固化温度对聚苯乙烯空心微球质量的影响

在乳液微封装技术制备聚苯乙烯空心微球的工艺中,固化过程是决定微球球形度及壁厚均匀性的关键阶段。基于乳粒发生器制备内径(85010) m、壁厚(25025) m的复合乳粒,以25 ℃,45 ℃和65 ℃作为固化温度,考察了固化温度对微球球形度和壁厚均匀性的影响。结果表明,固化温度越低,界面张力越高,乳液固化速率越慢,微球球形度和壁厚均匀性越好。当固化温度为25 ℃时,批次微球中球形偏离值优于2 m的微球产率为90%,壁厚偏差值优于2 m的微球产率为40%,明显优于固化温度为45 ℃和65 ℃时微球的质量。     

点火靶尺度聚苯乙烯空心微球的球形度

为提高惯性约束聚变(ICF)点火靶尺度(约2mm)聚苯乙烯(PS)空心微球的球形度,研究了油相与外水相界面张力、初始油相质量分数和固化旋转流场转速对PS微球球形度的影响。结果表明,将双重乳液体系外水相中的表面活性剂聚乙烯醇(PVA)替换为聚丙烯酸(PAA)后,油相与外水相之间的界面张力增大了约10倍,PS空心微球的球形度显著提高,球形偏离度小于1μm的微球比例由5%增加至约50%;但是,在较宽范围内改变油相初始质量分数及旋转固化流场转速,对PS微球球形度的影响并不显著,球形偏离度值小于1μm的PS微球比例介于40%~60%之间。     

点火靶尺度聚苯乙烯空心微球的球形度

为提高惯性约束聚变（ICF）点火靶尺度（约2 mm）聚苯乙烯（PS）空心微球的球形度,研究了油相与外水相界面张力、初始油相质量分数和固化旋转流场转速对PS微球球形度的影响。结果表明,将双重乳液体系外水相中的表面活性剂聚乙烯醇（PVA）替换为聚丙烯酸（PAA）后,油相与外水相之间的界面张力增大了约10倍,PS空心微球的球形度显著提高,球形偏离度小于1 m的微球比例由5%增加至约50%;但是,在较宽范围内改变油相初始质量分数及旋转固化流场转速,对PS微球球形度的影响并不显著,球形偏离度值小于1 m的PS微球比例介于40%~60%之间。     

制备大直径无气泡聚苯乙烯空心微球

高品质聚苯乙烯（PS）空心微球是惯性约束聚变（ICF）实验用多层塑料微球靶的重要芯轴,常由乳液技术制备。针对由乳液技术制备的PS微球壳壁内容易形成气泡而且大直径微球制备困难的问题,实验研究了对壳壁内存在的气泡以及消除方法和制备大直径PS微球的制备技术。     

制备大直径无气泡聚苯乙烯空心微球

 高品质聚苯乙烯（PS）空心微球是惯性约束聚变（ICF）实验用多层塑料微球靶的重要芯轴,常由乳液技术制备。针对由乳液技术制备的PS微球壳壁内容易形成气泡而且大直径微球制备困难的问题,实验研究了对壳壁内存在的气泡以及消除方法和制备大直径PS微球的制备技术。     

聚苯乙烯相对分子量对薄壁聚苯乙烯空心微球质量的影响北大核心CSCD

激光惯性约束聚变(ICF)作为探索受控核聚变的有效途径,有望获得清洁无污染的能源,而薄壁聚苯乙烯(PS)空心微球是ICF物理实验中亟需的一类微球。针对薄壁空心微球因径厚比(直径/壁厚)增大导致其在干燥、使用中易开裂的问题,研究了PS原料对薄壁微球质量的影响,探讨了其影响机制。结果表明:当油相PS质量分数为4%时,随着油相粘度增加,W1/O/W2复合乳粒稳定性逐渐提高;当油相质量分数不低于8%时,复合乳粒稳定性良好。PS原料对微球表面粗糙度影响较小,微球球形度和壁厚均匀性随初始油相粘度的增大而降低,在干燥过程中微球开裂率随原料力学性能提高而减小。在外水相中引入氟苯(FB)液滴,延缓固化速率,可减小油相粘度增加对微球球形度和壁厚均匀性的不利影响。     

厚壁空心微球的球形度和壁厚均匀性的表征研究

为建立高效简洁的厚壁空心微球球形度和壁厚均匀性的表征和测量方法,以内径850 m、壁厚25 m的厚壁聚苯乙烯（PS）微球为测量对象,分析球形度和壁厚均匀性的表征方法,探讨测量过程中采样方式对表征微球球形度和壁厚均匀性的影响。研究表明：对于批量微球球形度和壁厚均匀性的表征,当抽样数目不小于30时,测量结果之间的差异很小;而对于单一微球的球形度和壁厚均匀性的表征,至少3个不同投影面的测量结果的平均值才趋于稳定。不同投影面导致球形度或壁厚均匀性较差的批次样品的测量结果有一定差异,多次投影测量可提高测量结果的可靠性。     

微封装法制备聚苯乙烯空心微球的改进

 主要介绍了密度匹配微封装技术，利用此项技术制备的聚苯乙烯空心微球 球形度好于99%，同心度好于98%。另外还对球壳内壁气泡问题及大直径球壳的制备进 行了讨论。     

微封装法制备聚苯乙烯空心微球的改进

主要介绍了密度匹配微封装技术,利用此项技术制备的聚苯乙烯空心微球 球形度好于99%,同心度好于98%。另外还对球壳内壁气泡问题及大直径球壳的制备进 行了讨论。     

厚壁空心微球的球形度和壁厚均匀性的表征研究

为建立高效简洁的厚壁空心微球球形度和壁厚均匀性的表征和测量方法,以内径850μm、壁厚25μm的厚壁聚苯乙烯(PS)微球为测量对象,分析球形度和壁厚均匀性的表征方法,探讨测量过程中采样方式对表征微球球形度和壁厚均匀性的影响。研究表明:对于批量微球球形度和壁厚均匀性的表征,当抽样数目不小于30时,测量结果之间的差异很小;而对于单一微球的球形度和壁厚均匀性的表征,至少3个不同投影面的测量结果的平均值才趋于稳定。不同投影面导致球形度或壁厚均匀性较差的批次样品的测量结果有一定差异,多次投影测量可提高测量结果的可靠性。     

基底温度对中阶梯光栅厚铝膜质量的影响

大尺寸中阶梯光栅具有大孔径和极高的衍射级次,可以实现普通光栅难以达到的极高光谱分辨率。中阶梯光栅通常是利用刻划机在厚铝膜上刻划而成,所以制备大面积均匀性的高质量铝膜刻划基底是实现高性能大尺寸中阶梯光栅的关键因素。在较厚铝膜的制备工艺中,基底温度是至关重要的工艺参数。本文通过电子束热蒸发镀铝工艺在不同基底温度下制备了厚铝膜样品,并利用原子力显微镜、扫描电镜等手段从宏观和微观尺度详细分析了基底温度对铝膜质量的影响。铝膜平均晶粒尺寸从100℃时的264.34 nm增大到200℃时的384.97 nm和300℃时的596.35 nm,表面粗糙度Rq从100℃时的34.7 nm增长到200℃时的58.9 nm和300℃时的95.1 nm。结果表明,随着基底温度的升高表面粗糙度迅速增大,铝膜的表面质量严重退化。     

Room temperature synthesis of water-repellent polystyrene nanocomposite coating

A stable superhydrophobic polystyrene nanocomposite coating was fabricated by means of a very simple and easy method. The coating was characterized by scanning electron microscopy and X-ray photoelectron spectrum. The wettability of the products was also investigated. By adding the surface-modified SiO₂ nanoparticles, the wettability of the coating changed to water-repellent superhydrophobic, not only for pure water, but also for a wide pH range of corrosive liquids. The influence of the drying temperature and SiO₂ content on the wettability of the nanocomposite coating was also investigated. It was found that both factors had little or no significant effect on the wetting behavior of the coating surface.     

Influence of surface cleaning on dewetting of thin polystyrene films

Thin polystyrene (PS) films on top of silicon substrates are a frequently investigated model system in the framework of unstable films. However, with respect to stability the various experiments yielded contradictory results. Focussing on the influence of preparation conditions such as the surface cleaning solves these contradictions. By applying different surface cleans the PS film can be changed from a stable homogeneous one into a completely dewetted one. In addition to the type of clean applied, the time between cleaning the surface and spin-coating the polymeric layer on top turned out to be an important experimental parameter.Received: 1 August 2003PACS: 68.55.-a Thin film structure and morphology - 68.15. + e Liquid thin films - 68.47.Mn Polymer surfaces     

Effects of curing temperature on physical properties of hydrothermally-grown yttrium-doped ZnO nanorods

We investigated the effects of the curing temperature on physical properties of hydrothermal synthesized yttrium-doped ZnO (YZO) nanorods. Compared to the as-grown sample, the c-axis preference (i.e., the peak intensity of x-ray diffraction at the (002) Bragg angle) was much enhanced after curing in vacuum at 200 °C. In addition, 200-°C-cured YZO nanorods showed a significant decrease in the number of metastable oxygen bonds. These resulted in both the increase in ultra-violet emission and the decrease in oxygen-related deep-level emission.     

Influence of particle size on the breaking of aluminum particle shells

Rupturing the alumina shell (shell-breaking) is a prerequisite for releasing energy from aluminum powder. Thermal stress overload in a high-temperature environment is an important factor in the rupture of the alumina shell. COMSOL Multiphysics was used to simulate and analyze the shell-breaking response of micron-scale aluminum particles with different particle sizes at 650 ℃ in vacuum. The simulation results show that the thermal stability time and shell-breaking response time of 10 μm-100 μm aluminum particles are 0.15 μs-11.44 μs and 0.08 μs-3.94 μs, respectively. They also reveal the direct causes of shell breaking for aluminum particles with different particle sizes. When the particle size is less than 80 μm, the shell-breaking response is a direct result of compressive stress overload. When the particle size is between 80 μm and 100 μm, the shell-breaking response is a direct result of tensile stress overload. This article provides useful guidance for research into the energy release of aluminum powder.     

离子辐照对聚苯乙烯低温导电特性的影响

室温下用3MeV的硅离子对聚苯乙烯(PS)进行辐照,对辐照后的样品在室温至液氮温度范围的导电特性进行了测量.结果表明,当辐照剂量在1×1012cm-2附近,PS的室温电阻发生突变.随着温度的降低,PS电阻增大,在低辐照剂量下,电阻在155K附近急剧增加.对于高辐射剂量样品,在较高的温度下呈现热激活导电,在低温下电子通过隧穿传导.分析认为,PS电阻随温度的变化是由于不同剂量辐照离子在聚合物中形成的对电子传导有贡献的导电中心密度不同.通过拟合样品的渗流临界特性,分析了样品电阻随辐照剂量的变化 关键词： 聚苯乙烯 硅离子辐照 低温导电     

Influence of implant dose and target temperature on crystal quality and junction depth of boron-doped silicon layers

30 keV boron ions are implanted at doses of 2×10¹⁴ and 2×10¹⁵ cm^–2 in 100 silicon wafers kept at room or liquid-nitrogen temperatures. The samples are analyzed by double-crystal X-ray diffraction, transmission electron microscopy and secondary ion-mass spectrometry before and after furnace annealing at 800°C. The low-dose implant does not amorphize the substrate at any of the temperatures, and residual defects together with a remarkably enhanced boron diffusion are observed after annealing. The high-dose implant amorphizes the substrate only at low temperature. In this case, unlike the room-temperature implant, the absence of any residual defect, the incorporation of the dopant in substitutional position and a negligible profile braodening of boron are obtained after annealing. In principle, this process proves itself a promising step for the fabrication of p ⁺/n shallow junctions with good electrical characteristics.