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1.
M. I. Isaev 《Chemistry of Natural Compounds》1994,29(5):630-636
Literature information is given on the current state of the study of the chemical transformation of cycloartane triterpenoids. A method has been developed for the transformation of the genin part of glycosides of 20,24-epoxycycloartan-25-ols with retention of the carbohydrate constituents. Three 25-norglycosides have been synthesized from natural cyclosieversigenin glycosides, namely 16-acetoxy-3,6-dihydroxy-20R,25-norcycloartan-20,24-olide 3-O-[O--L-arabinopyranosyl-(12)--D-xylopyranoside] 6-O--D-xylopyranoside (VIII), sodium 3,6,16,20-tetrahydroxy-20R,25-norcycloartan-24-oate 6-O--D-glucopyranoside 3-O--D-xylopyranoside (XII), and 20R,25-norcycloartane-3,6,16,20,24-pentaol 6-O--D-glucopyranoside 3-O--D-xylopyranoside (XIII).Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 710–718, September–October, 1993. 相似文献
2.
By chromatography on Polikhrom-1, silica gel, and Florisil, an ethanolic extract of the digestive organs of the starfishPatiria pectinifera has yielded the steroid polyols 5-cholestan-3,6,8,15,16,26-hexaol and 5-cholestan-3,4,6,7,8,15,16,26-octaol 6-(sodium sulfate). The structures of the compounds have been shown by spectral characteristics and chemical transformations.Pacific Ocean Institute of Bioorganic Chemistry, Far Eastern Scientific Center, Academy of Sciences of the USSR, Vladivostok. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 738–741, November–December, 1984. 相似文献
3.
A. N. Svechnikova R. U. Umarova N. D. Abdullaev M. B. Gorovits T. T. Gorovits N. K. Abubakirov 《Chemistry of Natural Compounds》1984,19(4):432-434
A new triglycoside of the cycloartane series has been isolated from the roots ofAstragalus sieversianus Pall.; it is cyclosiversigenin 6-0--D-glucopyranoside 3-0-[0--L-rhamnopyranosyl-(1 2)--D-xylopyranoside].Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 460–463, July–August, 1983. 相似文献
4.
M. I. Isaev B. A. Imomnazarov Yu. M. Fadeev P. A. Kintya 《Chemistry of Natural Compounds》1992,28(3-4):315-320
Another six components ofAstragalus tragacantha Habl. have been identified on the basis of spectral characteristics and chemical transformations. We have previously described cyclocanthagenin and its 3-0--D-xylopyranoside — cyclocanthoside A — as products of the acid hydrolysis of cyclocanthoside D. Cyclocanthosides B, C, E, and G are here described for the first time and are (24S)-cycloartane-3,6,16,24,25-pentol 3-O-(4-O-acetyl--D-xylopyranoside) 6-O--D-glucopyranoside, (24S)-cycloartane-3,6,16,24,25-pentol 6-O-(6-O-acetyl--D-glucopyranoside) 3-O--D-xylopyranoside, (24S)-cycloartane-3,6, 16,24,25-pentol 6-O--D-glucopyranoside, and (24S)-cycloartane-3, 6, 16, 24, 25-pentol 6-O--D-glucopyranoside 3-O-[O--D-glucopyranosyl-(12)--D-xylopyranoside], respectively.Institute of Chemistry of Plant Substances, Uzbekistan Academy of Sciences, Tashkent. Institute of Ecological Genetics, Moldavian Academy of Sciences, Kishenev. Translated from Khimiya Prirodnykh Soedinenii, Nos. 3,4, pp. 360–367, May–August, 1992. 相似文献
5.
M. A. Agzamova M. I. Isaev M. B. Gorovits N. K. Abubakirov 《Chemistry of Natural Compounds》1987,22(6):671-676
The quantitatively main glycoside — cycloorbicoside A — has been isolated from the epigeal parts of the plantAstragalus orbiculatus, and on the basis of chemical transformations and spectral characteristics its structure has been established as (23R,24S)-16,23:16,24-diepoxycycloartane-3,7,25-triol 3-0--D-xylopyranoside.Institute of the Chemistry of Plant Substances Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 719–726, November–December, 1986. 相似文献
6.
Conclusions It has been established that patrinoside D1 is the -D-glucopyranosido(13) -D-xylopyranosido(12) -L-rhamnosido(14)--D-xylopyranoside (13) of oleanolic acidKhimiya Prirodnykh Soedinenii, Vol. 5, No. 2, pp. 84–89, 1969 相似文献
7.
M. I. Isaev M. B. Gorovits T. T. Gorovits N. D. Abdullaev N. K. Abubakirov 《Chemistry of Natural Compounds》1983,19(2):163-169
A new glycoside of the cycloartane series — askendoside C — has been isolated from the roots of the plantAstragalus taschkendicus Bge., and its structure has been established on the basis of chemical transformations and spectral characteristics as 24R-cycloartane-3,6,16,24,25-pentaol 3-[0--L-arabinopyranosyl-(12)--D-xylopyranoside].Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 173–180, March–April, 1983. 相似文献
8.
Glycosides of marine invertebrates. Structure of holothurin A2 from the holothurianHolothuria edulis
The structure of a new glycoside fromHolothuria edulis, holothurin A2, has been established with the aid of periodate oxidation, methylation, Smith degradation, and13C NMR spectroscopy. The structure of the glycoside has been determined as holost-9(11)-ene-3,12,17-triol 3-0-{2-0-[3-0-methyl--D-glucopyranosyl-(13)-0--D-glucopyranosyl-(14)-0--D-quinovopyranosyl]-4-0-sulfate--D-xylopyranoside}.Pacific Ocean Institute of Bioorganic Chemistry, Far Eastern Scientific Center, Academy of Sciences of the USSR, Vladivostok. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 215–219, March–April, 1982. 相似文献
9.
Two hederagenin glycosides — medicosides E and F — have been isolated from the roots ofMedicago sativa L. (Leguminosae). Medicoside E has the structure of hederagenin 28-O--D-glucopyranoside 3-O-[O--G-glucopyranosyl-(13)--D-xylopyranoside]. Medicoside F has the structure of hederagenin 28-O--D-glucopyranoside 3-O-[O--D-glucopyranosyl-(12)--L-arabinopyranoside].Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent. Institute of Organic Chemistry, Russian Academy of Sciences, Moscow. Translated from Khimiya Prirodnykh Soedinenii. No. 5, pp. 701–705, September–October, 1993. 相似文献
10.
A. A. Akimaliev N. Sh. Pal'yants P. K. Alimbaeva N. K. Abubakirov 《Chemistry of Natural Compounds》1980,15(5):587-591
Partial syntheses of glycosides of oleanolic acid — the 3-0--D-xylopyranoside (songoroside A), the 3,28-bis-0--D-xylopyranoside, and the 28-0--gentiobioside-3-0--D-xylopyranoside — and also the formation of 3-0--D-xylopyranosyloleanolic acid 13,28-lactone are described.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Institute of the Physiology and Experimental Pathology of High Mountain Regions of the Academy of Sciences of the KirgSSR, Frunze. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 668–673, September–October, 1979. 相似文献
11.
I. I. Kapustina A. I. Kalinovskii S. G. Polonik V. A. Stonik 《Chemistry of Natural Compounds》1987,23(2):209-213
Three new glycosides, D1, D2, and D3, have been isolated from the Far Eastern starfishDistolasterias nipon. They have been identified by chemical and physicochemical methods as 5-cholestane÷3,6,8,15,24-pentaol 3,24-di-O--D-xylopyranoside, t-cholest-22-ene-3,6,8,15,24-pentaol 3,24-di-O--D-xylopyranoside (II), and 5-cholestane-3,6,8,15,24-pentaol 24-O--D-glucopyranoside 3-O--D-xylopyranoside (III).Pacific Ocean Institute of Bioorganic Chemistry, Far Eastern Scientific Center, Academy of Sciences of the USSR, Vladivostok. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 250–255, March–April, 1987. 相似文献
12.
A new triterpene glycoside — salsoloside E — has been isolated from the epigeal part of the plantSalsola micranthera Botsch. family Chenopodiaceae. On the basis of chemical transformations and physicochemical characteristics its structure has been established as oleanolic acid 28-0--D-glucopyranoside 3-0-{[0--D-glucopyranosyl-(1 2)][0--D-xylopyranosyl-(1 4)]--D-glucuronopyranoside}.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 65–69, January–February, 1964. 相似文献
13.
The structures of two new cycloartane glycosides — cyclocarposides A and C, isolated from the herbAstragalus coluteocarpus Boiss. — have been established on the basis of spectral characteristics and chemical transformations. Cyclocarposides A and C are: 204R,24S-epoxycycloartane-3,6,17,25-tetraol 3-O-(2-O-acetyl--D-xylopyranoside)6-O-(2-O-acetyl--L-rhamnopyranoside) and 20R,24S-epoxycyloartane-3,6,16,25-tetraol 3-O-(2-O-acetyl--D-xylopyranoside) 6-O--L-rhamnopyranoside, respectively.Institute of Chemistry of Plant Substances, Uzbekistan Academy of Sciences, Tashkent. Pamir Biological Institute, Tadzhikistan Academy of Sciences, Khorog. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 694–698, November–December, 1992. 相似文献
14.
P. R. Patnaik 《Reaction Kinetics and Catalysis Letters》1989,40(2):381-386
Two consecutive reactions in a CSTR are anlyzed for the effect of random fluctuations in the feed rate. It is seen that noise generates oscillations when the reactor is operating at a stable steady state. Sufficient conditions for this are derived.
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15.
P. K. Kintya A. I. Stamova L. B. Bakinovskii V. V. Krokhmalyuk 《Chemistry of Natural Compounds》1978,14(3):290-294
Summary The chemical structures of two new steroid glycosides from the leaves ofPolygonatum latifolium have been shown. Polygonatoside E is 3-[0--D-glucopyranosyl-(1 3)-0--D-glucopyranosyl-(1 4)-0--d-galactopyranosyl-(1 3)--D-glucopyranosyloxy]-(25R)-spirost-5-ene, and protopolygonatoside E is 26--D-galactopyranosyl-(1 3)--D-glucopyranosyloxy]-(25R)-furost-5-en-22-ol.Institute of Chemistry, Academy of Sciences of the Moldavian SSR, Kishenev. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 350–354, May–June, 1978. 相似文献
16.
Adsorption of hydrogen, oxygen and carbon monoxide on Pd–Ag/Al2O3 catalysts of different compositions within the temperature range from 293 to 773 K has been investigated. Adsorption measurements have been carried out by the pulse chromatographic method. The results obtained reflect interactions of the above adsorbates with the alloy surface, strongly enriched in silver atoms, as a result of surface segregation processes.
, Pd–Ag/Al2O3 293–773 K. . , , .相似文献
17.
A. É. Timbekova A. L. Vereschagin A. A. Semenov N. K. Abubakirov 《Chemistry of Natural Compounds》1990,26(2):178-183
A new triterpene pentaglycoside — medicoside L — has been isolated from the roots ofMedicago sativa L. (Leguminosae). It has the structure of medicagenic acid 28-O--D-glucopyranoside 3-O-{[O--D-glucopyranosyl-(1 2)][O--L-rhamnopyranosyl-(1 3)]-O--D-glucopyranosyl-(1 2)}--D-glucopyranoside.Institute of the Chemistry of Plant Substances, Uzbek SSR Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 221–228, March–April, 1990. 相似文献
18.
M. A. Agzamova M. I. Isaev M. B. Gorovits N. K. Abubakirov 《Chemistry of Natural Compounds》1988,23(6):696-700
A bisdesmosidic glycoside — cycloorbicoside G — has been isolated from the epigeal parts of the plantAstragalus orbiculatus Ledeb. (Leguminosae), and on the basis of chemical transformations and spectral characteristics its structure has been established as (23R,24S)-16,23;16,24-diepoxycycloartane-3,7,25-triol 25-O--D-glucopyranoside 3-O--D-xylopyranoside.Institute of the Chemistry of Plant Substances, Uzbek SSR Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 837–842, November–December, 1987. 相似文献
19.
The by-products formed in the preparation of strophanthiodol 19-rhamnoside and 3, 19-bisrhamnoside by the orthoester method are 3,5-dihydroxy-8,19-epoxy-5,14, 17-card-20(22)-enolide and its 3--L-rhamnoside. 3,5-Dihydroxy-8,19-epoxy-5, 14,17-card-20(22)-enolide has been obtained by the action of a solution of HBr in nitromethane on strophanthidol.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 744–750, November–December, 1981. 相似文献
20.
Sh. Sh. Afiyatullov A. I. Kalinovskii V. A. Stonik 《Chemistry of Natural Compounds》1988,23(6):691-696
Two new triterpene glycosides — cucmariosides C1 and C2 — have been isolated from the Far Eastern holothurianEupentacta (=Cucumaria)fraudatrix Djakonov et Baranova. Their structures have been established with the aid of13C NMR and PMR spectroscopy, partial acid hydrolysis, periodate oxidation, and methylation as 16-acetoxy-3-{[3-O-methyl--D-xylopyranosyl-(13)--D-glucopyranosyl-(14)] [-D-xylopyranosyl-(12)]--D-quinovopyranosyl-(12)--D-xylopyranosyloxy}holosta-7,23,24(cis)-triene and 16-acetoxy-3-{[3-O-methyl--D-xylopyranosyl-(13)--D-glucopyranosyl-(14)] [-D-xylopyranosyl-(12)]--D-quinovopyranosyl-(12)--D-xylopyranosyloxy}holosta-7,22,24(trans)-triene, respectively.Pacific Ocean Institute of Bioorganic Chemistry of the Far-Eastern Scientific Center of the USSR Academy of Sciences, Vladivostok. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 831–837, November–December, 1987. 相似文献