Nucleation problems in metallurgy of the solid state: recent developments and open questions

Nucleation processes play a key role in the microstructure evolution of metallic alloys during thermomechanical treatments. These processes can involve phase transformations (such as precipitation) and structural instabilities (such as recrystallisation). Although the word ‘nucleation’ is used in both cases, the situation is profoundly different for precipitation and for recrystallisation on which this article is focussed. In the case of precipitation, species are conserved and the underlying physics is stochastic fluctuations, allowing the apparition of critical germs of the new phase. In the case of recrystallisation, the underlying physical phenomenon is the progressive growth of subgrain structures leading to an unstable configuration, allowing a dislocation free grain to grow at the expense of a dislocated one. The two cases require different types of modelling which are presented in the article. To cite this article: Y. Bréchet, G. Martin, C. R. Physique 7 (2006).     

Un coronographe interférentiel achromatique coaxial

We present a new type of stellar interfero-coronagraph, the ‘CIAXE’, which is a variant of the ‘AIC’, the Achromatic Interfero-Coronagraph. The CIAXE is characterized by a very simple, compact and fully coaxial optical combination. Indeed, contrarily to the classical AIC which has a Michelson interferometer structure, the CIAXE delivers its output beam on the same axis as the input beam. This will ease its insertion in the focal instrumentation of existing telescopes or next generation ones. Such a device could be a step forward in the field of instrumental search for exoplanets. To cite this article: J. Gay et al., C. R. Physique 6 (2005).     

Observations and modeling of lightning leaders

The development of atmospheric lightning is initiated by a ‘leader’ phase during which ionized channels appear in virgin air. The use of rapid cameras, the measure of fields and currents associated with the discharge allow one to compare the propagation of laboratory leaders with those of natural or artificially triggered lightning. The corresponding physical processes can be analyzed with the help of models developed for laboratory leaders provided that the non linear effects due to the intense current circulation leading to lightning leader thermalization are taken into account. A self-coherent simulation of triggered lightning leaders for both polarities is presented is this paper. Furthermore, these models make it possible to define the ‘stabilization field’ concept, equal to the minimum ambient field allowing the stable progress of a leader from a ground structure, expressed as a height and curvature function of this structure. This concept can be validated through triggered lightning tests. Finally, the stabilization field analysis is completed by a simplified analytical model based upon an electrostatic approach of propagation equilibrium. To cite this article: P. Lalande et al., C. R. Physique 3 (2002) 1375–1392.     

Semiclassical relativistic strings in and long scalar operators in SYM theory

We review recent progress in quantitative checking of AdS/CFT duality in the sector of ‘semiclassical’ string states dual to ‘long’ scalar N=4 super Yang–Mills operators. In particular, we describe the effective action approach, in which the same sigma model type action describing coherent states is shown to emerge from the AdS₅×S⁵ string action and from an integrable spin chain Hamiltonian representing the SYM dilatation operator. To cite this article: A.A. Tseytlin, C. R. Physique 5 (2004).

Résumé

Nous passons en revue les progrès récents sur les vérifications quantitatives de la dualité AdS/CFT dans le régime où les états « semiclassiques » de cordes sont du aux « longs » opérateurs scalaires de la théorie de super Yang–Mills N=4. En particulier, nous décrivons l'approche effective, dans laquelle le modèle sigma décrivant les états cohérents est montré émerger de l'action de la corde sur AdS₅×S⁵ et de l'Hamiltonien d'une chaîne de spin intégrable représentant l'opérateur de dilatation en SYM. Pour citer cet article : A.A. Tseytlin, C. R. Physique 5 (2004).     

Fundamental processes in long air gap discharges

The development of atmospheric lightning is initiated and sustained by the formation in virgin air of ‘streamer corona’ and ‘leader’ discharges, very similar to those observed in laboratory long sparks. Therefore, the experimental and theoretical investigations of these laboratory discharges have become of large interest to improve the physical knowledge of the lightning process and to develop self-consistent models that could be applied to new protection concepts.In the present paper the fundamental processes of the subsequent phases of long air gap discharges are analyzed, from the first corona inception and development to the leader channel formation and propagation. For all these processes simulations models are discussed that have been essentially derived and simplified by the authors, in order to develop sequential time-dependent simulation of the laboratory breakdown, with both positive and negative voltages. The possibility of extending these models to the case of natural lightning is discussed in the companion paper, presented in this same volume. To cite this article: I. Gallimberti et al., C. R. Physique 3 (2002) 1335–1359.     

QWIP detectors and thermal imagers

Standard GaAs/AlGaAs QWIPs (Quantum Well Infrared Photodetector) are now well established for long wave infrared (LWIR) detection. The main advantage of this technology is the duality with the technology of commercial GaAs devices. The realization of large FPAs (up to 640×480) drawing on the standard III–V technological process has already been demonstrated. The second advantage widely claimed for QWIPs is the so-called band-gap engineering, allowing the custom design of the quantum structure to fulfill the requirements of specific applications such as multispectral detection. QWIP technology has been growing up over the last ten years and now reaches an undeniable level of maturity. As with all quantum detectors, the thermal current, particularly in the LWIR range, limits the operating temperature of QWIPs. It is very crucial to achieve an operating temperature as high as possible and at least above 77 K in order to reduce volume and power consumption and to improve the reliability of the detection module. This thermal current offset has three detrimental effects: noise increase, storage capacitor saturation and high sensitivity of FPAs to fluctuations in operating temperature. For LWIR FPAs, large cryocoolers are required, which means volume and power consumption unsuitable for handheld systems. The understanding of detection mechanisms has led us to design and realize high performance ‘standard’ QWIPs working near 77 K. Furthermore, a new in situ skimmed architecture accommodating this offset has already been demonstrated. In this paper we summarize the contribution of THALES Research & Technology to this progress. We present the current status of QWIPs in France, including the latest performances achieved with both standard and skimmed architectures. We illustrate the potential of our QWIPs through features of Thales Optronique's products for third thermal imager generation. To cite this article: E. Costard et al., C. R. Physique 4 (2003).     

Helium and point defect accumulation: (ii) kinetic modelling

The main outstanding issues regarding modeling He diffusion and defect accumulation in α-iron are reviewed. During recent years, first principles calculations have provided a better understanding of defect stability and migration properties in pure α-iron, and accurate values of energetics of He migration and He-vacancy interactions. Such information has been used by several authors to study damage evolution under different irradiation conditions using both kinetic Monte Carlo and rate theory models. In this article a review of the main results is provided, in particular for He desorption. The influence of impurities such as carbon is discussed as well as the main challenges ahead for modeling. To cite this article: M.J. Caturla et al., C. R. Physique 9 (2008).     

Hard X-ray PhotoEmission Spectroscopy of strongly correlated systems

Hard X-ray PhotoEmission Spectroscopy (HAXPES) is a new tool for the study of bulk electronic properties of solids using synchrotron radiation. We review recent achievements of HAXPES, with particular reference to the VOLPE project, showing that high energy resolution and bulk sensitivity can be obtained at kinetic energies of 6–8 keV. We present also the results of recent studies on strongly correlated materials, such as vanadium sesquioxide and bilayered manganites, revealing the presence of different screening properties in the bulk with respect to the surface. We discuss the relevant experimental features of the metal–insulator transition in these materials. To cite this article: G. Panaccione et al., C. R. Physique 9 (2008).     

Prospective sur les besoins « défense » en détecteurs infrarougeMid-term defence needs for infrared detectors

In this paper, we propose to present the prospects for mid-term needs for infrared detectors. These needs are derived from expected evolutions in imaging techniques as well as from operational requirements. The main trends that shall allow the direct development in infrared detection are as much the pursuit of greater range, a better discrimination of targets, as the efforts to minimize cost, volume, weigh and consumption. These trends will lead to an examination of the specific needs for some kind of ‘smart’ infrared detector. Among these applications, we will investigate more deeply the technological requirements for flash and 3D imaging, hyperspectral and uncooled imaging. To cite this article: J.-C. Peyrard, C. R. Physique 4 (2003).     

Supersymmetric backgrounds from generalized Calabi–Yau manifolds

We show that the supersymmetry transformations for type II string theories on six-manifolds can be written as differential conditions on a pair of pure spinors, the exponentiated Kähler form e^iJ and the holomorphic form Ω. The equations are explicitly symmetric under exchange of the two pure spinors and a choice of even or odd-rank RR field. This is mirror symmetry for manifolds with torsion. Moreover, RR fluxes affect only one of the two equations: e^iJ is closed under the action of the twisted exterior derivative in IIA theory, and similarly Ω is closed in IIB. This means that supersymmetric SU(3)-structure manifolds are always complex in IIB while they are twisted symplectic in IIA. Modulo a different action of the B-field, these are all generalized Calabi–Yau manifolds, as defined by Hitchin. To cite this article: M. Graña et al., C. R. Physique 5 (2004).

Résumé

On montre que les transformations de supersymétrie pour les théories des cordes de type II peuvent être traduites dans des équations différentielles pour une paire de spineurs purs, l'exponentiel de la forme de Kähler e^iJ et la forme holomorphe Ω. Ces équations sont symétriques sous l'échange des deux spineurs purs et des formes de RR de rang pair ou impair. Cette propriété est la symétrie miroir pour les variétés avec torsion. On voit aussi que les fluxes de RR entrent seulement dans une des deux équations : e^iJ est fermé sous l'action de la dérivée extérieure « twisted » dans la corde de type IIA, et de la même manière Ω est fermé en type IIB. Cela implique que les variétés supersymétriques de structure SU(3) sont toujours complexes en type IIB ou bien symplectiques « twisted » en IIA. Ces variétés sont donc des variétés des Calabi–Yau généralisées selon la définition de Hitchin, mais avec une action du champ B différente. Pour citer cet article : M. Graña et al., C. R. Physique 5 (2004).     

Diffusion and coupled fluxes in concentrated alloys under irradiation: a self-consistent mean-field approach

When an alloy is irradiated, atomic transport can occur through the two types of defects which are created: vacancies and interstitials. Recent developments of the self-consistent mean field (SCMF) kinetic theory could treat within the same formalism diffusion due to vacancies and interstitials in a multi-component alloy. It starts from a microscopic model of the atomic transport via vacancies and interstitials and yields the fluxes with a complete Onsager matrix of the phenomenological coefficients. The jump frequencies depend on the local environment through a ‘broken bond model’ such that the large range of frequencies involved in concentrated alloys is produced by a small number of thermodynamic and kinetic parameters. Kinetic correlations are accounted for through a set of time-dependent effective interactions within a non-equilibrium distribution function of the system. The different approximations of the SCMF theory recover most of the previous diffusion models. Recent improvements of the theory were to extend the multi-frequency approach usually restricted to dilute alloys to diffusion in concentrated alloys with jump frequencies depending on local concentrations and to generalize the formalism first developed for the vacancy diffusion mechanism to the more complex diffusion mechanism of the interstitial in the dumbbell configuration. To cite this article: M. Nastar, C. R. Physique 9 (2008).     

Helium and point defect accumulation: (i) microstructure and mechanical behaviour

Ferritic/martensitic (F/M) steels are good candidate structural materials for the future fusion reactors and spallation sources. However, irradiation of steels is known to produce hardening, loss of ductility, shift in ductile to brittle transition temperature (DBTT) and reduction of fracture toughness and creep resistance starting at low doses. Helium (He), produced by transmutation during the irradiation, also impacts mechanical properties. Numerous experimental and theoretical studies on the evolution of the microstructure of steels under irradiation have been conducted until now. We review the effect of irradiation-induced point defects and in particular of He on the mechanical properties of F/M steels. To cite this article: R. Schäublin et al., C. R. Physique 9 (2008).     

A lightning initiation mechanism: application to a thunderstorm electrification model

The use of numerical models has greatly increased our understanding of the electrical and microphysical process within electrified clouds. We use the University of Washington, 1.5-dimensional thunderstorm model to examine the effects of including a runaway electron based lightning initiation mechanism. We find that this mechanism can significantly alter the electrification history of modeled storms and produce vertical electric field profiles that are very similar to those of observed storms. To cite this article: R. Solomon et al., C. R. Physique 3 (2002) 1325–1333.     

Negative bending mode curvature via Robin boundary conditions

We examine the band spectrum, and associated Floquet–Bloch eigensolutions, arising in straight walled acoustic waveguides that have periodic structure along the guide. Homogeneous impedance (Robin) conditions are imposed along the guide walls and we find that in certain circumstances, negative curvature of the lowest (bending) mode can be achieved. This is unexpected, and has not been observed in a variety of physical situations examined by other authors. Further unexpected properties include the existence of the bending mode only on a subset of the Brillouin zone, as well as permitting otherwise unobtainable velocities of energy transmission. We conclude with a discussion of how such boundary conditions might be physically reproduced using effective conditions and homogenization theory, although the methodology to achieve these effective conditions is an open problem. To cite this article: S.D.M. Adams et al., C. R. Physique 10 (2009).     

Atomic modeling of irradiation-induced hardening

We review recent results obtained by Molecular Dynamics (MD) simulations on the elementary interaction mechanisms between dislocations and irradiation defects, with the aim to obtain a fundamental understanding of plasticity in irradiated metals. The reactions obtained included defect shear, drag and absorption in edge and screw dislocations. We present the state of the art in both FCC and BCC metals and discuss the challenges faced by MD simulations, in particular in BCC metals in order to realistically simulate the thermally-activated glide of screw dislocations in the presence of obstacles. To cite this article: D. Rodney, C. R. Physique 9 (2008).     

Directive metamaterial-based subwavelength resonant cavity antennas – Applications for beam steering

This article presents the use of composite resonant metamaterials for the design of highly directive subwavelength cavity antennas. These metamaterials, composed of planar metallic patterns periodically organized on dielectric substrates, exhibit frequency dispersive phase characteristics. Different models of metamaterial-based surfaces (metasurfaces), introducing a zero degree reflection phase shift to incident waves, are firstly studied where the bandwidth and operation frequency are predicted. These surfaces are then applied in a resonant Fabry–Perot type cavity and a ray optics analysis is used to design different models of ultra-compact high-gain microstrip printed antennas. Another surface presenting a variable reflection phase by the use of a non-periodic metamaterial-based metallic strips array is designed for a passive low-profile steering beam antenna application. Finally, the incorporation of active electronic components on the metasurfaces, allowing an electronic control of the phase responses, is applied to an operation frequency reconfigurable cavity and a beam steering cavity. All these cavity antennas operate on subwavelength modes, the smallest cavity thickness being of the order of λ/60. To cite this article: A. Ourir et al., C. R. Physique 10 (2009).     

CO2 laser treatment system of tinea pedis

The CO₂ laser treatment system ‘Melase 1000’ has been developed for the treatment of Tinea pedis and the efficacy of the treatment using the system and its optimum irradiation condition are studied. The present system enables us to make the healing time of Tinea pedis treatment far shorter than conventional pharmaceuticals. This is in spite of using heat levels low enough for patients not to feel discomfort. Features offered by the system are a safe-and-easy operation and a stable laser power for a prolonged use. The efficacy of the present therapy is excellent; only two treatments a week for three weeks, i.e. six consecutive treatments, attained an improvement rate of 71.8% in the skin findings and a ‘usefulness’ of 66.2% determined from cases rated as ‘useful’ or ‘better’. The optimum laser irradiation condition for a single treatment found in this experiment is a light fluence of about 3 J/cm² and four laser pulses with a time interval between pulses of 1 s for a typical horny layer thinner than 0.5 mm.     

First principles calculations in iron: structure and mobility of defect clusters and defect complexes for kinetic modelling

Predictive simulations of the defect population evolution in materials under or after irradiation can be performed in a multi-scale approach, where the atomistic properties of defects are determined by electronic structure calculations based on the Density Functional Theory and used as input for kinetic simulations covering macroscopic time and length scales. Recent advances obtained in iron are presented. The determination of the 3D migration of self-interstitial atoms instead of a fast one-dimensional glide induced an overall revision of the widely accepted picture of radiation damage predicted by previously existing empirical potentials. A coupled ab initio and mesoscopic kinetic Monte Carlo simulation provided strong evidence to clarify controversial interpretations of electrical resistivity recovery experiments concerning the mobility of vacancies, self-interstitial atoms, and their clusters. The results on the dissolution and migration properties of helium in α-Fe were used to parameterize Rate Theory models and new inter-atomic potentials, which improved the understanding of fusion reactor materials behavior. Finally, the effects of carbon, present in all steels as the principal hardening element, are also shown. To cite this article: C.C. Fu, F. Willaime, C. R. Physique 9 (2008).