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1 INTRODUCTION In recent years, the rational design and synthesisof metal-directed supramolecular frameworks throughintermolecular hydrogen bonds, π-π stacking interac-tion or other weak interactions have received muchattention because of their interesting molecular topo-logies and various potential applications in catalysis,superconductor, magnetism, nonlinear optics, sen-sors and molecular recognition[1~4]. On the otherhand, the attachment of mono- or polypyridyl frag-ments to a ferr… 相似文献
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1 INTRODUCTION Supramolecular chemistry of manganese(II) car- boxylate coordination polymers has been inten- sively studied in recent years, within which ligand design is an important aspect in adjusting the coordi- nation framework and functionalities of the complexes formed[1~4]. Carboxyphenoxyacetic acids (CPOAH2), which have been known to show biological activities and are widely used in agriculture, are a family of multidentate flexible ligands with versatile binding abilities. … 相似文献
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1 INTRODUCTION During the last decade the manganese che- mistry has aroused great interest due to its diverse redox functions of enzymes in photosystem Ⅱ and its specially structural, magnetic and spectroscopic properties[1, 2]. A lot of manganese complexes involving carboxylate ligands have been reported, and their properties been fully explored[3, 4]. The coordination environment of the manganese site in biosystem often consists of oxygen and nitrogen atoms from the carboxylate groups… 相似文献
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Ju Tao LIU Xiao Hong WANG Jing Fu LIU Faculty of Chemistry Northeast Normal University Changchun 《中国化学快报》2004,15(7):859-862
A novel vanadate decamer, involving all vanadium atoms present in +5 oxidation and one formhydroxamic acid dimer cation readical, has been synthesized. The single-crystal X-ray diffraction shows that the orange crystal is formed in the triclinic system, space group Pi, a = 8. 4960 (17), b = 10.447 (2), c = 11.299 (2) A, α= 68. 82 (3)°,β= 87.35 (3)°, γ = 66.97(3)°. V = 855. 3(3) A3, Z = 8, R1 = 0. 0857, wR2=0. 2551. X-ray crystallographic and packing in superlattice studies showed that the crystal structure was constructed by electrostatic attraction of O-H…O hydrogen bonds between formhydroxamic acid dimer cation and decavanadate polyanion. Formhydroxamic acid dimer is got through controlling the condition of the reaction using formhydroxamic acid. 相似文献
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1 INTRODUCTION The investigation of coordination polymers has rapidly been expanded in last decade owing to their potential applications such as catalysis, molecular absorption, non-linear and magnetic materials. Among the varieties of such coordination polymers, the po- lymers of cadmium with dicarboxylates having fas- cinating structural topologies and good photolumi- nescence constitute a new family. Many reports are concerned about cadmium dicarboxylate polymers with 1D helix structu… 相似文献
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The title compound [Mn(DPMT)2Cl2(H2O)2] (DPMT = 1-[[2-(2,4-dichlorophenyl)- 1,3-dioxolan-2-yl]methyl]-1H-1,2,4-triazole) was synthesized by the reaction of MnCl2·4H2O and DPMT in ethanol solution and its structure was determined by single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P21/c with a = 23.913(4), b = 7.8883(13), c = 8.6291(14) , β = 95.816(3)o, V = 1619.4(5) 3, Z = 2, C24H26Cl6MnN6O6, Mr = 762.15, Dc = 1.563 g/cm3, μ = 0.950 mm-1, S = 1.045, F(000) = 774, R = 0.0462 and wR = 0.0981. The molecular structure is a centrosymmetric conformation, and two ligands are symmetrically located on both sides of the Mn atom. The manganese atom is surrounded by two nitrogen atoms from ligands, two chlorine atoms and two oxygen atoms from water molecules to form a slightly distorted octahedral geometry. 相似文献
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A novel three-dimensional(3-D) compound [Cd4(SeO3)2Cl4(H2O)]n(1) was prepared from a hydrothermal reaction and structurally characterized.Compound 1 crystallizes in the space group Fmmm of the orthorhombic system with eight formula units in a cell:a = 15.5165(4),b = 17.5090(9),c = 7.3318(5) ,V = 1991.9(2) 3,Cd4Cl4H2O7Se2,Mr = 863.38,Dc = 5.758 g/cm3,S = 1.075,μ(MoKα) = 16.820 mm-1,F(000) = 3088,R = 0.0427 and wR = 0.1220.Compound 1 features a 3-D structure with the cadmium atoms having two different coordination environments,i.e.,six-and eight-coordination geometries.Two different chain-like structures of cadmium-oxo polyhedra are interconnect to each other to give a 2-D layer of [Cd4(SeO3)2(H2O)]n4n+.Between the [Cd4(SeO3)2(H2O)]n4n+ layers is a novel chloride layer.A 3-D framework is constructed from these [Cd4(SeO3)2(H2O)]n4n+ layers linked by the chloride layers. 相似文献
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ZHAO Qi-Huaa MA Yong-Pingb WANG Qing-Huab FANG Rui-Binb a 《结构化学》2002,21(5):513-516
1 INTRODUCTION Cadmium (Ⅱ) complexes have been exten- sively studied from both chemical and structural views, mainly due to the capability of cadmium (Ⅱ) (shared by most d10 metal ions) to adopt different modes of coordination determined by the consideration of size, as well as electrostatic and covalent bonding forces[1]. And the field of coordination polymers has witnessed tremendous growth over the last decade[2]. Many coordination polymeric networks have been shown to posses intere… 相似文献
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MA Dong-sheng GAO Shan ** HUO Li-hua GAO Jin-sheng ZHAO Jin-gui College of Chemistry Chemical Engineering Heilongjiang University Harbin P. R. China 《高等学校化学研究》2005,21(1):104-108
Complex VO(C10H9NO3)(C13H10NO2)(C10H9NO2-3=N-salicylidene-L-alaninate, C13H10NO-2=N-phenylbenzohydroxamate) was synthesized and characterized by means of elemental analysis, IR, UV, 1H NMR spectroscopies, cyclic voltammetry and single crystal X-ray diffraction. The complex crystallized in a monoclinic system with space group P21 and crystal cell parameters a=0.9720(1) nm, b=1.8274(2) nm, c=1.2542(1) nm, β=104.868(9)°, V=2.1532(4) nm3, Mr=470.34, Z=2. The two oxygen atoms and the one nitrogen atom of the tridentate Schiff base ligand and the one oxime oxygen atom of the hydroxamate ligand coordinate to the vanadium atom, forming an equatorial plane, the two axial positions are respectively occupied by the oxygen atom of the oxovanadium and the carbonyl oxygen atom of the hydroxamate and the vanadium atom exhibits a distorted octahedral VO(ONO)(OO) coordination sphere. The 1H NMR spectrum suggests that the two isomers, endo and exo in a molar ratio of 1/1.7, coexist in the solution of the title complex in CDCl3. There exists a quasi-reversible one-electron redox reaction corresponding to VⅤ/VⅥ couple in the three non-aqueous solvents, and the redox potential E1/2 of the title complex substantially shifts in the direction of the positive voltage increase in the order: CH2Cl2<CH3CN<DMF. 相似文献
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A novel Mn(Ⅱ)complex Mn2(phen)2(p-MBA)4(H2O)has been hydrothermally synthesized by the reaction of P-methyl benzoic acid(p-MBA)with 1,10-phenanthroline(phen).Crystal data for this complex:monoclinic,space group C2/c,a=2.3328(3),b=1.5549(2),c=1.5557(2)nm,β=121.726(2)°,V=4.7997(11)nm3,Mr=1028.85,Dc=1.424 g/cm3,Z=4,F(000)=2128,μ(MoKa)=0.590mm-1,GOOF=1.060,R=0.0333 and wR=0.0767.In the crystal,each Mn(Ⅱ)ion is coordinated by two nitrogen atoms from one o-phenanthroline molecule.three oxygen atoms from three P-methyl benzoic acids and one oxygen atom from one water molecule,giving a six-coordinate distorted octahedral coordination geometry.Two neighboring Mn(Ⅱ)ions are bridged by two P-methyl benzoic acid groups and one water molecule,and their end positions are respectively coordinated by one 1,10-phenanthroline and one p-methyl benzoic acid molecule,giving a binuclear cage structure,of which the Mn(Ⅱ)…Mn(Ⅱ)distance is 0.3502 nm. 相似文献
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配合物[Mn(2,2''-bipy)(H2O)4]·(m-phth)的水热合成和晶体结构 总被引:1,自引:1,他引:1
A mononuclear manganese complex [Mn(2,2'-bipy)(H2O)4]·(m-phth) (2,2'-bipy=2,2'-bipyridine, m-phth=isophthalate) has been synthesized by hydrothermal methods. The crystal structure was determined by singlecrystal X-ray diffraction. The crystal is of orthorhombic, space group Pnna with a=0.766 8(8) nm, b =2.050 2(2)0.027 0, R=0.028 0 and wR=0.075 5. In the crystal the manganese atom is six-coordinated by two nitrogen atoms from 2,2'-bipyradine and four oxygen atoms from water molecules, completing an octahedral coordination geometry. The isophthalate molecules are included in the lattice and connected to Mn(2,2'-bipy)(H2O)4 by hydrogen bonding interactions to form a three-dimensional supramolecular structure. CCDC:286965. 相似文献
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1 INTRODUCTION Coordination polymers[1~3] with one-, two- or three-dimensional structure and supramolecular compounds[4, 5] formed by weak interactions, such as hydrogen bonds, Van Der Waals’ forces, short-range exclusion forces, etc., have a variety of possible applications ranging from semicon- ductor to catalysts and potentially valuable pro- perties reminiscent of zeolites. So, considerable increasing attention has been focused on the syn- thesis or building of these coordination po… 相似文献
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<正>A three-dimensional coordination polymer {[Cd_2(HCAM)_2(H_2O)_4]·3.5H_2O}_n was synthesized by the hydrothermal reaction of H_3CAM(H_3CAM=4-hydroxypyridine-2,6-dicerboxylic acid)and Cd(NO_3)_2·4H_2O.The structure was characterized by elemental analysis,thermal gravimetric analysis,infrared spectroscopy and single-crystal X-ray diffraction.It crystallizes in triclinic,space group P_1~-with a= 9.4389(19),b=11.009(2),c=11.192(2)(?),α=87.87(3),β= 74.63(3),γ=81.22(3)°,V=1108.2(4)(?)~3,Z=2,D_c=2.164g/cm~3,μ=2.011 mm~(-1),F(000)=710,R =0.0419 and wR=0.1170.X-ray analysis reveals that the title compound adopts a one-dimensional staircase structure by carboxyl of H_3CAM and water molecules,and it is further linked by hydrogen bonds to form a 3-D metal-organic open framework.The thermal gravimetric analysis displays that the framework exists stably below 300℃. 相似文献
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A novel coordination polymer [Eu2(C6H8O4)3(H2O)2]n·n(4,4’-bpy) (Mr = 928.51) was synthesized by the hydrothermal reaction of EuCl3·6H2O, adipic acid and 4,4’-bpy, and determined by elemental analysis, IR spectroscopy, thermal gravimetric analysis, single-crystal diffraction and fluorescence property. X-ray analysis reveals that a three-dimensional network has been formed between Eu3+ by carboxyl of adipic acid. The crystal is of orthorhombic, space group Pbcn with a = 21.870(7), b = 7.652(2), c = 19.624(6) (A), V = 3284.1(17)(A)3, Z = 4, Dc = 1.878 g/cm3, μ = 3.854 mm-1, F(000) = 1824, R = 0.0345 and wR = 0.0565. The coordination polymer exhibits intensive red light under UV excitation at room temperature, which is attributed to the 5D0→7F2 transition of Eu(Ⅲ) ions. 相似文献
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利用Na2MoO4·2H2O,MoO3,乙二胺,和H2O通过水热合成法合成了一维锯齿状化合物[(en)2(Mo6O20H4)]n.晶体解析表明,该化合物属于单斜晶系,P21/n空间群,a=0.80680(16)nm,b=1.4371(3)nm,c=0.88874(18)nm,β=97.89(3)°,V=1.0207(4)nm3,Z=2,Dc=3.305Mg·m-3,μ=3.681mm-1,F(000)=960.该化合物结构单元由二个游离的乙二胺分子和一个阴离子Mo6O4-20阴离子中,六20构成.在Mo6O4-个钼原子和八个相邻的氧原子构成两个八员环,在每个八员环的两侧分别存在着一个与三个钼原子相连的桥氧. 相似文献
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1 INTRODUCTION Metal organophosphonates have attracted considerable attention for over three decades due to their potential or practical applications, include- ing ion exchanges[1, 2], molecular sensors[3] and optics[4, 5]. Recently, a number of porous m… 相似文献
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A metal-organic coordination polymer [Cd2(PDC)2(bix)(H2O)2]n ·nH2O(H2PDC=2,4-pyridinedicarboxylic acid, bix=1,4-bis(imidazol-1-ylmethyl)-benzene) 1 has been hydrothermally synthesized and characterized by elemental analysis, IR, TG, fluorescence spectrum and single-crystal X-ray diffraction. Brown crystals crystallize in the orthorhombic system, space group P2 12 12 1 with a=11.741(3), b=14.190(4), c=18.963(5) , V=3159.4(14) 3 , C28H26Cd2N6O11, Mr=847.35, Dc=1.781 g/cm3 , F(000)=1680, Z=4, μ(MoKα)=1.415 mm 1 , the final R=0.0381 and wR=0.0882 for 5472 observed reflections (I >2σ(I)). The structure of 1 exhibits a threedimensional network structure. 相似文献
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杂多化合物在催化、医药、材料及光化学等方面具有广泛的应用前景 [1~ 4 ] ,其中钼磷多金属氧酸盐具有优异的氧化催化性能 [5,6 ] .近年来合成的新奇结构的钼磷多金属氧酸盐中已测定结构的有含帽[7,8] 和非帽[9~ 12 ] 系列 .本文利用水热法合成了未见文献报道的结构新颖的夹心型磷钼多金属氧酸盐[( CH3CH2 ) 4N]4 H3O{Na[( HMo2 O5) 3( HPO4 ) ( H2 PO4 ) 3]2 }· ( H2 PO4 ) 2 · 1 0 H2 O,并测定了其晶体结构 .1 实验与晶体结构分析1 .1 仪器与试剂 元素 Na用美国原子吸收分光光度计测定 ;C,H和 N用 Perkin- Elmer 2 4 0… 相似文献
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LI Yu-Mei CHE Yun-Xia② ZHENG Ji-Min 《结构化学》2006,25(5):572-576
1 INTRODUCTION The development of supramolecular and coordina- tion polymer complexes has recently attracted consi- derable attention due to the fundamental interest in self-assembly processes of transition-metal comple- xes, supramolecular chemistry and crystal enginee- ring[1~12]. The rational design of molecular architec- tures is essential for the creation of functional ma- terials with selective clathration[13, 14], molecular re- cognition[15, 16], catalysis[17, 18] and storage materi… 相似文献