共查询到20条相似文献,搜索用时 15 毫秒
1.
Zeper Abliz Junji Aoki Toyotoshi Ueda Teruo Kan Minoru Takekawa Satoshi Iwashima 《Journal of mass spectrometry : JMS》1993,28(5):607-614
Electron impact mass spectra were measured for five isomers of pyridinobenzanthrones and three isomers of benzobenzanthrones. The fragmentation pattern and intensity of M2+, [M – H]+, [M – CO]i+, [M – CO – H(or 2H)]i+ and [M – CO – HCN]i+ (i = 1, 2) ions indicated remarkable differences and very interesting features according to the isomers with or without nitrogen and condensation positions of a pyridino or benzo ring to the benzanthrone skeleton. Further, the competition of decompositions through [M – H]+, [M – CO]+˙ or [M – HCN]+˙ ions was confirmed by the observation of metastable ions and the appearance energies of fragment ions. Interesting observations from these results were expulsion of an H atom in close proximity to the area around an O?C group, a weak bonding interaction between sp2 C? H and an O?C group, inducing specific hydrogen rearrangement, and characteristic charge localization on heteroatoms. 相似文献
2.
The thermospray mass spectrometry (TSP/MS) of five N-methylcarbamates is presented. This is the first time that ions other than [M + H]+ and [M + NH4]+ have been reported using positive TSP/MS. Protonation of ROCONHCH3 yields the [CH3NH2CO]+· ion, with formation of the ion–molecule adduct [ROCONHCH3 · CH3NH2CO]+· through elimination of CO+· from [CH3NH2CO]+·, and the adduct [M + 75]+·, [ROCONHCH3 · OCONH2CH3]+·, is also obtained. 相似文献
3.
Ernst Pittenauer Günter Allmaier Erich R. Schmid Wolfgang Stanek Gottfried Heinisch 《Journal of mass spectrometry : JMS》1991,26(6):595-600
The mass spectrometric fragmentation behaviour of pyridazine and four monosubstituted derivatives containing a pbenylalkyl side-chain (3- and 4-benizylpyridazine, 3- and 4-(2-pbenylethyl)pyridazine) was investigated. In the electron impact ionization mess spectra of the 3-substituted compounds abundant [M – H]+ peaks are observed. This allows a clear distinction between 3- and 4-substituted pyridazines, as the spectra of the latter isomers show only very weak [M – H]+ signals. The stability of [M – H]+ ions derived from 3-alkylpyridazines (deduced from only the very low abundance of further fragment ions) gives strong evidence for a cyclic structure of these ions. One fragmentation pathway typical of the parent pyridazine, the [M - N2] fragmentation, was not detectable with any of the phenylalkylpyridazines investigated. Instead, loss of HCN, H3CN+ and N2H+ was observed. An interesting fragmentation, observed with 3-(2-phenylethyl)pyridazine, is the loss of +CH3 from the molecular ion and also from the [M – H]+ ion. 相似文献
4.
Dami Barcel 《Journal of mass spectrometry : JMS》1989,24(10):898-902
The effect of two completely different mobile phase compositions, reversed-phase acetonitrile-water + ammonium acetate and normal-phase cyclohexane, were compared in filament-on thermospray liquid chromatography-mass spectrometry (LC-MS) for the determination of selected chlorinated herbicides such as chloroatrazines and chlorinated phenoxyacetic acids. By using acetonitrile-water + 0.05 M ammonium acetate mixtures in positive ion mode thermospray LC-MS, the chloroatrazine herbicides showed the acetonitrile adduct ion [M + (CH3CN)H]+ as the base peak, whereas the chlorinated phenoxyacetic acids showed no signal. In contrast, when cyclohexane, which is reported for the first time as an eluent in the thermospray technique, was used as the mobile phase the chlorinated phenoxyacetic acid herbicides exhibited [M – H]+, [M – Cl]+ and M+˙ as the main ions. Negative ion mode thermospray LC-MS showed [M – H]? as the base peak for the chloroatrazines in the different mobile phases, whereas the chlorinated phenoxyacetic acids exhibited [M + H]?, [M + Cl]? or [M – HCl]? as the base peaks in cyclohexane and [M + acetate]? in acetonitrile-water-ammonium acetate. 相似文献
5.
Mass spectrometric monitoring of oxidation of aliphatic C6–C8 hydrocarbons and ethanol in low pressure oxygen and air plasmas
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Dilshadbek T. Usmanov Lee Chuin Chen Kenzo Hiraoka Hiroshi Wada Hiroshi Nonami Shinichi Yamabe 《Journal of mass spectrometry : JMS》2016,51(12):1187-1195
Experimental and theoretical studies on the oxidation of saturated hydrocarbons (n‐hexane, cyclohexane, n‐heptane, n‐octane and isooctane) and ethanol in 28 Torr O2 or air plasma generated by a hollow cathode discharge ion source were made. Ions corresponding to [M + 15]+ and [M + 13]+ in addition to [M ? H]+ and [M ? 3H]+ were detected as major ions where M is the sample molecule. The ions [M + 15]+ and [M + 13]+ were assigned as oxidation products, [M ? H + O]+ and [M ? 3H + O]+, respectively. By the tandem mass spectrometry analysis of [M ? H + O]+ and [M ? 3H + O]+, H2O, olefins (and/or cycloalkanes) and oxygen‐containing compounds were eliminated from these ions. Ozone as one of the terminal products in the O2 plasma was postulated as the oxidizing reagent. As an example, the reactions of C6H14+? with O2 and of C6H13+ (CH3CH2CH+CH2CH2CH3) with ozone were examined by density functional theory calculations. Nucleophilic interaction of ozone with C6H13+ leads to the formation of protonated ketone, CH3CH2C(=OH+)CH2CH2CH3. In air plasma, [M ? H + O]+ became predominant over carbocations, [M ? H]+ and [M ? 3H]+. For ethanol, the protonated acetic acid CH3C(OH)2+ (m/z 61.03) was formed as the oxidation product. The peaks at m/z 75.04 and 75.08 are assigned as protonated ethyl formate and protonated diethyl ether, respectively, and that at m/z 89.06 as protonated ethyl acetate. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
6.
Fragmentation patterns resulting from electron impact ionization of 3-(2′-hydroxyethyl)quinolin-2(1H)-one, three of its monosubstituted derivatives and four of its disubstituted derivatives were studied. The molecular ion of quinolinone-2-etbanol undergoes initial fragmentation with the loss of OH·, H2O, CO, ·CHO, CH2O, CH2OH·, CH2?CHOH and HCNO species. The [M – CHO]+ ion is tentatively suggested to have been formed by the expulsion of H· from the [M – CO]+· ion and the [M - CHO]+ peak may be considered as diagnostic of a 2-quinolone-3-ethanol. 相似文献
7.
Tuula Kuivalainen Risto Kostiainen Heikki Björk Rolf Uggla Markku R. Sundberg 《Journal of the American Society for Mass Spectrometry》1995,6(6):488-497
A study was carried out on the fragmentation of 12 protonated O,O-dimethyl O-aryl phosphorothionates by tandem quadrupole mass spectrometry. Some of the studied compounds are used in agriculture as pesticides. Energy-resolved and pressure-resolved experiments were performed on the [M + H]+ ions to investigate the dissociation behavior of the ions with various amounts of internal energy. On collisionally activated dissociation, the [M + H]+ ions decompose to yield the [M + H ? CH3OH]+, (CH3O)2PS+ (m/z 125), and (CH3O)2PO+ (m/z 109) ions as major fragments. The ions [M + H ? CH3OH]+ and (CH3O)2PS+ probably arise from the [M + H]+ ions of the O,O-dimethyl O-aryl phosphorothionates with the proton on the sulfur or on the oxygen of the phenoxy group. The origin of the hydroxy proton of the methanol fragment was in many cases, surprisingly, the phenyl group and not the reagent gas. This was confirmed by using deuterated isobutane, C4D10, as reagent gas in Cl. The fragment ions (CH3O)2PO+ and [ZPhS]+ are the results of thiono-thiolo rearrangement reaction. The precursor ion for the ion (CH3O)2PO+ arises from most compounds upon chemical ionization, whereas the precursor ion for the ion [ZPhS]+ arises only from a few compounds upon chemical ionization. The observed fragments imply that several sites carry the extra proton and that these sites get the proton usually upon ionization. The stability order and some characteristics of three protomers of O,O-dimethyl O-phenyl phosphorothionate were investigated by ab initio calculations at the RHF/3-21G* level of theory. 相似文献
8.
D. Carbone S. Fisichella S. Occhipinti G. Scarlata 《Journal of heterocyclic chemistry》1982,19(6):1505-1509
The mass spectra of some (Z)α-(4-R′-phenyl)-β-(2-thienyl-5-R)acrylonitriles (R = H, CH3, Br; R′ = H, CH3O, CH3, Cl, NO2) at 70 eV are reported. Mass spectra exhibit pronounced molecular ions. The compound's where R = H, and CH3 are characterized by the occurrence of a strong [M - H]+ peak. Moreover, in all the compounds a m/z 177 peak occurs. In the compounds where R = H, [M - HS]* and [M - CHS]* ions are present except the nitroderivatives. Where R = CH3, [M - HS]+ ion occurs. 相似文献
9.
The fragmentations of [(CH3)2SiO]n, (Dn), where n = 4, 5, 6, 7, 8, 9, 10, 12 and 15 are reported. The behaviour of these compounds under electron-impact is governed by the size of the siloxane ring. Rings smaller than D6 have base peaks corresponding to [M – 15]+ ions; larger rings all show base peaks of m/e 73 [Si(CH3)3]+. A transannular mechanism previously applied only to D5 and D6 is extended and modified to account for the behaviour of larger rings. A ring con-traction mechanism is proposed which leads to the formation of smaller rings and doubly charged ions. A new transannular mechanism is proposed to account for the production of [M – 177]+ and [M – 193]+ ions. 相似文献
10.
Gary W. Caldwell Kirk L. Sorgi Lorraine Scott Bruce E. Maryanoff Cynthia A. Maryanoff John A. Masucci Samuel O. Nortey William R. Sisco Arthur Micheel Chan-Yan Ko 《Journal of mass spectrometry : JMS》1989,24(12):1051-1059
The electron-impact (EI) mass spectral fragmentation of ten bis-O- (1-methylethylidene)fructopyranose derivatives and three related sugar sulfamates were investigated. In particular, 2,3:4,5-bis-O - (1-methylethylidene)-β-D-fructopyranose sulfamate (topiramate), a potent anticonvulsant, was examined in greater detail. The fragmentation of the 2,3:4,5-bis-O-(1-methylethylidene) fructopyranose derivatives in general was not very dependent on the nature of substitution; the mechanisms of the common and unique fragmentation patterns are presented. These compounds showed characteristic peaks at m/z [M – 15]+, [M – 15 – 58]+, [M – 15 – 58 – 60]+, [M ? CH2X]+ and [M ? CH2X – 58]+ where X = OSO2NR2 (R ? H, CH3, and/or Ph), OC (O)NHR, NH2, CI and OH. The fragmentation of isomeric bis-O-(1-methylethylidene) derivatives of aldopyranose, ketopyranose and ketofuranose sulfamates was also investigated. The results indicate that isomeric sugar sulfamates can be easily distinguished in the EI mode. Key fragmentation pathways are discussed for these compounds. 相似文献
11.
Aminomonosaccharides (glucosamine, galactosamine, and mannosamine) in H2O and D2O were ionized by atmospheric pressure chemical ionization (APCI) and their fragmentation patterns were investigated to identify them. All the aminomonosaccharides showed the same fragment ions but their relative ion intensities were different. Major product ions generated in H2O were [M + H]+, [M + H – H2O]+, and [2M + H – 3H2O]+, while in D2O were [MD6 + D]+, [MD6 + D – D2O]+, and [2MD6 + D – D2O – 2HDO]+. At a high fragmentor voltage above 120 V, the relative ion intensities of the major product ions showed different trends according to the aminomonosaccharides. For the use of H2O as solvent and eluent, the order of the ion intensity ratio of [M + H – H2O]+/[2M + H – 3H2O]+ was galactosamine > mannosamine > glucosamine. When using D2O as solvent and eluent, the order of the ion intensity ratios of [MD6 + D – D2O]+/[MD6 + D]+ and [2MD6 + D – D2O – 2HDO]+/[MD6 + D]+ was mannosamine > galactosamine > glucosamine. It was found that glucosamine, galactosamine, and mannosamine could be distinguished by the specific trends of the major product ion ratios in H2O and D2O. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
12.
Dorothe Berthomieu Jeanine Tortajada Jean-Pierre Morizur Henri-Edouard Audier 《Journal of mass spectrometry : JMS》1991,26(6):601-607
The reactions of metastable decomposing methyl acetoacetate (a mixture of keto a ad enol tautomers) are reported and discussed. The unimolecular fragmentations of the tautomers are different. The metastable decomposing radical cation of the keto form displays four specific ions: [M –CO]+˙, [M – CH2O]+˙, [M – CH2CO]+˙ and m/z 43. The results derived from D-, 13C- and 18O-labelled precursors together with thermochemical data have been used to study the mechanisms. Experimental results indicate that an unexpected isomerization occurs before dissociation. It formally corresponds to oxygen atom permutation of the two carbonyl groups without participation of the carbon atoms. This remarkable process is interpreted in terms of a mechanism involving ion-molecule complexes. 相似文献
13.
Thomas Hellman Morton 《Journal of mass spectrometry : JMS》1991,26(1):18-23
An ion–neutral complex is a non-covalently bonded aggregate of an ion with one or more neutral molecules in which at least one of the partners rotates freely (or nearly so) in all directions. A density-of-states model is described, which calculates the proportion of ion–neutral complex formation that ought to accompany simple bond cleavages of molecular ions. Application of this model to the published mass spectrum of acetamide predicts the occurrence of ions that have not hitherto been reported. Relative intensities on the order of 0.1 (where the abundance of the most intense fragment ion = 1) ere predicted for [M – HO]+ and [M – CH4]+˙ ions, which have the same nominal masses as the prominent [M – NH3]+˙ and [M – NH2]+ fragments. High-resolution mass spectrometric experiments confirm the presence of the predicted fragment ions. The [M – HO]+ and [M – CH4]+˙ fragments were observed with relative abundances of 0.02 and 0.04, respectively. Differences between theory and experiment may be ascribed to effects of competing distonic ion pathways. 相似文献
14.
The metastable ion supported fragmentation process in the mass spectra of the cyclohexadienyl derivative C6H7Mn(CO)3, the cycloheptadienyl derivative C7H9Mn(CO)3, the 1,2,3,4,5-and 1,2,3,5,6-pentahaptocyclootadienyl derivatives C8H11Mn(CO)3, the cyclooctatrienyl derivative C8H9Mn(CO)3 and the substituted cyclopentadienyl derivative (CH3)2NCH2C5H4Mn(CO)3, are described. Losses of carbonyl groups, generally stepwise, from the molecular ions to give the corresponding [M – 3CO]+· ions are first observed. Further fragmentation of the carbonyl-free [M – 3CO]+· ions can involve a variety of processes such as the following: (a) elimination of a neutral manganese atom to give a hydrocarbon fragment; (b) elimination of a neutral hydrocarbon fragment to give an [MnH]+· ion; (c) dehydrogenation; (d) elimination of a 2-carbon C2H2 or C2H4 fragment; (e) elimination of a C3H4 or C3H6 fragment as a neutral species when it is bridging two carbon atoms bonded to manganese, as in C8H9Mn(CO)3 and 1,2,3,4,5,h5-C8H11Mn(CO)3, respectively. Fragmentation of the [M – 3CO]+· ion in (CH3)2NCH2C5H4Mn(CO)3 presents the following additional features: (a) elimination of C6H6 with a nitrogen shift from carbon to manganese; (b) elimination of a neutral dimethylamino fragment to give [C6H6Mn]+·, which then loses neutral C6H6, C6H5 or Mn fragments and thus is formulated tentatively as [(fulvene)Mn]+· or [C6H5MnH]+· rather than [(benzene)Mn]+·. 相似文献
15.
J. H. Beynon R. M. Caprioli R. G. Cooks N. M. M. Nibbering T. A. Molenaar-Langeveld 《Journal of mass spectrometry : JMS》1975,10(10):824-830
The metastable ions [M]2+, [M – H]2+· and [M – H2]2+ from malononitrile fragment by loss of [CH]+, [C]+· and [C]+·, respectively. The reaction of the molecular ion involves the methylene and nitrile carbon atoms in the statistical probability ratio, while that of [M – H]2+· involves exclusively the nitrile carbon and that of [M ? H2]2+ involves an approximately equal contribution, from both sources. It is suggested that the metastable molecular ion fragments through a bipyrimidal intermediate. 相似文献
16.
The fragmentations of the acylium ions O?C+? CH2? CH2? CO2CH3 and O?C+? CH2? CH2? COCH3 generated from methyl levulinate are governed extensively by the interaction of the two carbonyl groups. Both species eliminate a molecule of CO unimolecularly and under CID conditions. The results derived from measurements of 13C and 18O labelled precursors, together with kinetic energy release values, have been used to study the mechanisms. In the first of these acylium ions, both carbonyl groups are equivalent; this phenomenon can be the result of a 1,4 methoxy shift. In the second acylium ion, only the oxygen atoms change their positions; this isomerization occurs via the [M? H]+ of γ-valerolactone. Some other fragmentation processes also discussed in relation to 2H labelling are the formation of the [M ? COOCH3] + ion and the loss of HCOOCH3 in the collision-induced dissociation mass spectra of the first acylium ion, and the formation of the [CH3CO]+ ion and the loss of H2O for the second one. 相似文献
17.
Jürgen Schmidt Dietmar Kuck Katrin Franke Haider Sultani Annegret Laub Ludger A. Wessjohann 《Journal of mass spectrometry : JMS》2019,54(6):549-556
Long‐chain ferulic acid esters, such as eicosyl ferulate ( 1 ), show a complex and analytically valuable fragmentation behavior under negative ion electrospay collision‐induced dissociation ((?)‐ESI‐CID) mass spectrometry, as studied by use of a high‐resolution (Orbitrap) mass spectrometer. In a strong contrast to the very simple fragmentation of the [M + H]+ ion, which is discussed briefly, the deprotonated molecule, [M – H]?, exhibits a rich secondary fragmentation chemistry. It first loses a methyl radical (MS2) and the ortho‐quinoid [M – H – Me]‐? radical anion thus formed then dissociates by loss of an extended series of neutral radicals, CnH2n + 1? (n = 0–16) from the long alkyl chain, in competition with the expulsion of CO and CO2 (MS3). The further fragmentation (MS4) of the [M – H – Me – C3H7]? ion, discussed as an example, and the highly specific losses of alkyl radicals from the [M – H – Me – CO]‐? and [M – H – Me – CO2]‐? ions provide some mechanistic and structural insights. 相似文献
18.
Mass-analysed ion kinetic energy spectrometry (MIKES) with collision-induced dissociation (CID) has been used to study the fragmentation processes of a series of deuterated 2,4,6-trinitrotoluene (TNT) and deuterated 2,4,6-trinitrobenzylchloride (TNTCI) derivatives. Typical fragment ions observed in both groups were due to loss of OR′ (R′ = H or D) and NO. In TNT, additional fragment ibns are due to the loss of R2′O and 3NO2, whilst in TNTCI fragment ions are formed by the loss of OCI and R2′OCI. The TNTCI derivatives did not produce molecular ions. In chemical ionization (Cl) of both groups. MH+ ions were observed, with [M – OR′]+ fragments in TNT and [M – OCI]+ fragments in TNTCI. In negative chemical ionization (NCI) TNT derivatives produced M?′, [M–R′]?, [M–OR′]? and [M–NO]? ions, while TNTCI derivatives produced [M–R]?, [M–Cl]? and [M – NO2]? fragment ions without a molecular ion. 相似文献
19.
Seymour Meyerson 《Journal of mass spectrometry : JMS》1970,3(1):119-125
Mass spectra of isotope-labeled triptycenes, triphenylmethanes and diphenylmethanes rule out the bulk of postulated decomposition mechanisms and fragment-ion structures. The formation of [M ? H]+ and [M ? 2H]2+ from triptycene, of [M ? H]+, [M ? CH3]+ and [M ? CH4]+ from triphenylmethane, and of [M ? H]2+ and [M ? 2H]2+-as well as the previously reported [M ? H]+ and [M ? CH3]+-from diphenylmethane all seem to be preceded or accompanied by complete loss of position identity of the α and ring hydrogens in the original molecules. A statistical preference for loss of α hydrogens is found in the process leading to [M ? 2H]+ and [M ? H]2+ from triptycene, as in the formation of [M ? H]2+ from toluene. 相似文献
20.
Based on the quasi-equilibrium theory of mass spectra it is shown that the intensity ratio [A]+/[M]+, where [A]+ is a fragment ion and [M]+ is the molecular ion, is given by [A]+/[M]+ = f′ (k1/kt) ((1/f) ? 1), where f is the fraction of molecular ions with insufficient energy to fragment, f′ is the fraction of [A]+ ions with insufficient energy to fragment, and k1/kt is the fraction of fragmenting molecular ions which form [A]+. For substituted acetophenones it is shown that f depends on the substituent present and that f′ k1/kt is also substituent dependent for formation of both [CH3CO]+ and [YC6H4CO]+. It is also shown that no direct information concerning the effect of a substituent on the rate of a particular fragmentation reaction can be obtained from intensity studies. The ionization potentials of the parent molecules and the appearance potentials of the [YC6H4CO]+ fragment ions have been measured for fifteen substituted acetophenones and the correlations with substituent constants are discussed. 相似文献