Direct observation of the differences between Raman scatering and population inversion transition for their emission frequencies and pulse waveforms

In FIR laser emissions optically by a CO₂ laser, it has been reported that there are two different process namely induced Raman scattering and population inversion transition.In this paper, we show that the two different process have clearly different characteristics in emission frequensies and pulse waveforms in the case of a TEA-CO₂ laser excitation.We used in this work an intra-cavity etalon for the study of the emission frequensies and also we used a MOM point contact diode for the detection of the wavaformes.Especially, we show that the FIR pulse waveformes are able to analyze numerically on the concept of rate equations.In conclusion, we indicate that molecules would be classified into two categories with regard to optically pumping by a TEA-CO₂ laser. One of them produce mainly Raman scattered emissions, and other produce only the FIR emissions from population inversion transition in spite of high power intensity excitation.     

The effect of mid-infrared and far-infrared emission,generated at NH3 excitation by intense radiation of a TEA CO2 laser,on ammonia absorption

The effect of Mid-InfraRed (MIR) ( 12 m) and Far-InfraRed (FIR) ( 100 m) emission from excited ammonia on the absorption of intense radiation of a TEA CO₂ laser has been studied experimentally under collisional and collisionless excitation conditions with ammonia pressures from 0.5 to 0.03 Torr. The energy of MIR and FIR emission was studied as a function of NH₃ pressure and laser energy fluence. Particular emphasis was given to the kinetics of MIR and FIR emission generation at different NH₃ pressures and to the measurement of the time delay of re-emitted pulses relative to the exciting CO₂ laser pulse. It has been found that the re-emission in the MIR range is highly collisional in nature. The intensity of MIR emission drops sharply (asp ³) with decreasing NH₃ pressure and its delay time relative to the exciting laser pulse increases. At the same time, re-emission in the FIR range (in the case of resonant excitation of NH3 at the 9R (30) line of CO₂ laser) is observed during an exciting pulse up top < 0.03 Torr. When binding the rotational sub-levels of a molecule with transitions, FIR emission acts as rotational relaxation and thus leads to an increase in NH₃ IR absorption even at collisionless excitation.     

An argon ion ring laser as a gyroscope

As a prototype gyroscope for a precision measurement of the Earth's rotation _E, we set up an argon ion ring laser with an area of 1.4 m². Different cavity geometries were tested in order to achieve a cancellation of the effect of the plasma flow. In a set-up with two laser tubes of the same type facing towards opposite directions, a stability of the beat frequency of 2–3 _E was measured. In a configuration with a double transition of the laser beam through the tube, the lock-in threshold was too high for the Earth's rotation to be measured, however, no effect of the plasma flow was observed.     

Effects of Buffer Gas N2 on Miniature Optically Pumped NH3 Submillimeter Wave Cavity Laser Emission at 67.2 μm

The effect of buffer gas N₂ on miniature optically pumped NH₃ submillimeter wave (SMMW) cavity laser emission at 67.2m was studied theoretically and experimentally. It has been found that: 1. N₂ had a positive effect on laser output of 67.2m, 2. sharp absorption in laser spectrum under certain gases mixture pressure corresponded to the threshold of 'bottleneck effect.     

New far infrared laser lines from 13CH2F2 and frequency measurements

We report new FIR laser lines from ¹³CH₂F₂ molecules optically pumped by a waveguide CO₂ laser. The increased tunability (300 MHz) with respect to a conventional CO₂ laser allows the pumping of ¹³CH₂F₂ vibrational transitions of large offset. 34 new laser lines have been discovered, ranging from 113.1 m to 491.4 m in wavelength, thus increasing the number of known FIR laser lines from this important molecule to 99. For all the new lines and many (36) of those known previously, precise offset measurements through the transferred Lamb-dip technique were performed. The frequency of six new laser lines was also directly measured by heterodyne detection with known laser lines.     

Tunable CW laser oscillation of NdP5O14 at 1.3 μm

Low-threshold tunable cw laser oscillation is achieved at the⁴ F _3/2⁴ I _13/2 transition of NdP₅O₁₄. Continuous tunign over 1.8% of the central wavelenght is possible with 55 mW of absorbed pump power. At gain line maximum near 1.32 , the output power exceeded 1 mW. Pump threshold as low as 8 mW was observed. Reliable cw operation of the 1.3 m NdP₅O₁₄ laser pumped by a 15 mW AlGaAs laser diode is demonstrated.     

Nonlinear properties of the laser as an amplifier

Summary The paper presents the results of a theoretical analysis of an optical traveling-wave amplifier, to whose input are applied monochromatic pulses of frequency equal to the transition frequency. At distances zp(c/2) |2N₂–N₁|/ /(N₁–N₂) where p>1, and for <2₀aN₁ all input pulses assume the form of a stationary pulse (see Eq. (33)). The stationary signal intensity, duration and total energy are substantially dependent on the nonresonant loss in the medium, the relaxation time T₂ and the initial inversion population difference N₁. For loss values >2₀aN₁ the input pulses are attenuated.In the amplifier model considered we have assumed the laser medium to have a uniformly broadened line. This enables us to apply the results of the investigation to a ruby laser which satisfies this condition (by excluding low temperatures).The neglect of pumping and the lifetime T₁ is permissible for values of not too close to 2₀aN₁.Izvestiya VUZ. Radiofizika, Vol. 8, No. 5, pp. 899–908, 1965     

GeO2-Core/SiO2-cladding optical fibers made by MCVD process for stimulated raman applications

GeO₂-core/SiO₂-cladding optical fibers (GESI fibers) and liquid core fibers with a cladding region of GeO₂ were designed and fabricated by the MCVD process. The attenuation level of the GESI fibers was about 0.5 dB/m in the near-infrared wavelength region at 2.35 m. GESI fibers showed a stimulated Raman scattering (SRS_ spectrum with six to seven Stokes shifts of 430 cm^–1. The spectrum of SRS expanded to 1.6 m when a Nd: YAG laser at a wavelength of 1.064 m was used.     

Two color oscillations of TE-CO2 laser and applications to two photon process of optically pumped FIR laser

We have developed the resonance system which is able to operate a TE-CO₂ discharge tube in two color emission source. The two color source is excellent in pumping efficiency, spacial overlap and time synchronization of the two emission CO₂ lines.We indicate that the competitive operation of the two emissions is well explained by a simple model.When a TE-CO₂ laser operates at the total pressure of below half atmospheric pressure, we make clear in this work that the operation of a TE-CO₂ laser forms depression like hole burning, with regards to the J of the upper laser level by J-J collisional relaxation during the laser emission.As an example of the two-photon source, two-photon pumping of NH₃ and FIR emissions are given in this paper.     

Degradation in gain for a free electron laser amplifier due to electron momentum spread

A finite spread in axial momentum for the electron beam in a free electron laser amplifier is shown to decrease the small-signal gain. For millimeter and sub-millimeter wave amplifiers, where exponential growth dominates the gain, it is shown that the gain is approximately 3 db below that for a cold beam if the relative momentum spread (u/u)_1/2 = (G_o/248)^1/2 (_o/L), where G_o1 is the gain in db for the cold-beam case, _o is the magnetic wiggler period, and L is the amplifier length. Exact numerical examples are given for representative FEL amplifiers at 35 and 550 GHz.This research was sponsored by the U.S. Office of Naval Research, and by the U.S.-Israel Binational Science Foundation.     

Femtosecond-pulse laser ablation of human corneas

A femtosecond pulse laser in the visible spectral region shows promise as a potentially new powerful corneal sculpting tool. It combines the clinical and technical advantages of visible wavelengths with the high ablation quality observed with nanosecond-pulse excimer lasers at 193 nm. A femtosecond and a nanosecond dye laser with pulse durations of 300 fs and 7 ns, and centre wavelengths at 615 nm and 600 nm, respectively, both focused to an area of the order of 10^–5 cm², have been applied to human corneal ablation. Nanosecond laser pulses caused substantial tissue disruption within a 30–100 m range from the excision edge at all fluences above the ablation threshold of F _th60 J cm^–2 (I _th9 GW cm^–2). Completely different excisions are produced by the femtosecond-pulse laser: high quality ablations of the Bowman membrane and the stroma tissue characterised by damage zones of less than 0.5 m were observed at all fluences above ablation threshold of F _th1 J cm^–2 or I _th3 TW cm^–2 (3×10¹² W cm^–2). The transparent cornea material can be forced to absorb ultrashort pulses of extremely high intensity. The fs laser generates its own absorption by a multiphoton absorption process.     

Computer controlled diode laser spectrometer with a helium evaporation cryostat and spectroscopy of thev 3 vibration of NCO

A computer-controlled diode laser spectrometer for the 1200 to 2500 cm^–1 spectral region is described. The spectrometer has been applied to high resolution spectroscopy of the NCO radical at 5.2 m. The lead-salt diode lasers are cooled to their operating temperature with a temperature adjustable helium evaporation cryostat. Computer-controlled tuning procedures for the frequency tuning of the diode lasers have been developed; they are independent of tables describing the tuning characteristics of the diode lasers. 41 lines of the antisymmetric stretching-vibrationv ₃ of the linear NCO radical have been observed. We were able to detect vibration-rotation transitions in both² _1/2 and² _3/2 fine structure sublevels. These measurements led to the precise determination of additional molecular constants.     

High power single-longitudinal-mode operation in a twisted-mode-cavity laser with a c-cut Nd:GdVO4 crystal

A twisted-mode-cavity laser was established by using a piece of c-cut Nd:GdVO₄ crystal as the lasers active material. Output spectra were scanned by a scanning Fabry–Perot interferometer, which demonstrated that the single-longitudinal-mode laser operation was realized in the twisted-mode-cavity laser configuration. A maximum single-longitudinal-mode laser output power of 2.1 W was obtained when the pump power was 11.5 W. The pump slope efficiency was about 20.0%. A passively Q-switched single-longitudinal-mode laser was also achieved in a twisted-mode cavity by inserting a piece of Cr⁴⁺:YAG as an intracavity saturable absorber. The Q-switched single-longitudinal-mode laser pulse duration was measured to be 100 ns and the single-pulse energy was about 40.0 J.     

Laser stark spectroscopy ofSO2 with the HCN laser

The Far Infrared (FIR) laser Stark spectrum ofSO ₂ was investigated using the 337 m line of the HCN laser. Two distinct families, one originating at low field and the other at high field, were observed. The high field transition is identified as theJ _K–1,K+1=22_5,1721_4,18, v₂=1 transition. A significant fourth-order Stark shift was observed for this transition in the presence of a large second-order Stark shift. The zero-field frequency of the assigned transition was obtained by accounting for the fourth-order contribution.Present Adress: Department of Chemistry, University of Rochester, Rochester, NY 14627.     

Mosaic Structure of (001)YBa2Cu3O7-δ/(10.2)Al2O3 Epitaxial Films and Millimeter Waveband Properties of Microstrip Resonators

The c-axis single-phase YBa₂Cu₃O_7- films ( = 0-0.15) on sapphire substrates prepared by the laser ablation technique and the band-pass stripline resonators for 34 GHz-range have been investigated. Increasing disorientation of mosaic block structure of YBa₂Cu₃O_7- films is related to increasing surface resistance R_s at 135 GHz-range and decreasing unloaded quality factor Q_o of linear stripline resonators. The linear dependence between the YBa₂Cu₃O_7- film mosaicity (M) and half-width B₁ of 00.13 reflecting component is determined. The reflection spreading is due to microstrains resulted mainly from the coherent adjustment of the YBa₂Cu₃O_7- film lattice to GdBa₂Cu₃O_7- sub-layer and sapphire substrate. Increasing number of the block characterized by a weak radial lattice adjustment () is demonstrated by spreading of 00.13 reflection. It is found out that depends on the Bragg angle of reflection due to inhomogenity of YBa₂Cu₃O_7- mosaic structure, which resulted from the gradual mosaicity decreasing with the depth.     

Four-wave mixing in alkali halide crystals and aqueous solutions

Noncollinear phase-matched nonresonant four-photon frequency mixing _p+ _p– _{L s} in crystals and aqueous solutions of LiCl, CsCl, KF, and KI is studied. The concentration of the aqueous solutions is varied between 0.5 mol/l and saturation. Picosecond laser pulses of a mode-locked Nd-glass laser are applied as pump pulses. The energy conversion of laser light at frequency _L to frequency _S is measured and the nonlinear susceptibilities ⁽³⁾ are calculated. The dependence of the hyperpolarizabilities on concentration is analysed and gives information on the solute-solvent interaction.     

Absolute frequency measurement of acetylene transitions in the region of 1540 nm

An optical frequency comb has been used to measure the frequency of a diode laser system, locked to the P(10), P(11), P(15), P(16), P(20), and P(21) transitions in the ₁+₃ overtone band of ¹³C₂H₂. When locked to any of these transitions, the laser frequency showed a stability of 4×10^-12 in 1 s and a reproducibility of better than 1 kHz. The frequency of the reference P(16) transition was found to be P(16)=194369569383.83 kHz with an uncertainty of 0.32 kHz, based on measurements of a single system, and 2.5 kHz, based on the reproducibility of independent systems. PACS 06.30.Ft; 33.20Ea; 42.62.Fi     

Resonant coherent transients in a gas in the standing-wave field

Polarization decay in the presence of a standing electromagnetic wave field at a Doppler broadened transition is investigated theoretically and experimentally. It is shown that in the direction opposite to the propagation of an excited pulse the polarization decays at a transition frequency rather than at an exciting field frequency as usual. This permits the use of transients both in studies of relaxation processes and in Doppler-free super-high resolution spectroscopy. A resonant coherent transient has been used in measurements of relaxation decay constants of a dipole moment for collisions in SF₆ (=10.6m). This method has enabled one to resolve reliably the structure of theQ(38) transition (=10.6m) of theF ₁ ⁰ +E ₀=F ₂ ⁰ line of the 0v ₃ band in SF₆ within a Doppler absorption line.     

Spectroscopic study of a TEA CO2 laser of the CO2/X,X=H2; N2/H2 type

The spectral output of a TEA CO₂ laser utilizing nonconventional CO₂/H₂ and CO₂/N₂/H₂ gas mixtures was analysed. A simultaneous multiline output in P-branch of the 00°110°0 transition was recorded. A domination of the P(18) line is typical for the first, and that of the P(20) line for the second gas mixture. The enhancement of the P(18) line intensity in spectra (different from P(20) line domination-CO₂/N₂/H₂ mixture) is explained primarily by a smaller contribution of the R(23) line gain (01¹111¹0 CO₂ band), to P(20) line (00°110°0 band). All measurements were conducted with a nondispersive optical cavity.