共查询到18条相似文献,搜索用时 78 毫秒
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炔基硒醚是合成一些有机硒化合物的重要起始物。本文研究发现,在三溴化金(Au Br3)催化下,端位炔和二芳基二硒醚在弱碱(如碳酸钾)存在下反应,生成炔基芳基硒醚,产率为69%~98%;在空气参与下,于80℃下进行反应,反应条件简单,且二硒醚的两个硒原子均可以被利用。二甲基亚砜(DMSO)是合适的溶剂,在极性较小的溶剂(如甲苯、四氢呋喃)中,此反应不能进行。芳基炔(如苯乙炔、对甲基苯乙炔、对氯苯乙炔等)、烯基炔(如环己烯乙炔)和烷基炔(如1-壬炔)均能顺利进行此反应。当芳基炔苯环的间位或邻位连有取代基时,反应产率较低(69%~82%),而对位无论是连有吸电子基还是给电子基,该反应均可以得到很高的产率(95%)。 相似文献
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原子经济反应:氢氧化铯催化下二硒醚与端炔反应合成炔硒醚 总被引:8,自引:0,他引:8
氢氧化铯是无机超强碱,它能夺去端炔上的氢而产生稳定炔负离子,这种炔负离子与亲电的酮、醛反应生成相应的炔醇,但是与亲电的杂原子反应形成碳杂键的研究尚未见报道,碳杂键的形成是合成杂原子有机化合物的主要途径,所以研究无机超强碱催化下的碳杂键形成反应,有可能开辟-个合成杂原子有机化合物的新领域,不论在理论上还是在应用上都具有重要意义。 相似文献
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Methylalumoxane (MAO) was found to be an active catalytic precursor for the chemo- and regioselective dimerization of a wide range of aryl- and alkyl-substituted terminal alkynes yielding the corresponding geminal dimers A. For an olefin-functionalized terminal alkyne (RC&tbd1;CH, R = MeC=CH(2)), the geminal dimer undergoes an intermolecular [4 + 2] cycloaddition forming compound B. 相似文献
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Terminal alkynes couple smoothly in the presence of Phl(OAc)2 or Phl(OH)OTs, catalytic amount of Cul and base, affording conjugated diynes. 相似文献
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Mlodie Birepinte Pier Alexandre Champagne Jean-Franois Paquin 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2022,134(1):e202112575
A photoinitiated anti-hydropentafluorosulfanylation of terminal alkynes using SF5Cl and (TMS)3SiH as the hydrogen atom donor is reported. This transformation generates selectively (Z)-(1-alken-1-yl)pentafluoro-λ6-sulfanes (Z:E : >85:15), thus allowing the preparation of this previously unknown geometrical isomer. DFT calculations highlight that the selectivity is due to the intrinsic preference of SF5-substituted vinylic radicals to adopt a cis geometry, and to increased steric contacts during the transition structures leading to the minor (E)-products. 相似文献
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Copper‐Promoted Oxidative Coupling of Enamides and Alkynes for the Synthesis of Substituted Pyrroles 下载免费PDF全文
Mi‐Na Zhao Zhi‐Hui Ren Prof. Yao‐Yu Wang Prof. Dr. Zheng‐Hui Guan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(7):1839-1842
An efficient copper‐promoted oxidative coupling of enamides with alkynes has been developed for the synthesis of substituted pyrroles. The reaction proceeded through C?H and N?H bond functionalization of enamides under mild conditions. 相似文献
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A simple and efficient protocol for Fe/Cu cocatalyzed oxidative homocoupling reaction of terminal alkynes to symmetrical 1,4‐disubstituted‐1,3‐diynes was presented. The results showed that both CuBr and FeCl3 played crucial roles in the reaction. It is noteworthy that this protocol employs mild, efficient, aerobic and ligand free conditions. The alkynes, including aromatic, heteroaromatic and aliphatic alkynes, were transformed into the corresponding 1,3‐diynes in good to excellent yields. 相似文献
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Promoted by metallic dysprosium, carbonyl compounds react smoothly with propargyl bromide to afford the corresponding homopropargylic alcohols in good to excellent yields without observation of allenic alcohols. In addition, this reaction is regioselective and chemoselective. 相似文献
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Ali Sharifi Mojtaba Mirzaei M. Reza Naimi-Jamal 《Monatshefte für Chemie / Chemical Monthly》2006,137(2):213-217
Summary. A variety of 1,3-diyne compounds are prepared in a solvent-free reaction on KF/alumina in the presence of catalytic amounts
of Cu(OAc)2·H2O with up to 96% yields at room temperature. 相似文献