Stimulated hyper-Raman emission from sodium vapour

The first observation of tunable stimulated hyper-Raman scattering is reported. A dye laser (ω_p) focussed into sodium vapour produced stimulated hyper-Raman emission (2ω_p?ω_3s-4p) at ～ 2.3 μm when 2ω_p was tuned near the 3s-4d two- photon resonance. Photon conversion efficiencies up to 2% were obtained. The hyper-Raman emission was tuned over a ～ 160 cm^?1 range, and could be observed with pump powers as low as ～ 2kW.     

Localized optical phonons in GaAs/AlAs superlattices grown on (311)A and (311)B surfaces

A study is reported of optical vibrational modes in [311]-grown GaAs/AlAs superlattices. An analysis of the TO and LO localized modes observed in IR reflectance spectra showed that the difference between the TO and LO mode frequencies in superlattices grown on (311)A and (311)B surfaces is due to the different localization lengths of these modes. The dispersion of transverse optical phonons in GaAs derived from IR reflectance spectra is in a good agreement with Raman scattering data. Fiz. Tverd. Tela (St. Petersburg) 40, 550–552 (March 1998)     

First-order Raman scattering in germanium resonant with the E0 gap

We have measured the absolute Raman efficiency as well as the dispersion for first order scattering by the optical zone center phonon in germanium with the incident photon energies in the range of the E₀ gap energy. At 77 K a Raman polarizability of 68±14 Ų is found for an incident photon energy of 0.826 eV. The deformation potential d is determined to be 40 eV assuming C^″₀ ? 1 for the strength parameter of the E₀ gap.     

Nonlinear Raman scattering of photons by a channeled particle

Channeled particles are characterized by the discrete spectrum of bound transverse motion. The interaction of photons with channeled particles in single crystals can be accompanied by energy transitions between the levels of transverse motion of the channeled particle. The Raman scattering of photons at a quasibound channeled particle leads to the appearance of a combination of frequencies: the incident radiation frequency ω₀ and the frequency Δω_{m, n}, i.e., ω = ω₀ ± Δω_m,n where Δω_m,n = 2Δε_m,nγ²; Δε_{m, n} is the energy of the transition between quantum states (m and n) of the transverse motion of the channeled particle; and γ = E/mc² is the Lorentz factor of the channeled particle. The appearance of a violet satellite (the anti-Stokes component) in the Raman scattering spectrum is analyzed. The three-photon Raman-type transition, which is the process of the simultaneous absorption of two photons with the frequency ω₀ with the emission of a photon with the frequency ωs = 2ω₀ ± 2Δε_m,nγ², is considered. The conditions for resonance observation during the formation of the second harmonic (ω = 2ω₀) are discussed.     

三角激光脉冲尾波加速粒子模拟

电子俘获是激光尾波场加速电子的主要机理，增大电子的初速度可以使更多的电子被尾波场俘获.提出三角脉冲激发尾波加速电子的方案，三角脉冲平缓上升沿激发受激Raman散射，用以初步加速电子，三角脉冲陡峭下降沿激发尾波场，将更多的电子加速到接近光速.2D3V粒子模拟结果证实了这一点.同时表明：脉冲长度为几个等离子体波长的超强激光在稀薄等离子体中传播时，还激发侧向Raman散射.在侧向受激Raman散射中，静电波增长最快的波矢模式为k_p=(2ω_p/ω₀ 关键词： 有质动力 电子俘获 前向受激Raman散射 侧向受激Raman散射     

Coherent phonon excitation in bismuth

Ultrafast time-resolved reflectivity of a bismuth thin film evaporated on a silicon substrate is measured to investigate coherent phonons in bismuth. The reflectivity result is analyzed by a linear chirp approximation to obtain the time dependent frequencies of coherent phonons. Not only the optical modes are detected, which are generated by a combination of impulsive stimulated Raman scattering and displacive excitation of coherent phonon, acoustic phonon modes are also observed, which are emitted by the A_1g optical phonon.     

Double resonance interference in third-order light mixing

The first observation of interference effects between two sharp resonant contributions to the third-order nonlinear susceptibility χ₍₃₎ (ω₃=ω₀+ω₁?ω₂) is reported. Using two tunable near ir frequencies, ω₀=ω₁ and ω₂, the was seen in crystalline CuCl when 2ω₁ and ω₁?ω₂ were close to the sharp Z₃ exciton at 3.21 eV and the 210 cm^-1 Raman line, respectively. Three different tunable visible frequencies were used to observe similar interference effects in a benzene-cyclohexane mixture when ω₀?ω₂ and ω₁?ω₂ were close to the 992 cm^-1 Raman line of benzene and the 801 cm^-1 Raman line of cyclohexane, respectively.     

Nonstationary Casimir effect in cavities with two resonantly coupled modes

We study the peculiarities of the nonstationary Casimir effect (creation of photons in cavities with moving boundaries) in the special case of two resonantly coupled modes with frequencies ω₀ and (3+Δ)ω₀, parametrically excited due to small amplitude oscillations of the ideal cavity wall at the frequency 2ω₀(1+δ) (with |δ|,|Δ|⪡1). The effects of thermally induced oscillations in time dependences of the mean numbers of created photons and the exchange of quantum purities between the modes are discovered. Squeezing and photon distributions in each modes are calculated for initial vacuum and thermal states. A possibility of compensation of detunings is shown.     

Surface optical Raman modes in GaN nanoribbons

Raman scattering studies were performed in GaN nanoribbons grown along [1 0 0]. These samples were prepared inside Na‐4 mica nanochannels by the ion‐exchange technique and subsequent annealing in NH₃ ambient. Detailed morphological and structural studies including the crystalline orientation were performed by analyzing the vibrational properties in these GaN nanoribbons. Pressure in the embedded structure was calculated from the blue shift of the E₂(high) phonon mode of GaN. Possible red shift of optical phonon modes due to the quantum confinement is also discussed. In addition to the optical phonons allowed by symmetry, two additional Raman peaks were also observed at ∼633 and 678 cm⁻¹ for these nanoribbons. Calculations for the wavenumbers of the surface optical (SO) phonon modes in GaN in Na‐4 mica yielded values close to those of the new Raman modes. The SO phonon modes were calculated in the slab (applicable to belt‐like nanoribbon) mode, as the wavenumber and intensity of these modes depend on the size and the shape of the nanostructures. The effect of surface‐modulation‐assisted electron–SO phonon scattering is suggested to be responsible for the pronounced appearance of SO phonon modes. A scaling factor is also estimated for the interacting surface potential influencing the observed SO Raman scattering intensities. Copyright © 2010 John Wiley & Sons, Ltd.     

Longitudinal-transverse splitting of dipole modes in hyper-Raman scattering spectra of liquid CCl4

The first observation of the longitudinal-transverse splitting of dipole vibrations in liquid CCl₄ is reported. Using the hyper-Raman scattering technique, we have obtained the spectra of transverse (313, 760 and 782 cm^-1) and longitudinal (?770 and 800 cm^-1) modes in CCl₄. Polarization analysis is shown to be used to distinguish longitudinal and transverse modes of dipole vibrations in hyper-Raman spectra.     

Surface enhanced Raman scattering of light by ZnO nanostructures

Raman scattering (including nonresonant, resonant, and surface enhanced scattering) of light by optical and surface phonons of ZnO nanocrystals and nanorods has been investigated. It has been found that the nonresonant and resonant Raman scattering spectra of the nanostructures exhibit typical vibrational modes, E ₂(high) and A ₁(LO), respectively, which are allowed by the selection rules. The deposition of silver nanoclusters on the surface of nanostructures leads either to an abrupt increase in the intensity (by a factor of 10³) of Raman scattering of light by surface optical phonons or to the appearance of new surface modes, which indicates the observation of the phenomenon of surface enhanced Raman light scattering. It has been demonstrated that the frequencies of surface optical phonon modes of the studied nanostructures are in good agreement with the theoretical values obtained from calculations performed within the effective dielectric function model.     

“Negative” absorption and “negative” emission in nonlinear optics

The nonlinear susceptibilities X³ (ω₂ = ω₁ ? ω₁ + ω₂) calculated for stimulated Raman scattering (SRS) and two- photon absorption (TPA) under the condition of one-photon resonance in the case of a multilevel system with broad overlapping absorption bands (corresponding to polyatomic molecules) are discussed. Spectra of Im X³ with changed sign in some spectral regions are shown. The result is connected with a disbalance of the system, due to the large relaxation constants.     

Multiphoton Spectroscopy

Abstract

Absorption and cmission spectroscopies, which are widely utilized by chemists, can be classified as one–photon spectroscopy. A molecule is excited from its ground state of energy E₀ to thc excited state of E_e by the absorption of one photon of frequency given by the Bohr's condition (hω=E_e-E₀). The reverse transition is accompanied by the emission of one photon of the same frcquency. Therefore, the molecular state energies can be directly obtained by the photon encrgies absorbed or emitted. Infrared, microwave, electronic absorption, and emission spectroscopies belong to this category of one–photon spectroscopy.     

First-order Raman scattering in cylindrical wurtzite nanowire

We have presented a theoretical study on electron resonant Raman scattering (ERRS) process associated with the bulk longitudinal optical (LO), surface optical (SO) and quasi-confined (QC) phonon modes in a free-standing wurtzite nanowire (NW). We consider the Fröhlich electron–phonon interaction in the framework of the dielectric continuum model. Numerical calculations on the GaN material reveal that differential cross-section (DCS) is sensitive to the wire size. The bulk LO and high-frequency quasi-confined (QC₊) phonons make main contributions to the DCS and the impact of the SO phonon can be negligible in the ERRS process. Moreover, scattering intensity of the bulk LO phonon is strongly enhanced as the incident photon energy approaches the energy band-gap of the GaN.     

表面等离子激元非线性表面增强拉曼散射效应

本文采用热蒸发法制备得到纳米Ag颗粒作为增强拉曼衬底, 利用入射光子与纳米颗粒表面价电子的相互作用机理, 激发出高能表面等离子激元, 其表面等离子形成的高能"热点"起到表面增强拉曼散射效果. 通过比较不同入射光强下的拉曼峰强, 指出纳米Ag颗粒的增强拉曼散射效果可以实现低探测光强下的高散射强度, 即纳米Ag颗粒的表面等离子激元具有非线性的表面增强拉曼散射效果, 可降低对样品的光、热损伤, 以利于拓展拉曼散射光谱的应用范围. 同时比较不同纳米Ag颗粒衬底的表面增强拉曼散射效果表明, 采用的热蒸发工艺具有较大的工艺域度, 具有较强的工艺兼容性.     

Estimation of dispersion curve of transverse acoustic phonons in CdI2 by Raman scattering

Shear type rigid layer modes in various polytypes of CdI₂ have been measured by Raman scattering. The dispersion curve of transverse acoustic phonons in the [0 0 ξ] direction is estimated from the observed frequencies of the rigid layer modes. The analysis of the estimated dispersion curve indicates that interlayer forces in CdI₂ are mainly short range ones.     

The effects of incommensurability on the phonon modes in the one-dimensional superionic conductor K-hollandite

Polarized Raman and infrared spectra of the one dimensional (1-D) superionic conductor (K_2xMg_xTi(_8?x)O₁₆; x = 0.77) have been measured over the phonon frequency region 10–1000 cm^?1 as a function of temperature and pressure. The majority of the IR and Raman active modes predicted by group theory for the (Ti, Mg)O₆ framework were observed. The frequencies and their IR and Raman scattering cross-sections for the incommensurate lattice of K⁺ ions were calculated using a one dimensional linear chain model. This model assumes Coulomb interaction between nearest neighbors that are located in a sinusoidal potential due to the framework lattice. Several broad Raman bands were attributed to amplitudon type modes from the one dimensional incommensurate K⁺ ion sublattice. The IR active phason modes could not be identified unambiguously due to the underlying TiO framework vibrations which are known to possess large anharmonicity and oscillator strenghts.     

Physical insight of superconductivity of Nb2AlC: in situ Raman spectrometry investigation

Superconductivity of Nb₂AlC has been previously reported, but the origin is not clear. In this paper, in situ Raman spectra of Nb₂AlC are measured in the temperature range from 80 to 380 K at ambient pressure. The line‐width of E_2g (ω₁) mode increases with temperature which originates from the anharmonic phonon–phonon scattering. On the contrary the line‐widths of E_2g (ω₂) and A_1g (ω₄) modes decrease continuously at elevated temperature. The phenomenon is explained by the electron–phonon coupling. The origin of superconductivity is therefore interpreted by the coupling of Nb 4d electrons with E_2g (ω₂) and A_1g (ω₄) phonon modes. Copyright © 2013 John Wiley & Sons, Ltd.     

Lysine IR emission spectrum excited by moderately intense visible radiation

The excitation of IR emission is observed for thin films illuminated by continuous visible light in the absence of light absorption in the sample. The effect is demonstrated by the example of the lysine molecule and explained by the resonant combined action of optical photons with frequencies ω_i and ω_j, whose differences ω_i?ω_j=Ω coincide with the frequencies of the lysine vibrational modes.