共查询到20条相似文献,搜索用时 46 毫秒
1.
《Solid State Ionics》2006,177(9-10):821-826
The temperature dependence of the spin-lattice relaxation time, T1 and the line width of the 7Li nucleus were measured in delithiated LixCoO2 (x = 0.6, 0.8, 1.0). Two different relaxation behaviors were observed in the temperature dependence of T1− 1 in a x = 0.8 sample. These would have arisen from inequivalent Li sites in two coexisting phases; an original hexagonal (HEX-I) and a modified hexagonal (HEX-II) phase in the x = 0.8 sample. We analyzed using a phenomenological non Debye-type relaxation model. Motional narrowing in the line width was observed in each sample, the result revealing that Li+ ions begin to move at low temperature in samples with less Li content. It was found that the activation energy associating with Li+ ion hopping in the HEX-II phase is smaller than that in the HEX-I phase. These results show that the HEX-II phase produced in the Li deintercalation process would be suitable for Li+ ionic diffusion in multi-phase LixCoO2, and it is expected that this would enable fast ionic diffusion. Li+ ionic diffusion related to phase transition is discussed from 7Li NMR results. 相似文献
2.
The present paper accounted for the synthesis, differential scanning calorimetric and vibrational spectroscopy of [C2H5NH3]2ZnCl4grown at room temperature. Differential scanning calorimetric (DSC) disclosed five phase transitions at T1=231 K, T2=234 K, T3=237 K, T4=247 K and T5=312 K. The temperature dependence of the dielectric constant at different temperatures proved that this compound is ferroelectric below 238 K. Raman spectra as function temperature have been used to characterize these transitions and their nature, which indicates a change of the some peak near the transitions phase. The analysis of the wavenumber and the line width based on the order–disorder model allowed to obtain information relative to the thermal coefficient and the activation energy near the transitions phase. 相似文献
3.
Helena ?těpánková Karel Kou?il Vojtěch Chlan Peter G?rnert Robert Müller Josef ?těpánek 《Journal of magnetism and magnetic materials》2010,322(9-12):1323-1326
57Fe nuclear magnetic resonance (NMR) spectra of hexaferrite BaFe12O19 powder samples prepared by glass crystallization method were measured at 4.2 K and analyzed in comparison to spectra of single crystals. Samples with various mean particle dimensions were tested. NMR spectral lines corresponding to individual iron sublattices showed pronounced frequency shifts of their positions and a significant line broadening compared to single crystals. The significant contribution to the line shifts and line shape had a uniform macroscopic origin giving identical absolute value of shifts and the same line shapes for all measured lines of a particular sample. Estimations of demagnetization fields based on mean particle dimensions reasonably corresponded to the observed frequency shifts for particle mean diameter 67 nm, or had a higher value for a sample with mean diameter of 340 nm, for which a presence of domain walls was detected by NMR. In the spectrum of a sample with the smallest particles (~16 nm), an additional contribution having broader lines and faster spin-spin relaxations was found. It could be assigned to weaker exchange interactions or deviations of magnetic moment directions from the hexagonal axis in a surface layer. 相似文献
4.
《Solid State Communications》2002,121(2-3):67-71
Beryllium has been implanted into both n- and p-type 6H–SiC with post-implantation annealing at 1600 °C. Photoluminescence (PL) measurements have been performed, and PL lines at 420.5, 431 nm, and a broad band at around 505 nm have been observed. The line at 420.5 nm is attributed to an intrinsic defect DII-center induced by beryllium implantation. The effects of excitation intensity and temperature during the PL experiments are investigated. Based on the excitation laser dependence PL result, the new doublet lines at around 431 nm are thought to be associated with beryllium related bound excitons. The broad band corresponding to the green luminescence at room temperature has been attributed to the recombination of free carriers to beryllium bound levels. 相似文献
5.
《Solid State Ionics》2006,177(1-2):129-135
LixV2O5 (0.4 < x < 1.4) prepared by solid-state reaction were studied by 7Li and 51V NMR spectroscopy. 7Li NMR spectra showed a narrowing of the line width in relation to Li+ionic diffusion. Analysis of LixV2O5 using a Debye-type relaxation model showed a low activation energy ∼0.07 eV in the sample of x = 0.4 below room temperature, and revealed a Li+ionic diffusion with larger activation energy ∼0.5 eV above 450 K in lithium-rich samples. The latter is ascribed to the existence of a multi-phase system comprising stable ɛ- and γ-phases, resulting from complicated phase transitions at high temperature. These shapes and shifts enable the classification of the β-, ɛ-, δ-, and γ-phases. The ionic diffusion of Li+ ions is discussed in relation to the complicated phase transitions. 相似文献
6.
Hf metal with ∼ 3 wt% Zr impurity has been reinvestigated by perturbed angular correlation (PAC) spectroscopy using a LaBr3(Ce)–BaF2 detector set up to understand the microscopic behavior of this metal with temperature. From present measurements, five quadrupole interaction frequencies have been found at room temperature where both pure hcp fraction (∼33%) with 12 nearest neighbor Hf surrounding the probe 181Hf atom and the probe–impurity fraction (∼33%) corresponding to 11 nearest neighbor Hf plus one dissimilar Zr atom are clearly distinguished. At room temperature, the results for quadrupole frequency and asymmetry parameter are found to be ωQ=51.6(4) Mrad/s, η=0.20(4) for the impurity fraction and ωQ=46.8(2) Mrad/s, η=0 for the pure fraction with values of frequency distribution width δ=0 for both components. At 77 K, only 1 NN Zr impurity (∼93%) and pure hcp (∼7%) components have been found with a value of δ ∼ 10% for the impurity fraction. A drastic change in microstructural configuration of Hf metal is observed at 473 K where the impurity fraction increases to ∼ 50% and the pure hcp fraction reduces to ∼ 15% with abrupt changes in quadrupole frequencies for both components. The pure fraction then increases with temperature and enhances to ∼50% at 973 K. In the temperature range 473–973 K, quadrupole frequencies for both components are found to decrease slowly with temperature. Using the Arrhenius relation, binding energy (B) for the probe–impurity pair and the entropy of formation are measured from temperature dependent fractions of probe–impurity and pure hcp in the temperature range 473–773 K. The three other minor components found at different temperatures are attributed to crystalline defects. 相似文献
7.
《Journal of magnetism and magnetic materials》2002,247(1):55-61
A study of the effect of annealing on the magnetic properties of single crystals Sn1−xEuxTe is reported. The width of the electron paramagnetic resonance line of the crystal is found to decrease upon annealing but its g-value of 1.991 is nearly unaffected. Magnetization results indicate that the pair exchange interaction is weakly antiferromagnetic with a value of −0.67 K for the non-annealed sample and −0.29 K after annealed sample. Susceptibility measurements performed as a function of temperature also indicate the presence of EuTe clusters in the as-grown Sn1−xEuxTe crystals. Therefore it was deduced that the Eu2+ ions tend to form clusters, particularly pairs, in the as-grown crystal and these clusters disappear after annealing, as the Eu2+ ions occupy isolated sites in the SnTe host lattice. 相似文献
8.
An unusual structural phase transition in the crystalline compound Rb2HfF6 near room temperature has been observed from perturbed angular correlation (PAC) spectroscopy. Our measurements in this compound produce two different crystalline configurations characterized by ωQ=74.1(1) Mrad/s, η~0, δ~0 and ωQ=24.7(2) Mrad/s, η=0.53(1), and δ=4(2)%. From PAC measurements in different samples, it is found that crystal structure corresponding to ωQ=74 Mrad/s, η~0 transforms to the other quite arbitrarily with temperature and no definite temperature corresponding to this transition has been observed. This can possibly be attributed to displacive phase transition. 相似文献
9.
O.M. Lyulin A.V. Nikitin V.I. Perevalov Isamu Morino Tatsuya Yokota Ryoichi Kumazawa Takeshi Watanabe 《Journal of Quantitative Spectroscopy & Radiative Transfer》2009,110(9-10):654-668
The absorption spectra of mixtures of methane (CH4) with N2 and O2 at different partial pressures of both CH4 and buffer gases for three temperatures 240, 267, and 296 K have been recorded using the Bruker IFS 125 HR FTIR spectrometer in the 5550–6236 cm?1 region. The multispectrum fitting procedure has been applied to these spectra to recover the spectral line parameters. The main goal of this procedure was the determination of the N2- and O2-broadening and shifting coefficients and the exponents of their temperature dependences. These parameters have been derived for 452 assigned lines with good values of the signal to noise ratio. The rotational dependence of the mean values of these parameters is discussed. The temperature dependence exponents were observed for both N2 and O2 buffer gases. 相似文献
10.
《Applied Acoustics》2007,68(11-12):1468-1484
Measurements of the surface impedance and the physical parameters of seven glass wool samples and six polyester fibre samples with flow resistivities between 4100 and 69,900 Pa s m−2 have been made. Comparisons of measured absorption coefficients and those predicted from the Johnson–Allard formulae using the measured and deduced physical parameters show discrepancies that exceed 20% for some samples and frequencies. By modifying the Johnson–Allard formula for effective density and by introducing a correction factor that is a function of flow resistivity based on data fitting, it has been found possible to improve the predictions. However, it has also been found that a similar modification of the formula for bulk modulus is necessary to reduce the discrepancies with data to below 5% in the frequency range between 800 Hz and 5 kHz. 相似文献
11.
M. Sanzharov J. Vander Auwera O. Pirali P. Roy J.-B. Brubach L. Manceron T. Gabard V. Boudon 《Journal of Quantitative Spectroscopy & Radiative Transfer》2012,113(15):1874-1886
Following our recent study devoted to measurements of intensities of pure rotation lines of methane, room temperature far infrared spectra of methane diluted in nitrogen at five total pressures between 100 and 800 hPa have been recorded at the AILES beamline of the SOLEIL synchrotron. One hundred and five N2 broadening coefficients of methane pure rotation lines have been measured in the 83–261 cm?1 spectral range using multi-spectrum non-linear least squares fitting of Voigt profiles. Pressure-induced line shifts were not needed to fit the spectra to the noise level and line mixing effects were neglected. One hundred and seventy-six self broadening coefficients have also been measured in the 59–288 cm?1 spectral range using the pure methane spectra recorded in our previous work. The measured N2 broadening coefficients were compared to semi-classical calculations. 相似文献
12.
《Journal of magnetism and magnetic materials》2001,233(3):131-135
A new lithium naphthalocyanine dye aggregate [Li2Nc][LiNc] is reported as a potential electron paramagnetic resonance (EPR) oximetry probe for accurate measurement of oxygen concentration in biological systems. The Li2Nc is diamagnetic; however, the LiNc molecule has an unpaired electron and hence is paramagnetic. The aggregate shows a strong and single line EPR signal that is non-saturating at normal EPR power levels. An oxygen-dependent peak-to-peak EPR spectral width ranging from 0.51 G (at pO2: 0 mmHg) to 26.2 G (at pO2: 760 mmHg) has been observed. The application of this probe has been demonstrated in the measurement of arterial and venous oxygen tensions in a rat. 相似文献
13.
A. Fayt A. Jolly Y. Benilan L. Manceron F. Kwabia-Tchana J.-C. Guillemin 《Journal of Quantitative Spectroscopy & Radiative Transfer》2012,113(11):1195-1219
The far infrared spectrum of cyanogen has been studied at high resolution to improve the rotational analysis of the ν5 band system around 234 cm?1. Present in the sample in natural abundances, both isotopologues N13CCN and 15NCCN have also been studied. The weak ν4–ν5 difference band centered at 270 cm?1 has been studied for the first time. On the basis of a global rovibrational analysis limited to the ν2, ν4, and ν5 modes, energy levels up to 2300 cm?1 have been considered to contribute to the overall spectrum intensity at room temperature leading to a new line list of 196,994 lines. The line intensity prediction has been used to correct previous line intensity measurements by taking into account line mixing. A new vibrational transition moment has been deduced and compared to new band intensity measurements obtained by low resolution studies which are also presented in this paper. The agreement between both approaches is very good and rules out the apparent disagreement between line intensity and band intensity measurements observed in the past. An intensity study of 15NCCN is also proposed here thanks to the availability of a pure sample. Those results open the way to the search for isotopologues of cyanogen in Titan's atmosphere. 相似文献
14.
Temperature history and distribution of steel workpiece (X20Cr13) was measured by a high tech infrared camera under ultrasonic assisted dry creep feed up grinding. For this purpose, a special experimental setup was designed and fabricated to vibrate only workpiece along two directions by a high power ultrasonic transducer. In this study, ultrasonic effects with respect to grinding parameters including depth of cut (ae), feed speed (vw), and cutting speed (vs) has been investigated. The results indicate that the ultrasonic vibration has considerable effect on reduction of temperature, depth of thermal damage of workpiece and width of temperature contours. Maximum temperature reduction of 25.91% was reported at condition of vs = 15 m/s, vw = 500 mm/min, ae = 0.4 mm in the presence of ultrasonic vibration. 相似文献
15.
A line tunable singly resonant noncritically phase matched narrow band width ZnGeP2 (ZGP) optical parametric oscillator pumped by the output idler radiation from a KTA OPO based on a 20 mm long KTA crystal pumped from a Q-switched Gaussian shaped Nd:YAG laser beam with a grating having grooves density 85 lines/mm has been demonstrated in the spectral ranges of 3–7 μm. The measured threshold of oscillation energy was 10 μJ. The conversion efficiency was 20.5% and slope efficiency of the ZGP OPO was 20% using a 23 mm long ZGP crystal at 26 mm cavity length. Line width of the generated infrared radiation from ZGP OPO was 37–60 nm. 相似文献
16.
《Journal of Physics and Chemistry of Solids》2007,68(5-6):855-860
A procedure has been developed to determine the reliable form of the glass-crystal transformation function, and to deduce the kinetic parameters by using differential scanning calorimetry data, obtained from experiments performed under non-isothermal conditions. It is an integral method, which is based on a transformation rate independent of the thermal history and expressed as the product of two separable functions of absolute temperature and the fraction transformed. Considering the same temperatures for the different heating rates, one obtains a constant value for temperature integral, and, therefore, a plot of a function of the volume fraction transformed versus the reciprocal of the heating rate leads to a straight line with an intercept of zero, if the reaction mechanism is correctly chosen. Besides, by using the first mean value theorem to approach the temperature integral, one obtains a relationship between a function of the temperature and other function of the volume fraction transformed. The logarithmic form of the quoted relationship leads to a straight line, whose slope and intercept allow to obtain the activation energy and the frequency factor. The method developed has been applied to the crystallization kinetics of the Sb0.12As0.36Se0.52 glassy alloy and it has been found that the kinetic model of normal grain growth is the most suitable to describe the crystallization of the quoted alloy. The mean values obtained for the activation energy and the frequency factor have been 27.36 kcal mol−1 and 1.5×109 s−1, respectively. 相似文献
17.
《Solid State Ionics》2006,177(9-10):869-875
The electrochemical reduction of molten Li–Na–K carbonates at 450 °C provides “quasi-spherical” carbon nanoparticles with size comprised between 40 and 80 nm (deduced from AFM measurements). XRD analyses performed after washing and heat-treatment at various temperatures have revealed the presence of graphitised and amorphous phases. The d002 values were close to the ideal one obtained for pure graphite. Raman spectroscopy has pointed out surface disordering which increases with increasing temperature of the heat-treatment. The presence of Na and Li on the surface of the carbon powder has been evidenced by SIMS. The maximum Na and Li contents were observed for carbon samples heat-treated at 400 °C. Their electrochemical performances vs. the insertion/deinsertion of lithium cations were studied in 1 M LiPF6–EC : DEC : DMC (2 : 1 : 2). The first charge–discharge cycle is characterised by a high irreversible capacity as in the case of hard-disordered carbon materials. However, the potential profile in galvanostatic mode is intermediate between that usually observed for graphite and amorphous carbon: rather continuous charge–discharge curves sloping between 1.5 and 0.3 V vs. Li / Li+, and successive phase transformations between 0.3 and 0.02 V vs. Li / Li+. The best electrochemical performances were obtained with carbon powders heat-treated at 400 °C which exhibits a reversible capacity value of 1080 mAh g− 1 (composition of Li2.9C6). This sample has also both the lowest surface disordering (deduced from Raman spectroscopy), and the highest Na and Li surface contents (deduced from SIMS). 相似文献
18.
W.A. Pisarski J. Pisarska R. Lisiecki W. Ryba-Romanowski 《Opto-Electronics Review》2017,25(3):238-241
Erbium-doped lead silicate glass has been investigated for near-infrared emission and up-conversion applications. Near-infrared emission due to 4I13/2 → 4I15/2 transition of Er3+ is relatively broad (70.5 nm) and long-lived (3.7 ms). Also, up-conversion luminescence spectra of Er3+ ions in lead silicate glass have been examined as a function of temperature. The relative intensities of luminescence bands corresponding to 2H11/2 → 4I15/2 and 4S3/2 → 4I15/2 transitions of Er3+ were determined with temperature. The fluorescence intensity ratio and temperature sensitivity were calculated. The maximum sensitivity for Er3+ doped lead silicate glass is close to 26.4 × 10?4 K?1 at T = 590 K. 相似文献
19.
《Current Applied Physics》2009,9(1):179-183
Temperature dependence of the photoluminescence (PL) transitions in the range of 10–300 K was studied for ZnO thin films grown on sapphire by pulsed laser deposition. The low temperature PL spectra were dominated by recombination of donor bound excitons (BX) and their phonon replicas. With increasing temperature, free exciton (FX) PL and the associated LO phonon replicas increased in intensity at the expense of their bound counterparts. The BX peak with line width of ∼6 meV at 10 K exhibited thermal activation energy of ∼17 meV, consistent with the exciton-defect binding energy. The separation between the FX and BX peak positions was found to reduce with increasing temperature, which was attributed to the transformation of BX into the shallower donor bound exciton complexes at consecutive lower energy states with increasing temperature, which are possible in ZnO. The energy separation between FX peak and its corresponding 1-LO phonon replica showed stronger dependence on temperature than that of 2-LO phonon replica. However, their bound counterparts did not exhibit this behavior. The observed temperature dependence of the energy separation between the free exciton and it is LO phonon replicas are explained by considering the kinetic energy of free exciton. The observed PL transitions and their temperature dependence are consistent with observations made with bulk ZnO crystals implying high crystalline and optical quality of the grown films. 相似文献
20.
The double-layered LaSr2Mn2O7 manganite was synthesized by the sol–gel process. Two samples with the average grain size from ~150 nm to ~1 μm were prepared by controlling the sintering temperature. Both samples had a tetragonal structure, with a small fraction of impurity phase in the S-1250 sample. In order to investigate the probable influence of grain size on the conduction mechanism, resistivity of the samples was measured as a function of temperature, and the data obtained was analyzed by different conduction mechanisms. It was found that with increase in the grain size, resistivity decreased at all temperature ranges. The results show that the adiabatic small polaron hopping (SPH) model is probably responsible for conduction at high temperature range, and that the 3D variable range hopping (VRH) model shows a better correlation with the experimental data for low temperature range. These analyses indicate the influence of grain size on the parameters obtained from fitting the data by both models. 相似文献