Surface plasma oscillations in layer metal particles

Light scattering cross section and positions of two surface plasma resonances in a layer metal particle containing dielectric foreign nucleus are calculated within the random phase approximation. The results obtained provide a possible explanation of contradictions in size dependence of surface plasma resonance position [1, 2] and are able to explain two peak structure of photoabsorption cross section of small silver particle observed in [1].     

Thermo-mechanical behavior of nano aluminum particles with oxide layers during melting

Molecular dynamics simulations were performed to study the thermo-mechanical behavior of nano aluminum particles coated with crystalline and amorphous oxide layers during melting. The analysis employs the Streitz–Mintmire potential, along with micro-canonical (NVE) and isobaric–isoenthalpic (NPH) ensembles. The effect of particle size in the range of 5–10 nm with oxide thickness in the range of 1–2.5 nm was investigated. The melting phenomenon was characterized using a combination of structural and thermodynamic parameters. Various fundamental processes, including structural changes, stress development, and phase transformations in both the aluminum core and the oxide shell, were examined and quantified systematically. The diffusion of aluminum cations through the oxide layer was also explored. In addition, a structural analysis was applied to determine the stress field in the oxide shell due to the volume dilatation in the aluminum core. In the particle-size range considered here, the oxide layer melts at ~1,100 K, substantially lower than the value for bulk alumina (2,327 K). The oxide thickness exerts a weak influence on the melting temperature of the shell. The aluminum core melts at a temperature considerably lower than its bulk value of 940 K, a situation comparable to that of a pure nano aluminum particle. This study is an important milestone in the development of a multi-scale theory for the ignition and combustion of nano-particulate aluminum.     

The influence of striction density perturbations on the excitation of plasma oscillations inside thermal inhomogeneities of plasma

In this paper, we continue our studies begun in [Izv. Vyssh. Uchebn. Zaved., Radiofiz.,41, No. 3, 270 (1998)].Calculating the coefficients and nonlinear phase shift in the equation for plasma-wave intensity introduced in the eralier paper, we have solved the problem of the influence of striction perturbations of the plasma density on the excitation of shortwave plasma oscillations by an electromagnetic wave; the above oscillations are captured in a volume of inhomogeneities, which are extended along the magnetic field and have reduced electron density that crosses the level of the upper-hybrid resonance. The dissipative processes of absorption and emission of plasma waves beyond the inhomogeneity are assumed to be weak. The variation of excitation and reflection of plasma waves from the resonance level due to deformation of the plasma- density profile is described. The band of effective generation of eigenmodes of captured oscillations as a function of the total wave-phase increment in an inhomogeneity is determined. The effect of penetration of the field of a high-power plasma wave into the non-transmittance region as a result of the striction expulsion of plasma is calculated. With allowance for the nonlinear phenomena in question, we estimated the heating of artificial inhomogeneities of thermal origin as a result of collisional absorption of the plasma oscillations excited in a volume of inhomogeneities under the action of a high-power radio wave. The materials of this paper were reported at the IIIrd International School on Space Plasma Physics. Institute of Terrestrial Magnetism, Ionosphere, and Radio Wave Propagation, Russian Academy of Sciences, Troitsk, Moscow Region, Russia. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 41, No. 10, pp. 1226–1247, October 1998.     

Crystalline silicon surface passivation investigated by thermal atomic-layer-deposited aluminum oxide

Atomic-layer-deposited(ALD) aluminum oxide(Al_2O_3) has demonstrated an excellent surface passivation for crystalline silicon(c-Si) surfaces, as well as for highly boron-doped c-Si surfaces. In this paper, water-based thermal atomic layer deposition of Al_2O_3 films are fabricated for c-Si surface passivation. The influence of deposition conditions on the passivation quality is investigated. The results show that the excellent passivation on n-type c-Si can be achieved at a low thermal budget of 250℃ given a gas pressure of 0.15 Torr. The thickness-dependence of surface passivation indicates that the effective minority carrier lifetime increases drastically when the thickness of Al_2O_3 is larger than 10 nm. The influence of thermal post annealing treatments is also studied. Comparable carrier lifetime is achieved when Al_2O_3 sample is annealed for 15 min in forming gas in a temperature range from 400℃ to 450℃. In addition, the passivation quality can be further improved when a thin PECVD-SiN_x cap layer is prepared on Al_2O_3, and an effective minority carrier lifetime of2.8 ms and implied Voc of 721 mV are obtained. In addition, several novel methods are proposed to restrain blistering.     

Investigation on the thermal radiation properties of antimony doped tin oxide particles

This paper reports the preparation of antimony doped tin oxide crystalline powders by chemical coprecipitation method. The influence of sintering temperature and the sintering retention time on the thermal infrared emissivity is analysed. The thermal infrared reflectivity is measured and the optimum doping concentration is proposed.     

Numerical investigation of the flow of ultradisperse particles of the aluminum oxide in the solid-fuel rocket engine nozzle

The work deals with the two-phase flow investigation. The computations were done for a continuous coagulation model within the framework of the phenomenological multi-fluid model of the medium. A conclusion was drawn that the diminution of the particles size leads to a reduction of two-phase losses in the nozzle unit of the solid-fuel engine.     

Excitation of an optical satellite by thermal electron oscillations of a lithium plasma

An optical satellite excited by thermal electron plasma oscillations is observed near the 2P–3P forbidden line of a dense lithium plasma. The observations are compared with predictions of second order time-dependent Stark theory.     

Burning of aluminum particles in water

Experiments in a constant-volume reactor and in a model rocket combustor demonstrated the possibility of convective burning of mixtures of water with PAP-2 flaky aluminum powder with the formation of alumina and hydrogen. It was shown that the porosity of the mixture is an important factor determining the mode of its burning. The burning occurred at a pressure of several hundred atmospheres in the convective mode.     

Photonic Bloch oscillations of correlated particles

A photonic realization of Bloch oscillations (BOs) of two correlated electrons that move on a one-dimensional periodic lattice, based on spatial light transport in a square waveguide array with a defect line, is theoretically proposed. The signature of correlated BOs, such as frequency doubling of the oscillation frequency induced by particle interaction, can be simply visualized by monitoring the spatial path followed by an optical beam that excites the array near the defect line.     

高频感应热等离子体中粉末颗粒的运动行为研究

建立了高频电感耦合等离子体炬的二维轴对称模型,利用商用软件FLUENT对钛粉颗粒在纯氩热等离子体内的运动轨迹进行了模拟,研究了前驱体粒径及载气流量的变化对粉末颗粒受力过程的影响。研究结果表明,粒径小的颗粒受炬内回流作用的影响较大,颗粒运动轨迹杂乱,而粒径大的颗粒受回流的影响则很小;降低载气流量可以使钛粉的受热更加充分,使得更多的颗粒被加热至熔化,可提高粉末的球化率。     

Free surface entrainment of oxide particles and their role in ultrasonic treatment performance of aluminum alloys

Although the ultrasonic treatment of molten aluminum has been studied for long period, there is still much to be revealed for this process. Many studies have focused on the investigation of acoustic cavitation and streaming under the horn tip and their effects on the treatment efficiency. However, to the best of our knowledge, no attempt has been done to explain phenomena occurring near or on the melt free surface. Thus, the goal of this study is to investigate phenomena occurring at the free surface during ultrasound irradiation and clarify their possible influence on the ultrasound treatment performance. The results of high temperature and water model experiments reveal that ultrasound irradiation significantly promotes the formation of alumina particles on the melt free surface around sonotrode, and part of these particles can be entrained into aluminum melts. Furthermore, TEM observation results suggested that the entrained alumina inclusions can serve as nucleation sites for the primary Al₃Zr compounds. Most importantly, the oxidation and entrainment of particles from free surface are likely to be controllable by the immersion depth of sonotrode into molten aluminum.     

Pyrophoricity of nano-sized aluminum particles

The temperature histories are calculated for spherical nano-sized aluminum particles with no protective oxide shell inserted in air at 300 K. In calculations, initial particle temperatures varied and the minimum initial temperature leading to the particle ignition was determined. The particle, initially without any oxide coating, was assumed to react adiabatically forming a monomolecular oxide coverage; the following oxidation was assumed to be governed by the Cabrera–Mott reaction mechanism. Convection and radiation heat losses were considered. Convection was accounted for using a transition regime heat transfer model by Fuchs. Aluminum particles with diameters less than about 68 nm are predicted to be pyrophoric, e.g., ignite without appreciable initial pre-heating.     

Observation of resistance oscillations in small-area superconducting aluminum films

In simply-connected, micron-size, aluminum thin-film structures in a perpendicular magnetic field, resistance oscillations with a period close to the quantum of magnetic flux through the area of the structure are observed. The results obtained attest to the fact that when Abrikosov vortices penetrate into a small-area superconducting film (mesoscopic superconducting film), the film behaves similarly to a Little-Parks thin-film interferometer. Pis’ma Zh. éksp. Teor. Fiz. 64, No. 8, 555–558 (25 October 1996)     

Damping of longitudinal plasma oscillations

Attenuation of electron oscillations in a fully ionized plasma is investigated by solving linearized kinetic equation without external fields. The general dispersion relation for longitudinal plasma oscillations is obtained using the BGK model. Damping due to electron ion collisions is obtained with a correction term. It is also observed that damping rate decreases ask increases, which is in agreement with McBride.     

Ionic plasma oscillations in superionic conductors

Some superionic conductors behave as if their charge was carried by nearly free charged particles. If this is the case, these free particles should undergo plasma oscillations. The plasma oscillations may already have been observed in superionic AgI and CuI. Similar oscillations might also be observable in ionic liquids such as melted AgI.