction energy and promoting the PDMS molecule motion over the filler surface. A quantum-chemical (QCh) modelling has been performed to study a microscopic aspect of water impact on the intermolecular interactions in the system. The results obtained for a series of superclusters simulating fragments of the real silica filler surface, both hydroxylated and silylated, interacting with five-member PDMS oligomer in presence of individual water molecules and of a 'water drop', of several H-bonded water molecules, are in good agreement with results from IGC adsorption experiments.     

X光光电子能谱法测定胶片中氟,硅和铝的研究

应用Ｘ光光电子能谱法测定了几种彩色胶片表面层中氟的１ｓ能级的结合能；分别比较了水处理前后、溅蚀前后胶片护膜层氟的变化，表明氟化物分布在护膜最表层，是一种易溶于水的氟化物；测定了彩色片护膜层所含硅２ｐ能级的结合能，与自制彩色片护膜层测定结果比较，优质片含一种较多负电性，用与自制片的无机硅不同的硅化物作毛面剂；对溅蚀前后优质片和自产彩色片中的硅铝比变化进行比较，提出优质彩色片Ｆ－４００的护膜层可能是双     

水下声辐射激励水表面声波的特征参数测量

采用激光干涉方法对水下声辐射激励水表面声波的特征参数频率和振幅进行了测量研究。从理论上对水表面声波激光相干测量信号的频谱构成进行了分析,在此基础上提出了水表面声波两个重要声学参数频率和振幅的解算方法,并通过数值仿真进行了验证。搭建了一套简单的激光干涉测量实验系统,对不同频率和声压激励的水表面声波进行了测量实验,验证了水表面声波频率和振幅解调方法的准确性。对水表面声波横向传播的振幅衰减现象进行了初步的实验研究,结果表明水表面声波的频率越高,振幅的横向衰减越快。研究表明激光相干检测方法能够准确地实现水表面声波振幅和频率的测量。      

Classical trajectory calculations of the dissociation of hydrogen on copper: III. The effect of surface roughness

Further calculations have been performed for the dissociation of H₂ on copper in which the empirical potential surface has been increased in roughness as suggested by our previous studies. This change is effected through an increase in the barriers to adatom surface diffusion, keeping the minimum energy requirements for dissociation about the same. The result is to bring the calculation into satisfactory agreement with molecular beam experiments. We examine the effect of changing the internal energy (vibration and rotation), mass, (D₂), the adatom binding site, and evaluate the validity of the correlating parameter E⊥ = Ecos²θ.     

Einfluss adsorbierter wasserfilme auf die Van der Waals kraft zwischen quarzglasoberflächen

A method to determine Van der Waals forces at low distances is described. Results of experiments carried out with adsorbed water films are in excellent agreement with the theory of Dzyaloshinski. The thickness of adsorbed water films has been varied by changing the vapour pressure of the surrounding atmosphere. The influence of thickness of adsorbed water films has been studied. At high relative humidities the attractive force can be calculated with the help of Dzyaloshinskiis theory by using the dielectric properties of water. The experimentally determined Van der Waals force is discussed in relation to the surface energy of the interface.     

The structure of a stepped copper (410) surface determined by ion scattering spectroscopy

Ion Scattering Spectroscopy applied in the multiple scattering mode is used to determine the structure of a stepped Cu(410) surface. The energy of singly scattered ions is influenced by the presence of neighbour surface atoms. This effect can be used to determine interatomic distances up to about 10Å, as is shown by the results of 8 keV Ar⁺ and 11 keV Ne⁺ scattered through θ = 50°. The edge-edge distance of the stepped copper surface appears to be in accordance with the results of LEED experiments obtained by other investigators. The experiments show a good agreement with the results of the analytical 3-atom model of Poelsema. The energy of the so-called “plateau collision” appears to depend on the effective plateau length l as measured in the plane of incidence. Lengths l between 15 and 60 Å can be determined with an accuracy of 5 Å. Results are shown for 8 and 12 keV Ar⁺, θ = 40° and 60°, and 8 keV Kr⁺ θ = 40°. The experimental dependence of the energy on lis described correctly by a phenomenological model.     

Simulation of Ion Paths in the Target Material for the Injection Complex of the BELA Facility

To realize the simulation experiments with the use of two ion beams at the injection complex of the BELA accelerator (Based on ECR ion source Linear Accelerator), it is necessary to determine the energy and irradiation angle of the beam of light ions which will be implanted into the region of radiation damage induced by heavy-ion beam. The depth of light-ion implantation is determined by the energy and kind of particles initiating the damage, as well as by their incidence angle. It is supposed that the incidence direction of heavy ions will coincide with the normal to the specimen surface. In our work, the necessary implantation zone for the iron ion beam with an energy of 3.2 MeV is located at depths of 300–800 nm. The simulation of the hydrogen and helium ion paths in the material of the iron target in the energy range from 150 to 600 keV at the angle to the normal from 0° to 65° is performed. The range of energies and irradiation angles for the hydrogen and helium ions are determined for the implantation into the radiation-induced defect-formation zone.     

Experimental design to measure the anchoring energy on substrate surface by using the alternating-current bridge

The anchoring property of the substrate surface of liquid crystal cells plays an important role in display and nondisplay fields. This property directly affects the deformation of liquid crystal molecules to change the phase difference through liquid crystal cells. In this paper, a test method based on the alternating-current bridge is proposed to determine the capacitance of liquid crystal cells and thus measure the anchoring energy of the substrate surface. The anchoring energy can be obtained by comparing the capacitance–voltage curves of twisted nematic liquid crystal cells with different anchoring properties in experimental and theoretical results simulated on the basis of Frank elastic theory. Compared with the other methods to determine the anchoring energy, our proposed method requires a simple treatment of liquid crystal cells and allows easy and high-accuracy measurements, thereby expanding the test ideas on the performance parameters of liquid crystal devices.     

Kinetics of water flow through a polymer gel

The water flow through the poly(acrylamide) gel under a constant water pressure is measured by newly designed apparatus. The Young modulus and Poisson’s ratio of the rod shape gels are measured by the uni-axial elongation experiments, which determine the longitudinal modulus independently from the water flow experiments. The time evolution of the water flow in the dilute gel is calculated based on the collective diffusion model of the polymer network coupled with the friction between the polymer network and the water. The calculated results are compared with the time evolution of the flow experiments, and the values of the longitudinal modulus and the friction coefficient are estimated. The estimated values are consistent with the results of our mechanical-response experiments and the light scattering experiments reported previously. We find that the time evolution of the water flow is well described by a single characteristic relaxation time predicted by our model for dilute gels.     

On the thermodynamic driving force for polymer intercalation in smectite clays

The view that the intercalation of a polymer in an unmodified smectite clay is driven by the entropic increase that results from displacement of adsorbed water is re-assessed in the light of experiments that show rapid melt intercalation into a clay that has been heat-treated to remove gallery water. Dehydrated smectite clays with collapsed layers take up poly(ethylene glycol) from the melt in only 1?ks or from aqueous solution in under 18?ks, re-establishing the basal plane spacing to that for intercalation in untreated clay, 1.8?nm. Differential scanning calorimetry showed that the intercalation of poly(ethylene glycol) into montmorillonite is exothermic with an enthalpy change of ?153?J?g^?1 based on the intercalated polymer and the heat of wetting for the internal surfaces of montmorillonite by poly(ethylene glycol) is ?0.08?J?m^?2. These results confirm the observation of re-expansion of heat-treated clays and imply that the reduction in free energy on intercalation results from a significant enthalpic change as well as an entropic change for clays with interlayer water, and primarily from an enthalpic change for clay in the absence of water.     

Depth distribution of vacancies generated by irradiating a solid surface with a flux of accelerated ions

Kinetic transport theory is used to find analytical expressions for the absorbed doses of the primary-particle flux and primary-particle energy as functions of distance into a solid with finite or semi-infinite thickness when the surface of the latter is irradiated by a flux of accelerated ions (atoms) in the direction normal to the surface. The theory was compared with experiments in which solid silicon films with thicknesses 50, 100, and 400 nm were irradiated by a flux of accelerated boron atoms with energies from 10 to 20 keV. These expressions were used to calculate the depth distribution of vacancies generated in a solid whose surface is irradiated by a flux of accelerated ions. The method developed can be used to determine the depth distribution of vacancies created by fluxes of accelerated electrons, neutrons, or photons. Zh. Tekh. Fiz. 68, 60–65 (April 1998)     

Pulse laser ablation at water–air interface

We studied a new pulse laser ablation phenomenon on a liquid surface layer, which is caused by the difference between the refractive indices of the two materials involved. The present study was motivated by our previous study, which showed that laser ablation can occur at the interface between a transparent material and a gas or liquid medium when the laser pulse is focused through the transparent material. In this case, the ablation threshold fluence is reduced remarkably. In the present study, experiments were conducted in water and air in order to confirm this phenomenon for a combination of two fluid media with different refractive indices. This phenomenon was observed in detail by pulse laser shadowgraphy. A high-resolution film was used to record the phenomenon with a Nd:YAG pulse laser with 10-ns duration as a light source. The laser ablation phenomenon on the liquid surface layer caused by a focused Nd:YAG laser pulse with 1064-nm wavelength was found to be followed by the splashing of the liquid surface, inducing a liquid jet with many ligaments. The liquid jet extension velocity was around 1000 m/s in a typical case. The liquid jet decelerated drastically due to rapid atomization at the tips of the ligaments. The liquid jet phenomenon was found to depend on the pulse laser parameters such as the laser fluence on the liquid surface, laser energy, and laser beam pattern. The threshold laser fluence for the generation of a liquid jet was 20 J/cm². By increasing the incident laser energy with a fixed laser fluence, the laser focused area increased, which eventually led to an increase in the size of the plasma column. The larger the laser energy, the larger the jet size and the longer the temporal behavior. The laser beam pattern was found to have significant effects on the liquid jet’s velocity, shape, and history.     

一种风沙运动的颗粒动力学静电起电模型

基于水的电离理论和颗粒动力学理论,提出了一种风沙运动颗粒碰撞的静电起电模型：颗粒表面覆盖有水分子薄层,颗粒间的碰撞导致能量转移和颗粒温度变化;水电离生成H₃O⁺和OH^-离子,当两个温度不同或水分子薄层正(负)离子浓度不同的颗粒相接触时,H₃O⁺比OH^-以更快地速度从浓度高的地方向浓度低的地方迁移. 在动力学的模拟计算中采用0.1mm,0.2mm和0.4mm三种粒径的沙粒以示沙 关键词： 风沙运动 静电 颗粒动力学 尘卷风     

FRET structure with non-radiative acceptor provided by dye-linker–glass surface complex and single-molecule photodynamics by TIRFM-polarized imaging

We present our recent study of microscopic single-molecule imaging on the artificial complex of tetramethylrhodamine linked with a propyl chain onto silica glass surface, i.e. an asymmetric fluorescence resonance energy transfer (FRET) structure with non-radiative acceptor. In the synthesis of the complex, we used a mixture of two kinds of isomers to introduce rather small photodynamic difference among them. This isomeric structure change will provide more or less a distinctive photophysical change in e.g. non-radiative relaxation rate. Our recent observation at room temperatures, so far, shows that such contributions can be discriminated in the histograms of the fluorescent spot intensities; broad but distinctive multi-components appear. To identify the isomeric difference as a cause of structures, some configurational assumptions are necessary. One such basic prerequisite is that the transition dipoles of the chromophores should be oriented almost parallel to the glass surface. In order to make clear the modeling, we also provide preliminary experiments on the polarization dependence of the imaging under rotating polarization in epi-illumination.     

Water adsorption on hydrogenated Si(1 1 1) surfaces

The adsorption of water on the hydrogen terminated Si(1 1 1) surface is studied by means of first-principles calculations as well as contact angle measurements. Possible initial adsorption configurations for single water molecules and the potential energy surface are calculated. Only small adsorption energies of the order of meV are predicted. Calculations for higher coverage show that the water-water interactions are stronger than the water-surface bonding. The contact angle formed between a water droplet on the surface approximated from the total-energy calculations amounts to 88°, while our measured value is 91°.     

高煤级煤岩流变作用的谱学研究

为研究高煤级煤岩在不同流变条件下大分子结构的变化特征,对沁水盆地南部高煤级原生结构煤岩及其变温变压流变实验后的煤岩进行了FTIR和激光拉曼光谱测试和分析。结果表明：不同温压条件形成的不同类型流变煤岩的大分子结构和组成具有明显的差别。煤岩变温变压流变实验(温度300～400 ℃、围压50～100 MPa、应变小于10%和应变速率10-4～10-7·s-1)会使其大分子结构产生改变,并实现化学结构重组：当温度为300或350 ℃,高煤级煤岩易形成脆性流变或脆韧性流变,机械能转化为热能,一些键能较弱的支链和官能团断裂并且结构脱落,产生裂解小分子,其过程以应力降解作用为主,而芳香结构增多,同时出现应力缩聚;而温度上升至400 ℃以上,高煤级煤岩即可发生韧性流变,次生缺陷发育,机械能转化为应变能,脱落的小分子优先嵌入或吸附在大分子结构的缺陷或表面,脂肪和芳香结构的变化,其过程既有应力降解作用又有应力缩聚作用,而且以应力缩聚作用为主;围压和样品注水状态对大分子结构影响不明显。     

Using capillary forces to estimate the adhesion strength of Magnaporthe grisea spores on glass

The Magnaporthe grisea is a fungus whose spores strongly adhere to plant leaves, and to solid surfaces in general. In this note, we give an estimate of the adhesion force, F_det, of a spore on a glass surface, in water. F_det is defined as the force to be applied to a spore to pull it out from the surface. In our experiments, spores are detached from the glass in a few milliseconds by means of a capillary force. The latter is provided by a water/air or a water/oil interface, in contact with the spore body. We thus find F_det of the order of 10⁻⁶ N.     

Adsorption, reaction and desorption of hydrogen on modified Pd(1 1 1) surfaces

The interaction of hydrogen (deuterium) with different modified Pd(1 1 1) surfaces has been investigated. The focus was put on the energy and angel dependence of the desorbing molecules from oxygen covered, potassium covered and vanadium oxide covered surfaces. Conventional adsorption/desorption as well as permeation/desorption experiments were performed. For the oxygen covered surface optimum reaction rates for water production and the energy distribution of the reaction products were determined, both for the reaction of oxygen with molecular hydrogen as well as with atomic hydrogen. Potassium on the surface enhances the activation barrier for hydrogen adsorption resulting in a hyper-thermal desorption flux and a forward focused angular distribution of desorption. Permeation/desorption of deuterium from ultra-thin vanadium oxide films yield mainly thermalized desorbing molecules or slightly hyper-thermal, depending on the oxidation state of the surface oxide.     

Water vapour sorption on hydrophilic and hydrophobic nanoporous materials

The aim of this study is to compare water vapour sorption isotherms on various mesoporous materials in their pristine state and after silanisation. Commonly the pristine state is regarded as hydrophilic and the silanised one as hydrophobic. Water vapour sorption experiments are discussed for a highly ordered nanoporous aluminium oxide with straight cylindrical channels of ca. 25 nm diameter and for various controlled porous glasses (CPGs) with disordered pores in the range of 13 nm diameter. The water sorption isotherms exhibit in both cases a hysteresis over the entire humidity range. At higher humidities the pristine materials show capillary condensation whereas for the silanised samples this phase transition does not occur or even a loss of water is recorded as for the silanised Al₂O₃. Surprisingly, for the silanised Al₂O higher water uptake is observed in the low humidity region. Application of the excess surface work (ESW) method delivers a reduced structural component in the long range interaction of the water molecules with a hydrophobic surface. Inverse gas chromatography studies of the silanised CPGs result in an increased short range dispersive part of the surface energy with the increasing degree of silanisation.