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1.
This work describes the synthesis of GO, rGO and their nanocomposites with PEO. GO and rGO were prepared by the modified Hummers method and in-situ reduction of GO utilizing green reductant L (+) Ascorbic acid. The nanocomposites were characterized by Fourier-transform infrared spectroscopy (FT-IR), X-ray powder diffraction (XRD), Field emission scanning electron microscopy (FE-SEM), Thermogravimetric Analysis (TGA), and Universal Testing Machine (UTM). FT-IR and XRD confirmed the synthesis of GO and rGO. FE-SEM confirmed the uniformly exfoliated GO and rGO nanosheets in the polymer matrix. Hydrogen bonding was the main interaction mechanism for GO with PEO while no interaction was detected by FT-IR for rGO. Enhanced thermal stability was observed for both GO/PEO and rGO/PEO nanocomposites. The mechanical analysis showed an increase in Young's modulus, tensile strength, and elongation at break for GO/PEO nanocomposites, which is attributed to the homogeneous dispersion and hydrophilic hydrogen bonding interaction of GO with PEO. 相似文献
2.
Graphene oxide (GO) and reduced graphene oxide (CRGO), as a graphene derivatives, possess unique properties and a high aspect ratio, indicating great potential in nanocomposite fields. The present work reports the fabrication of the nanocomposite films by a simple and environmentally friendly process using aqueous solution and optimized time sonication for better exfoliation of the graphene sheets within Poly(Vinyl alcohol) (PVA) as matrix. The films were characterized using high-resolution TEM (HRTEM), X-ray diffraction (XRD), Microtensile testing, Differential scanning calorimetry (DSC) and Thermogravimetric analysis (TGA). The TEM images revealed a successfully exfoliation of the GO/CRGO nanosheets. XRD combined with TGA and DSC measurements showed an improvement in the thermal stability and tunable thermal properties. In addition, the Young's modulus and tensile yield strength of the composite films containing 1 wt% GO were obtained to be 4.92 GPa and 66 MPa respectively. These excellent reinforcement effects were achieved by the strong interaction between the components. 相似文献
6.
Graphene and related materials such as carbon nanotubes and graphene oxide are promising materials for future applications in chemical sensing and electronics. Electronic noise in these materials is typically very high due to the low number of carriers and the inverse dependence of 1/ f noise on the number of carriers. We have investigated the changes in 1/ f noise amplitude with temperature in exfoliated graphene and reduced graphene oxide devices. We show that using reduced graphene oxide results in an intriguing environmental coupling to noise amplitude. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
7.
This work presented a hybrid architecture of graphene oxide (GO)/ZnO nanorods (ZNs) with ZNs attached parallel onto GO sheets. ZNs were synthesized by refluxing zinc acetate dehydrate in methanol solution under basic conditions followed by surface modification of 3-aminopropyl triethoxysilane (ATS), and then the preformed ZNs were attached onto GO sheets by reaction of the amino groups on the outer wall of ZNs with the carboxyl groups on the GO surface. Transmission electron microscopy (TEM) image of the as-prepared hybrid reveals the morphology of the architecture of GO/ZNs hybrid. Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA) ultraviolet-visible (UV-vis) and fluorescence spectroscopy were also performed to characterize the structure and properties of the GO/ZNs hybrid. It was shown that ZNs maintained their initial morphology and crystallinity in the hybrid and the luminescence quenching of yellow-green emission of ZNs confirmed the electron transfer from excited ZnO to GO sheets. 相似文献
9.
Graphene oxide (GO), the functionalized graphene with oxygenated groups (mainly epoxy and hydroxyl), has attracted resurgent interests in the past decade owing to its large surface area, superior physical and chemical properties, and easy composition with other materials via surface functional groups. Usually, GO is used as an important raw material for mass production of graphene via reduction. However, under different conditions, the coverage, types, and arrangements of oxygen-containing groups in GO can be varied, which give rise to excellent and controllable physical properties, such as tunable electronic and mechanical properties depending closely on oxidation degree, suppressed thermal conductivity, optical transparency and fluorescence, and nonlinear optical properties. Based on these outstanding properties, many electronic, optical, optoelectronic, and thermoelectric devices with high performance can be achieved on the basis of GO. Here we present a comprehensive review on recent progress of GO, focusing on the atomic structures, fundamental physical properties, and related device applications, including transparent and flexible conductors, field-effect transistors, electrical and optical sensors, fluorescence quenchers, optical limiters and absorbers, surface enhanced Raman scattering detectors, solar cells, light-emitting diodes, and thermal rectifiers. 相似文献
10.
The wide structure and chemical-composition spectrum of the main technological material of molecular graphenics—reduced graphene oxide (RGO)—is explained from a quantum-chemical standpoint. The proposed concept is used to consider the results of experimental investigations of a natural analog of RGO, namely, shungite carbon, by high-resolution electron microscopy and nanopoint energy dispersive spectral analysis. The results obtained are used to propose an atomic-microscopic model for the structure of shungite carbon. 相似文献
11.
Surface adhesion properties are important to various applications of graphene-based materials. Atomic force microscopy is powerful to study the adhesion properties of samples by measuring the forces on the colloidal sphere tip as it approaches and retracts from the surface. In this paper we have measured the adhesion force between the colloid probe and the surface of graphene (graphene oxide) nanosheet. The results revealed that the adhesion force on graphene and graphene oxide surface were 66.3 and 170.6 nN, respectively. It was found the adhesion force was mainly determined by the water meniscus, which was related to the surface contact angle of samples. 相似文献
12.
We report on EPR and NMR study of reduced graphene oxide (RGO) produced by the Hummers method. We show that this RGO sample reveals isolated Mn 2+ ions, which originate from potassium permanganate used in the process of the sample preparation. These ions form paramagnetic charge-transfer complexes with the graphene planes and contribute to the 13C spin–lattice relaxation. 相似文献
13.
In this work, a cost-effective and facile method was adopted for the fabrication of graphene oxide nanoscrolls (GONS) by low frequency (20 kHz) ultrasonication with tunable dimensions. The graphene oxide (GO) was synthesized by modified Hummer’s method using synthetic graphite as a base material. Later, GO suspension (0.05 g L −1) were made using methanol as solvent and subjected to different ultrasonication conditions. It was found that GO sheets curls themselves into nanoscrolls by overcoming the energy barrier for scrolling with the help of bubble cavitation energy provided by ultrasonication. Also, the effect of ultrasonication power (100–150 W) for irradiation time (0.5–3 h) over the GONS dimensions were investigated. The spiral wounded GONS structures were shown using electron microscopy. Raman Spectroscopy, Thin-film X-Ray Diffraction, Energy Dispersive X-Ray, FT Infrared Spectroscopic analysis were also done to endorse GONS formation. Factors affecting GONS formation such as sonication power and solvent selection were studied as scrolling of GO sheets are strongly dependent on sonication parameters and solvent characteristics. It was found that GONS length varies inversely with irradiation time for identical power density. Also, a solvent with relatively large Hansen solubility parameter, lower dipole movement and less negative value of zeta potential support GONS formation of longer length. Raman analysis overlays the rapid oxygen-defect site cleavage mechanism. The obtained GONS unlocks further developments in various engineering applications like adsorption, drug delivery and filtration membrane. 相似文献
14.
Graphene Oxide (GO) sheets, suspended in an aqueous solution, were deposited on freshly cleaved highly oriented pyrolytic graphite (HOPG) and studied using Raman spectroscopy, atomic force microscopy (AFM) and scanning tunneling microscopy (STM). AFM phase imaging shows a distinct contrast between GO and the underlying HOPG substrate. Raman spectroscopy clearly showed the presence of GO sheets on the top of HOPG substrate. The AFM and STM images also reveal wrinkling, folding, and tearing of individual GO sheets after depositing onto an HOPG substrate. We have also observed a distinct cracking of a GO sheet after folding. We attribute this new cracking phenomenon to a weakening of C–C bonds during the oxidation of a graphene sheet. 相似文献
15.
Whilst graphene materials have become increasingly popular in recent years, the followed synthesis strategies face sustainability, environmental and quality challenges. This study proposes an effective, sustainable and scalable ultrasound-assisted mechano-chemical cracking method to produce graphene oxide (GO). A typical energy crop, miscanthus, was used as a carbon precursor and pyrolysed at 1200 °C before subjecting to edge-carboxylation via ball-milling in a CO 2-induced environment. The resultant functionalised biochar was ultrasonically exfoliated in N-Methyl-2-pyrrolidone (NMP) and water to form GOs. The intermediate and end-products were characterised via X-ray diffraction (XRD), Raman, high-resolution transmission electron microscopy (HR-TEM) and atomic force microscopy (AFM) analyses. Results show that the proposed synthesis route can produce good quality and uniform GOs (8–10% monolayer), with up to 96% of GOs having three layers or lesser when NMP is used. Ultrasonication proved to be effective in propagating the self-repulsion of negatively-charged functional groups. Moreover, small amounts of graphene quantum dots were observed, illustrating the potential of producing various graphene materials via a single-step method. Whilst this study has only investigated utilising miscanthus, the current findings are promising and could expand the potential of producing good quality graphene materials from renewable sources via green synthesis routes. 相似文献
16.
The distributions of positive carbon cluster ions produced by laser ablation of graphene (G) and graphene oxide (GO) are found to be quite different. Under a typical experimental condition, narrow distributions of even-numbered clusters from C60+ to C162+ were observed for G, and broad distributions including even-numbered clusters from C100+ to C400+ and odd-numbered clusters from C189+ to C395+ were observed for GO. The threshold of laser energy for G is lower than that of GO. Further results of collision-activated dissociation mass spectrometry indicate that the cluster ions generated from G are structurally similar but are different with those generated from GO or nanodiamonds. It is proposed that the experimentally observed difference can be attributed to the different mechanisms behind the process. A top-down mechanism including both direct transformation of G to fullerene and fragmentation of large-sized fullerenes is suggested for the generation of carbon cluster cations in the process of laser ablation of G. For GO, the experimental results are close to those of nanodiamonds and other materials reported previously and can be explained by the generally accepted bottom-up mechanism. 相似文献
17.
The effects of switching were investigated in composite films based on multifunctional polymers. i.e., derivatives of carbazole (PVK) and fluorene (PFD), as well as based on particles of graphene (Gr) and graphene oxide (GO). The concentration of Gr and GO particles in the PVK(PFD) matrix was varied in the range of 2–3 wt %, which corresponded to the percolation threshold in these systems. The atomic composition of the composite films PVK: GO was examined using X-ray photoelectron spectroscopy. It was found that the effect of switching in structures of the form Al/PVK(PFD): GO(Gr)/ITO/PET manifests itself in a sharp change of the electrical resistance of the composite film from a low-conducting state to a relatively high-conducting state when applying a bias to Al-ITO electrodes of ∼0.1–0.3 V (E ∼ 3–5 × 104 V/cm), which is below the threshold switching voltages for similar composites. The mechanism of resistance switching, which is associated with the processes of capture and accumulation of charge carriers by Gr (GO) particles introduced into the matrices of the high-molecular-weight (PVK) and relatively low-molecular-weight (PFD) polymers, was discussed. 相似文献
18.
A method is proposed to produce large-area single-layer graphene oxide films on the surface of semiconductor silicon wafers by precipitation from aqueous suspensions. Graphene oxide is synthesized from natural crystalline graphite during chemical oxidation and represents a wide-gap insulator. Single-layer graphene with a homogeneous-fragment size up to 50 μm can be formed by the reduction of graphene oxide films, and this size is significantly larger than those achieved to date. 相似文献
19.
本文通过外加电场改变氧化石墨烯团簇分子的共振能量,利用激光激发氧化石墨烯产生的共振荧光特性测量氧化石墨烯在电场作用下的极化动力学特性. 发现存在外加电场使得荧光共振峰的半高全宽趋于饱和的时间特性,而不同的氧化石墨烯团簇分子的荧光共振峰的暂态特性同时反映了电场对氧化石墨烯产生定向极化和变形极化的动力学特性.
关键词:
氧化石墨烯
团簇分子
电场
极化动力学 相似文献
20.
The challenge of creating a graphene spin field effect transistor (spin‐FET) demands a magnetic gate dielectric material whose magnetization can be switched electrically. We have grown films of Cr 2O 3 on top of graphite and graphene by pulsed laser deposition that shows this crucial functionality. We demonstrate that the Cr 2O 3 films are magnetoelectric by poling them in combined electric and magnetic fields and then using magnetic force microscopy to observe spontaneous surface domain structure as a function of poling field. In addition, we show that the electric field created by a conducting AFM tip can be used to write magnetic patterns in the film that demonstrate the kind of continuous magnetoelectric control needed for a prototype spin‐FET. (© 2016 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
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