Muon trapping and diffusion in Al and In after electron irradiation at 9 K

The transverse spin relaxation of positive muons has been measured on an Al single crystal and on polycrystalline In after irradiation with 2 MeV electrons at 9 K or 11 K, sample transfer at 4.2 K, and various subsequent annealing treatments. The Al data are analysed in terms of diffusion-limited trapping by vacancies. This yields a muon diffusivityD _μ which within experimental accuracy is proportional toT between 4 K and 50 K, indicating that in this temperature intervalD _μ is dominated by one-phonon-assisted incoherent tunnelling. In In only very small effects due to the irradiation could be observed. The muons appear to be localized in octahedral interstices. From the motional averaging taking place above about 20 K the diffusivity ofD _μ in In is deduced.     

Effect of electron irradiation on creep and dislocation structure of aluminium

The effect of electron irradiation and strain on structure of technical-purity aluminium subjected to constant-load tensile creep tests was investigated. The dislocation structure was statistically analyzed. The effect of electron irradiation appears in the creep rate reduction and generation of radiation defect clusters, the density of which is approximately proportional to the dose. The effect on the dislocation distribution is dependent on the dose as well. Doses1·2×10¹⁷ cm^–2 speed up the formation of a polygonal structure characterizing the steady-state creep.     

Positron annihilation in alkali-halide crystals after electron irradiation

The effect of electron beam irradiation on the positron annihilation in KCl, KBr, NaCl single crystals was investigated. The narrowing of the angular correlation curves increases up to the saturation value with the absorbed radiation dose. The shape of the received narrow components differs from the narrow component measured in the additively colored samples. This phenomenon shows the considerable influence of the hole centres upon the positron annihilation in ionic crystals. Paper presented at 3rd Internat. Conf. Positron Annihilation, Otaniemi, Finland (August 1973).     

Restricted diffusion in grossly inhomogeneous fields

We analyze the effects of geometrical restriction on the nuclear magnetization of spins diffusing in grossly inhomogeneous fields where radio-frequency (RF) pulses are weak relative to the total field inhomogeneity, making the rotation angle space-dependent and thus exciting multiple coherence pathways. We show how to separate the effects of restricted diffusion from the effects of the pulses in the case when the change in the field experienced by a diffusing spin in the course of the experiment is small compared to the RF magnitude. We then derive explicit formulas for the contribution of individual coherence pathways to the total magnetization in arbitrary pulse sequences. We find that, for long diffusion times, restriction can dramatically alter the spectrum and the shape of a particular echo, while for short times, the correction will be proportional to the pore space surface-to-volume ratio. We demonstrate these results on the example of the early echoes of the Carr-Purcell-Meiboom-Gill (CPMG) pulse sequence.     

Athermal migration of vacancies in iron and copper induced by electron irradiation

Abstract

Irradiation with high-energy particles induces athermal migration of point defects, which affects defect reactions at low temperatures where thermal migration is negligible. We conducted molecular dynamics simulations of vacancy migration in iron and copper driven by recoil energies under electron irradiation in a high-voltage electron microscope. Minimum kinetic energy required for migration was about 0.8 and 1.0 eV in iron and copper at 20 K, which was slightly higher than the activation energy for vacancy migration. Around the minimum energy, the migration succeeded only when a first nearest neighbour (1NN) atom received the kinetic energy towards the vacancy. The migration was induced by higher kinetic energies even with larger deflection angles. Above several electron-volts and a few 10s of electron-volts, vacancies migrated directly to 2NN and 3NN sites, respectively. Vacancy migration had complicated directional dependence at higher kinetic energies through multiple collisions and replacement of atoms. The probability of vacancy migration increased with the kinetic energy and remained around 0.3–0.5 jumps per recoil event for 20–100 eV. At higher temperatures, thermal energies slightly increased the probability for kinetic energies less than 1.5 eV. The cross section of vacancy migration was 3040 and 2940 barns for 1NN atoms in iron and copper under irradiation with 1.25 MV electrons at 20 K: the previous result was overestimated by about five times.     

Restricted diffusion within a single pore

The time-dependent diffusion of 3Heatoms perpendicular to the axis of a single macroscopically large cylindrical pore is studied using a steady (or constant) gradient-recalled echo sequence. Measurements of the effective 3Hediffusion coefficient extending from the free-diffusion regime to the motionally averaged regime are presented, and are well-described by analytic solutions to the Bloch-Torrey equation based on the gaussian phase approximation. Our data yield the value 0.140(6)m2/s for the self diffusion coefficient of 3Heat a temperature of 296 K and a pressure of 1.00 Torr. Adaptations of these methods should enable the study of complex pore geometries as model systems.     

Low temperature thermal properties of crystalline quartz after electron irradiation

Measurements of the temperature specific heat (between 0.12K and 8K) and thermal conductivity (between 0.5K and 20K) of crystalline -quartz after electron irradiation are reported. In the temperature region below 1K the specific heat is larger than in the unirradiated sample. This can be attributed to low energy excitations which are created during irradiation and which are associated with Al impurities. The thermal conductivity is reduced after irradiation. Below 4K the additional thermal resistivity varies asT ^–1.5. The phonon scattering by radiation-induced excitations in -quartz is weak compared to phonon scattering by two level systems (TLS) in vitreous silica.     

Vacancy effects on one-dimensional migration of interstitial clusters in iron under electron irradiation at low temperatures

We performed in situ observation of one-dimensional (1D) migration of self-interstitial atom (SIA) clusters in iron under electron irradiation at 110–300 K using high-voltage electron microscopy. Most 1D migration was stepwise positional changes of SIA clusters at irregular time intervals at all temperatures. The frequency of 1D migration did not depend on the irradiation temperature. It was directly proportional to the damage rate, suggesting that 1D migration was induced by electron irradiation. In contrast, the 1D migration distance depended on the temperature: distribution of the distance ranged over 100 nm above 250 K, decreased steeply between 250 and 150 K and was less than 20 nm below 150 K. The distance was independent of the damage rate at all temperatures. Next, we examined fluctuation in the interaction energy between an SIA cluster and vacancies of random distribution at concentrations 10^?4–10^?2, using molecular statics simulations. The fluctuation was found to trap SIA clusters of 4 nm diameter at vacancy concentrations higher than 10^?3. We proposed that 1D migration was interrupted by impurity atoms at temperatures higher than 250 K, and by vacancies accumulated at high concentration under electron irradiation at low temperatures where vacancies are not thermally mobile.     

Defect production rates in electron irradiated aluminium

Abstract

The cross section for atomic displacement has been determined at 7.5°K by means of electrical resistivity measurements in electron irradiated aluminium up to transferred energies of 1100 eV. These data and those from the literature have been evaluated with respect to the displacement function (DF). Below 200 eV the DF could be derived from the data with sufficient accuracy by solving the integral equation which describes the displacement cross section. Above 200 eV a family of non-linear and linear DF's has been found which fits the data within the experimental error. From the linear DF's one obtains an average threshold energy of (62±6) eV according to Kinchin and Pease.     

Hot electron diffusion in CdTe

The longitudinal diffusion coefficient of electrons in CdTe has been measured with the time-of-flight technique at 300 K for field strength ranging from Ohmic values up to 60 kV/cm. The diffusion coefficient increases with increasing fields up to a maximum of 100 cm²/sec at E ≈ 15 kV/cm, that is at the threshold field for negative differential mobility, and then decreases. This behaviour, typical of Gunn effect materials, is in agreement with theoretical calculations and it is due to a first increase of electron mean energy followed by a dominant decrease of mobility.     

Hot electron diffusion in CdTe

The parallel and transverse components of diffusion constants of electrons in CdTe have been computed for fields of 30, 40, and 50 kV/cm using the Monte Carlo method. Results are presented for the velocity autocorrelation function and for the ac diffusion constants for two models of energy band structure and scattering constants, used earlier in the literature. The diffusion constants as obtained from the two models are significantly different, but none are in agreement with the available experimental results.     

Femtosecond laser-induced heating of electron gas in aluminium

The distribution function of free electrons in metal is calculated for irradiation of aluminium with an ultrashort laser pulse of moderate intensity. We consider inverse Bremsstrahlung absorption, electron-electron and electron-phonon interaction. Our theoretical model is based on Boltzmann equations and describes each considered process by a corresponding collision integral. The results show the excitation and relaxation of the free electron gas. Energy transfer to the phonon gas is calculated. Our model predicts linear absorption for intensities up to damage threshold. The calculated absorbed energy compares very well with known absorption characteristics.     

CEMS study on aluminium implanted iron

Up to now a great deal of investigations in ion beam mixing of iron-aluminium layers are known. However, the easier way to produce such layers by direct implantation of aluminium ions in iron is less studied. In the present work aluminium implanted iron layers are studied. Iron samples were implanted with aluminium ions at 50, 100, and 200 keV, respectively, with doses between 5×10¹⁶ and 5×10¹⁷ cm⁻². Independent of energy, at doses up to 2×10¹⁷ cm⁻², besides alpha iron further magnetic fractions with a Fe₃Al-like structure are formed while at a dose of 5×10¹⁷ cm⁻² amorphous nonmagnetic components are formed.     

Optical properties of polycrystalline alumina after irradiation with iron ions and annealing

Optical absorption of polycrystalline corundum (polycor) after irradiation with iron ions and subsequent annealing in vacuum was studied. It was found that substitutional, intrinsic radiation, biographical defects, and complexes on their basis have an effect on the absorption parameters and optical transitions between localized states and allowed bands. The contributions to changes in the optical properties of individual substitutional defects, their clusters, and complexes with the participation of substitutional defects and radiation defects were singled out. The influence of defects and iron oxides formed upon annealing on absorption was estimated. The most proable nature of clusters of substitutional defects and impurity-vacancy complexes was identified.     

Hyperfine interactions of iron implanted into aluminium

Stable⁵⁷Fe implanted into Al at energies of 20 to 70 keV and doses of 10¹⁴ to 2·10¹⁷ ions/cm² was studied with conversion electron Mössbauer spectroscopy at room and liquid nitrogen temperatures. Spectra composed of a single line and a doublet were observed. Similarly as in the splat-quenched FeAl alloys iron monomers and iron associations, mostly dimers, are observed. The isomer shifts of both components differ considerably and do not change with iron concentration. The splitting of the doublet increases with iron concentration, the increase being reproduced by computer simulations of electric field gradients in lattices with a random distribution of charge defects. The observed probability of formation of iron associates is higher than in random systems, especially at high iron doses.     

Diffusion in the aged aluminium film on iron

Metallic coatings of many types can be applied to steel to provide outstanding, long-term corrosion protection. A thin Al film is studied at an Fe substrate by the molecular dynamics method at temperatures ranging from 300 K to 1173 K. Al atoms are found to penetrate the Fe matrix at a temperature of 873 K. The potential energy of the system changes step-like at a temperature of 1173 K. At such temperature mean square atomic displacement significantly changes. The behaviors of the Al and Fe diffusion coefficients are mainly determined by the temperature dependence of the diffusion activation energy.     

Internal friction of electron irradiated cold-worked aluminium

Aggregation state of transparent solid ammonia, prepared by slow freezing at 193°K, was investigated by three different methods-radiolytical yields comparison for transparent and opaque samples, density measurements, and x-ray diffraction.

Contrary to the hypothesis of the glassy state of the transparent solid ammonia applied by the previous author, the crystal character of this solid has been proved.