Statistical mechanism of the formation of the energy spectra of sputtered molecular clusters

The energy spectra of Si _n O _m ^? clusters sputtered from Si targets by Xe⁺ ions with O₂ pumping onto a bombarded surface, as well as by O ₂ ⁺ ions, are studied. It is shown that the form of the Si _n O _2n+1 ^? energy distributions does not depend on the experimental conditions. Significant differences in the energy spectra of O and Si monomers as compared to Si _n O _2n+1 ^? clusters are revealed. The mentioned features of the energy distribution of Si _n O _m ^? clusters are explained within the framework of the statistical recombination mechanism of their formation in combinatorial synthesis processes.     

Absolute cross sections of electron attachment to molecular clusters: Part I. Formation of (CO2) N −

A procedure of determining absolute cross section σ^? of electron attachment to (CO₂)_N clusters at pair collisions in crossed beams is suggested. The cross section is measured as a function of energy (E = 0.1–50 eV) and of cluster mean size N in a beam $(\bar N = 2 - 4000 molecules)$ . It is found that, even at $\bar N > 200$ and E ≤ 3 eV, σ^? is equal to, or larger than, 7 × 10^?13 cm², i.e., by more than one order of magnitude exceeds the maximal cross section of CO₂ ionization by electron impact. The dependences σ^? $(\bar N,E)$ have two wide continua at E ≤ 5.2 eV and E ≥ 6.9 eV, which correlate well with known functions of CO₂ electron-impact-induced excitation. These continua are attributed largely to formation of (CO₂) _N ^? ions during electron thermalization and solvation in the clusters. At E → 0, the polarization capture of an incident electron by the cluster leads to a sharp increase in cross section σ^?(E). From the dependences σ^? $(\bar N,E)$ measured, the thermalization and sovation probabilities for electrons with E ≤ 0.8 eV and the rate of electron energy loss in the cluster are found.     

Production and loss of N 2 + , Ne+ and Ne 2 + during the decay period of plasmas produced in neon-nitrogen mixtures

Studies of the time dependencies of the number density of N ₂ ⁺ , Ne⁺ and Ne ₂ ⁺ ions have been made during the decay period of plasmas produced in neon containing various concentrations of nitrogen molecules. Reaction rate constants were obtained for N ₂ ⁺ +N₂+Ne→N ₄ ⁺ +Ne((1.2±0.2)×10^?29 cm⁶ sec^?1) and Ne⁺+N₂→N ₂ ⁺ + Ne ((2.9±0.3) × 10^?12 cm³ sec^?1). The ambipolar diffusion coefficient of N ₂ ⁺ in neon was found to beD _a p _o =350±20 cm² sec^?1 Torr.     

Investigating the dissociation energies of niobium and vanadium oxide clusters synthesized by ion sputtering

The mass distributions and fragmentation routes of Nb _n O _m ⁺ and V _n N _m ⁺ clusters sputtered from an metal surfaces with Xe⁺ ions under O₂ pressure of P = 4?5 × 10^?3 Pa in a bombardment chamber are studied by means of secondary ion mass spectrometry. The spectra of kinetic energy release distribution (KERD) are measured for the most probable routes of the fragmentation of Nb _n O _m ⁺ and V _n N _m ⁺ and clusters, on the basis of which the activation energies of the decomposition (dissociation) of Nb _n O _m ⁺ and V _n N _m ⁺ clusters are determined within the model of evaporative ensemble and the theory of monomolecular reactions. The results show the closeness of the numerical values of dissociation energies derived using both models.     

Low energy π-π resonances in the Veneziano model

We attempt to impose elastic unitarity on the forward π-π scattering using the Veneziano Amplitude together with a crossing symmetric subtraction term as an input. TheN/D method is used and thep, ? mesons are interpreted as CDD poles. The self consistency requirement led to the evalutation of the low energy parameters and theS andP-wave phase shifts. The values of the scattering lengths obtained area ₀ ⁰ =0.084m _π ^?1 ,a ₂ ⁰ =?0.024m _π ^?1 ,a ₁ ¹ =0.047m _π ^?3 .     

Correlation femtoscopy of Kaons in the SELEX experiment

Preliminary results from the correlation femtoscopy of identical kaons in the SELEX experiment (Fermilab E781) are presented. Kaons are selected in inclusive reactions of Σ^?C(Cu) interactions at an initial energy of 610 GeV. Kaon pairs are studied in all possible charged states: K _s ⁰ K _s ⁰ , K _s ⁰ K⁺, K _s ⁰ K^?, K⁺K⁺, K⁺K^? and K^?K^?. The source sizes of the hadronization region of neutral and charged kaon pairs are measured.     

Pulse ENDOR studies on the radical pair P 700 +· A 1 ·− and the photoaccumulated quinone acceptor A 1 ·− of photosystem I

The secondary acceptor A₁ of the electron transport chain(s) of photosystem (PS) I is a phylloquinone (vitamin K₁, VK₁). Pulse electron paramagnetic resonance and electron nuclear double resonance (ENDOR) experiments at X-band frequencies were performed on the photoaccumulated acceptor radical A ₁ ^·? and the radical pair state P ₇₀₀ ^·+ A ₁ ^·? in PS I ofThermosynechococcus elongatus. The data obtained were compared with data from the respective radical anion of VK₁ in organic solvents. The unusualg tensor magnitude of A ₁ ^·? is explained by the hydrophobic binding pocket of this radical. The hyperfine couplings and the spin (and charge) density distribution is very different for A ₁ ^.? in PS I and VK ₁ ^·? in frozen alcoholic solution. This is attributed to a rather strong one-sided hydrogen bond to A ₁ ^·? . The presence of a hydrogen bond to A ₁ ^·? has only a minor effect ong. The hyperfine coupling constants of A ₁ ^·? determined from the radical pair spectra deviate only slightly from those derived from photoaccumulated A ₁ ^·? in PS I treated with dithionite at high pH. ENDOR resonances of the proton in a H bond were detected and an estimate of the strength and geometry of this bond to A ₁ ^·? was obtained. The significance of the hydrogen bond and other (hydrophobic) interactions of A₁ with the surrounding are briefly discussed.     

Decay energy of183Re→183W

The electron capture decay energy of¹⁸³Re has been determined from the fraction ofK-capture in the transition to the 453.08 keV level in¹⁸³W by delayed coincidences. From this value the total decay energy from₁₈₃Re→¹⁸³W is obtained to beQ=555 _?7 ⁺⁹ keV according to the theory ofBrysk andRose with corrections ofBahcall. The resulting logft values and consequences for the decay scheme are discussed.     

Evidence for a 3.6 minute isomeric 12− state of the πh 11 2/−1 vi 13 2/−1 configuration in206Tl and effective two-particle interactions

Using the²⁰⁴Hg(α, pn)-reaction andα-particles of energies 39–55 MeV, we have found an isomeric 3.6 min 12^? state in²⁰⁶Tl at 2,642.9 keV which has the two-hole configurationπh ₁₁ ^2/?1 vi ₁₃ ^2/?1 The 12^? state decays mainly by anE5 transition of energy 1,021.4 keV to a 7⁺ state at 1,621.5 keV whose main configuration isπs ₁ ^2/?1 vi ₁₃ ^2/?1 There is, in addition, evidence for a weak 565 keVM 4 branch to an 8⁺ state at 2,078 keV whose main configuration should beπh ₁₁ ^2/?1 vf ₅ ^2/?1 . The 7⁺ state decays by a stretched cascade ofγ-rays to states of the following values ofJ ^π and excitation energy: 5 _? ⁺ , 1,405.4 keV; 4^?, 952.1 keV; 2^?, 265.8 keV and 0^?, 0 keV. The main configurations of these states areπh ₁₁ ^2/?1 vp ₁ ^2/?1 ,πd ₃ ^2/?1 vf ₅ ^2/?1 ,πd ₃ ^2/?1 vp ₁ ^2/?1 andπs ₁ ^2/?1 vp ₁ ^2/?1 respectively. From the nuclear masses of²⁰⁸Pb,²⁰⁷Pb,²⁰⁷Tl, and²⁰⁶Tl and the experimental excitation energies it is possible to obtain the proton hole-neutron hole interaction in²⁰⁶Tl. This interaction is compared with the calculations of Kuo and Herling and the discrepancies are discussed. The 12^?→8⁺ M4 transition rate is reduced because of destructive interference between the protonh _11/2→d _3/2 and the neutroni _13/2→f _5/2 contributions. The magnitude of the reduction is accurately reproduced by the wave functions of Kuo and Herling. The 12^?→7⁺ E5 transition rate is about twice as large as the single-holeπh ₁₁ ^2/?1 πs ₁ ^2/?1 transition rate. This deviation is fully explained by the configuration admixtures in the 7⁺ state, given by Kuo and Herling.     

High spin shell model excitations in149Gd

The high spin level structure of the three-neutron nucleus¹⁴⁹Gd has been investigated by in-beamγ-ray and electron spectroscopy with (α, xn) reactions. The observed levels are characterized as members of the shell model multipletsνf ₇ ^2/3 ,νh _9/2 f ₇ ^2/2 ,νf ₇ ^2/3 ×3^?,νh _9/2 f ₇ ^2/2 ×3^?, and tentativelyνf ₇ ^2/3 ×(3^?)². The energies of theν f ₇ ^2/3 states agree only moderately with those calculated using empirical two-nucleon interactions taken from¹⁴⁸Gd, which indicates the importance of long range contributions already atN=85.     

Fragmentation processes of vanadium and niobium oxide clusters sputtered by ion bombardment

The mass distribution of emitted V _n O _m ^? and Nb _n O _m ^? clusters and their unimolecular decay by all stoichiometrically possible fragmentation channels, which takes place under the sputtering of niobium and vanadium surfaces and blowing by oxygen, are studied. It is shown that the formation, excitation, and unimolecular fragmentation of V _n O _m ^? and Nb _n O _m ^? clusters can be described by a statistical recombination mechanism. Clusters are formed over the target surfaces as a result of binary collisions of independently sputtered ions, atoms, and molecules.     

Search for Θ+(1540) in exclusive proton-induced reaction p + C(N) \to \Theta ^ + \bar \kappa ^0 + C(N) at the energy of 70 GeV

A search for narrow Θ⁺(1540), a candidate for a pentaquark baryon with positive strangeness, has been performed in an exclusive proton-induced reaction $p + C(N) \to \Theta ^ + \bar \kappa ^0 + C(N)$ on carbon nuclei or quasifree nucleons at $E_{beam} = 70GeV(\sqrt s = 11.5GeV)$ studying nK ⁺, pK _S ⁰ , and pK _L ⁰ decay channels of Θ⁺(1540) in four different final states of the $\Theta ^ + \bar K^0 $ system. In order to assess the quality of the identification of the final states with neutron or K _L ⁰ , we reconstructed Λ(1520) → nK _S ⁰ and ? → K _L ⁰ K _S ⁰ decays in the calibration reactions p + C(N) → Λ (1520)K ⁺+C(N) and p+C(N) → p?+C(N). We found no evidence for a narrow pentaquark peak in any of the studied final states and decay channels. Assuming that the production characteristics of the $\Theta ^ + \bar K^0 $ system are not drastically different from those of the Λ(1520)K ⁺ and p? systems, we established upper limits on the cross-section ratios $\sigma (\Theta ^ + \bar K^0 )/\sigma (\Lambda (1520)K^ + ) < 0.02$ and $\sigma (\Theta ^ + \bar K^0 )/\sigma (p\phi ) < 0.15$ at 90% C.L. and a preliminary upper limit for the forward-hemisphere cross section $\sigma (\Theta ^ + \bar K^0 )$ nb/nucleon.     

The decay of the Bethe-Salpeter kernel inP(ϕ)2 quantum field models

We extend methods of high temperature expansions to show that for even weakly coupledP(?)₂ quantum field models the Bethe-Salpeter kernel has 4 particle decay. More precisely ifK denotes the Euclidean Bethe-Salpeter kernel $$|K(x_1 ,x_2 ,x_3 ,x_4 )| \leqq Oe^{ - m_0 (1 - \varepsilon )d_2 } ,$$ wherex=(x ⁰,x ¹),d ₂=2|x ₁ ⁰ +x ₂ ⁰ ?x ₃ ⁰ ?x ₄ ⁰ |+|x ₁ ⁰ ?x ₂ ⁰ |+|x ₃ ⁰ ?x ₄ ⁰ | and ε(λ)→0 as λ→0. Our methods apply to otherr particle irreducible kernels.     

Mass spectrometer studies of the ion composition in the pink afterglow

The time dependences of the ion number densities in the pink afterglow of nitrogen, as represented by the ion wall currents, have been measured. The ions were extracted through an orifice from a flow system and analysed by a quadrupol mass spectrometer. It has been found thatN ₂ ⁺ ions are dominating in the early afterglow. With the beginning of the ionization processN ₃ ⁺ and at pressure >6 TorrN ₄ ⁺ become the majority ions. The ratio of the number densities(N ₃ ⁺ )/(N ₂ ⁺ ) reaches a maximum during the increase of the ionization processes before the maximum is reached. This behaviour suggestsN ₃ ⁺ ions to be the primary ions created by the ionization processes. The time dependences of the ion number densities (N ₂ ⁺ ), (N ₃ ⁺ ) and(N ₄ ⁺ ) are found to vary similar, showing that the ions are strongly coupled by conversion processes. The conversion processes are discussed. In the maximum of ionization at a total pressure of 4.4 Torr the ratios of the number densities of the afterglow ions (N ₂ ⁺ )∶(N ₃ ⁺ )∶(N ₄ ⁺) are 1∶1.9∶0.64.     

Differential analyzing power in pp′ scattering on a 28Si nucleus in the case of the excitation of high-spin particle-hole states

The experimental energy dependence of the differential analyzing power for 5 ₁ ^? , T=0 and 6 ₁ ^? , T=1 levels in the ²⁸Si nucleus is compared with the results of the calculations based on the DWBA-91 code. Information obtained for the nuclear structure from an analysis of inelastic scattering is discussed.     

Investigation of N 2 + (C 2Σ u + → X 2Σ g + fluorescence excited through auger decay of the 1s −1π* resonance

A theoretical investigation of N ₂ ⁺ (C ²Σ _u ⁺ → X ²Σ _g ⁺ molecular fluorescence excited through the Auger decay of the 1s ^?1π* resonance is carried out. The fluorescence cross sections are calculated with due regard for the dependence of the matrix element of the C → X dipole transition on the internuclear distance, the interference between channels of excitation via different vibrational levels v _r of the 1s ^?1π* resonance, the rotational structure of the fluorescence band, and the predissociation of the N ₂ ⁺ C ²Σ _u ⁺ v′ ≥3) states. The calculated cross sections are in good agreement with the experimental results of recent measurements. The results of the calculations have demonstrated that the observed dependence of the cross section of the (C ²Σ _u ⁺ (v′) → X ²Σ _g ⁺ (v″) fluorescence on the excitation energy and the fluorescence wavelength for a group of bands with equal values of the difference Δv = v′ ? v″ is associated with transitions between the vibrational levels of the electronic states involved in the excitation and subsequent cascade decay of the 1s ^?1π* resonance: N₂ (v ₀ = 0) → N*₂(1s ^?1π*(v _r)) ? N ₂ ⁺ : (C ²Σ _u ⁺ (v′) → X ²Σ _g ⁺ (v″).     

Comparative study of the semiempirical three-parameter potential energy functions for diatomic molecules

A comparative study is made of four three-parameter semiempirical potential energy functions for 32 electronic states of diatomic molecules and their ions:n ₂:X¹gS _g ⁺ ,B ³π_g,A ³ gS_u,C ³ _u,B′ ³ gS_u.a ¹ π_g, a′gS _u ^? ,Ω ¹δ_u N ₂ ⁺ :X ² gS _g ^gS +A ² π,C ² gS _u ⁺ ,B ² gS _u ⁺ CO:X¹gS⁺,a ³ π, a′³ gS_u,e ³ gS^?,d ³gD₁,A ¹π CO⁺:X²gS⁺,A ² π,B ²gS⁺ O₂:X³gS _g ^? ,B ³ gS_u,c ¹ gS _u ^? ,b ¹gS _g ^s ,a ¹ δ_g,c ³ δ_u O ₂ ⁺ :X ²π_g,A ² π_g, a¹ π_g,b ⁴ gS _g ^? A program for numerically integrating the radial Schrödinger equation by the Cooley method is worked out. Certain additional units are introduced to conserve computer time. The resulting vibrational levels are compared with the experimental levels for all the electronic states studied. It is concluded on the basis of this analysis that it is not possible to describe equally well all the electronic states of various molecules on the basis of any single three-parameter potential function. A method for choosing a potential function for describing some particular electronic state of a diatomic molecule is proposed.     

Nuclear bremsstrahlung and electron-positron pair creation in heavy-ion collisions

Nuclear bremsstrahlung is investigated as a background effect in the X-ray-spectroscopy of superheavy electronic molecules. The intensity ratio between electric dipole and quadrupole radiation as function of frequency is given. The total cross section for electron-positron pair creation due to conversion of bremsstrahlungs-photons was found to beσ=3.8·10^?8b for the ₅₄ ¹³² Xe- ₉₂ ²³⁸ U system andσ=5.8·10^?8b for the ₉₂ ²³⁸ U? ₉₂ ²³⁸ U system at the Coulomb barrier. This demonstrates that bremsstrahlung pair creation can be neglected compared with the induced positron production in overcritical quasimolecules.     

Search for the K L 0 → π0ν \tilde v decay at the INEP U-70 accelerator: The KLOD project

The rare decay K _L ⁰ → π⁰ν $ \tilde v $ branching ratio measurement is one of the clearest Standard Model test. Calculations based on the SM predict Br(K _L ⁰ → π⁰ν $ \tilde v $ ) ≈ 2.8 × 10^?11, but the most accurate experimental value Br(K _L ⁰ → π⁰ν $ \tilde v $ ) < 6.7 × 10^?8 (90% C.L.). We present design of a new experimental setup KLOD (U-70 accelerator, IHEP, Protvino) for K _L ⁰ → π⁰ν $ \tilde v $ branching ratio measurement. Sensitivity of the KLOD experiment will be enough for registration of 2.4 events K _L ⁰ → π⁰ν $ \tilde v $ for every 10 days of the data taking (according to SM predictions).