共查询到20条相似文献,搜索用时 15 毫秒
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Courtney Reichhardt 《Molecular physics》2014,112(7):887-894
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Electrochemical double-layer capacitors, or ‘supercapacitors’ are attracting increasing attention as high-power energy storage devices for a wide range of technological applications. These devices store charge through electrostatic interactions between liquid electrolyte ions and the surfaces of porous carbon electrodes. However, many aspects of the fundamental mechanism of supercapacitance are still not well understood, and there is a lack of experimental techniques which are capable of studying working devices. Recently, solid-state NMR has emerged as a powerful tool for studying the local environments and behaviour of electrolyte ions in supercapacitor electrodes. In this Trends article, we review these recent developments and applications. We first discuss the basic principles underlying the mechanism of supercapacitance, as well as the key NMR observables that are relevant to the study of supercapacitor electrodes. We then review some practical aspects of the study of working devices using ex situ and in situ methodologies and explain the key advances that these techniques have allowed on the study of supercapacitor charging mechanisms. NMR experiments have revealed that the pores of the carbon electrodes contain a significant number of electrolyte ions in the absence of any charging potential. This has important implications for the molecular mechanisms of supercapacitance, as charge can be stored by different ion adsorption/desorption processes. Crucially, we show how in situ NMR experiments can be used to quantitatively study and characterise the charging mechanism, with the experiments providing the most detailed picture of charge storage to date, offering the opportunity to design enhanced devices. Finally, an outlook for future directions for solid-state NMR in supercapacitor research is offered. 相似文献
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Heise H Köhler FH Xie X 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2001,150(2):198-206
The paramagnetic metallocenes and decamethylmetallocenes (C(5)H(5))(2)M and (C(5)Me(5))(2)M with M=V (S=3/2), Mn (S=5/2 or 1/2), Co (S=1/2), and Ni (S=1) were studied by (1)H and (13)C solid-state MAS NMR spectroscopy. Near room temperature spinning sideband manifolds cover ranges of up to 1100 and 3500 ppm, and isotropic signal shifts appear between -260 and 300 ppm and between -600 and 1640 ppm for (1)H and (13)C NMR spectra, respectively. The isotropic paramagnetic signal shifts, which are related to the spin densities in the s orbital of ligand atoms, were discussed. A Herzfeld--Berger spinning sideband analysis of the ring carbon signals yielded the principal values of the paramagnetic shift tensors, and for metallocenes with a small g-factor anisotropy the electron spin density in the ligand pi system was determined from the chemical shift anisotropy. The unusual features of the (1)H and (13)C solid-state NMR spectra of manganocene were related to its chain structure while temperature-dependent (1)H MAS NMR studies reflected antiferromagnetic interaction between the spin centers. 相似文献
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Todd A. Wagler William A. Daunch Matthew Panzner Wiley J. Youngs Peter L. Rinaldi 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2004,170(2):747-344
Solid-state (33)S MAS NMR spectra of a variety of inorganic sulfates have been obtained at magnetic field strengths of 4.7, 14.1, 17.6, and 18.8 T. Some of the difficulties associated with obtaining natural abundance (33)S NMR spectra have been overcome by using a high magnetic field strength and magic angle spinning (MAS). Multiple factors were considered when analyzing the spectral linewidths, including magnetic field inhomogeneity, dipolar coupling, chemical shift anisotropy, chemical shift dispersion, and quadrupolar coupling. In most of these sulfate samples, quadrupolar coupling was the dominant line broadening mechanism. Nuclear electric quadrupolar coupling constants (C(q)) as large as 2.05 MHz were calculated using spectral simulation software. Spectral information from these new data are compared with X-ray measurements and GAUSSIAN 98W calculations. A general correlation was observed between the magnitude of the C(q) and the increasing difference between S-O bond distances within the sulfate groups. Solid-state (33)S spin-lattice (T(1)) relaxation times were measured and show a significant reduction in T(1) for the hydrated sulfates. This is most likely the result of the modulation of the time-dependent electric field gradient at the nuclear site by motion of water molecules. This information will be useful in future efforts to use (33)S NMR in the compositional and structural analysis of sulfur containing materials. 相似文献
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《Composite Interfaces》2013,20(2):167-175
Rubber composites filled with carbon black and mica flakes were investigated by solid-state NMR and dynamic mechanical measurements. The results show that in rubber (butyl, EPDM, and chloroprene) and rubber composites filled with mica flakes there exists an interphase of considerable fraction with a different T1ρ value from the matrix. The hindered segmental motion in this interphase appears in the dynamic mechanical measurement with a high and broad tan δ and a high loss modulus E". The value of E" increases with increasing percentage of mica. 相似文献
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For the first time, 17O NMR studies were performed on 17O-enriched crystalline pyrophosphates (magnesium-, sodium- and barium-pyrophosphate) by means of triple-quantum magic-angle spinning (3QMAS) and double-rotation (DOR) in the high external field of 17.6 T. Oxygen atoms in bridging positions (P-OB-P) exhibit a significant higher quadrupole coupling constant compared to oxygen atoms in terminal positions (P-OT). With increasing cationic radius a higher value of the chemical shift of the terminal oxygen atoms is observed. 相似文献
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Wagler TA Daunch WA Panzner M Youngs WJ Rinaldi PL 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2004,170(2):336-344
Solid-state (33)S MAS NMR spectra of a variety of inorganic sulfates have been obtained at magnetic field strengths of 4.7, 14.1, 17.6, and 18.8 T. Some of the difficulties associated with obtaining natural abundance (33)S NMR spectra have been overcome by using a high magnetic field strength and magic angle spinning (MAS). Multiple factors were considered when analyzing the spectral linewidths, including magnetic field inhomogeneity, dipolar coupling, chemical shift anisotropy, chemical shift dispersion, and quadrupolar coupling. In most of these sulfate samples, quadrupolar coupling was the dominant line broadening mechanism. Nuclear electric quadrupolar coupling constants (C(q)) as large as 2.05 MHz were calculated using spectral simulation software. Spectral information from these new data are compared with X-ray measurements and GAUSSIAN 98W calculations. A general correlation was observed between the magnitude of the C(q) and the increasing difference between S-O bond distances within the sulfate groups. Solid-state (33)S spin-lattice (T(1)) relaxation times were measured and show a significant reduction in T(1) for the hydrated sulfates. This is most likely the result of the modulation of the time-dependent electric field gradient at the nuclear site by motion of water molecules. This information will be useful in future efforts to use (33)S NMR in the compositional and structural analysis of sulfur containing materials. 相似文献
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Tim W.T. Tsai Yao-Hung Tseng Jerry C.C. Chan 《Journal of Physics and Chemistry of Solids》2008,69(11):2628-2633
A series of binary borosilicate glasses prepared by the sol-gel method are shown to be bioactive. Tetraethyl orthosilicate (TEOS) and trimethylborate (TMB) in acidic medium are used to prepare xB2O3·(1−x)SiO2 glass systems for x=0.045-0.167. The formation of a layer of apatite-like mineral on the glass surface becomes apparent after soaking in simulated body fluid for 48 h. We have measured the 11B-11B homonuclear second moments of the borosilicate glasses and inferred that no macroscopic phase separation occurred in our glasses. The 11B chemical shift data also show that the formation of clustered boroxol rings is negligible in our glass system. Although the bioactivity of our borosilicate glasses is less than that of CaO-SiO2 sol-gel glasses, these simple binary systems could be taken as reference glass systems for the search of new bioactive borosilicate glasses. 相似文献
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Solid-state varible-temperature/magic angle spinning(VT/MAS) 1H NMR measurements were carried out on deuterated polyethylene. From these experimental results it was found that the 1H chemical shift induced by conformational and morphological changes of the polyethylene sample is within the linewidth of ≈ 0.5 ppm. Furthermore, from MAS/dipolar decoupling experiments it was found that the resonance frequency of the proton varies linearly with the inverse square of the deuterium decoupling power. This experimental finding is discussed theoretically. 相似文献
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Analytical methods based on solid-state NMR are becoming increasingly popular. However, these flourishing activities bring up the issue of how accurately NMR can assess an analyte proportion in a solid sample. The use of a chemical intensity reference for this purpose is a natural but often unsuitable choice, due to sample stability or preciousness. We propose here a protocol to perform quantitative measurements in solid-state NMR, by calibration of the circuit response through a low-power pulse injected during the acquisition (the so-called ERETIC method). Although this method has been in use for some time in liquid-phase and in vivo NMR, we point out here some peculiarities and useful applications typical of solids. Namely, the temperature dependence of the signal intensity imposes care in the application to MAS experiments. 相似文献
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Solid state NMR is the primary tool for studying the quantitative, site-specific structure, orientation, and dynamics of biomineralization proteins under biologically relevant conditions. Two calcium phosphate proteins, statherin (43 amino acids) and leucine rich amelogenin protein (LRAP; 59 amino acids), have been studied in depth and have different dynamic properties and 2D- and 3D-structural features. These differences make it difficult to extract design principles used in nature for building materials with properties such as high strength, unusual morphologies, or uncommon phases. Consequently, design principles needed for developing synthetic materials controlled by proteins are not clear. Many biomineralization proteins are much larger than statherin and LRAP, necessitating the study of larger biomineralization proteins. More recent studies of the significantly larger full-length amelogenin (180 residues) represent a significant step forward to ultimately investigate the full diversity of biomineralization proteins. Interactions of amino acids, a silaffin derived peptide, and the model LK peptide with silica are also being studied, along with qualitative studies of the organic matrices interacting with calcium carbonate. Dipolar recoupling techniques have formed the core of the quantitative studies, yet the need for isolated spin pairs makes this approach costly and time intensive. The use of multi-dimensional techniques to study biomineralization proteins is becoming more common, methodology which, despite its challenges with these difficult-to-study proteins, will continue to drive future advancements in this area. 相似文献
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Structural phase transition at 290 K and the implication on the intermediate phase above 290 K in powdered RbMnCl3 are observed by using a solid-state 87Rb NMR spectroscopy. Quadrupole coupling constants (e2qQ/h), the asymmetry parameters (η), and the relative peak intensities for two physically nonequivalent Rb sites, Rb(I) and Rb(II), are determined from nonlinear least-squares fits to the 87Rb NMR powder patterns in the temperature range from 260 to 330 K. Quadrupole coupling constants and the asymmetry parameters are examined for the detection of the phase transition resulting in a significant structural change in the Rb(II) site. In addition, changes in the relative peak intensity between the Rb(I) and Rb(II) sites seem to suggest the existence of an anomalous intermediate phase, which is complemented by the differential scanning calorimetry and X-ray diffraction studies. 相似文献