共查询到20条相似文献,搜索用时 31 毫秒
1.
A. I. Burkhanov Yu. V. Kochergin K. Bormanis A. Kalvane 《Bulletin of the Russian Academy of Sciences: Physics》2010,74(9):1264-1266
The dielectric nonlinearity in BaBi2Nb2O9 and SrBi2Ta2O9 layered ceramics was studied by measuring their polarization loops and reverse dependences of permittivity. It was shown
that the features of the dielectric response of BaBi2Nb2O9 and SrBi2Ta2O9 in strong fields can be explained by glass-like properties and the contribution of the domain structure of the ferroelectric
material to repolarization processes, respectively. 相似文献
2.
Anton A. Kohutych Ruslan M. Yevych Sergij I. Perechinskii Yulian M. Vysochanskii 《Central European Journal of Physics》2010,8(6):905-914
The temperature and frequency dependencies of sound attenuation for the proper uniaxial ferroelectric Sn2P2S6, which has a strong nonlinear interaction of the polar soft optic and fully symmetrical optic modes that is related to the
triple well potential, were studied by Brillouin spectroscopy. It was found that the sound velocity anomaly is described in
the Landau-Khalatnikov approximation with one relaxation time. For explanation of the observed temperature and frequency dependencies
of the sound attenuation in the ferroelectrric phase, the accounting of several relaxation times is needed and, for quantitative
calculations, the mode Gruneisen coefficients are more appropriate as interacting parameters than are the electrostrictive
coefficients. Relaxational sound attenuation by domain walls also appears in the ferroelectric phase of Sn2P2S6 crystals. 相似文献
3.
L. N. Korotkov T. N. Korotkova R. R. Levitskii S. I. Sorokov A. S. Vdovych 《Bulletin of the Russian Academy of Sciences: Physics》2011,75(10):1331-1334
The time dependences of polarization of K0.88(NH4)0.12H2PO4 mixed crystal have been studied within the temperature range of 74–100 K. Two mechanisms of polarization relaxation were
found. The first mechanism is caused by domain walls lateral motion and their interaction with point lattice defects. The
second one supposedly is due to polar regions infiltration through the regions of frustrated paraelectric phase. 相似文献
4.
T. V. Sviridova L. Yu. Sadovskaya A. I. Kokorin E. A. Konstantinova V. E. Agabekov D. V. Sviridov 《Russian Journal of Physical Chemistry B, Focus on Physics》2017,11(2):348-353
The thin-film photocatalysts TiO2/MoO3 and TiO2/MoO3:V2O5 obtained by a combination of sol–gel and sintering techniques were studied using the photooxidation of probing dyes, EPR spectroscopy, X-ray diffraction analysis, and electron microscopy. It was shown that due to charge accumulation caused by UV irradiation, these photocatalysts retain their oxidative activity and ability for self-sterilization in the dark for a long time after irradiation was terminated (up to 5 h for TiO2/MoO3:V2O5). 相似文献
5.
Thin films of Sb2Te3 and (Sb2Te3)70(Bi2Te3)30 alloy and have been deposited on precleaned glass substrate by thermal evaporation technique in a vacuum of 2?×?10?6 Torr. The structural study was carried out by X-ray diffractometer, which shows that the films are polycrystalline in nature. The grain size, microstrain and dislocation density were determined. The Seebeck coefficient was determined as the ratio of the potential difference across the films to the temperature difference. The power factor for the (Sb2Te3)70 (Bi2Te3)30 and (Sb2Te3) is found to be 19.602 and 1.066 of the film of thickness 1,500 Å, respectively. The Van der-Pauw technique was used to measure the Hall coefficient at room temperature. The carrier concentration was calculated and the results were discussed. 相似文献
6.
L. T. Denisova L. A. Irtyugo V. V. Beletskii V. M. Denisov 《Physics of the Solid State》2016,58(7):1300-1303
Oxide compounds Pr2Sn2O7 and Nd2Sn2O7 have been obtained by solid-phase synthesis. The effect of temperature on the heat capacity of Pr2Sn2O7 (360–1045 K) and Nd2Sn2O7 (360–1030 K) has been studied using differential scanning calorimetry. The thermodynamic properties of the compounds (changes in enthalpy, entropy, and the reduced Gibbs energy) have been calculated by the experimental data of Cp = f(T). 相似文献
7.
S. F. Dubinin V. E. Arkhipov S. G. Teploukhov V. D. Parkhomenko Ya. M. Mukovskii É. A. Neifel’d 《Physics of the Solid State》2005,47(2):267-271
Charge ordering in a layered manganite La1.2Sr1.8Mn2O7 crystal with structural domains was studied using neutron diffraction in the temperature range 175–700 K. The wave vector of the charge ordering in the crystal is found to be q ? {0.2, 0, 0}2π/a. It is argued that the actual domain structure of the anisotropic crystal affects its charge-ordering state. 相似文献
8.
Two sets of samples of SnO2/In2O3/TiO2 system have been fabricated with different concentrations of component materials. In the first set TiO2 with rutile structure was used, while in the second set it has the structure of anatase. Thin films (up to 50 nm) of obtained
mixtures were deposited. Their sensitivity and selectivity with respect to methane (CH4) were studied. Nanostructure on the
basis of 70%SnO2 — 10%In2O3 — 20%TiO2(anatase) exhibits sufficient sensitivity to methane. 相似文献
9.
The results of ab initio FLAPW-GGA computations of the band structure of two new layered low-temperature superconductors BaRh2P2 and BaIr2P2 (with a ThCr2Si2 tetragonal structure) are presented. As distinct from the family of the isostructural FeAs superconductors, they feature the complete replacement of the magnetic (Fe) metal by the nonmagnetic 4d (Rh) and 5d (Ir) metals. For BaRh2P2 and BaIr2P2, the energy bands, the distributions of the densities of electronic states, the Fermi surface topology, and the coefficients of the low-temperature electron specific heat and the molar Pauli paramagnetic susceptibility have been determined. An increase in T C in the BaRh2P2 (1 K) → BaIr2P2 (2.1 K) transition can assumingly be attributed to the features of their phonon subsystem. 相似文献
10.
This paper reports on the results of the ab initio FLAPW-GGA band structure calculations for two new layered phases SrRu2As2 and BaRu2As2, which are isostructural and isoelectronic to the known tetragonal (Ca,Sr,Ba)Fe2As2 basis phases of the FeAs superconductor family. The energy bands, densities of states, topology of the Fermi surface, low-temperature
electron specific heats, and molar Pauli paramagnetic susceptibilities of SrRu2As2 and BaRu2As2 are determined for the first time and discussed in comparison with those for BaFe2As2 and BaRh2As2. 相似文献
11.
G. A. Komandin A. S. Prokhorov V. I. Torgashev E. S. Zhukova B. P. Gorshunov A. A. Bush 《Physics of the Solid State》2011,53(4):736-744
The spectra of complex permittivity of a Ba2Mg2Fe12O22 single crystal belonging to the family of Y-type hexaferrites have been measured over a wide temperature range (10–300 K) with the aim of determining the dynamic parameters
of the phonon and magnetic subsystems in the terahertz and infrared frequency ranges (3–4500 cm−1). A factor-group analysis of the vibrational modes has been performed, and the results obtained have been compared with the
experimentally observed resonances. The oscillator parameters of all nineteen phonon modes of E
u
symmetry, which are allowed by the symmetry of the Ba2Mg2Fe12O22 crystal lattice, have been calculated. It has been found that, at temperatures below 195 and 50 K, the spectral response
exhibits new absorption lines due to magnetic excitations. 相似文献
12.
V. G. Zalesskii A. D. Polushina E. D. Obozova A. V. Dmitriev P. P. Syrnikov S. G. Lushnikov 《JETP Letters》2017,105(3):189-194
The dielectric response, conductivity, and domain structure of (Na1/2Bi1/2)TiO3 single crystals are studied in the temperature range of 290–750 K for the [100], [110], and [111] crystallographic directions. It is shown that the region of optical isotropization is observed in polarized light in the temperature range of 570–620 K. In this case, the birefringence (Δn) decreases and disappears (together with the image of the domain structure) for the [100] directions. The region of optical isotropization in the [111] directions is characterized by the disappearance of the image of the domain structure and by the existence of individual regions with partial quenching. The domain structure in the [110] directions remains distinguished against the background of a significant decrease in Δn in the indicated temperature range. The region of isotropization is also manifested in the temperature dependence of the imaginary part of the dielectric response and is determined by the isotropic character of the conductivity in the range of 570–620 K. The bulk conductivity has a thermally activated character with activation energies E a = 50?60 meV at T < 500 K and E a = 700?900 meV for T > 620 K. The low-frequency dispersion of the dielectric response is determined by the Maxwell–Wagner mechanism and is due to an increase in the ionic conductivity at temperatures above 620 K. The anisotropy of the susceptibility holds in the entire studied ranges of frequencies (25 Hz–1 MHz) and temperatures. 相似文献
13.
R. B. Morgunov E. V. Kurganova S. M. Aldoshin N. A. Sanina T. N. Rudneva 《Physics of the Solid State》2007,49(9):1723-1730
The magnetic properties of the binuclear nitrosyl-iron complexes Fe2(SC3H5N2)2(NO)4 are investigated. It is demonstrated that several types of particles, such as dimers with a pair of spins 1/2, dimers with a pair of spins 5/2, and paramagnetic particles with spin 3/2, make a contribution to the magnetic properties of the complexes. A decrease in the temperature below 25 K leads to a change in the shape of the EPR spectra corresponding to these dimers, so that Lorentzian lines (homogeneous broadening) transform into Gaussian lines (inhomogeneous broadening). This is accompanied by a stepwise change in the EPR line width and g factors. The change in the line shape indicates that complexes become asymmetric at low temperatures, possibly, due to the decrease in the spin exchange frequency below the frequency of the microwave field of the spectrometer. 相似文献
14.
N. S. Saetova A. A. Raskovalov B. D. Antonov T. V. Yaroslavtseva O. G. Reznitskikh E. V. Zabolotskaya N. I. Kadyrova A. A. Telyatnikova 《Ionics》2018,24(7):1929-1938
Lithium vanadium-borate glasses with the composition of 0.3Li2O–(0.7-x)B2O3–xV2O5 (x?=?0.3, 0.325, 0.35, 0.375, 0.4, 0.425, 0.45, and 0.475) were prepared by melt-quenching method. According to differential scanning calorimetry data, vanadium oxide acts as both glass former and glass modifier, since the thermal stability of glasses decreases with an increase in V2O5 concentration. Fourier transform infrared spectroscopy data show that the vibrations of [VO4] structural units occur at V2O5 concentration of 45 mol%. It is established that the concentration of V4+ ions increases exponentially with the growth of vanadium oxide concentration. Direct and alternative current measurements are carried out to estimate the contribution both electronic and ionic conductivities to the value of total conductivity. It is shown that the electronic conductivity is predominant in the total one. The glass having the composition of 0.3Li2O-0.275B2O3-0.475V2O5 shows the highest electrical conductivity that has the value of 7.4?×?10?5 S cm?1 at room temperature. 相似文献
15.
V. Yu. Ivanov V. A. Pustovarov E. S. Shlygin A. V. Korotaev A. V. Kruzhalov 《Physics of the Solid State》2005,47(3):466-473
Low-temperature (T = 7 K) time-resolved selectively photoexcited luminescence spectra (2–6 eV) and luminescence excitation spectra (8–35 eV) of wide-bandgap chrysoberyl BeAl2O4, phenacite Be2SiO4, and beryl Be3Al2Si6O18 crystals have been studied using time-resolved VUV spectroscopy. Both the intrinsic luminescence of the crystals and the luminescence associated with structural defects were assigned. Energy transfer to impurity luminescence centers in alexandrite and emerald was investigated. Luminescence characteristics of stable crystal lattice defects were probed by 3.6-MeV accelerated helium ion beams. 相似文献
16.
A. A. Gippius A. S. Moskvin E. N. Morozova K. S. Okhotnikov 《Journal of Experimental and Theoretical Physics》2007,105(1):86-89
The results of the measurements of the 6, 7Li and 23Na nuclear magnetic resonance (NMR) and 63, 65Cu nuclear quadrupole resonance in LiCu2O2 and NaCu2O2 quasi-one-dimensional compounds with a spin chains in the paramagnetic and magnetically ordered states are presented. The shape of the NMR line below T c = 24 and 13 K for LiCu2O2 and NaCu2O2, respectively, is characteristic of the incommensurate static modulation of the local magnetic field matching with the incommensurate spiral modulation of the magnetic moments. The differences in the shape of the NMR spectra of 23Na and 7Li are discussed in terms of the features of the crystal structure of LiCu2O2 and NaCu2O2. 相似文献
17.
The structure of domain walls and new-phase nucleation are investigated in a four-sublattice antiferromagnet (AFM) of the La2CuO4 type placed in a magnetic field which initiates an AFM-weak-ferromagnet (WFM) magnetic structural phase transition. The critical fields for nucleus growth are found in the case of two types of domain walls present. The magnetization curve is calculated and a two-step mechanism is proposed for the AFM-WFM phase transition observed in La2CuO4. 相似文献
18.
Weak-ferromagnetic (or antiferromagnetic) resonance of Cu and electron spin resonance (ESR) of Gd are observed both in insulating GdSr2Cu2NbO8 and in superconducting GdSr2Cu2RuO8. The Cu resonance implies that the CuO2 planes are magnetic and indicates that the superconducting layer of GdSr2Cu2RuO8 is SrO (not CuO2), as in its related superconducting compound without cuprate planes, doped Sr2YRuO6. 相似文献
19.
S. A. Gridnev A. A. Kamynin A. S. Shportenko P. V. Kulakov M. V. Hahlenkov D. P. Kozlenko B. N. Savenko S. E. Kichanov E. V. Lukin 《Bulletin of the Russian Academy of Sciences: Physics》2016,80(9):1092-1096
Dielectric properties of 0.85BiFeO3–0.15MgFe2O4 composite fabricated with conventional ceramic technology are studied in the temperature interval of 20–250°C at frequencies of 25 Hz to 1 MHz. Dielectric relaxation is observed, the nature of which is discussed in the context of a mechanism of interaction between ferroelectric domain boundaries and point defects. 相似文献
20.
Photoacoustic spectroscopy (PAS) is one of the important branches of spectroscopy, which enables one to detect light-induced
heat production following the absorption of pulsed radiation by the sample. As2S3, As2Se3 and GeSe2 exhibit a wide variety of photo-induced phenomena that enable them to be used as optical imaging or storage medium and various
electronic devices, including electro-optic information storage devices and optical mass memories. Therefore, accurate measurement
of thermal properties of semiconducting films is necessary to study the memory density. The thermal conductivity of thin films
of As2S3 (thickness 100 μm and 80 μm), As2Se3 (thickness 100 μm and 80 μm) and GeSe2 (thickness 120 μm and 100 μm) has been measured using PAS technique. Our result shows that the thermal conductivity of thicker films is larger than the
thinner films. This can be explained by the thermal resistance effect between the film and the surface of the substrate.
相似文献