Rheological characteristics of glass-fibre-filled polypropylene melts

The rheological properties of glass fibre-filled polypropylene melts have been investigated. A high pressure capillary rheometer has been used for the experimental study. The effect of shear rate, temperature, and fibre concentration on the melt viscosity and viscoelastic properties have been studied. An equation has been proposed to correlate the melt viscosity with shear rate, temperature and fibre content. A master curve relation on this basis has been brought out using the shift factora _T . a _T shift factor (=/ _r ) - A _i coefficients of the polynomical of eq. (1) (i = 0, 1, 2, ,n) - B constant in the AFE equation (eq. (2)) (Pa s) - B constant in eq. (3) - D extrudate diameter - d capillary diameter - activation energy at constant shear rate (kcal/mole) - E activation energy at constant shear stress (kcal/mole) - T melt temperature (K) - X fraction glass fibre by weight - shear rate (s^–1) - shear viscosity (Pa s) - normal stress coefficient (Pa s²) - ₁ – ₂ first normal-stress difference (Pa) - shear stress (Pa) - r at reference temperature     

Rheological models for gypsum plaster pastes

Shear stress and shear rate data obtained for gypsum plaster pastes were correlated by means of different rheological models. The pastes were prepared from a commercial calcium sulfate hemihydrate at various water/plaster ratios ranging from 100/150 to 100/190. The tests were performed at 25°C using a rotating coaxial cylinder viscosimeter. The measurements were accomplished by applying a step-wise decreasing shear rate sequence. Discrimination among the models was made: (1) on the basis of the fitting goodness; (2) by checking the physical meaning of the calculated parameters; (3) on the basis of the stability of the parameters and of their prediction capacity beyond the limits of the experimental data. In the light of above, the Casson model seemed to be most effective for application to gypsum plaster pastes. K Consistency - n Power-law index - N Number of experimental data - P Number of parameters - Shear rate (s^–1) - ₀ Viscosity (Pa · s) - _d Dispersing medium viscosity (Pa · s) - _p Plastic viscosity (Pa · s) - Viscosity at zero shear rate (Pa · s) - Viscosity at infinite shear rate (Pa · s) - [] Intrinsic viscosity - ² Variance - Shear stress (Pa) - ₀ Yield stress (Pa) - Solid volume fraction - _m Maximum solid volume fraction     

Application of a modified rotary rheometer to the investigation of slurries

A new technique for investigating some of the rheological properties of slurries is proposed. A commercial concentric cylinder viscometer was modified so that a continuous coaxial flow could be superimposed on the Couette flow; this eliminated the influence of sedimentation of the solid particles. The influence of the changed strain was measured and found to be small. Relations between the shear stress and shear rate, temperature, mass fraction of solids and particle size were determined for a coal-oil slurry. The power-law coefficients were calculated. The influence of solid particles on the power-law coefficientsk _m andn _m was determined and approximated by empirical equations. d particle size, mm (determined by sieve mesh) - average particle size, mm - D pipeline diameter, m - g mass fraction of coal in a mixture, i.e. mass of coal/mass of mixture - k power-law coefficient, Nsⁿ m^–2 - n power-law flow index - L length of pipeline, m - p pressure, Pa - r correlation coefficient - t temperature, °C - average flow velocity, ms^–1 - level of confidence - shear rate, s^–1 - µ viscosity, Pa s - shear stress, Pa - volume fraction of coal, i.e. volume of coal/volume of mixture - correction coefficient - L pure liquid - m mixture - i inner cylinder - e outer cylinder - r real (true) value - p performed in a rheometer - w at the wall of pipeline     

Rheological properties of reactive polymer melts.

A new method for describing the rheological properties of reactive polymer melts, which was presented in an earlier paper, is developed in more detail. In particular, a detailed derivation of the equation of a first-order rheometrical flow surface is given and a procedure for determining parameters and functions occurring in this equation is proposed. The experimental verification of the presented approach was carried out using our data for polyamide-6.Notation E Dimensionless reduced viscosity, eq. (34) - E ₀ Newtonian asymptote of the function (36) - E power-law asymptote of the function (36) - E _{= 1} the value ofE at = 1 - k degradation reaction rate constant, s^–1 - k ₁ rate constant of function (t), eq. (26), s^–1 - k ₂ rate constant of function (t), eq. (29), s^–1 - K(t) residence-time-dependent consistency factor, eq. (22) - M _w weight-average molecular weight - M _x x-th moment of the molecular weight distribution - R gas constant - S _x M _x /M _w - t residence time in molten state, s - t _j thej-th value oft, s - T temperature, K - % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xd9vqpe0x% c9q8qqaqFn0dXdir-xcvk9pIe9q8qqaq-xir-f0-yqaqVeLsFr0-vr% 0-vr0db8meaabaqaciGacaGaaeqabaWaaeaaeaaakeaaieGaceWFZo% Gbaiaaaaa!3B4E!\[\dot \gamma \] shear rate, s^–1 - _i thei-th value of , s^–1 - _r =1 the value of at = 1, s^–1 - ^* reduced shear rate, eq. (44), s^–1 - dimensionless reduced shear rate, eq. (35) - viscosity, Pa · s - shear-rate and residence-time dependent viscosity, Pa · s - zero-shear-rate degradation curve - degradation curve at - _{t0 (t)} zero-residence-time flow curve - Newtonian asymptote of the RFS - instantaneous flow curve - power-law asymptote of the RFS - _0,0 zero-shear-rate and zero-residence-time viscosity, Pa · s - _E=1 value of viscosity atE=1, Pa · s - ^* reduced viscosity, eq. (43), Pa · s - zero-residence-time rheological time constant, s - density, kg/m³ - (t),(t) residence time functions     

Laminar source flow between parallel porous disks with equal suction and injection

An analysis is presented for laminar source flow between parallel stationary porous disks with suction at one of the disks and equal injection at the other. The solution is in the form of an infinite series expansion about the solution at infinite radius, and is valid for all suction and injection rates. Expressions for the velocity, pressure, and shear stress are presented and the effect of the cross flow is discussed.Nomenclature a distance between disks - A, B, ..., J functions of R _w only - F static pressure - p dimensionless static pressure, p(a ²/ ²) - Q volumetric flow rate of the source - r radial coordinate - r dimensionless radial coordinate, r/a - R radial coordinate of a point in the flow region - R dimensionless radial coordinate of a point in the flow region, R - Re source Reynolds number, Q/2a - R _w wall Reynolds number, Va/ - reduced Reynolds number, Re/r ² - critical Reynolds number - velocity component in radial direction - u dimensionless velocity component in radial direction, a/ - average radial velocity, Q/2a - u dimensionless average radial velocity, Re/r - ratio of radial velocity to average radial velocity, u/u - velocity component in axial direction - v dimensionless velocity component in axial direction, v - V magnitude of suction or injection velocity - z axial coordinate - z dimensionless axial coordinate, z a - viscosity - density - kinematic viscosity, / - shear stress at lower disk - shear stress at upper disk - ₀ dimensionless shear stress at lower disk, - ₁ dimensionless shear stress at upper disk, - dimensionless stream function     

Slip flow of non-plasticized PVC compounds

Measurements on seven rigid PVC compounds were carried out with a slit rheometer working in combination with an injection moulding machine. Plastication of the compounds occurred in the screw of the plastication unit, which also forced the melt through the die with a controlled forward velocity. The rectangular slit had a length of 90 mm and a widthB of 20 mm. The heightH could be varied between 0.8 and 3.3 mm. Pressures and temperatures were recorded at several positions in and before the die. Measurements were carried out at shear rates from 10 to 2000 s^–1.When the reduced volume output was plotted against the wall shear stress _W , only four compounds showed master curves independent ofH, which is indicative of wall adhesion. In the other cases this plot did not produce such a master curve, but the plot of the mean velocity against _W was independent ofH (slip curve). This indicated that slip flow prevailed with a slip velocityv _G When, in the case of wall slip, the smooth inner surfaces of the die were replaced by surfaces with grooves perpendicular to the direction of flow, slip flow was prevented and the flow curves were shifted to much higher values of _Wc Above a critical value of the wall shear stress ( _Wc ) at which slip flow began, the output became nearly independent of _W . From the measurements made below _Wc a vs. relation for the shear flow could be derived, which was used to calculate the superimposed shear flow . Exact values of the slip velocity were then given by . Wall slip only occurred for compounds with a high shear viscosity, which corresponds to a high molecular weight (K-value).Dedicated to Professor H. Janeschitz-Kriegl on the occasion of his 60th birthday.     

Model analysis of nonlinear viscoelastic behaviour by use of a single integral constitutive equation: Stresses and birefringence of a polystyrene melt in intermittent shear flows

Summary A single integral constitutive equation with strain dependent and factorized memory function is applied to describe the time dependence of the shear stress, the primary normal-stress difference, and, by using the stress-optical law, also the extinction angle and flow birefringence of a polystyrene melt in intermittent shear flows. The theoretical predictions are compared with measurements. The nonlinearity of the viscoelastic behaviour which is represented by the so called damping function, is approximated by a single exponential function with one parametern. The damping constantn as well as a discrete relaxation time spectrum of the melt can be determined from the frequency dependence of the loss and storage moduli.

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Zusammenfassung Eine Zustandsgleichung vom Integraltyp mit einer deformationsabhängigen und faktorisierten Gedächtnisfunktion wird zur Beschreibung der Zeitabhängigkeit der Schubspannung, der ersten Normalspannungsdifferenz und, unter Verwendung des spannungsoptischen Gesetzes, auch des Auslöschungswinkels und der Strömungsdoppelbrechung einer Polystyrol-Schmelze bei Scherströmungen herangezogen. Die theoretischen Voraussagen werden mit Messungen verglichen. Die Nichtlinearität des viskoelastischen Verhaltens, repräsentiert durch die sogenannte Dämpfungsfunktion, wird durch eine einfache Exponentialfunktion mit nur einem Parametern angenähert. Die Dämpfungskonstanten kann, wie auch ein diskretes Relaxationszeitspektrum der Schmelze, aus der Frequenzabhängigkeit der Speicher- und Verlustmoduln bestimmt werden.

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a _i weight factor of thei-th relaxation time - a _T shift factor - C stress-optical coefficient - n flow birefringence in the shear flow plane - shear relaxation modulus - G() shear storage modulus - () shear loss modulus - H() relaxation time spectrum - h( _t,t ² ) damping function - M _w weight-average molecular weight - M _n number-average molecular weight - n damping constant - p ₁₂ shear stress - p ₁₁ –p ₂₂ primary normal stress difference - t current time - t past time - extinction angle - ( — _i) delta function - time and shear rate dependent viscosity - | ^*| absolute value of the complex viscosity - shear rate - _t,t relative shear strain between the statest andt - memory function - angular frequency - relaxation time - _i i-th relaxation time of the line spectrum - time and shear rate dependent primary normal stress coefficient - s steady-state value - t time dependence - ° linear viscoelastic behaviour With 6 figures and 1 table     

Heat transfer between gas-liquid spray stream flowing perpendicularly to the row of the cylinders

Experimental investigation and analysis of heat transfer process between a gas-liquid spray flow and the row of smooth cylinders placed in the surface perpendicular to the flow has been performed. Among others, there was taken into account in the analysis the phenomenon of droplets bouncing and omitting the cylinder as well as the phenomenon of the evaporation process from the liquid film surface.In the experiments test cylinders were used, which were placed between two other cylinders standing in the row.From the experiments and the analysis the conclusion can be drawn that the heat transfer coefficients values for a row of the cylinders are higher than for a single cylinder placed in the gasliquid spray flow.

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Wärmeübergang an eine senkrecht anf eine Zylinderreihe auftreffende Gas-Flüssigkeits-Sprüh-Strömung

Zusammenfassung Es wurden Messungen und theoretische Analysen des Wärmeübergangs zwischen einer Gas-FlüssigkeitsSprüh-Strömung und den glatten Oberflächen einer Zylinderreihe durchgeführt, die senkrecht zum Sprühstrahl angeordnet waren. Dabei wurde in der Analyse unter anderem das Phänomen betrachtet, daß die Tropfen die Zylinderwand treffen und verfehlen können und daß sich ein Verdampfungsprozeß aus dem flüssigen Film an der Zylinderoberfläche einstellt.Gemessen wurde an einem zwischen zwei Randzylindern befindlichen Zylinder.Die Experimente und die Analyse gestatten die Schlußfolgerung, daß der Wärmeübergangskoeffizient für eine Zylinderreihe höher ist als für einen einzelnen Zylinder in der Sprühströmung.

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Nomenclature a distance between axes of cylinders, m - c _l specific heat capacity of liquid, J/kg K - c _g specific heat capacity of gas, J/kg K - D cylinder diameter, m - g _l mass velocity of liquid, kg/m²s - ¯k average volume ratio of liquid entering film to amount of liquid directed at the cylinder in gas-liquid spray flow, dimensionless - k() local volume ratio of liquid entering film to amount of liquid directed at the cylinder in gas-liquid spray flow, dimensionless - L specific latent heat of vaporisation, J/kg - m mass fraction of water in gas-liquid spray flow, dimensionless - M constant in Eq. (9) - p pressure, Pa - p _g statical pressure of gas, Pa - p _w pressure of gas on the cylinder surface, Pa - p external pressure on the liquid film surface, Pa - r cylindrical coordinate, m - R radius of cylinder, m - T temperature, K, °C - T _l, t_l liquid temperature in the gas-liquid spray, K, °C - T _w,t_w temperature of cylinder surface, K, °C - T temperature of gas-liquid film interface, K - U liquid film velocity, m/s - w gas velocity on cylinder surface, m/s - w _g gas velocity in free stream, m/s - W _l liquid vapour mass ratio in free stream, dimensionless - W liquid vapour mass ratio at the edge of a liquid film, dimensionless - x coordinate, m - y coordinate, m - z complex variable, dimensionless - average heat transfer coefficient, W/m²K - local heat transfer coefficient, W/m² K - average heat transfer coefficient between cylinder surface and gas, W/m² K - _g, local heat transfer coefficient between cylinder surface and gas, W/m² K - mass transfer coefficient, kg/m²s - liquid film thickness, m - _lg dynamic diffusion coefficient of liquid vapour in gas, kg/m s - pressure distribution function on a cylinder surface - function defined by Eq. (3) - _l liquid dynamic viscosity, kg/m s - _g gas dynamic viscosity, kg/m s - cylindrical coordinate, rad, deg - _l thermal conductivity of liquid, W/m K - _g thermal conductivity of gas, W/m K - mass transfer driving force, dimensionless - _l density of liquid, kg/m³ - _g density of gas, kg/m³ - _w shear stress on the cylinder surface, N/m² - _w shear stress exerted by gas at the liquid film surface, N/m² - air relative humidity, dimensionless - T -T _w - _w =T _wT_l Dimensionless parameters I= enhancement factor of heat transfer - m ^*=M _l/M_g molar mass of liquid to the molar mass of gas ratio - Nu _g= D/ _g gas Nusselt number - Pr _g=c _{g g}/_g gas Prandtl number - Pr _l=c_lll liquid Prandtl number - ¯r=(r–R)/ dimensionless coordinate - Re _g=w_gD _g/_g gas Reynolds number - Re _g,max=w_g,max D _g/_g gas Reynolds number calculated for the maximal gas velocity between the cylinders - Sc=m ^* _g/_l–g Schmidt number =/R dimensionless film thickness     

Non-isothermal flow of polymer melts in a curved tube

The results of a numerical study (using finite differences) of heat transfer in polymer melt flow is presented. The rheological behaviour of the melt is described by a temperature-dependent power-law model. The curved tube wall is assumed to be at constant temperature. Convective and viscous dissipation terms are included in the energy equation. Velocity, temperature and viscosity profiles, Nusselt numbers, bulk temperatures, etc. are presented for a variety of flow conditions. Br — Brinkman number - c specific heat, J/kg K - De — Dean number - E dimensionless apparent viscosity, eq. (14d) - G dimensionless shear rate, eq. (19) - k parameter of the power-law model, °C^–1, eq. (7) - mass flow rate, kg/s - m ₀ parameter of the power-law model, Pa · s ⁿ , eq. (7) - n parameter of the power-law model, eq. (7) - Nu 2r _p/ — Nusselt number, eqs. (28,31) - p pressure, Pa - Pe — Péclet number - P —(p/)/r _c — pressure gradient, Pa/m - dissipated energy, W, eq. (29) - total energy, W, eq. (30) - r radial coordinate, m - r _c radius of tube-curvature, m, fig. 1 - r _p radius of tube, m, fig. 1 - r _t variable, m, eq. (6) - R dimensionless radial coordinate, eq. (14a) - R _c dimensionlessr _c, eq. (14a) - R _t dimensionlessr _t, eq. (14a) - t temperature, °C - bulk temperature, °C, eq. (27) - t ₀ inlet temperature of the melt, °C - t _w tube wall temperature, °C - T dimensionless temperature, eq. (14c) - T _w dimensionless tube wall temperature - T dimensionless bulk temperature - u ₁ variable, s^–1, eq. (4) - u ₂ variable, s^–1, eq. (5) - U ₁ dimensionlessu ₁, eq. (18) - U ₂ dimensionlessu ₂, eq. (18) - v velocity in-direction, m/s - average velocity of the melt, m/s - V dimensionlessv, eq. (14b) - dimensionless , eq. (15) - z r _c — centre length of the tube, m - Z dimensionlessz, eq. (14e) - heat transfer coefficient, W/m² K - shear rate, s^–1, eq. (8) - — shear rate, s^–1 - apparent viscosity, Pa · s, eq. (7) - ₀ — apparent viscosity, Pa · s - angular coordinate, rad, fig. 1 - thermal conductivity, W/m K - melt density, kg/m³ - axial coordinate, rad, fig. 1 - rate of strain tensor, s^–1, eq. (8) - (—p) pressure drop, Pa     

Viscoelastic properties of pathological synovial fluids for a wide range of oscillatory shear rates and frequencies

Summary A series of pathological synovial fluids are examined for viscoelastic properties in oscillatory shear flow at frequencies of physiological significance. When tested at varying amplitudes of shear at a frequency of 2 Hertz, the fluids show marked nonlinearity for shear rates above 10 sec^–1, the elastic component of the shear stress truncating in the range from 1 to 10 dynes/cm². At low shear rates, the fluids are linear and viscoelastic and have frequency dispersions matching the character of Gaussian chain theory for polymer solutions. Enzymatic degradation of the hyaluronate destroys the viscoelasticity, leaving a Newtonian fluid of relatively low viscosity. The concentration and molecular weight of the hyaluronate produce substantial intermolecular interaction. The relaxation times, viscosity, and elasticity of the synovial fluids are greatly increased over values expected for noninteracting molecules of hyaluronic acid in solution. While both the viscosity and elasticity vary greatly among the pathological fluids, the elasticity is the more sensitive indicator of viscoelastic properties.

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Zusammenfassung Es wird eine Serie pathologischer Synovialflüssigkeiten bezüglich ihrer viskoelastischen Eigenschaften in einer oszillatorischen Scherströmung mit physiologisch signifikanten Frequenzen untersucht. Bei einer Frequenz von 2 Hz zeigen die Flüssigkeiten eine ausgeprägte Nichtlinearität, wenn ein rms-Wert von 10 s^–1 überschritten wird: Die elastische Komponente der Schubspannung flacht im Bereich von 1–10 dyn/cm² ab. Bei niedrigen Schergeschwindigkeiten verhalten sich die Flüssigkeiten dagegen linear-viskoelastisch, und ihre Frequenzabhängigkeit läßt sich durch die Theorie der Gaußschen Netzwerk-Lösungen beschreiben. Enzymatischer Abbau des Hyaluronats zerstört die Viskoelastizität, so daß eine newtonsche Flüssigkeit mit relativ niedriger Viskosität übrig bleibt. Infolge seiner Konzentration und seines Molekulargewichts unterliegt das Hyaluronat einer erheblichen intermolekularen Wechselwirkung. Relaxationszeiten, Viskosität und Elastizität zeigen erheblich größere Werte, als sie für nicht in Wechselwirkung stehende Hyaluronsäure-Moleküle in Lösung zu erwarten wären. Obgleich bei den verschiedenen pathologischen Flüssigkeiten sowohl die Viskosität als auch die Elastizität stark schwanken, stellt sich doch die Elastizität als der von den viskoelastischen Eigenschaften empfindlichere Indikator heraus.

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List of Symbol a Tube radius (cm) - b Gaussian chain segment length (cm) - c _m Mass concentration (g/cm³) - f Frequency (Hz) - G ^* Complex shear rigidity (dynes/cm²) - h ^* Hydrodynamic interaction factor for the Gaussian chain theory - k Boltzmann's constant (ergs/deg) - M Molecular weight - N Number of Gaussian subchain segments - N _a Avogadro's number - P ^* Pressure gradient, complex form (dynes/cm³) - P, P Real and imaginary parts ofP ^* (dynes/cm³) - t Time (sec) - T Absolute temperature (K) - u Volume rate of flow (cm³/sec) - Shear rate, instantaneous value (sec^–1) - Shear rate, amplitude (sec^–1) - Critical shear rate for onset of nonlinearity (sec^–1) - _p Eigenvalue,p-th value - ^* Complex coefficient of viscosity (P) - _v Viscosity, real part of ^* (P) - _E Elasticity, imaginary part of ^* (P) - ₀ Limiting viscosity at zero frequency (P) - _s Viscosity of solvent (P) - Limiting viscosity at infinite frequency (P) - []₀ Intrinsic viscosity at zero frequency (cm³/g) - Phase angle between shear rate and shear stress (rad) - (/f) Gaussian chain theory parameter - Shear stress, instantaneous value (dynes/cm²) - _M Shear stress, amplitude (dynes/cm²) - ^* Shear stress, complex form (dynes/cm²) - _v Viscous component of the shear stress (dynes/cm²) - _E Elastic component of the shear stress (dynes/cm²) - _p Relaxation time,p-th value (sec) - ₁ Terminal (longest) relaxation time (sec) - Radian frequency (rad/sec) With 7 figures and 3 tables     

A three-parameter model describing the experimental relation between shear stress and shear rate for laminar flow of aqueous polymer solutions

Summary A three-parameter model is introduced to describe the shear rate — shear stress relation for dilute aqueous solutions of polyacrylamide (Separan AP-30) or polyethylenoxide (Polyox WSR-301) in the concentration range 50 wppm – 10,000 wppm. Solutions of both polymers show for a similar rheological behaviour. This behaviour can be described by an equation having three parameters i.e. zero-shear viscosity ₀, infinite-shear viscosity , and yield stress ₀, each depending on the polymer concentration. A good agreement is found between the values calculated with this three-parameter model and the experimental results obtained with a cone-and-plate rheogoniometer and those determined with a capillary-tube rheometer.

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Zusammenfassung Der Zusammenhang zwischen Schubspannung und Schergeschwindigkeit von strukturviskosen Flüssigkeiten wird durch ein Modell mit drei Parametern beschrieben. Mit verdünnten wäßrigen Polyacrylamid-(Separan AP-30) sowie Polyäthylenoxidlösungen (Polyox WSR-301) wird das Modell experimentell geprüft. Beide Polymerlösungen zeigen im untersuchten Schergeschwindigkeitsbereich von ein ähnliches rheologisches Verhalten. Dieses Verhalten kann mit drei konzentrationsabhängigen Größen, nämlich einer Null-Viskosität ₀, einer Grenz-Viskosität und einer Fließgrenze ₀ beschrieben werden. Die Ergebnisse von Experimenten mit einem Kegel-Platte-Rheogoniometer sowie einem Kapillarviskosimeter sind in guter Übereinstimmung mit den Werten, die mit dem Drei-Parameter-Modell berechnet worden sind.

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a Pa^–1 physical quantity defined by:a = {1 – ( / ₀)}/ ₀ - c l concentration (wppm) - D m capillary diameter - L m length of capillary tube - P Pa pressure drop - R m radius of capillary tube - u m s^–1 average velocity - v _r m s^–1 local axial velocity at a distancer from the axis of the tube - shear rate (–dv _r /dr) - local shear rate in capillary flow - s^–1 wall shear rate in capillary flow - Pa s dynamic viscosity - _a Pa s apparent viscosity defined by eq. [2] - ( _a ) Pa s apparent viscosity in capillary tube at a distanceR from the axis - ₀ Pa s zero-shear viscosity defined by eq. [4] - Pa s infinite-shear viscosity defined by eq. [5] - l ratior/R - kg m^– density - Pa shear stress - ₀ Pa yield stress - _r Pa local shear stress in capillary flow - _R Pa wall shear stress in capillary flow _R = (PR/2L) - _v m³ s^–1 volume rate of flow With 8 figures and 1 table     

Transport in ordered and disordered porous media II: Generalized volume averaging

In this paper we develop the averaged form of the Stokes equations in terms of weighting functions. The analysis clearly indicates at what point one must choose a media-specific weighting function in order to achieve spatially smoothed transport equations. The form of the weighting function that produces the cellular average is derived, and some important geometrical theorems are presented.Roman Letters A interfacial area of the- interface associated with the local closure problem, m² - A _e area of entrances and exits for the-phase contained within the averaging system, m² - A _p surface area of a particle, m² - d _p 6V _p/A_p, effective particle diameter, m - g gravity vector, m/s² - I unit tensor - K _m permeability tensor for the weighted average form of Darcy's law, m² - L general characteristic length for volume averaged quantities, m - L _p general characteristic length for volume averaged pressure, m - L characteristic length for the porosity, m - L _v characteristic length for the volume averaged velocity, m - l characteristic length (pore scale) for the-phase - l _i i=1, 2, 3 lattice vectors, m - (y) weighting function - m(–y) (y), convolution product weighting function - _v special weighting function associated with the traditional averaging volume - m _v special convolution product weighting function associated with the traditional averaging volume - m _g general convolution product weighting function - m _V unit cell convolution product weighting function - m _C special convolution product weighting function for ordered media which produces the cellular average - m _D special convolution product weighting function for disordered media - m _M master convolution product weighting function for ordered and disordered media - n unit normal vector pointing from the-phase toward the-phase - p pressure in the-phase, N/m² - p_m superficial weighted average pressure, N/m² - p _m intrinsic weighted average pressure, N/m² - p traditional intrinsic volume averaged pressure, N/m² - p p p _m , spatial deviation pressure, N/m² - r ₀ radius of a spherical averaging volume, m - r _m support of the convolution product weighting function, m - r position vector, m - r position vector locating points in the-phase, m - V averaging volume, m³ - V volume of the-phase contained in the averaging volume, m³ - V _cell volume of a unit cell, m³ - V velocity vector in the-phase, m/s - vm superficial weighted average velocity, m/s - v _m intrinsic weighted average velocity, m/s - V volume of the-phase contained in the averaging volume, m³ - V _p volume of a particle, m³ - v traditional superficial volume averaged velocity, m/s - v v p _m spatial deviation velocity, m/s - x position vector locating the centroid of the averaging volume or the convolution product weighting function, m - y position vector relative to the centroid, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V /V, volume average porosity - _m m * . weighted average porosity - mass density of the-phase, kg/m³ - viscosity of the-phase, Ns/m² - V /V, volume fraction of the-phase     

An analytical solution for the temperature profiles during injection molding,including dissipation effects

An analytical solution is obtained for the stationary temperature profile in a polymeric melt flowing into a cold cavity, which also takes into account viscous heating effects. The solution is valid for the injection stage of the molding process. Although the analytical solution is only possible after making several (at first sight) rather stringent assumptions, the calculated temperature field turns out to give a fair agreement with a numerical, more realistic approach. Approximate functions were derived for both the dissipation-independent and the dissipation-dependent parts which greatly facilitate the temperature calculations. In particular, a closed-form expression is derived for the position where the maximum temperature occurs and for the thickness of the solidified layer.The expression for the temperature field is a special case of the solution of the diffusion equation with variable coefficients and a source term.Nomenclature a thermal diffusivity [m²/s] - c specific heat [J/kg K] - D channel half-height [m] - L channel length [m] - m 1/ - P pressure [Pa] - T temperature [°C] - T _W wall temperature [°C] - T _i injection temperature [°C] - T _A Br independent part of T - T _B Br dependent part of T - T ^core asymptotic temperature - v _z() axial velocity [m/s] - W channel width [m] - x cross-channel direction [m] - z axial coordinate [m] - (x) gamma function - (a, x) incomplete gamma function - M(a, b, x) Kummer function - small parameter - () temperature function - thermal conductivity [W/mK] - viscosity [Pa · s] - ₀ consistency index - power-law exponent - density [kg/m] - similarity variable Dimensionless variables Br Brinkman number - Gz Graetz number -      

Elastohydrodynamic lubrication in a plane slider bearing

Summary The present work deals with the case of a two-dimensional slider bearing with a rigid pad and an elastic bearing. Fluid viscosity is assumed to be only a pressure function. We determined the bearing deformation, the pressure distribution and the load capacity at different values of the inclination angle of the slider, with a numerical integration of the system consisting of the elasticity and Reynolds equations. The results show that, with an iso-viscous fluid, bearing elasticity causes a load capacity decrease. Instead bearing elasticity together with the variation of fluid viscosity due to pressure causes a load capacity greater than that of the iso-viscous case (=0).

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Sommario Il presente lavoro studia il problema della coppia prismatica lubrificata con pattino rigido di allungamento infinito e cuscinetto deformabile; si suppone che la viscosità del fluido sia funzione della sola pressione. Il sistema di equazioni, costituito dall'equazione di Reynolds e dall'equazione dell'elasticità, è stato risolto numericamente, determinando la deformazione del cuscinetto, andamento della pressione e la capacità di carico per diversi valori dell'inclinazione del pattino. I risultati dimostrano che, con fluido isoviscoso, la deformabilità del cuscinetto determina una riduzione della capacità di carico. Se si considera, invece, effetto combinato dell'elasticità del cuscinetto e della variazione della viscosità del fluido, la capacità di carico risulta maggiore di quella che si ottiene con fluido isoviscoso (=0).

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Nomenclature /L - /L - x/L - x/L - - ¯C CZ/h ₁ - E elasticity modulus - h film thickness - H elastic deformation of the bearing - h ₁ minimum film thickness - h ₂ inlet thickness - inclination of the pad - h Z/h ₁ - HZ/h ₁ - L pad length - viscosity - ₀ viscosity with no over-pressure - p over pressure - p P _ec-P _rc where:ec=elastic caserc=rigid case - P h ₁ ² /6₀VL - h ₂/h ₁=1+L/h ₁ - FV bearing velocity - W load capacity per unit width - Wh ₂ ¹ /6₀ VL ² - Z E h ₃ ¹ /12 ₀ VL ² A first version of this paper was presented at the 7th National AIMETA congress, held at Trieste, October 2–5, 1984. This work was supported by C.N.R.     

A three-parameter model describing the behaviour of a viscoelastic liquid in a tangential annular flow

A three-parameter model describing the shear rate-shear stress relation of viscoelastic liquids and in which each parameter has a physical significance, is applied to a tangential annular flow in order to calculate the velocity profile and the shear rate distribution. Experiments were carried out with a 5000 wppm aqueous solution of polyacrylamide and different types of rheometers. In a shear-rate range of seven decades (5 10^–3 s^–1 < < 1.2 10⁵ s^–1) a good agreement is obtained between apparent viscosities calculated with our model and those measured with three different types of rheometers, i.e. Couette rheometers, a cone-and-plate rheogoniometer and a capillary tube rheometer. a physical quantity defined by:a = {1 – ( / ₀)}/ ₀ (Pa^–1) - C constant of integration (1) - r distancer from the center (m) - r ₁,r ₂ radius of the inner and outer cylinder (m) - v _r local tangential velocity at a distancer from the center (v _r = _r r) (m s^–1) - v ₂ local tangential velocity at a distancer ₂ from the center (m s^–1) - shear rate (s^–1) - local shear rate (s^–1) - ₁ wall shear rate at the inner cylinder (s^–1) - dynamic viscosity (Pa s) - _a apparent viscosity (_a = / ) (Pa s) - _a1 apparent viscosity at the inner cylinder (Pa s) - ₀ zero-shear viscosity (Pa s) - infinite-shear viscosity (Pa s) - shear stress (Pa) - _r local shear stress at a distancer from the center (Pa) - ₀ yield stress (Pa) - ₁, ₂ wall shear-stress at the inner and outer cylinder (Pa) - _r local angular velocity (s^–1) - ₂ angular velocity of the outer cylinder (s^–1)     

Viscous heating and heat transfer in cone-and-plate rheogoniometry

Summary At higher shear rates the relation between shear stress and shear rate appears to deviate from the for Newtonian fluids expected linear behaviour. In cone-and-plate rheogoniometry one of the most important causes of that is the effect of viscous heating. Accurate measurements carried out with a 10 cm diameter cone and plate lead to a semi-logarithmic, linear relationship between temperature increase and time for a Newtonian oil which dynamic viscosity varies approximately linearly with time. A simple model based on a heat balance describes this behaviour quantitatively.

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Zusammenfassung Bei newtonschen Flüssigkeiten weisen die Experimente eine Abweichung vom linearen Zusammenhang zwischen Schubspannung und Schergeschwindigkeit auf. Im Kegel-Platte-Meßsystem ist die Wärmeproduktion durch innere Reibung die wichtigste Ursache der Abweichung. Bei newtonschen Flüssigkeiten, deren dynamische Viskosität sich ungefähr linear mit der Temperatur verändert, ergeben sorgfältig ausgeführte Messungen mit einem Kegel von 10 cm Durchmesser einen linearen Zusammenhang zwischen der Zeit und dem Logarithmus der Temperaturzunahme. Ein aus der Wärmebilanz abgeleitetes Modell vermag dieses Verhalten quantitativ zu beschreiben.

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Symbols A platen surface (m²) - B viscosity constant from eq. [1] (Pa s K^–1) - S _B standard deviation ofB (Pa s K^–1) - S _t0 standard deviation oft ₀ (s) - S _t0 standard deviation oft ₀ (s) - S ₀ standard deviation of ₀ (Pa s) - t time (s) - t ₀ time def. by eq. [5] (s) - t ₀ time def. by eq. [11] (s) - T temperature (°C) - T ₀ temperature of the surrounding air (°C) - T highest experimental temperature (°C) - V volume of the fluid between the platen (m³) - W heat capacity of the system (J K^–1) - heat transfer coefficient (W m^–2 K^–1) - shear rate (s^–1) - dynamic viscosity (Pa s) - ₀ dynamic viscosity atT ₀ (Pa s) - dimensionless temperature def. by eq. [4a] (–) - dimensionless time def. by eq. [4b] (–) - dimensionless time def. by eq. [10] (–) With 4 figures and 2 tables     

Memory effects during the flow of thixotropic fluids in pipes

Summary The paper presents the phenomenon of thioxotropy from the point of view of the theory of fluids with fading memory. In the first part of the paper the mechanism of thixotropy was discussed in order to justify the application of the concept of structural parameter (this parameter occurs in the previously presented rheological model of thixotropic materials). In the second part of the paper an equation was derived, which enables the prediction of the mean value of the friction factor during the flow of a thixotropic fluid in a pipe. According to the obtained equation the friction factor is a function of three dimensionless numbers: the generalized Reynolds number, a modified Deborah number and a new dimensionless number which may be called a structural number. The preliminary experimental results confirmed the applicability of the obtained equation.

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Zusammenfassung Die Veröffentlichung behandelt das Phänomen der Thixotropie vom Standpunkt der Theorie der Flüssigkeiten mit schwindendem Gedächtnis. Im ersten Teil wird der Mechanismus der Thixotropie untersucht und die Einführung eines sog. Strukturparameters begründet (dieser Parameter kommt bereits in dem früher behandelten rheologischen Modell eines thixotropen Körpers vor). Im zweiten Teil wird dann eine Formel abgeleitet, welche die Voraussage des mittleren Wertes des Widerstandskoeffizienten bei der Strömung einer thixotropen Flüssigkeit durch ein Rohr ermöglicht. Dieser Formel gemäß ist der Widerstandskoeffizient eine Funktion von drei dimensionslosen Zahlen: einer verallgemeinerten Reynolds-Zahl, einer modifizierten Deborah-Zahl und einer neuen dimensionslosen Zahl, die als Struktur-Kennzahl bezeichnet werden kann. Die vorläufigen Versuchsergebnisse bestätigen die Brauchbarkeit der abgeleiteten Formel.

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a rheological parameter in eq. [1], s^–1 - A rheological parameter in eq. [1]; function defined in eq. [15] - b rheological parameter in eq. [1] - B constant in eq. [15] - c rheological parameter in eq. [4] - c function defined in eq. [4] - C function defined in eq. [48] (see also eq. [43]) - D pipe diameter,m - K ₁,K₂ coefficients of proportionality in eq. [6] - k rheological parameter in eq. [12], Nsⁿ/m² - k ^* rheological parameter in eq. [1], Ns^m/m² - L pipe length, m - m rheological parameter in eq. [1] - n rheological parameter in eq. [12] - N number of particles in unit volume - p pressure, Pa - p ₀ pressure at the pipe entrance, Pa - r radial coordinate, m - R pipe radius, m - s rheological parameter in eq. [1] - t time, s - u _z axial local velocity in the pipe, m/s - v mean linear velocity in the pipe, m/s - z axial coordinate, m - rheological parameter in eq. [5], = 1 s - shear rate, s^–1 - nominal shear rate defined by eq. [39], s^–1 - structural parameter - substantial derivative of structural parameter, s^–1 - _e equilibrium structural parameter in eqs. [2] and [5] - _en nominal structural parameter - ₀ initial value of structural parameter - function of natural time - mean value of natural time, s - shear stress, Pa - ₀ shear stress field atZ = 0 (at pipe entrance) - _y0 equilibrium yield stress, Pa - shear stress field atz - fluid density, kg/m³ - v number of bonds in an average aggregate - mean value of the friction factor - De modified Deborah number defined by eq. [46] - Re generalized Reynolds number defined by eq. [45] - Se structural number defined by eq. [41a] With 4 figures and 1 table     

Polypropylene and polyethylene blends

Summary The flow behaviour of blends of an isotactic polypropylene (PP) and a high density polyethylene (PE) in the molten state was studied as a function of composition, temperature and shear rate to examine the degree of compatibility under shear. PP and PE were melt blended in a laboratory single screw mixing extruder at the compositions 0, 25, 50, 75 and 100 percentage of PE by weight and shear stress versus shear rate data were obtained using an Instron capillary viscometer at different temperatures. Viscosity-shear rate data of PP-PE blends at different temperatures constitute master curves at constant blend composition, when plotted as /₀ versus ₀/T. This type of behaviour is commenly observed for homopolymer systems. Therefore these experimental findings indicate that the PP-PE system forms either a compatible blend in the molten state under shear flow conditions or a morphology which is independent of temperature.

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Zusammenfassung Es wurde das Fließverhalten von Mischungen eines isotaktischen Polypropylens (PP) und eines Polyäthylens mit hoher Dichte (PE) im Schmelzzustand untersucht in Abhängigkeit von der Zusammensetzung, der Temperatur und der Schergeschwindigkeit. Damit sollte der Grad der Kompatibilität unter Scherbeanspruchung geprüft werden. PP und PE wurden in einem Labor-Einschnecken-Misch-Extruder mit Anteilen von 0, 25, 50, 75 und 100 Gewichts-Prozent PE zusammengemischt. Die Fließkurven wurden bei verschiedenen Temperaturen in einem Instron-Kapillar-Rheometer gemessen. Die Viskositätsverläufe als Funktion der Schergeschwindigkeit bei verschiedenen Temperaturen lassen sich bei konstantem Mischungsverhältnis zu Masterkurven zusammenfassen, wenn man /₀ gegen ₀/T aufträgt. Dieses Verhalten findet man gewöhnlich nur für Homopolymerisate. Daher zeigen diese experimentellen Ergebnisse an, daß die PP-PE-Systeme im Schmelzzustand unter der Bedingung des Scherfließens entweder eine kompatible Mischung bilden oder aber eine temperaturunabhängige Morphologie aufweisen.

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In partial fulfilment of the Teknisk Licentiate degree (Ph.D.).

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With 11 figures and 3 tables     

An experimental study of the lateral migration of a droplet in a creeping flow

The distribution of droplets in a plane Hagen-Poiseuille flow of dilute suspensions has been measured by a special LDA technique. This method assumes a well defined relation between the velocity of the droplets and their lateral position in the channel. The measurements have shown that the droplet distribution is non-uniform and depends on the viscosity ratio between the droplets and the carrier liquid. The results have been compared with a theory by Chan and Leal describing the lateral migration of suspended droplets.List of symbols a particle radius, m - d half width of the channel, m - Re flow Reynolds number, = 2 _m · d · /µ - flow velocity, m/s - _m flow velocity at the channel axis, m/s - We Weber number, = 2 _m ^Emphasis>/2 · d · / - x distance from center line (x = 0) of the channel, m - non-dimensional distance from the channel center line, _x ^d - y distance along the channel (y = 0 at channel inlet), m - non-dimensional distance along the channel, = y/2d - non-dimensional, normalized distance along the channel, = · _m · µ/ - interfacial tension, N/m - viscosity ratio of dispersed (droplet) phase to viscosity of continuous phase - µ viscosity of continuous phase, Pa · s - density of continuous phase, kg/m³ - phase density difference, kg/m³ Experiments were performed at Max-Planck-Institut, Göttingen     

The effect of non-steady wall shear on pressure surges in conduits carrying viscous liquids

Summary A study is made of the attenuation of pressure surges in a two-dimension a channel carrying a viscous liquid when a valve at the downstream end is suddenly closed. The analysis differs from previous work in this area by taking into account the transient nature of the wall shear, which in the past has been assumed as equivalent to that existing in steady flow. For large values of the frictional resistance parameter the transient wall shear analysis results in less attenuation than given by the steady wall shear assumption.Nomenclature c /, ft/sec - e base of natural logarithms - F(x, y) integration function, equation (38) - (x) mean value of F(x, y) - g local acceleration of gravity, ft/sec² - h width of conduit, ft - k (2m–1)^{2 2} L/h ² c, equation (35) - k* 12L/h ² c, frictional resistance parameter, equation (46) - L length of conduit, ft - m positive integer - n positive integer - p pressure, lb/ft² - p ₀ constant pressure at inlet of conduit, lb/ft² - P pressure plus elevation head, p+gz, equation (4) - mean value of P over the conduit width h - P ₀ p ₀+gz ₀, lbs/ft² - R frictional resistance coefficient for steady state wall shear, lb sec/ft⁴ - s positive integer; also, condensation, equation (6) - t time, sec - t ct/L, dimensionless time - u x component of fluid velocity, ft/sec - u _m mean velocity in conduit, equation (12), ft/sec - u ₀(y) velocity profile in Poiseuille flow, equation (19), ft/sec - transformed velocity - U initial mean velocity in conduit - x distance along conduit, measured from valve (fig. 1), ft - x x/L, dimensionless distance - y distance normal to conduit wall (fig. 1), ft - y y/h, equation (25) - z elevation, measured from arbitrary datum, ft - z ₀ elevation of constant pressure source, ft - isothermal bulk compression modulus, lbs/ft² - _n , equation (37) - _n (2n–1)/2, equation (36) - viscosity, slugs/ft sec - / = kinematic viscosity, ft²/sec - density of fluid, slugs/ft³ - ₀ density of undisturbed fluid, slugs/ft³ - ø angle between conduit and vertical (fig. 1) The research upon which this paper is based was supported by a grant from the National Science Foundation.