This review provides a survey of lithography techniques and the resist materials employed with these techniques. The first part focuses on the conventional lithography methods used to fabricate complex micro- and nano-structured surfaces. In the second part, emphasis is placed on patterning with unconventional lithography techniques such as printing, molding, and embossing, and on their development into viable, high-resolution patterning technologies. 相似文献
A combination of soft lithographic printing and soft templating has been used to fabricate high-resolution interdigitated micro-supercapacitors (MSC). Surfactant-assisted self-assembly produces high surface area ordered mesoporous carbons (490 m2 g−1). For the first time, such precursors have been printed by nano-imprint lithography as microdevices with a line width of only 250 nm and a spacing of only 1 μm. The devices are crack-free with low specific resistance (1.2×10−5 Ωm) and show good device capacitance up to 0.21 F cm−3. 相似文献
The in situ generation of molecules that bridge nanogaps generated by on‐wire lithography is achieved by using click chemistry. C. A. Mirkin, M. A. Ratner, and co‐workers show in their Communication on page 5178 ff. that these molecular junctions give high yields, and they describe how this strategy can be generalized to incorporate diverse molecular architectures within the nanogaps. Tracking of the molecular assembly process within the nanogaps is allowed by their strong electromagnetic field.
Complex 3D microparticle, as an emerging and attractive field, has attracted more and more attention due to its versatile morphologies and broad range of applications. In this review, we provide an overall recent progress in 3D microparticles fabricated by microfluidic lithography. This review will focus on the synthesis mechanisms, synthesis process, the resultant 3D microparticles, and their applications. Finally, we will look into the future trends in complex 3D microparticles. This review will be beneficial for researchers in numerous fields, including functional materials, sensors, encryption, and biomedical engineering. 相似文献
In this work, an engineered hydrogel system with a 2D and 3D tunable cross‐linking degree is presented. A precise chemical design by the introduction of cross‐linkable units, having reaction orthogonality, allows to control the network formation both in time and space and to selectively alter the hydrogel physical properties. Hydrogel chemistry has been tailored in order to produce spatially controlled stiffness changes and drive cell morphology through mechanical cues. Elastic modulus rises by more than double after photocross‐linking, as shown by atomic force microscopy measurements. Biological response is also analyzed and stiffness‐dependent cell spreading and proliferation are verified. Different pattern geometries are successfully realized by UV lithography, allowing 2D cross‐linking modulation. Furthermore, 3D mechanical tuning at micro‐ and submicrometer scale by two‐photon polymerization makes this system a biologically relevant matrix to study cell functions and tissue development.
The concept of using cantilever‐free scanning probe arrays as structures that can modulate nanoscale ink flow and composition with light is introduced and evaluated. By utilizing polymer pen arrays with an opaque gold layer surrounding the base of the transparent polymer pyramids, we show that inks with photopolymerizable or isomerizable constituents can be used in conjunction with light channelled through the pyramids to control ink viscosity or composition in a dynamic manner. This on‐tip photo‐modulated molecular printing provides novel chemically and mechanically controlled approaches to regulating ink transport and composition in real time and could be useful not only for rapidly adjusting feature size but also for studying processes including photoreactions and mass transport at the nanoscale, self‐assembly, and cell–material interactions. 相似文献
Summary: Fluorescent images that illustrate acid‐catalyzed tert‐butoxycarbonyl (tBoc) deprotection patterns in polymer films were obtained using fluorescent sensors based on 7‐hydroxycoumarin dyes. Three commercial 7‐hydroxycoumarins, which are highly fluorescent, become practically nonemissive upon protection of the 7‐hydroxyl position with tBoc. In thin polymer films, the protected “prefluorescent” probes can return to their deprotected, fluorescent states by reaction with catalytic amounts of photogenerated acid and mild heating.
Protected probes become highly fluorescent after acid‐induced deprotection. 相似文献