Equation of solvated ion oscillations in solution under an external periodic electric field

An equation describing ion oscillations with respect to solvent molecules is derived as a result of the consideration of the interaction of an external electric field with free and bound charges in the volume of a salt solution in a polar dielectric liquid. An analysis of the equation shows that the ion motion represents a drift toward one of the electrodes forming the field in the electroinsulated solution volume if amplitudes and durations of sinusoidal field half-periods are different.     

Absorption optical bistability in semiconductors under the action of an external electric field

The conditions for the realization of absorption optical bistability under the simultaneous action of two (radiative and nonradiative) mechanisms of recombination of free charge carriers are investigated. It is shown that, in the diffusion mechanism of stream of free electrons from the beam axis, the temperature dependence of radiative recombination does not expand the temperature range of the thermostat in which the optical bistability occurs. A scheme is proposed with application of an external transverse electric field, which makes it possible to realize absorption optical bistability at any ambient temperature. An important advantage of this scheme is the conservation of the state of a bistable system after the action of a light pulse and a significant decrease in the energy spent on cooling of the medium.     

Saturated sodium chloride solution under an external static electric field: A molecular dynamics study

The behavior of saturated aqueous Na Cl solutions under a constant external electric field(E) was studied by molecular dynamics(MD) simulation. Our dynamic MD simulations indicated that the irreversible nucleation process towards crystallization is accelerated by a moderate E but retarded or even prohibited under a stronger E, which can be understood by the competition between self-diffusion and drift motion. The former increases with E, thereby accelerating the nucleation process, whereas the latter pulls oppositely charged ions apart under a stronger E, thereby decelerating nucleation.Additionally, our steady-state MD simulations indicated that a first-order phase transition occurs in saturated solutions at a certain threshold Ec. The magnitude of Ec increases with concentration because larger clusters form more easily when the solution is more concentrated and require a stronger E to dissociate.     

Enhancement of the diffraction efficiency of the hologram recorded in photorefractive media under the action of external electric field

Diffraction efficiency as a function of the applied electric field for the non-linear regime has been calculated by solving numerically the beam coupling equations. The refractive index variation used in the beam coupling equations was calculated directly from the material rate equations via the total space charge field. The diffraction efficiency of the holograms recorded in photorefractive media is not only a function of the applied external electric field but also a function of crystal thickness, diffusion field, reduced fringe contrast modulation ratio and absorption coefficient of the materials. The effects of these parameters on the efficiency of the holograms have been studied in details. In the absence of the external applied field, it is found that the diffraction efficiency of the holograms could be maximized for a thinner photorefractive crystal having lower absorption coefficient and higher value of diffusion field, which could exist at a much lower value of reduced fringe contrast modulation ratio of the index grating. More efficient holograms can be recorded in the presence of the externally applied electric field as compared to the case of no external field.     

Tribological system in the boundary friction mode under a periodic external action

A mechanical analog of a tribological system in the boundary friction mode is studied. A thermodynamic model is used to analyze the first-order phase transition between liquidlike and solidlike structures of a lubricant. The time dependences of the friction force, the relative velocity of the interacting surfaces, and the elastic component of the shear stresses appearing in the lubricant are obtained. It is shown that, in the liquidlike state, the shear modulus of the lubricant and the elastic stresses become zero. The intermittent (stick-slip) friction mode detected experimentally is described. It is shown that, as the lubricant temperature increases, the frequency of phase transitions between the lubricant structural states decreases and the total friction force and elastic stress amplitudes lower. When the temperature or the elastic strain exceeds the corresponding critical value, the lubricant melts and a kinetic slip mode in which the elastic component of the friction force is zero takes place.     

Charging of a conducting sphere moving in a weakly ionized gas under an arbitrarily oriented external uniform electric field

A charging conducting sphere moving in a weakly ionized gas is investigated. An external uniform electric field is applied with arbitrary orientation relative to the gas flow. The ion current is obtained analytically and investigated numerically in ballistic assumption. It is shown that charging regimes depend not only on the net charge of the sphere but also on the gas flow type, and the parameter ξ_± – the ratio of ion drift velocity far from the sphere to the gas velocity. The cases |ξ_±|<1 and |ξ_±|>1 yield two different charging regimes for Stokes and potential flows. For the potential flow, the ion current has been found analytically in continuous ξ_±-parameter space. The stationary charge of an isolated sphere is also calculated numerically as a function of α. It achieves maximum magnitudes in direct (α=0) and back (α=π) flows respectively.     

Hot electrons and exciton-electron collision in GaAs under external electric field

The emission due to free exciton-electron collision has been investigated in relatively high purity n-GaAs under the external electric field. With increasing electric field, the emission peak shifts to lower energy while the higher energy side of the peak broadens. The emission spectra were also compared with the theory. From the higher energy tail, we estimated the electron temperature as a function of the electric field.     

Dielectric properties of pyridine N-oxide aqueous solution under the static electric field and microwave field

Molecular dynamics simulations of the pyridine N-oxide aqueous solution have been performed in the canonical ensemble macroscopic canonical ensemble (NVT) both in the absence and presence of an external electromagnetic field. It extracts the radial distribution function for each concentration solution, dielectric constant and other information on dielectric properties. Analysing the microscopic dielectric information of the aqueous solution under the static electric field (0–3×10⁹ V/m) and microwave frequencies (2.45G, 0–3×10⁹ V/m), and comparing the dielectric information between the different concentrations and different field strengths, we can get the dielectric properties of two kinds of polar aqueous solution under microwave irradiation. Thus, this project can provide the data of the sample to other correlation studies.     

Molecular properties and potential energy function model of BH under external electric field

Using the density functional B3P86/cc-PV5Z method, the geometric structure of BH molecule under different external electric fields is optimized, and the bond lengths, dipole moments, vibration frequencies, and other physical properties parameters are obtained. On the basis of setting appropriate parameters, scanning single point energies are obtained by the same method and the potential energy curves under different external fields are also obtained. These results show that the physical property parameters and potential energy curves may change with external electric field, especially in the case of reverse direction electric field. The potential energy function without external electric field is fitted by Morse potential, and the fitting parameters are obtained which are in good agreement with experimental values. In order to obtain the critical dissociation electric parameter, the dipole approximation is adopted to construct a potential model fitting the corresponding potential energy curve of the external electric field. It is found that the fitted critical dissociation electric parameter is consistent with numerical calculation, so that the constructed model is reliable and accurate. These results will provide important theoretical and experimental reference for further studying the molecular spectrum, dynamics, and molecular cooling with Stark effect.     

Equivalent image charges of a prolate spheroid under an external electric field

This paper presents the image charges for a prolate spheroid under an external electric field. The equivalent image charges can substitute the spheroid to represent the potential that the free or polarization charges, induced by the external field on the spheroid, contribute to the exterior. In order to generalize the image charges for an arbitrary external field, we apply cylindrical image charges along the interfocal line of the spheroid, and explain the determination of the charge distribution and the calculation of the potential from the images. Examples are included to demonstrate the applicability of the image charges in field calculation.     

Effect of an external electric field on two-dimensional nucleation

Summary Two-dimensional nuclei of different possible shapes are considered in the presence of an external electric field which is applied either perpendicular or parallel to the nucleation surface. The additional driving force needed for the formation of a nucleus due to the electric field is found and used in the nucleation theory. The results show that the electric field can either stimulate or inhibit the nucleation process depending on the ratio of the dielectric constants and the orientation of the applied electric field with respect to the nucleation surface. The dependence of the two-dimensional nucleation rate on the intensity of electric field is also determined.

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Riassunto Si considerano nuclei bidimensionali di differenti forme possibili in presenza di un campo elettrico esterno che è applicato sia perpendicolare che parallelo alla superficie di nucleazione. Si trova e si usa nella teoria di nucleazione l’ulteriore forza guida necesaria per la formazione di un nucleo a causa del campo elettrico. I risultati mostrano che il campo elettrico può sia stimolare che inibire il processo di nucleazione che dipende dal rapporto delle costanti dielettriche e dell’orientamento del campo elettrico applicato rispetto alla superficie di nucleazione. Si determina anche la dipendenza del valore di nucleazione bindimensionale dall’intensità del campo elettrico.

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Резюме Рассматриваются двумерные ядра различных возможиых форм в присутствии внешнего электрического поля, которое либо перпендикулярно, либо параллельно поверхности вародышеобразования. Определяется и используется в теории зародяшеобразования дополнительная движущая сила, необходимая для образования ядра, всл⪟дствие действия электрического поля. Полученные результатя показяают, что электрическое поле может либо стимулировать, либо тормозить процесс зародышеобразования в зависимости от отношения диэлектричеких постоянных и от ориентации приложенного электричеслог поля отнонительно поверхности зародышеодразования. Такзе определяется зависимость скорости образвания двумерных ядер от интенсивности электрического поля.

     

外电场对弹簧振子系统运动特性的影响

设计了一个受周期驱动带电弹簧振子的实验装置，并建立系统的动力学方程，用线性稳定性分析的方法确定平衡点并分析平衡点的稳定性，利用数值计算并结合多种分析方法求解和判断非线性方程解的各种性质，得到存在电场力作用情况下系统的一些新特性。     

Deformation of germanium under the joint action of an electric current and a magnetic field

The specific features in the behavior of deformation characteristics of low-ohmic p-type germanium single crystals subjected to different types of combined plastic deformation and the anisotropy of the electrical resistance of specimens in the longitudinal and transverse directions have been investigated. Both the acceptor and donor actions of dislocations have been observed in the motion of charge carriers along the direction of compression of the specimen. Under conditions of the joint action of a weak magnetic field and a combined plastic deformation, a decrease in the macroplasticity effects has been revealed. Anisotropy of the electrical resistance of p-Ge specimens in the longitudinal and transverse directions has been found. A possible explanation of the observed effect is given.     

外加横向电场作用下石墨烯纳米带电子结构的密度泛函紧束缚计算

采用基于密度泛函理论的紧束缚方法计算研究了外加横向电场对边缘未加氢/加氢钝化的扶手椅型石墨烯纳米带的电子结构及电子布居数的影响.计算结果表明,石墨烯纳米带的能隙变化受其宽带影响.当施加沿其宽度方向的横向外加电场时,纳米带的能带结构及态密度都会产生较大的变化.对于具有半导体性的边缘未加氢纳米带,随着所施加电场强度的增加,...     

The rotary and kinetic moments of charged particle in fluctuational thermal electric field in condensed matter upon the action of external magnetic field

Presented are common and distinctive mechanisms of behavior of rotary and kinetic moments of an individual free charged particle, which particle is located in the potential well of condensed matter, depending on the type of the applied external magnetic field (MF): constant and alternating fields are orthogonal or co-linear (the combined field). It is shown, that the action of combined MF leads to energy resonance of rotary moment and to amplification of kinetic moment, whereas the action of orthogonal MF leads to magnetic resonance. The problem of appearance of additional magnetization of matter depending on the type of MF is discussed.     

Exact treatment of the Jaynes–Cummings model under the action of an external classical field

We consider the usual Jaynes–Cummings model (JCM), in the presence of an external classical field. Under a certain canonical transformation for the Pauli operators, the system is transformed into the usual JCM. Using the equations of motion in the Heisenberg picture, exact solutions for the time-dependent dynamical operators are obtained. In order to calculate the expectation values of these operators, the wave function has been constructed. It has been shown that the classical field augments the atomic frequency ω₀ and mixes the original atomic states. Changes of squeezing from one quadrature to another is also observed for a strong value of the coupling parameter of the classical field. Furthermore, the system in this case displays partial entanglement and the state of the field losses its purity.     

谐振子在含时均匀外场作用下跃迁概率的精确解

采用尝试波函数的方法求解了含时受迫振子的严格波函数,并给出了跃迁概率的精确解。     

Influence of external electric field on the transfer of protons in hydrogen-bonded systems

The LCAO MO self-consistent field method in combination with the 6-31** basis set is used to calculate sections of the potential energy surface for a proton in the NH₃…HCl system in the presence of an external electrostatic field. The field strength is varied in the range of 0.000 to 0.017 a. u. In the absence of the field, the potential of the proton in the isolated complex has one well, the N–Cl distance is equal to 2.92 Å, and the NH₃…H–Cl bond is a hydrogen bond. With increasing distance between the N and Cl atoms, a second well appears in the potential, with the well near the Cl atom remaining deeper. In the presence of an external electric field, with increasing its strength, the depth of the well near the N atom increases, while the height of the barrier for proton transfer from the chlorine to the nitrogen atom decreases. At a certain field strength, the well near the nitrogen atom becomes deeper than that near the chlorine atom, so the proton moves to the nitrogen, making the complex ionic. Thus, the external electric field can influence the type of chemical bond in NH₃…HCl system.