Special energies and special frequencies

Special frequencies have been asserted to be zeros of the density of frequencies corresponding to a random chain of coupled oscillators. Our investigation includes both this model and the random one-dimensional Schrödinger operator describing an alloy or its discrete analogue. Using the phase method we exactly determine a bilateral Lific asymptotic of the integrated density of statesk(E) at special energiesE _s , which is not only of the classical type exp(–c/|E–E _s |^1/2) but also exp(–c/|E–E _s |) is a typical behaviour. In addition, other asymptotics occur, e.g. |E–E _s | ^c , which show thatk(E) need not bek .     

Realizability of a model in infinite statistics

Following Greenberg and others, we study a space with a collection of operatorsa(k) satisfying the q-mutator relationsa(l)a (k)a(l)= _k,l (corresponding forq=±1 to classical Bose and Fermi statistics). We show that then!×n! matrixA _n (q) representing the scalar products ofn-particle states is positive definite for alln ifq lies between –1 and +1, so that the commutator relations have a Hilbert space representation in this case (this has also been proved by Fivel and by Bozejko and Speicher). We also give an explicit factorization ofA _n (q) as a product of matrices of the form(1–q ^jT)^±1 with 1jn andT a permutation matrix. In particular,A _n (q) is singular if and only ifq ^M=1 for some integerM of the formk ²–k, 2kn.     

Nonradiative excitation energy transport in one-component disordered systems

High-accuracy Monte Carlo simulations of the time-dependent excitation probabilityG ^s (t) and steady-state emission anisotropyr _M /r _0M for one-component three-dimensional systems were performed. It was found that the values ofr _M /r _0M obtained for the averaged orientation factor only slightly overrate those obtained for the real values of the orientation factor _ik ² . This result is essentially different from that previously reported. Simulation results were compared with the probability coursesG ^s (t) andR(t) obtained within the frameworks of diagrammatic and two-particle Huber models, respectively. The results turned out to be in good agreement withR(t) but deviated visibly fromG ^s (t) at long times and/or high concentrations. Emission anisotropy measurements on glycerolic solutions of Na-fluorescein and rhodamine 6G were carried out at different excitation wavelengths. Very good agreement between the experimental data and the theory was found, with _ex0-0 for concentrations not exceeding 3.5·10^–2 and 7.5·10^–3 M in the case of Na-fluorescein and rhodamine 6G, respectively. Up to these concentrations, the solutions investigated can be treated as one-component systems. The discrepancies observed at higher concentrations are caused by the presence of dimers. It was found that for _ex <_0-0 (Stokes excitation) the experimental emission anisotropies are lower than predicted by the theory. However, upon anti-Stokes excitation (_ex>_0-0), they lie higher than the respective theoretical values. Such a dispersive character of the energy migration can be explained qualitatively by the presence of fluorescent centers with 0-0 transitions differing from the mean at _0-0.     

Sensitivity of approximate formulas for determining optical constants of thin films

The sensitivity of approximate formulas for determining the optical constants of thin films using measurement of reflectancesR and transmittancesT at normal incidence have been investigated theoretically. The ranges of refractive indexn, absorption indexk,2nk (=₂) andn ²–k ²(=₁) within relative errors of 5%, 10%, and 20% may be obtained. Selected signs of (₁)⁺ or (₁)^– have been determined. Validity of the condition n₀ A=n _s A has been also evaluated (A=1–R –T andA=1–R–T).     

Projective quantum spaces

Associated to the standard SU _q (n) R-matrices, we introduce quantum spheresS _q ^2n-1 , projective quantum spaces _q ^n-1 , and quantum Grassmann manifoldsG _k( _q ⁿ ). These algebras are shown to be homogeneous spaces of standard quantum groups and are also quantum principle bundles in the sense of T. Brzeziski and S. Majid.     

On the layering transition of an SOS surface interacting with a wall. I. Equilibrium results

We consider the model of a 2D surface above a fixed wall and attracted toward it by means of a positive magnetic fieldh in the solid-on-solid (SOS) approximation when the inverse temperature is very large and the external fieldh is exponentially small in . We improve considerably previous results by Dinaburg and Mazel on the competition between the external field and the entropic repulsion with the wall, leading, in this case, to the phenomenon of layering phase transitions. In particular, we show, using the Pirogov-Sinai scheme as given by Zahradník, that there exists a unique critical valueh _k ^* () in the interval (1/4e ^–4k , 4e ^–4k ) such that, for allh(h _k+1 ^* ,h _k ^* ) and large enough, there exists a unique infinite-volume Gibbs state. The typical configurations are small perturbation of the ground state represented by a surface at heightk+1 above the wall. Moreover, for the same choice of the thermodynamic parameters, the influence of the boundary conditions of the Gibbs measure in a finite cube decays exponentially fast with the distance from the boundary. Whenh=h _k ^* () we prove instead the convergence of the cluster expansion for bothk andk+1 boundary conditions. This fact signals the presence of a phase transition. In the second paper of this series we will consider a Glauber dynamics for the above model and we will study the rate of approach to equilibrium in a large finite cube with arbitrary boundary conditions as a function of the external fieldh. Using the results proven in this paper, we will show that there is a dramatic slowing down in the approach to equilibrium when the magnetic field takes one of the critical values and the boundary conditions are free (absent).     

The Dynamics of Intramolecular Excited State Relaxation of <Emphasis Type="Italic">N</Emphasis>-Anthryl Substituted Pyridinium Cations

N-(1-Anthryl)-2,4,6-trimethyl-pyridinium (I), N-(2-anthryl)-2,4,6-trimethyl-pyridinium (II) and 10-(1-anthryl)-1,2,3,4,5,6,7,8-octahydro-acridinium cations (III) with anomalously high fluorescence Stokes shift have been investigated. Fluorescence kinetics analysis at various temperatures showed that in the range 293–77 K, the radiative deactivation rate constants (k_f) increase by 5.5 to 30 times. The low-temperature time-resolved emission spectra of I–III were found to be consistent with the model: A A^* B^* where A^* is the local excited twisted form and B^* is the relaxed more planar, bent conformer of the molecule. The rate constants of the excited relaxed state formation (k₁) and back reaction (k_–1) of compounds studied were estimated.     

Fluctuations of intensity and arrival angles for light waves in spatially-limited collimated beams in a turbulent atmosphere

This paper presents results of an experimental investigation of fluctuations of intensity and arrival angle as a function of the parameter = ka²/L (where k = 2 /,a is the beam radius, and L is the length of the track) for tracks of different lengths. It is shown that, depending on the value of ₀ ² = 1.23 C _n ² k^7/6 L^11/6, the intensity fluctuations can both increase, and also decrease with increase of . The fluctuations of arrival angle have a maximum for beams for which the parameter 5.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, Vol. 16, No. 9, pp. 108–112, September, 1973.     

On the relative entropy

ForA any subset of () (the bounded operators on a Hilbert space) containing the unit, and and restrictions of states on () toA, ent _A (|)—the entropy of relative to given the information inA—is defined and given an axiomatic characterisation. It is compared with ent _A ^A (|)—the relative entropy introduced by Umegaki and generalised by various authors—which is defined only forA an algebra. It is proved that ent and ent ^S agree on pairs of normal states on an injective von Neumann algebra. It is also proved that ent always has all the most important properties known for ent ^S : monotonicity, concavity,w* upper semicontinuity, etc.     

Energy spectrum and angular distribution of muons from the decay of heavy leptons produced in colliding electron-positron beams

On the basis of an arbitrary (V, A) structure of the neutral weak ¯ee and LL currents (L=^–, M⁰) a study is made of the processes of production in colliding electron-positron beams of pairs of heavy leptons with subsequent decays in accordance with the schemes e⁺e^––(µ^–v_µv) + ⁺( anything) and e⁺e^–M⁰(µ^–e⁺v_e) + M⁰( anything). The energy spectrum and asymmetry of the distribution of the produced muons are investigated.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 66–70, February, 1981.     

Quantum Ergodicity of Boundary Values of Eigenfunctions

Suppose that ⁿ is a bounded, piecewise smooth domain. We prove that the boundary values (Cauchy data) of eigenfunctions of the Laplacian on with various boundary conditions are quantum ergodic if the classical billiard map on the ball bundle B^*() is ergodic. Our proof is based on the classical observation that the boundary values of an interior eigenfunction , =² is an eigenfunction of an operator F_h on the boundary of with h=^–1. In the case of the Neumann boundary condition, F_h is the boundary integral operator induced by the double layer potential. We show that F_h is a semiclassical Fourier integral operator quantizing the billiard map plus a small remainder; the quantum dynamics defined by F_h can be exploited on the boundary much as the quantum dynamics generated by the wave group were exploited in the interior of domains with corners and ergodic billiards in the work of Zelditch-Zworski (1996). Novelties include the facts that F_h is not unitary and (consequently) the boundary values are equidistributed by measures which are not invariant under and which depend on the boundary conditions. Ergodicity of boundary values of eigenfunctions on domains with ergodic billiards was conjectured by S. Ozawa (1993), and was almost simultaneously proved by Gerard-Leichtnam (1993) in the case of convex C^1,1 domains (with continuous tangent planes) and with Dirichlet boundary conditions. Our methods seem to be quite different. Motivation to study piecewise smooth domains comes from the fact that almost all known ergodic domains are of this form.The first author was partially supported by an Australian Research Council Fellowship.The second author was partially supported by NSF grant #DMS-0071358 and DMS-0302518.     

On the shape of wedding cakes

The large-scale morphology of a growing surface is characterized for a simple model of crystal growth in which interlayer transport is completely suppressed due to the Ehrlich-Schwoebel effect. In the limit where the ratio of the surface diffusion coefficient to the deposition rateD/F the surface consists of wedding-cake-like structures whose shape is given by the inverse of an error function. The shape can be viewed as a separable solution of the singular diffusion equationu ₁=[u ^–2 u _x ] _x . As an application, expressions for the number of exposed layers as a function of coverage and diffusion length are derived.     

Combination of temperature-programmed thermal desorption and laser-induced thermal desorption

The combination of temperature-programmed thermal desorption with heating rates of the order of 1 K s^–1 and laser-induced thermal desorption with of the order of 10¹⁰ K s^–1 has proved to be a suitable method to determine both the frequency factor v and the activation energy E _d of desorption. The systems Ni(110)/N₂ and Ni(110)/CO serve as examples.     

Far-infrared laser stark spectroscopy of CH3OH and13CH3OH

The high resolution laser Stark spectra of methanol and¹³C-substituted methanol have been studied up to Stark fields of about 60 000V/cm with the HCN and DCN lasers. Numerous families of absorption lines have been observed in both parallel and perpendicular polarizations. For methanol, the transitions J _k =7₅ 6₄ A, _t=0; J _k =11₄ 10₃ E _l , _t=0; and J _k =17₃ 16₂ E₂, _t=0 have been identified while the assignments for¹³C-substituted methanol are J _k =14₈ 15₇ A, _t=0; J _k =15₃ 14₂ A⁺, _t=0; J _k =10₇ 9₆ A, _t=0; and J _k =27₉ 27₈ E₁, _t=0. Zero-field frequencies for the assigned transitions are given with improved accuracy over those calculated from available molecular constants, especially for¹³CH₃OH.     

Gelation and Cluster Growth with Cluster-Wall Interactions

Metallic cluster growth within a reactive polymer matrix is modeled by augmenting coagulation equations to include the influence of side reactions of metal atoms with the polymer matrix: where > 0 and where c _k denotes the concentration of the kth cluster and p denotes the concentration of reactive sites available within the polymer matrix for reaction with metallic atoms. The initial conditions are required to be non-negative and satisfy and p(0) = p ₀. We assume that for 01, which encompasses both bond linking kernels (R _jk = j k ) and surface reaction kernels (R _jk = j + k ). Our analytical and numerical results indicate that the side reactions delay gelation in some cases and inhibit gelation in others. We provide numerical evidence that gelation occurs for the classical coagulation equations ( = 0) with the bond linking kernel (d ) for 1/2<1. We examine the relative fraction of metal atoms, which coagulate compared to those which interact with the polymer matrix, and demonstrate in particular a linear dependence on ^–1 in the limiting case R _{= jk} , p ₀=1.     

EPR and Thermoluminescence in ZnO Single Crystals with Anionic Vacancies

The radiation defects created in hydrothermal ZnO–Li single crystals by irradiating them with electrons, protons, and highenergy ions have been investigated. The anionic vacancies (Fcenters) in ZnO are established to be the centers of radiationless recombination of the charge carriers with a photoionization energy of 2.3 eV (a signal of the photoEPR with the gfactor for the F⁺center: g = 1.9948 and g = 1.9963). The anionic vacancies in the form of the F and F⁺ states are a good reference of the electron and hole processes. The [F_Li]^×centers that correspond to the oxygen vacancies localized near the point defects Li_Zn are detected. In the temperature range 530–660 K, ZnO crystals display thermally stimulated processes such as the healing of anionic vacancies (530–630 K) and the disappearance of the [F_Li]^×centers (610–660 K).     

Ballistic annihilation and deterministic surface growth

A model of deterministic surface growth studied by Krug and Spohn, a model of the annihilating reactionA+Binert studied by Elskens and Frisch, a one-dimensional three-color cyclic cellular automaton studied by Fisch, and a particular automaton that has the number 184 in the classification of Wolfram can be studied via a cellular automaton with stochastic initial data called ballistic annihilation. This automaton is defined by the following rules: At timet=0, one particle is put at each integer point of . To each particle, a velocity is assigned in such a way that it may be either +1 or –1 with probabilities 1/2, independent of the velocities of the other particles. As time goes on, each particle moves along at the velocity assigned to it and annihilates when it collides with another particle. In the present paper we compute the distribution of this automaton for each timet . We then use this result to obtain the hydrodynamic limit for the surface profile from the model of deterministic surface growth mentioned above. We also show the relation of this limit process to the process which we call moving local minimum of Brownian motion. The latter is the processB _x ^min ,x , defined byB _x ^min min{B _y ;x–1yx+1} for everyx , whereB _x ,x , is the standard Brownian motion withB ₀=0.     

Instability in degenerate two-photon running wave laser

The stability of the homogeneously broadened and degenerate two-photon running wave laser is analysed by using the full set of matter-field equations. The stability depends on the relative size of the relaxation constants. For 2k>1+r(k=/,r=/; is the cavity loss of the field and , are the longitudinal and transversal decay constants, respectively) no stable lasing state exists. Forr<k<(1+r)/2 an instability occurs. With the decrease in pumping the stable lasing state loses its stability due to Hopf-bifurcation.     

Photoinduced Electron Transfer From Carbazole to Halomethanes in a Gas Phase

Intermolecular photoinduced electron transfer (PET) in a gas phase was studied using carbazole vapor fluorescence quenching by halomethanes (CHCl₃, CH₂Br₂, CCl₄, CHBr₃). The fluorescence quenching rate constants k _q changing from 2.3·10⁵ sec^–1·torr^–1 in mixtures with CHCl₃ to 4.6·10⁶ sec^–1·torr^–1 in mixtures with CHBr₃ at a constant temperature of 403 K were estimated. The dependence of the carbazole fluorescence decay rates in the presence of halomethanes on the free energy change G during transfer of the electron from carbazole to halomethanes is considered. It is suggested to take into account the influence of the vibrational energy of the carbazole molecule E _vib and its temperature changes in estimation of the G values. The differences between PET in the gas and liquid phases were analyzed. It is found that for mixtures with CCl₄ and CHBr₃ the negative temperature dependence of k _q is observed, when the decay rates and efficiencies of the intermolecular PET decreased with temperature increase in the range 403–573 K, i.e. these mixtures the electron transfer is not a barrier-restricted process.     

Image-potential surface states on Ag(100): A reinvestigation

Employing inverse photoemission we have remeasured the energy dispersionE(k) of the lowest-lying image state on Ag(100) with improved energy resolution (electrons and photons, E=0.35 eV) andk-resolution (k<0.1 Å^–1). In a least-square fit with the binding energyE _B atk=0 and the effective massm ^* as parameters we obtainE _B =E _vac –0.67 eV andm ^*=1.5 m in agreement with our earlier findings but differing from the two-photon photoemission values (0.53 eV and 1.15 m).