MgF_2作为镁离子内扩散LiNbO_3单晶扩散源的研究

利用ＭｇＦ_２作为扩散源进行镁离子内扩散ＬｉＮＯ_３单晶基片的研究．经电子探针显微镜分析表明，镁的扩散层镁离子浓度分布具有近似半抛物形和阶跃形分布，并得到镁的激活能为１０４ＫＪ／．Ｘ射线衍射分析发现，当镁离子内扩散超过一定程度时，在镁的扩散层出现具有ＬｉＮｂ_３Ｏ_８的物相结构，并发现该物相结构的出现与ＬｉＮＯ_３体内锂离子的外扩散和扩散表面氟离子的存在有关．由扫描电子显微镜观察到氟离子以ＬｉＦ的形式出现，并随着扩散程度的增大，挥发和脱离开扩散层表面．     

镁离子内扩散铌酸锂研究（Ⅰ）：电子探针显微分析表征

对ｙ切铌酸锂单晶基片镁离子内扩散后，镁的 经电子探针显微分析表明，随着扩散镁离子浓度具有近似半抛物形分布，由此得到镁激活能为２２１ｋＪ．ｍｏｌ＾－１。探索性地分析了锂外扩散的机理，并提出了一种抑制锂外扩散的方法。对镁离子浓度分布进行了理论模型，其结果基本上与实验符合。     

MgF2作为镁离子内扩散LiNbO3单晶扩散源的研究

利用ＭｇＦ₂作为扩散源进行镁离子内扩散ＬｉＮＯ₃单晶基片的研究．经电子探针显微镜分析表明，镁的扩散层镁离子浓度分布具有近似半抛物形和阶跃形分布，并得到镁的激活能为１０４ＫＪ／mol.X射线衍射分析发现，当镁离子内扩散超过一定程度时，在镁的扩散层出现具有ＬｉＮｂ₃Ｏ₈的物相结构，并发现该物相结构的出现与ＬｉＮＯ₃体内锂离子的外扩散和扩散表面氟离子的存在有关．由扫描电子显微镜观察到氟离子以ＬｉＦ的形式出现，并随着扩散程度的增大，挥发和脱离开扩散层表面． 关键词：     

镁离子内扩散铌酸锂研究(Ⅰ)——电子探针显微分析表征

对y切铌酸锂单晶基片镁离子内扩散后,镁的扩散层经电子探针显微分析(EPMA)表明,随着扩散深度镁离子浓度只有近似半抛物形分布,由此得到镁激活能为221kJ·mol~(-1)。探索性地分析了锂外扩散的机理,并提出了一种抑制锂外扩散的方法。对镁离子浓度分布进行了理论模拟,其结果基本上与实验符合。文中所得结果可用于铌酸锂单晶光纤芯-包层波导结构的实现,经选择适当参数(扩散温度、扩散时间、MgO膜厚度、晶纤直径)可望达到低次模传输。 关键词：     

镁离子内扩散铌酸锂研究(Ⅱ)—— X射线衍射和扫描电子显微镜表征

对不同扩散条件的铌酸锂单晶基片进行了X射线衍射分析(XRD)和扫描电子显微镜观察(SEM)。结果表明,在扩散表面富镁层出现一新相结构,可能是由Li-Mg-Nb-O组成的三元系相结构,这一新相被认为是镁离子内扩散的真正扩散源。并对晶格发生畸变、镁离子内扩散机理以及镁的扩散层折射率变化机理进行了分析和讨论。 关键词：     

刚性光纤元器件芯,皮玻璃的相互散

通过扫描电子显微镜观察到刚性光纤元器件芯、皮玻璃之间有扩散层,用干涉仪测量了扩散层的折射率范围。本文从玻璃网络结构观点解释了这一扩散机理,并就刚性光纤元器件芯、皮玻璃配方设计中如何使离子扩散减到最小程度提出了可行性措施。     

镁离子电池正极材料VS_4掺杂改性的第一性原理研究

阳离子掺杂能够有效提高材料的电化学性能,而对掺杂材料结构和电化学性质的研究能从理论上解释产生这种变化的原因.本文采用基于密度泛函理论的第一性原理方法,研究了过渡族金属掺杂的镁离子电池正极材料TM_(0.125)V_(0.875)S_4(TM=Mo、Fe、Co、Ni)的几何和电子结构变化,计算结果显示:通过采用范德华力修正的GGA+vdw-DF方法,获得了和实验结果相一致的晶格常数.阳离子掺杂后,a轴和b轴晶格常数减小,而c轴晶格常数增大.电子态密度分析表明离子掺杂能够有效降低带隙,提高材料的电子电导率.通过对镁离子扩散进行微动弹性带(NEB)计算,发现Fe掺杂能够有效降低扩散能垒,提高材料的离子迁移率.     

锂离子外扩散对扩镁铌酸锂表层结晶特性的影响

利用常规X射线衍射和掠入射X射线衍射对在空气中进行镁离子内扩散的扩镁铌酸锂单晶表层的富氧化镁层特性进行了研究,揭示出镁离子内扩散初期随着体内锂离子的外扩散,首先在富氧化镁层形成Li₃Mg₂NbO₆和Mg₄Nb₂O₉的化合物结构,Li₃Mg₂NbO₆出现在富氧化镁的内表层,而Mg₄Nb关键词：     

高n双电子复合伴线对类氦镁离子Kα共振线贡献的理论计算

利用多组态Dirac-Fock方法计算了类氦镁离子的双电子复合截面.分析了类锂镁离子高n双电子伴线结构及其对类氦镁离子Kα共振线的影响.结果表明类锂镁离子高n双电子伴线和类氦镁离子Kα共振线之间存在着严重的混合,会导致Kα共振线强度的增加、谱形的加宽以及位置的移动.     

哺乳动物尿液中钙镁离子浓度的1H NMR测定方法

哺乳动物体液中的钙镁离子浓度能够反映体内营养代谢的平衡与一些疾病的发生发展. 尿液中钙镁离子浓度的准确测量需要不受基质影响的便捷新方法. 该文使用过量乙二胺四乙酸(EDTA)为探针并通过¹H NMR方法测定钙镁离子与EDTA络合物的含量,建立了一种快速原位的尿液钙镁离子浓度测量方法. 将此方法分别用于人、大鼠及小鼠的尿液测定,发现3类哺乳动物的尿液钙镁离子浓度存在显著的物种依赖性和较大的相同物种个体间差异. 上述为生物体液中钙镁离子浓度的快速定量测量提供了便捷方法,也提供了3类哺乳动物尿液钙镁离子浓度的基础数据.     

Magnesium ion-conductive poly(ethylene carbonate) electrolytes

Magnesium (Mg) electrolytes are presently under investigation for their promising performance capabilities in the next generation of batteries. The present work studies Mg-ion transport in polymers using different types of Mg salts. Polymer electrolytes comprising poly(ethylene carbonate) (PEC) with Mg salts (MgX₂; X?=?TFSI, ClO₄) were prepared by solution casting. The structural, thermal, and electrochemical properties of flexible self-standing membranes were studied as potential Mg electrolytes. The impedance results at 90 °C found the highest conductivities of 6.0?×?10^?6 S cm^?1 for PEC-Mg(TFSI)₂, and 5.2?×?10^?5 S cm^?1 for PEC-Mg(ClO₄)₂, at 40 mol%. FT-IR measurements revealed changes in the peak fraction from the region of carbonyl group, which explain the interaction with Mg ions. The glass transition temperature of the TFSI system decreased with increasing salt concentration due to the plasticizing effect of TFSI anions. Thermal gravimetric analysis revealed that the highest values of the 5% weight-loss temperature at 40 mol% are 174 °C for PEC-Mg(TFSI)₂ and 160 °C for PEC-Mg(ClO₄)₂. The electrochemical stability of PEC-Mg(TFSI)₂ at 40 mol% was up to 2.2 V. To confirm the redox reaction of Mg ions in PEC, CV measurement was carried out using symmetrical cells with quasi Mg electrodes. Cathodic and anodic current peaks were clearly observed, and the presence of these peaks indicates Mg-ion conduction in PEC.     

Specification of spectral line shape and multiplex dispersion by self-imaging and moiré technique

Due to finite width of a spectral line, the visibility of the moiré fringes formed by a grating and the self-image of another similar grating reduces by the increase of the self-image order. This effect is exploited to specify the spectral line shape by evaluating the Fourier transform of a function related to the visibility. Even, by using in-expensive optics, the technique can provide the spectral line shapes of rather broad widths—of the order of nanometer and more—by precisions that are comparable by those obtained by expensive Fourier transform spectrometers.Besides, it is shown that by comparing the line shapes obtained with and without a dispersive medium between the gratings, one can specify the dispersion function of the medium in the wavelength range covered by the spectrum.     

The rigorous electromagnetic theory of the diffraction of vector beams by a circular aperture

The rigorous electromagnetic theory of the diffraction of vector beams by an aperture is proposed and numerically evaluated by the diffraction of vector Gaussian beams by a circular aperture. The results are compared with those, by using the vector Rayleigh–Sommerfeld diffraction integrals and angular-spectrum expression theory, showing a good consistency. The numerical calculation shows that the result calculated by the rigorous theory is much more precise than those calculated by the integral method in diffraction near field, and a highly consistency reaches by the three methods in diffraction far field. A further extension of the theory is discussed.     

Progress in Ultrasonic Spray Pyrolysis for Condensed Matter Sciences Developed From Ultrasonic Nebulization Theories Since Michael Faraday

This review outlines, in great detail, the history of the phenomenon of ultrasonic nebulization of liquids since the discovery of such an effect by Michael Faraday and the explanation of the phenomenon by capillary wave mechanism and “cavitation” hypothesis. Capillary waves described by the Kelvin equation are confirmed by Lang's experiment and more theoretical models by Peskin & Raco and Jokanovic. Cavitation bubbles have been elaborated by the Rayleigh-Plesset equation as well as the correlation equations between predicted and experimentally measured droplet diameter. Correlation equations such as one by Rajan & Pandit and Avvaru et al. have been considered. Ultrasonic spray pyrolysis for materials processing and the theories that predict the final particle size distribution are introduced. The popularity of the technique is shown by the rising number of research groups in the world processing various materials by this method due to its cost-effectiveness, purity of its products, and controllability of particle size as well as final properties.     

直流清洗电极电场对束流参数影响的测量与研究

 本文采用保角变换法推导了直流清洗电极电场的计算公式,分析和研究了合肥光源直流清洗电极电场对束流参数的影响。例如,直流清洗电场存在垂直方向的二极分量将引起闭轨变化,四分量将产生工作点偏移,六极分量会产生附加校正色品。并给出了一些测量结果。     

碳化硅反射镜坯体光学加工的残余应力测量与分析

测量并分析了碳化硅反射镜坯体光学加工的残余应力。采用X射线衍射法测定了磨削成形、研磨以及抛光过程引入的表面残余应力的性质和大小;采用逐层抛光法测定了在用120#粒度金刚石砂轮磨削时引入的残余应力层厚度。研究结果表明:在用120#金刚石砂轮磨削加工时沿磨削方向和垂直于磨削方向分别引入了残余拉应力和残余压应力,其大小分别为40MPa和70MPa,应力层深度约为60μm,大于裂纹层深度;在用W7金刚石微粉研磨时引入了残余压应力,在其作用范围内残余应力平均值为60～80MPa;在抛光时理论上会引入残余压应力。在此基础上提出了在碳化硅反射镜坯体的光学加工过程中,可以通过研磨消除磨削引入的裂纹层和残余应力层。     

实时全息术检测透明物的一种新方法

介绍了实时全息术检测透明物的一种新方法,它采用物光再现的参考光和参考光通过全息图的直透光所形成的干涉图纹检测透明物体的变化。证明了这组干涉图纹与用参考光再现的物光和物光通过全息图的直透光所形成的干涉图纹分布规律相似,仅在相位上相差π。还讨论了这组干涉图纹的衬比和获得最佳衬比的条件。此方法可消除物光光路上某些因素带来的相位畸变,避开待测物体自发光的干扰,并可在全息图后方任意位置进行记录,这使实时全息术在实践中更具有灵活性,有助于它在更广阔领域内的应用。     

Chiral-Quantum-Optics-Based Supervised Learning

Based on the excellent control of single photons realized by atom-photon-chiral couplings,a novel quantum-optics scheme for supervised learning is proposed. The single-photon rotating and phase-shift operations, which can be controlled by another single photon, are realized by proper atom-photon-chiral couplings. Then, an algorithm to perform the supervised learning tasks, composed by integrating the realized gates, and implemented by the tunable gate parameters, is realized.     

化学水浴法和磁控溅射法制备硫化镉薄膜的性能研究

以氯化铵、氯化镉、氢氧化钾和硫脲为反应物采用化学水浴法制备了硫化镉薄膜,为了作对比研究,采用射频磁控溅射以硫化镉为靶材,氩气为溅射气体,制备了硫化镉薄膜。采用X射线衍射、扫描电子显微镜和紫外-可见光光谱仪分别表征了硫化镉薄膜的结构、形貌和光学吸收特性。结果表明,采用以上两种方法制备的硫化镉均具有(002)择优取向,溅射法制备的硫化镉薄膜较致密,薄膜表面较光滑,平均晶粒尺寸在20～30nm;水浴法制备的硫化镉薄膜颗粒尺寸较小,缺陷较多。除了在短波段溅射所得硫化镉薄膜的透过率略差于水浴法所得硫化镉薄膜之外,溅射法制备的硫化镉薄膜的性能整体上优于水浴法制备的薄膜。两种方法制备的硫化镉薄膜的能隙在2.3～2.5eV。