Converging radial flow of dilute polymer solutions

A characteristic time of dilute polymer solutions is determined from a converging radial flow experiment. The influence of the intradisk separation and of the polymer concentration on this time is studied. Present results are compared to results obtained with a diaphragm. The main limitations of the experiments are pointed out.     

A reassessment of the wall effect of non-newtonian flow of polymer solutions

An apparatus for checking slip interpretation of flow anomalies in the laminar capillary flow of macromolecular solutions is described. It consists of a two-dimensional flow channel, having a uniform width of 1.5 inch and an alternative, convergent taper that is adjustable. Dilute aqueous solutions of the polymers Carbopol, Natrosol, and Polyox are recirculated in steady laminar flow from a large reservoir. Velocities, pressures, and wall shear stresses are measured. Local velocities are obtained by the local injection of conductive tracer fluid, whose passage is sensed by sets of electrodes stationed along the flow. Wall shear stresses are measured on a small, freely displaceable, traction surface flush with the channel wall. The tests cover concentrations of Carbopol of 0.1% to 0.4%, Natrosol of 0.5% to 1%, and Polyox of 0.5% to 1%. Approximate viscosities range from about 10 to 1000 cP. Wall shear rates up to 1000 s^–1 are attained.The results are in good agreement with the established viscometric properties of the tested materials. Actual shear stresses agree with those calculated from pressure drops, and velocities exhibit no detectable anomaly near the wall. Any velocity anomaly in the experiment would have to be less than 3% of the mean flow velocity.An order of magnitude analysis, based on particulate behavior, is made in an attempt to delineate an underlying mechanism.     

Torsional flow stability of highly dilute polymer solutions

We examine the torsional flow stability, to axisymmetric disturbances, of a variety of multimode and non-linear constitutive models in a bounded parallel plate geometry. The analysis is facilitated by the construction of a regular perturbation scheme in the ratio of polymer to total viscosity. As a model for Boger fluids this corresponds to the assumption that the Boger fluid is highly dilute. The consequent simplification provided by the perturbation scheme allows us to examine the effects of a discrete spectrum of relaxation times, shear thinning, second normal stress difference, and finite extensional viscosity on the torsional instability.     

Constitutive equation for dilute polymer solutions in strong elongational flow

A constitutive equation is proposed, which is constructed using both phenomenological and structural ideas. In this formulation, the kinematics of the fluid is characterized by the deformation rate and a structural vector. The vector follows an evolutionary law which is inspired by known molecular models. The expression for the stress is given by introducing a dissipative term related to the strong hydrodynamic interaction of the distorted molecules and a deformation term for the molecules, as well as by using the second law of thermodynamics.A study of the general properties of the evolutionary equation and its response in a homogeneous two-dimensional flow provides evidence of the performance of the proposed model.     

The flow of dilute polymer solutions in confined geometries: a consistent numerical approach

Starting from rigorous expressions derived from phase space kinetic theory for dumbbell models of polymer solutions, a new numerical approach is presented. It enables one to solve the Langevin equations governing the motion of the dumbbells in a confined geometry consistently with the momentum balance equation. As an example, we discuss the flow of a polymer solution between two parallel shearing planes. For this purpose, we consider linear and nonlinear dumbbell models and investigate typical phenomena such as, for example, the slip effect.     

Normal stress effect in dilute polymer solutions

Rheologica Acta - The non-linear, steady flow behavior of dilute solutions of poly ethylene oxide at high shear rates is experimentally studied. The shear stress-shear rate relations at low and...     

Extensional flow resistance of dilute polyacrylamide and surfactant solutions

The extensional flow behaviour of dilute aqueous solutions of a partiallyhy-drolyzed polyacrylamide and a surfactant were investigated in an extensional flow cell. The cell was designed such that fluids were subjected to steady shear before undergoing extensional motion in a converging channel. Extensional resistance was monitored by measuring the pressure drop through the channel. Such measurements were made over a range of extensional rates at fixed values of the upstream shear rate. Solutions of different concentrations were tested — up to 40 ppm of polyacrylamide and 450 ppm of surfactant — at various temperatures in the case of surfactant and for different types and amounts of salt in the case of polyacrylamide. Of the results, the more notable are that the extensional resistance of polyacrylamide solutions is affected much more by CaCl₂ than by NaCl and that surfactant solutions do not exhibit extensional resistance unless they are pre-sheared.     

Unified gas-kinetic particle method for dilute granular flow and its application in a solid jet

Because of its complexity,the problem of multiscale structure in granular flow has been receiving increasing attention.In this work,in order to conduct an in-depth exploration of the multiscale structure,a unified gas-kinetic particle(UGKP)method suitable for granular flow is constructed,in which the collision damping term and return-to-isotropy term are added to characterize the collision between particles.For the above two collision terms,the former characterizes the inelastic collision of particles,while the latter emphasizes the importance of the isotropic distribution of particles,which makes the results more reliable and reasonable.The construction of unified gas-kinetic schemes(UGKS)for granular flow has been reported in previous research.However,because of the need for discrete velocity space,the calculation size is quite large,making it impossible to use UGKS directly to investigate the multiscale problem.However,for UGKP,the flux contributed by particle free transport is calculated by free-streaming particles instead of discrete velocity space so that the corresponding calculation is much smaller than UGKS.The validity of the method is verified by numerical simulation of the solid jet compared with the particle-in-cell(PIC)method.In addition,since the sampled particles are used to obtain the flux contributed by the free transport,UGKP is more efficient than UGKS for solving multiscale problems.     

Hydrodynamic interactions of dilute polymer solutions under shear flow in a narrow channel

Hydrodynamic interactions on dilute solutions of spherical beads under shear flow are calculated with the method of induced forces. The Navier-Stokes equation is considered in the Stokes approximation. Hydrodynamic interactions cause the drag to be anisotropic in space.Numerical solutions are obtained for the added stress, caused by polymeric molecules in solution in a narrow channel under shear flow. The polymeric molecules are considered as Hookean spring-dumbbells.Slip velocity and the effective viscosity are obtained taking different dumbbells' bead radii. Transversal migration in the channel is obtained for different bead radii.     

Diffusion of macromolecular solutions in the turbulent boundary layer of a cylindrical pipe — Evolution of wall concentration

Summary In this paper, we are presenting a model of the evolution of the wall concentration of a macromolecular solution (PEO) annularly injected in a cylindrical pipe in a turbulent flow. This model valid for all diffusion zones is based on mathematical and physical considerations and proves to be in good agreement with the experimental data.

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Zusammenfassung Es wird ein Modell der Entwicklung der Wandkonzentration einer makromolekularen Lösung (PÄO) vorgestellt, die in einem wandnahen Ringspalt in die turbulente Strömung durch ein zylindrisches Rohr injiziert worden ist. Dieses für alle Diffusionszonen gültige Modell basiert auf mathematischen und physikalischen Betrachtungen und erweist sich für die Beschreibung der experimentellen Daten als gut geeignet.

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C _w wall concentration - C _i initial concentration before injection - L ₀ distance from the slot at which the wall concentration drops toe ^-1 of its original value - L _IT ,L _IF ,L _F characteristic lengths - L _I length scale of the second region - x downstream distance from the source - n _I ,n _T ,n _F characteristic exponents - K ₀,K _I ,K _F characteristic constants - ln natural logarithm - q _i flow rate of injection - Q _T flow rate - C _j =C _{i · q i} /Q _T concentration in homogeneous medium - A, B, C, m constants - p andq annex variables - Re Reynolds number With 7 figures     

Molecular orientation in non-Newtonian flow of dilute polymer solutions around spheres

A novel approach is presented to study the benchmark problem of flow around spheres in model dilute solutions of monodisperse samples of atactic polystyrene in di-octyl phthalate. Spheres are held stationary on flexible cantilevers of known spring-constant, k, while the polymer solutions are pumped past at controlled flow rates, allowing access to a wide range of Deborah number. In this way the non-Newtonian forces experienced by the spheres can be measured as a function of Deborah number, while detailed observations and measurements of birefringence are made, enabling assessment of macromolecular strain and orientation. In addition the flow field around a sphere has been measured in an a-PS solution. Experiments have been performed on a single sphere and on two spheres axially aligned in the direction of flow. The extensional flow around the downstream stagnation point of the single sphere is found to play a pivotal role in the development of molecular strain and stress, resulting in flow modification and subsequent non-Newtonian behaviour. The flow birefringence in the wake is found to modify severely the flow around a second, downstream, sphere, affecting the non-Newtonian forces encountered by the second sphere. This provides an explanation for the time interval dependent terminal velocity often observed when two spheres follow the same path through viscoelastic liquids.     

Measurement of the normal stress coefficients of dilute polymer solutions from the flow in a curved tube

Summary A third order simple fluid model has been used to determine the sum of the first and second normal stress coefficients of dilute polymer solutions from measurement of the streamline pattern produced by the flow in a curved tube. For solutions of the polyacrylamide Separan AP 30 in the concentration range 20–80 p.p.m.w. the second normal stress coefficient is negative and of greater magnitude than the first normal stress coefficient.

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Zusammenfassung Das Modell der einfachen Flüssigkeit dritter Ordnung wird dazu verwendet, um die Summe des ersten und zweiten Normalspannungskoeffizienten verdünnter Polymerlösungen durch Ausmessung des Stromlinienbildes der Strömung in einem gekrümmten Rohr zu bestimmen. Bei Lösungen von Polyacrylamid Separan AP 30 im Konzentrationsbereich 20–80 Gewichtsp.p.m. ist der zweite Normalspannungskoeffizient negativ und größer als der erste.

     

Friction reduction and degradation in turbulent flow of dilute polymer solutions

An experimental study of friction reduction and polymer degradation in turbulent pipe flow is described for dilute water solutions of guar gum, CMC, Separan NP-10 and Polyox WSR-301. The tests are made in a turbulent-flow rheometer with a 2 mm I.D. pipe over a Reynolds number range from 8,000 to 25,000. The maximum attainable friction reduction for guar gum, Separan NP-10 and Polyox WSR-301 is found to be almost equal, but large differences in effectiveness occur. The most effective polymers (Polyox WSR-301 and Separan NP-10) are also the most liable to degradation. Mixing of polymers does not ameliorate the maximum friction reducing ability of the most effective component.     

Characteristics of HPAM dilute polymer solutions in three elongational flow situations

Previous work has shown that anomalous pressure behaviour occurs when dilute polymer solutions are subjected to elongational flows such as those existing upstream of a capillary tube entrance, of an orifice and of the stagnation point of a Pilot tube probe. Tests have been conducted with aqueous solutions of HPAM at various concentrations using the above three flow geometries. It is shown that pressure anomalies occured when critical values of the ratio between a velocity and length scale, representative of the strain rate, are exceeded. They are proportional to the power of the strain rate with an exponent larger than one. Based on previous and present results, it appears that the polymer solutions' behaviour may be characterized by three parameters: an anomalous stress magnitude, a relaxation time (inverse of the critical strain rate) and the exponent of the power law. The first two parameters depend on the polymer type, concentration and molecular weight, while the third depends only on the polymer type. The anomalous pressure is also affected by the conformation of the molecules as shown by results obtained with HPAM solutions containing varied amounts of NaCl.     

Experiments on elongational flow of dilute polymer solutions: Part II: velocity field for the flow through small apertures

Following Part I which reported on the jet reaction and the excess pressure drop, this paper describes the results of flow velocities measured upstream of small apertures for dilute polymer solutions. The results suggest the existence of the two flow regimes reorted by Boger and Cable: the vortex growth regime and the divergent flow regime. The former corresponds to the regime of zero jet reaction and the latter to the regime of positive jet reaction. The axial velocity development for PEO solutions along the center line upstream of the aperture is found to yield an extremely high velocity rise at the onset of the vortex region and to give a nearly constant elongational rate within the vortex region. The constant elongational rate takes values such that the product with the relaxation time is about 0.5. Separan solutions do not provide so high a velocity rise at the onset of the vortex region but show an exponential rate of elongation in the vortex region.It is shown, by using the upper convected Maxwell model, that the steep velocity rise at the onset of the vortex region is given in the simplified flow model and the constant elongational rate within the vortex region holds the elongational stress nearly constant.     

The velocity field of dilute cationic surfactant solutions in a Couette-viscometer

With the aid of particle image velocimetry (PIV) momentary two-dimensional velocity fields of dilute cationic surfactant solutions are measured in an annular gap between coaxial cylinders. In the shear-induced state the velocity profiles of the surfactant solutions differ from a Couette profile drastically: Time dependent flows with high shear rates near the walls are observed. The flow is almost one-dimensional, velocity components in radial or axial direction cannot be detected. The velocity profile can exhibit a local maximum. A macroscopic heterogeneous structure is observed, domains with high viscosity alternate with low viscosity regions. Elastic phenomena are observed in a relaxation experiment. Existing rheometric data of cationic surfactant solutions in the shear-induced state give only apparent viscosities.     

Brownian dynamics simulations of star-branched polymers in dilute solutions in extensional flow

Using Brownian dynamics (BD) simulations of FENE bead-spring models, the dynamics of star-branched polymers in dilute solutions under extensional flow have been investigated. Studies on star polymers in transient extensional flow reveal that the initial transient stress response at low strains is governed by both the number of arms and the shortest arm. On the other hand, the steady-state behavior of star polymers in elongational flow is limited by the maximum effective “contour” length of the molecules. The distribution of arm extension and birefringence of the star-branched molecule are broader and the mean is shifted to lower values, when compared to equivalent linear systems. As a result, the degree of arm extension at steady-state decreases as the number of arms in the star increases. Both an analysis of individual ensembles in Brownian dynamics simulations and a study of a simple force balance indicate that the constraint imposed on the star arms by the central branch point and contributions from “asymmetric” arm arrangements give rise to overall less extended and oriented star-branched molecules with broader arm extension and birefringence distributions. The results obtained from stress-conformation hysteresis simulation indicate that less-stretched arms exhibit more retarded relaxation, as the number of arms increases in star-branched molecules. The effect of excluded volume (EV) interactions, incorporated through the Lennard–Jones potential, on the dynamics of star polymers in extensional flow appears unimportant.