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Sibo Wang Wangshu Yao Jinliang Lin Zhengxin Ding Xinchen Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2014,126(4):1052-1056
Metal–organic frameworks (MOFs) have shown great promise for CO2 capture and storage. However, the operation of chemical redox functions of framework substances and organic CO2‐trapping entities which are spatially linked together to catalyze CO2 conversion has had much less attention. Reported herein is a cobalt‐containing zeolitic imidazolate framework (Co‐ZIF‐9) which serves as a robust MOF cocatalyst to reduce CO2 by cooperating with a ruthenium‐based photosensitizer. The catalytic turnover number of Co‐ZIF‐9 was about 450 within 2.5 hours under mild reaction conditions, while still keeping its original reactivity during prolonged operation. 相似文献
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Negative Thermal Expansion in the Metal–Organic Framework Material Cu3(1,3,5‐benzenetricarboxylate)2
Yue Wu Atsushi Kobayashi GregoryJ. Halder VanessaK. Peterson KarenaW. Chapman Nina Lock PeterD. Southon CameronJ. Kepert 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2008,120(46):9061-9064
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