共查询到20条相似文献,搜索用时 46 毫秒
1.
Hopp B. Smausz T. Kresz N. Nagy P.M. Juhász A. Ignácz F. Márton Z. 《Applied Physics A: Materials Science & Processing》2003,76(5):731-735
Allergic-type diseases are current nowadays, and they are frequently caused by certain metals. We demonstrated that the metal
objects can be covered by Teflon protective thin layers using a pulsed laser deposition procedure. An ArF excimer laser beam
was focused onto the surface of pressed PTFE powder pellets; the applied fluences were 7.5–7.7 J/cm2. Teflon films were deposited on fourteen-carat gold, silver and titanium plates. The number of ablating pulses was 10000.
Post-annealing of the films was carried out in atmospheric air at oven temperatures between 320 and 500 °C. The thickness
of the thin layers was around 5 μm. The prepared films were granular without heat treatment or after annealing at a temperature
below 340 °C. At 360 °C a crystalline, contiguous, smooth, very compact and pinhole-free thin layer was produced; a melted
and re-solidified morphology was observed above 420 °C. The adhesion strength between the Teflon films and the metal substrates
was determined. This could exceed 1–4 MPa depending on the treatment temperature. It was proved that the prepared Teflon layers
can be suitable for prevention of contact between the human body and allergen metals and so for avoidance of metal allergy.
Received: 12 June 2002 / Accepted: 13 June 2002 / Published online: 4 November 2002
RID="*"
ID="*"Corresponding author. E-mail: bhopp@physx.u-szeged.hu 相似文献
2.
X. Zhu S. Lu H.L.W. Chan C.L. Choy K.H. Wong 《Applied Physics A: Materials Science & Processing》2003,76(2):225-229
Compositionally graded (Ba1-xSrx)TiO3 (BST) (x:0.0∼0.25) thin films were grown on Pt (111)/TiO2/SiO2/Si (100) substrates using layer-by-layer pulsed laser deposition in the temperature range 550–650 °C. Both downgraded (Ba/Sr
ratio varying from 100/0 at the bottom surface to 75/25 at the top surface) and upgraded (Ba/Sr ratio varying from 75/25 at
the bottom surface to 100/0 at the top surface) BST films were prepared. Their microstructures were systematically studied
by X-ray diffractometry and scanning electron microscopy. A grain morphology transition from large ‘rosettes’ (>0.30 μm) to
small compact grains (70–110 nm) was observed in the downgraded BST films as the deposition temperature was increased from
550 to 650 °C. No such grain morphology transition was detected in the upgraded BST films. Dielectric measurements with metal
electrodes revealed an enhanced dielectric behavior in the downgraded films. This enhancement is mainly attributed to the
large compressive stress field built up near the interface between the downgraded film and substrate. Furthermore, the BaTiO3 layer in the downgraded BST films not only serves as a bottom layer but also as an excellent seeding layer for enhancing
the crystallization of the subsequent film layers in the downgraded films.
Received: 10 December 2001 / Accepted: 12 March 2002 / Published online: 19 July 2002
RID="*"
ID="*"Corresponding author. Fax: 86-25/359-5535, E-mail: xhzhu@public1.ptt.js.cn 相似文献
3.
J.-M. Liu N. Chong H.L.W. Chan K.H. Wong C.L. Choy 《Applied Physics A: Materials Science & Processing》2003,76(1):93-96
Epitaxial (001) aluminum nitride (AlN) thin films on (111) Si substrates are prepared using pulsed-laser deposition. The epitaxial
structure of the as-prepared thin films is characterized by checking the X-ray-diffraction θ-2 θ scan and pole-figure, using
scanning electron microscopy, infrared radiation (IR) spectroscopy and Raman spectroscopy. The surface acoustic-wave resonance
at 345 MHz for a 1.5 μm thick AlN film on a (111) Si substrate is observed using an inter-digital electrode.
Received: 18 September 2001 / Accepted: 29 January 2002 / Published online: 3 June 2002
RID="*"
ID="*"Corresponding author. Fax: +86-25/359-5535, E-mail: liujm@nju.edu.cn 相似文献
4.
HgCdTe thin films have been deposited on Si(1 1 1) substrates at different substrate temperatures by pulsed laser deposition (PLD). An Nd:YAG pulsed laser with a wavelength of 1064 nm was used as laser source. The influences of the substrate temperature on the crystalline quality, surface morphology and composition of HgCdTe thin films were characterized by X-ray diffraction (XRD), selected area electron diffraction (SAED), atomic force microscopy (AFM) and energy dispersive X-ray spectroscopy (EDS). The results show that in our experimental conditions, the HgCdTe thin films deposited at 200 °C have the best quality. When the substrate temperature is over 250 °C, the HgCdTe film becomes thermodynamically unstable and the quality of the film is degraded. 相似文献
5.
S.H. Sun G.W. Meng Y.W. Wang T. Gao M.G. Zhang Y.T. Tian X.S. Peng L.D. Zhang 《Applied Physics A: Materials Science & Processing》2003,76(2):287-289
Tin dioxide (SnO2) nanobelts have been successfully synthesized in bulk quantity by a simple and low-cost process based on the thermal evaporation
of tin powders at 800 °C. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) observations reveal
that the nanobelts are uniform, with lengths from several-hundred micrometers to a few millimeters, widths of 60 to 250 nm
and thicknesses of 10 to 30 nm. X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX) and selected-area electron
diffraction analysis (SAED) indicate that the nanobelts are tetragonal rutile structure of SnO2. The SnO2 nanobelts grow via a vapor–solid (VS) process.
Received: 3 June 2002 / Accepted: 10 June 2002 / Published online: 10 September 2002
RID="*"
ID="*"Corresponding author. Fax: +86-551/559-1434, E-mail: gwmeng@mail.issp.ac.cn 相似文献
6.
N. Navi H. Kim J.S. Horwitz H.D. Wu S.B. Qadri 《Applied Physics A: Materials Science & Processing》2003,76(5):841-846
The structural and the microwave dielectric properties of BaxSr(1-x)TiO3 films (BST) with x=0.5, 0.6 and 0.7, containing 1 mol % W have been investigated. The films were grown by pulsed-laser deposition
on MgO (001) substrates at a temperature of 720 °C in an oxygen pressure from 3 to 500 mTorr. The film structures were determined
by X-ray diffraction. The lattice parameters were fitted to a tetragonal distortion of a cubic lattice. The out-of-plane lattice
parameter (c) was calculated from the position of the (004) reflection. Using c, the in-plane lattice parameter, a, was calculated
from the position of the (024) and (224) reflections. A deviation in the calculated values for a, beyond the systematic error,
was found in the in-plane lattice parameter, suggesting an in-plane orthorhombic distortion (a, a’). Films with x=0.7 showed
a minimum in-plane distortion due to a better lattice match with the substrate. The ratio of the in-plane and out-of-plane
lattice parameters was calculated as a measure of the lattice distortion (a/c and a’/c). The dielectric properties of the
films deposited were measured at room temperature at 2 GHz using gap capacitors fabricated on top of the dielectric film.
For all Ba/Sr ratios investigated in the W-doped material, the dielectric Q (1/cosδ) was observed to be insensitive to the
oxygen deposition pressure. A peak in the change in the dielectric constant, as a function of an applied electric field (0–80 kV/cm),
was observed for films deposited in 50 mTorr of oxygen. The largest K-factor, K=(ε(0)-ε(V )/ε(0)×Q(0)), for films deposited
from a BST x=0.6 (1 mol % W-doped) target was observed in the film that had a minimum in-plane strain, where a∼a’ and c was
greater than a and a’.
Received: 4 July 2002 / Accepted: 5 July 2002 / Published online: 17 December 2002
RID="*"
ID="*"Permanent address: Nuclear Research Center–Negev, P.O. Box 9001 Beer-Sheva, Israel
RID="**"
ID="**"Corresponding author. Fax: +1-202/767-5301, E-mail: horwitz@ccsalpha3.nrl.navy.mil 相似文献
7.
Y. Du M.-S. Zhang J. Wu L. Kang S. Yang P. Wu Z. Yin 《Applied Physics A: Materials Science & Processing》2003,76(7):1105-1108
SrTiO3 thin films were prepared on a fused-quartz substrate by pulsed laser deposition (PLD). Dense and homogeneous films with a
thickness of 260 nm were prepared. Optical constants (refractive index n and extinction coefficient k) were determined from
the transmittance spectra using the envelope method. The optical band gap energy of the films was found to be 3.58 eV, higher
than the 3.22 eV for bulk SrTiO3, attributable to the film stress exerted by the substrate. The dispersion relation of the refractive index vs. wavelength
follows the single electronic oscillator model. The refractive index and the packing density for the PLD-prepared SrTiO3 thin films are higher than those for the SrTiO3 films prepared by physical vapor deposition, sol–gel and RF sputtering.
Received: 18 March 2002 / Accepted: 7 October 2002 / Published online: 8 January 2003
RID="*"
ID="*"Corresponding author. Fax: +86-25/359-5535, E-mail: mszhang@nju.edu.cn 相似文献
8.
E. Millon J. Perrière R.M. Défourneau D. Défourneau O. Albert J. Etchepare 《Applied Physics A: Materials Science & Processing》2003,77(1):73-80
The elemental composition and the surface morphology of thin films grown by laser ablation of barium titanate with femtosecond
pulses at 620 nm laser wavelength have been systematically studied according to the experimental pulsed-laser deposition parameters
: laser energy density, oxygen pressure, substrate temperature, target–substrate distance and substrate position (in- and
off-axis geometry). Firstly, even at high temperature (700 °C), the deposits consist of coalesced particles up to 1-μm in
size, mixed in a poorly crystallised tetragonal BaTiO3 thin film. The particles formed in femtosecond pulsed-laser deposition induce a high surface roughness, which is observed
whatever the experimental growth conditions and does not correspond to the droplets often observed during laser ablation in
the nanosecond regime. As shown by plasma expansion dynamics, these particles propagate toward the substrate in the plasma
plume with a low velocity, and are assumed to be produced by gas-phase reactions. Moreover, the cationic concentration evaluated
through the Ba/Ti ratio strongly depends on the oxygen pressure in the ablation chamber and the angular position of the substrate
along the normal to the target at laser impact. Indeed, the films appear to be enriched in the heavy element (Ba) when the
substrate is located at high angular deviation. This fact is correlated to an increase in the lighter species (i.e. Ti) in
the central part of the plasma plume.
Received: 30 April 2002 / Accepted: 26 August 2002 / Published online: 8 January 2003
RID="*"
ID="*"Corresponding author. Fax: +33-1/4354-2878, E-mail: millon@gps.jussieu.fr
RID="**"
ID="**"Also at: LSMCL, Université de Metz, 57078 Metz Cedex 3, France 相似文献
9.
E. Cappelli C. Scilletta G. Mattei V. Valentini S. Orlando M. Servidori 《Applied Physics A: Materials Science & Processing》2008,93(3):751-758
The structure of thin films deposited by pulsed laser ablation (PLD) is strongly dependent on experimental conditions, like
laser wavelength and fluence, substrate temperature and pressure. Depending on these parameters we obtained various kinds
of carbon materials varying from dense, mainly tetrahedral amorphous carbon (ta-C), to less compact vertically oriented graphene
nano-particles.
Thin carbon films were grown by PLD on n-Si 〈100〉 substrates, at temperatures ranging from RT to 800°C, from a rotating graphite target operating in vacuum. The laser ablation of the graphite target was performed by a UV pulsed ArF excimer laser (λ=193 nm) and a pulsed Nd:YAG laser, operating in the near IR (λ=1064 nm).
The film structure and texturing, characterised by X-ray diffraction analysis, performed at grazing incidence (GI-XRD), and
the film density, evaluated by X-ray reflectivity measurements, are strongly affected both by laser wavelength and fluence
and by substrate temperature.
Micro-Raman and GI-XRD analysis established the progressive formation of aromatic clusters and cluster condensation into vertically
oriented nano-sized graphene structures as a direct function of increasing laser wavelength and deposition temperature. The
film density, negatively affected by substrate temperature and laser wavelength and fluence, in turn, results in a porous
bulk configuration and a high macroscopic surface roughness as shown by SEM characterisation. These structural property modifications
induce a relevant variation also on the emission properties of carbon nano-structures, as evidenced by field emission measurements.
This work is dedicated to our friend Giorgio who passed away 20th August. 相似文献
10.
Y. W. Li Z. G. Hu F. Y. Yue W. Z. Zhou P. X. Yang J. H. Chu 《Applied Physics A: Materials Science & Processing》2009,95(3):721-725
(La0.5Sr0.5)CoO3 (LSCO) thin films have been fabricated on silicon substrate by the pulsed laser deposition method. The effects of substrate
temperature and post-annealing condition on the structural and electrical properties are investigated. The samples grown above
650°C are fully crystalline with perovskite structure. The film deposited at 700°C has columnar growth with electrical resistivity
of about 1.99×10−3 Ω cm. The amorphous films grown at 500°C were post-annealed at different conditions. The sample post-annealed at 700°C and
10−4 Pa has similar microstructure with the sample in situ grown at 700°C and 25 Pa. However, the electrical resistivity of the
post-annealed sample is one magnitude higher than that of the in situ grown sample because of the effect of oxygen vacancy.
The temperature dependence of resistivity exhibits semiconductor-like character. It was found that post-annealing by rapid
thermal process will result in film cracks due to the thermal stress. The results are referential for the applications of
LSCO in microelectronic devices. 相似文献
11.
W. Wang Z. Liu Y. Liu C. Xu C. Zheng G. Wang 《Applied Physics A: Materials Science & Processing》2003,76(3):417-420
Using a simple wet-chemical route, we synthesized CuO nanorods with diameters of ca. 5–15 nm and lengths of up to 400 nm.
The purity, crystallinity, morphology, structure features, and chemical composition of the as-prepared CuO nanorods were investigated
by powder X-ray diffraction, transmission electron microscopy, high-resolution transmission electron microscopy, X-ray photoelectron
spectroscopy, and Raman spectroscopy.
Received: 22 March 2002 / Accepted: 12 June 2002 / Published online: 28 October 2002
RID="*"
ID="*"Corresponding author. Fax: +86-25/359-5535, E-mail: wangqun@nju.edu.cn 相似文献
12.
J.M. Fernández-Pradas G. Sardin J.L. Morenza 《Applied Physics A: Materials Science & Processing》2003,76(2):251-256
Calcium phosphate coatings were deposited with a KrF excimer laser onto titanium alloy to study their homogeneity. Deposition
was performed at a high deposition rate under a water vapour atmosphere of 45 Pa and at a substrate temperature of 575 °C.
Samples were also submitted to annealing under the same conditions of deposition for different times just after deposition.
The effects of the annealing were also investigated. The morphology of the coatings was studied by scanning electron microscopy.
Their structure and phase distribution was analysed by X-ray diffractometry and infrared and micro-Raman spectroscopies. Besides
the non-uniform thickness, the results reveal an inhomogeneity in the spatial distribution of calcium phosphate phases in
the coatings. The phase distribution can be almost completely correlated with the deposition rate. High deposition rates (0.5 nm/pulse)
occurring in the centre of deposition results in the formation of amorphous calcium phosphate, while lower deposition rates
favour the presence of hydroxyapatite and alpha tricalcium phosphate. At intermediate deposition rates, beta tricalcium phosphate
is found, probably because the superimposed effect of energetic particles bombardment. The annealing process promotes the
crystallisation of the amorphous material. The importance of the deposition rate in the phases obtained is stated after comparing
these results with a previous work where homogeneous hydroxyapatite coatings were obtained under the same conditions of laser
fluence, temperature and pressure, but at lower deposition rates.
Received: 22 November 2001 / Accepted: 12 March 2002 / Published online: 5 July 2002
RID="*"
ID="*"Corresponding author. Fax: +34-93/402-1138, E-mail: jmfernandez@fao.ub.es 相似文献
13.
Stress anisotropy in circular planar magnetron sputter deposited molybdenum films and its annealing effect 总被引:2,自引:0,他引:2
Y.G. Wu E.H. Cao Z.S. Wang J.M. Wei W.X. Tang L.Y. Chen 《Applied Physics A: Materials Science & Processing》2003,76(2):147-152
As part of the program to develop a free-standing thin-film filter for soft X-ray optics application, stress anisotropy in
the molybdenum films deposited by dc circular planar magnetron sputtering were studied by X-ray diffraction (XRD) as a function
of sputtering argon gas pressure over a range of 0.8–1.5 Pa. Surface morphology of the films has been investigated by optical
microscopy and scanning tunneling microscopy (STM). It is found that, for the film deposited at 0.8 Pa pressure, the stresses
are more compressive in the tangential than in the radial direction; the highest compressive stress exists in the center area.
The film deposited at 1.5 Pa pressure has the highest stress anisotropy, and the stresses are less tensile in the tangential
than in the radial direction. Annealing in vacuum is more effective in reducing tensile stress and stress anisotropy in the
tensile stressed film than in the compressively stressed film.
Received: 14 September 2001 / Accepted: 21 January 2002 / Published online: 5 July 2002
RID="*"
ID="*"Corresponding author. Fax: +86-21/6598-6323, E-mail: ygwu@mail.tongji.edu.cn 相似文献
14.
Crystal structure, morphology, depth profile of elements and mid-infrared optical constants of ‘mild’ lead telluride film 总被引:1,自引:0,他引:1
B. Li S. Zhang F. Zhang L. Zeng 《Applied Physics A: Materials Science & Processing》2003,76(6):965-968
The characterizations of a so-called ‘mild’ PbTe layer thermal-evaporated from an excess of Te (<1 mol.%) evaporable materials
are reported. The results reveal that the film obtained is polycrystalline and has a single-phase NaCl-type PbTe crystal structure.
It is also demonstrated that the film has a homogeneous surface morphology and a high degree of homogeneous distribution of
Te-rich components along the layer. The study of mid-infrared optical constants of a surface-polished film indicates that
the influence of surface scattering on optical properties is very small.
Received: 3 July 2002 / Accepted: 7 August 2002 / Published online: 4 December 2002
RID="*"
ID="*"Corresponding author. Fax: +86-21/6516-9946, E-mail: lbincome@yahoo.com 相似文献
15.
X.Y. Chen B. Yang T. Zhu K.H. Wong J.M. Liu Z.G. Liu 《Applied Physics A: Materials Science & Processing》2002,74(4):567-569
(110)-textured MgO films were grown on Si (100) with etching and without etching by pulsed laser deposition. The deposited
MgO films were shown to be droplets-free. The MgO film was used as a buffer layer to further grow Pt film on Si (100). A completely
(110)-oriented Pt film was obtained on such a buffer layer and its surface is very smooth with a roughness of about 7.5 nm
over 5×5 μm. This can be used as a new oriented Pt electrode on silicon for devices.
Received: 23 January 2001 / Accepted: 27 April 2001 / Published online: 27 June 2001 相似文献
16.
Manganese oxide (hausmannite) nanowires were prepared by annealing precursor powders at a temperature of 800 °C for 3 h, which
were produced in a novel inverse microemulsion (IμE) system. The microstructures of the as-prepared Mn3O4 nanowires were investigated by means of X-ray diffraction, transmission electron microscopy, and Raman spectra. It has been
found that the Mn3O4 nanowires were relatively straight and their surfaces were smooth with a typical diameter of 75–150 nm. The formation mechanism
of the Mn3O4 nanowires is discussed.
Received: 30 May 2002 / Accepted: 7 October 2002 / Published online: 17 December 2002
RID="*"
ID="*"Corresponding author. Fax: +86-25/359-5535, E-mail: wangqun@nju.edu.cn 相似文献
17.
M. Yorozu J. Yang Y. Okada T. Yanagida F. Sakai S. Ito A. Endo 《Applied physics. B, Lasers and optics》2003,76(3):293-297
Polarization-dependent spatial beam profiles of femtosecond X-ray pulses generated by a laser Compton scheme were measured.
The X-ray pulses were generated by the interaction at an angle of 90° between 100-fs laser light and a 3-ps, 3π-mm mrad electron
beam. The polarization of the laser light was linear in two different directions, either parallel or perpendicular to the
electron beam axis. The measured profiles showed good agreement with theoretical results.
Received: 5 July 2002 / Revised version: 17 October 2002 / Published online: 5 February 2003
RID="*"
ID="*"Corresponding author. Fax: +81-424/684477, E-mail: msf_yorozu@shi.co.jp 相似文献
18.
Myunghee Kim Jitsuo Ohta Atsushi Kobayashi Hiroshi Fujioka Masaharu Oshima 《固体物理学:研究快报》2008,2(1):13-15
AlN films have been grown on atomically flat carbon face 6H‐SiC (000 ) substrates by pulsed laser deposition and their structural properties have been investigated. In‐situ reflection high‐energy electron diffraction observations have revealed that growth of AlN at 710 °C proceeds in a Stranski–Krastanov mode, while typical layer‐by‐layer growth occurs at room temperature (RT) with atomically flat surfaces. It has been revealed that the crystalline quality of the AlN film is dramatically improved by the reduction in growth temperature down to RT and the full width at half maximum values in the X‐ray rocking curves for 0004 and 10 2 diffractions of the RT‐grown AlN film are 0.05° and 0.07°, respectively. X‐ray reciprocal space mapping has revealed that the introduction of misfit dislocations is suppressed in the case of RT growth, which is probably responsible for the improvement in crystalline quality. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
19.
J.K. Jian X.L. Chen W.J. Wang L. Dai Y.P. Xu 《Applied Physics A: Materials Science & Processing》2003,76(2):291-294
Single-crystalline SnO2 nanowires, nanobelts and nanodendrites were synthesized by a simple gas-reaction route on a large scale at 900 °C. They were
characterized by means of X-ray powder diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), energy-dispersive
X-ray spectroscopy (EDS), transmission electron microscopy (TEM) and selected-area electron diffraction (SAED). FE-SEM images
showed that the products consisted of nanowires, nanobelts and nanodendrites that represent a novel morphology reported for
the first time. XRD, SAED and EDS indicated that they were single-crystalline tetragonal SnO2. The influence of experimental conditions on the morphologies of the products is discussed.
Received: 3 June 2002 / Accepted: 10 June 2002 / Published online: 10 September 2002
RID="*"
ID="*"Corresponding author. Fax: 86-10/82649531, E-mail: xlchen@aphy.iphy.ac.cn 相似文献
20.
The authors’ endeavors over the last few years with respect to boron nitride (BN) nanotube metal filling are reviewed. Mo
clusters of 1–2 nm in size and FeNi Invar alloy (Fe ∼60 at. %; Ni ∼40 at. %) or Co nanorods of 20–70 nm in diameter were embedded
into BN nanotube channels via a newly developed two-stage process, in which multi-walled C nanotubes served as templates for
the BN multi-walled nanotube synthesis. During cluster filling, low-surface-tension and melting-point Mo oxide first filled
a C nanotube through the open tube ends, followed by fragmentation of this filling into discrete clusters via O2 outflow and C→BN conversion within tubular shells at high temperature. During nanorod filling, C nanotubes containing FeNi
or Co nanoparticles at the tube tips were first synthesized by plasma-assisted chemical vapor deposition on FeNi Invar alloy
or Co substrates, respectively, and, then, the nanomaterial was heated to the melting points of the corresponding metals in
a flow of B2O3 and N2 gases. During this second stage, simultaneous filling of nanotubes with a FeNi or Co melt through capillarity and chemical
modification of C tubular shells to form BN nanotubes occurred. The synthesized nanocomposites were analyzed by scanning and
high-resolution transmission electron microscopy, electron diffraction, electron-energy-loss spectroscopy and energy-dispersive
X-ray spectroscopy. The nanostructures are presumed to function as ‘nanocables’ having conducting metallic cores (FeNi, Co,
Mo) and insulating nanotubular shields (BN) with the additional benefit of excellent environmental stability.
Received: 10 October 2002 / Accepted: 25 October 2002 / Published online: 10 March 2003
RID="*"
ID="*"Corresponding author. Fax: +81-298/51-6280, E-mail: golberg.dmitri@nims.go.jp 相似文献