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1.
A method is proposed for the implementation of large-sample prompt-gamma neutron activation analysis (LS-PGNAA). The method was tested with four different sample materials at the thermal PGNAA facility at JAERI, Japan. The macroscopic scattering cross section (Σ s) and absorption cross section (Σ a) of the samples were determined by monitoring the neutron flux in four positions just outside the sample container. With the Σ s and Σ a determined, the spatial neutron density distribution [n(r)] inside the sample material was derived. Taking n(r) and the gamma-ray self-absorption into account simultaneously, the effective geometric gamma-ray detection efficiency for large samples as a function of gamma-ray energy was calculated. Taking silicon as test element, the concentrations found agreed to within 7% with the known concentrations in the four sample materials examined, both when using relative standardization and with absolute standardization.  相似文献   

2.
In order to correct for neutron self-shielding in large-sample prompt gamma NAA, a method has been developed to determine the macroscopic scattering and absorption cross sections, i.e., Σ a and Σ s, using four Cu flux monitors placed around the sample. With Monte Carlo computations, the neutron densities throughout the sample and the resulting and the corresponding self-shielding factor as calculated from the Σ a and Σ s as obtained through the Cu monitors were compared to the true values. The derived Σ a and Σ s were found to be sufficiently accurate as long as Σ t = Σ a + Σ s was less than 0.6 cm−1 and Σ s/Σ t was greater than 0.1.  相似文献   

3.
The first vertical ionization potentialsI(ns) of 69 monosulfides XSY (X, Y=H, Hal, organic, or heteroorganic substituent) are related to the inductive σI resonance (σ R + ) and polarizability (σα) constants of the substituents by dependences of theI(nS)=a+bΣσI+bΣσR+bΣσα type. TheI(ns) values are also affected by hyperconjugation which increases on going from XSH to XSY (Y≠H) compounds. The first calculations of the σ R + parameters characterizing the conjugation of Si-, Ge-, Sn-, and Pb-containing substituents with the S.+ radical cation center are reported. The reasons for weakening of resonance donor properties of heteroorganic substituents of the +M-type in the systems studied as compared to those of the same substituents in the corresponding aromatic radical cations are considered. Translated fromIzvestiya Akademii Nauk. Seriya Khmicheskaya, No. 1, pp. 25–31, January, 2000.  相似文献   

4.
The first vertical ionization potentialsI(ns) of 69 monosulfides XSY (X, Y=H, Hal, organic, or heteroorganic substituent) are related to the inductive σI resonance (σ R + ) and polarizability (σα) constants of the substituents by dependences of theI(nS)=a+bΣσI+bΣσR+bΣσα type. TheI(ns) values are also affected by hyperconjugation which increases on going from XSH to XSY (Y≠H) compounds. The first calculations of the σ R + parameters characterizing the conjugation of Si-, Ge-, Sn-, and Pb-containing substituents with the S.+ radical cation center are reported. The reasons for weakening of resonance donor properties of heteroorganic substituents of the +M-type in the systems studied as compared to those of the same substituents in the corresponding aromatic radical cations are considered. Translated fromIzvestiya Akademii Nauk. Seriya Khmicheskaya, No. 1, pp. 25–31, January, 2000.  相似文献   

5.
The small-angle neutron scattering (SANS) method for measuring the self-diffusion coefficient D has been analyzed for effects of polydispersity in degree of polymerization for the case of linear polymers diffusing by reptation. Polydispersities corresponding to Mw/Mn = 1.0?10 were considered. It is shown that in all cases a meaningful effective diffusion coefficient De can be obtained from the short time recovery of the SANS intensity. This quantity De ≤ 1.3 D(Mw), where D(Mw) is the diffusion coefficient of a monodisperse polymer having molecular weight M = Mw. The method relies on SANS intensities extrapolated to zero scattering angle; realistic extrapolation is shown to give rise to quite acceptable errors on the order of 0.05 De.  相似文献   

6.
Stray neutron distribution in a medical cyclotron vault room was evaluated by neutron activation analysis (NAA). Neutrons were generated in the production of radioactive nuclides, such as 18F, 11C, 13N and 15O, for diagnostic usage. Indium foil was adopted to evaluate the stray fast and thermal neutron intensity based on 115In(nf, n′)115mIn and 115In(nth, γ)116m1In reactions, respectively. The indium foils were weighed, sealed and placed at 62 points around the 6.7×8.2 m2 cyclotron room. Additionally, each indium foil was exposed for over 80 minutes during cyclotron operation and γ-peaks were analyzed using an HPGe detector to evaluate the number of stray fast (Φ f) or thermal (Φ th) neutrons. The minimum to maximum numbers of fast and thermal neutrons were (3.47±0.11)×103 to (1.06±0.21)×104 n·cm−2·s−1 and 9 to 965 n·cm−2·s−1, respectively. The minimum detectable limit for stray neutrons was included herein to demonstrate the reliability. Accordingly, 60 and two points, respectively, the confidence level associated with the reported intensities of fast and thermal neutrons reached 95%. The low qualified ratio in the evaluation of stray thermal neutrons might have been caused by either the high Compton scattering plateau or the low intensity of the gamma-ray peak in the relevant spectrum.  相似文献   

7.
The increased attention has been focused on the re-searches of soft materials proposed by Pierre-Gilles de Gennes, a Nobel Prize Laureate in Physics. A special issue of “Science” on soft surfaces was published in 2002 to review specific surface properti…  相似文献   

8.
An analytical expression has been developed to calculate the neutron self-shielding in a cylindrical sample using the elemental thermal neutron absorption cross sections, σ abs , and the newly-defined epithermal neutron absorption cross-sections, σ abs,ep . The σ abs,ep were measured experimentally for 13 nuclides and calculated from resonance parameters for 76 nuclides. Agreement between the two was good to about 20% in most cases. A spreadsheet program was written to use these nuclear parameters to perform iterative self-shielding corrections of concentrations measured by NAA. In cases with up to 30% self-shielding, the correction factors had uncertainties varying from 2% to 3%.  相似文献   

9.
Small-angle neutron scattering (SANS) experiments have been conducted on mixtures of nearly monodisperse hydrogenated polybutadiene (HPB) and its deuterated counterpart (DPB) in molten and semicrystalline states. A direct comparison of scattering patterns from molten and quench-crystallized samples shows unambiguously that chain conformation is unchanged by crystallization over large and intermediate size scales. The HPB's are shown to have slightly larger coil dimensions than linear polyethylenes of the same molecular weight. The scattering law for mixtures of different chain lengths was also investigated. Mismatched mixtures of monodisperse components give rise to scattering with an angle dependence well described by the Debye function for a Gaussian chain, even in the 50/50 composition range. This permits evaluation of SANS parameters [apparent radius gyration (Rg)e and apparent degree of polymerization Ne] by analysis of the full scattering curve, removing the restrictions that the Guinier condition (qRg < 1) be satisfied. The values of (Rg)e and Ne obtained from experiment are in good agreement with predictions of the scattering law for ideal mixtures.  相似文献   

10.
Micelle formation in aqueous sodium hexadecyl sulfate solutions is studied by small-angle neutron scattering. Measurements are carried out at different concentrations (1.1, 2.2, 3.2, 5.4, 10.9 and 32.8 mM/dm3) and at different temperatures (40°, 50°, and 60°C). The monotonous evolution of interparticle correlation can be observed on the measured scattering patterns. At high concentrations (10.9 and 32.8 mM/dm3) scattering patterns are described by interacting ellipsoids, but at low concentrations by non-interacting ellipsoids. Computation of the distance distribution function proved the ellipsoidal shape at 10.9 and 32.8 mM/dm3, but showed an unexpectedly large particle dimension and elongation of the micelles at lower concentrations.  相似文献   

11.
Quartz crystal microbalance (QCM) was used to study the self-assembly of per-6-thio-β-cyclodextrin (t7-βCD) on gold surfaces, and the subsequent inclusion interactions of immobilized βCD with adamantane-poly(ethylene glycol) (5,000 MW, AD-PEG), 1-adamantanecarboxylic acid (AD-C) and 1-adamantylamine (AD-A). From a 50 μM solution of t7-βCD in 60:40 DMSO:H2O, a t7-βCD layer was formed on gold with surface density of 71.7 ± 2.7 pmol/cm2, corresponding to 80 ± 3% of close-packed monolayer coverage. Gold sensors with immobilized t7-βCD were then exposed alternately to six different concentrations of AD-PEG, 500 μM AD-C or 500 μM AD-A aqueous solutions for association, and water for dissociation. Association of AD-PEG conformed to a Langmuir isotherm, with a best fit equilibrium constant K = 125,000 ± 18,000 M−1. For AD-C and AD-A, association (k a ) and dissociation (k d ) rate constants were extracted from kinetic profiles by fitting to the Langmuir model, and equilibrium constants were calculated. The parameters for AD-C were found to be: k a = 100 ± 5 M−1 s−1, k d = 110 (±18) × 10−4 s−1, and K = 9,400 ± 1,700 M−1. For AD-A, k a = 58 ± 6 M−1 s−1, k d = 154 (±7) × 10−4 s−1, and K = 3,800 ± 400 M−1. The results demonstrate the utility of QCM as a tool for studying small molecule surface adsorption and guest–host interactions on surfaces. More specifically, the kinetic and thermodynamic data of AD-C, AD-A, and AD-PEG inclusion with immobilized t7-βCD form a basis for further surface association studies of AD-X conjugates to advance surface sensory and coupling applications.  相似文献   

12.
The microstructure of the normal micelles formed by dimeric surfactants with long spacers, [Br(CH3)2N+(C m H2 m +1)-(CH2) S  -(C m H2 m +1)N+(CH3)2Br, m = 10 and s = 8, 10 and 12], has been investigated by small-angle neutron scattering and compared with previously reported results for micelles of the same dimeric surfactants with shorter spacers (m = 10 and s = 2, 3, 4 and 6). It was found that for dimeric surfactants with long spacers (s = 8 and 10), both micellar growth and variation in shape occur to only a small extent, if at all, compared with dimeric surfactants with short spacers. However, for the dimeric surfactant with the longest spacer, s = 12, the extent of micellar growth and shape variation is also large. These results are due to the differences in conformation of dimeric surfactants with short spacers (s = 2–6) compared with that of the surfactants with long spacers (s = 8–12). Received: 15 June 1998 Accepted: 22 July 1998  相似文献   

13.
ko-factors of 35 isotopes used in reactor neutron activation analysis were measured with a high degree of accuracy (1–2%). To minimize systematic errors, measurements were carried out using different reactor types, irradiation conditions (18 < Φse), Ge(Li) detectors, sample detector geometry, etc. Analyst-oriented tabulations including all necessary nuclear data, “best values”, as well as recommended ko-values are given to facilitate analytical work with the new method. Some practical aspects as well as limitations of the ko-method are also outlined together with the applied neutron flux and cross-section conventions. Research associate of the National Fonds voor Wetenschappelijk Onderzoek, Belgium  相似文献   

14.
Reactions of eaq, OH radicals and H atoms were studied with n-allylthiourea (NATU) using pulse radiolysis. Hydrated electrons reacted with NATU (k = 2.8×109 dm3 mol−1 s−1) giving a transient species which did not have any significant absorption above 300 nm. It was found to transfer electrons to methyl viologen. At pH 6.8, the reduction potential of NATU has been determined to be −0.527 V versus NHE. At pH 6.8, OH radicals were found to react with NATU, giving a transient species having absorption maxima at 400–410 nm and continuously increasing absorption below 290 nm. Absorption at 400–410 nm was found to increase with parent concentration, from which the equilibrium constant for dimer radical cation formation has been estimated to be 4.9×103 dm3 mol−1. H atoms were found to react with NATU with a rate constant of 5 × 109 dm3 mol−1 s−1, giving a transient species having an absorption maximum at 310 nm, which has been assigned to H-atom addition to the double bond in the allyl group. Acetoneketyl radicals reacted with NATU at acidic pH values and the species formed underwent reaction with parent NATU molecule. Reaction of Cl.−2 radicals (k = 4.6 × 109 dm3 mol−1 s−1) at pH 1 was found to give a transient species with λmax at 400 nm. At the same pH, reaction of OH radicals also gave transient species, having a similar spectrum, but the yield was lower. This showed that OH radicals react with NATU by two mechanisms, viz., one-electron oxidation, as well as addition to the allylic double bond. From the absorbance values at 410 nm, it has been estimated that around 38% of the OH radicals abstract H atoms and the remaining 62% of the OH radicals add to the allylic double bond.  相似文献   

15.
We have obtained interaction dipole moment curves for the rare gas heterodiatoms Rg...Xe (Rg = He, Ne, Ar, and Kr) from conventional ab initio and density functional theory calculations with flexible Gaussian-type basis sets. All methods seem to reproduce fairly similar dipole moment curves for all pairs. Our best values for the interaction dipole moment (at the respective experimental equilibrium separation R e) were obtained at the coupled-cluster theory with single, double, and perturbatively linked triple excitations level of theory: μint(RgXe)/eα0 = − 0.0025(He), − 0.0047(Ne), − 0.0055(Ar), and − 0.0037(Kr). The same trend (in absolute terms) is observed at the MP2 level of theory for the derivative of the dipole moment at R e, as (dμint (RgXe)/dR) e /e = 0.0043 (He), 0.0082 (Ne), 0.0091 (Ar), and 0.0059 (Kr). Around R e , μint(HeXe) ≡ μHeXe varies at the MP2 level of theory as [μHeXe(R) − μHeXe(R e)]/ea0 = 0.0043(RR e) − 0.0033(RR e)2 + 0.0018(RR e)3 − 0.0005(RR e)4.  相似文献   

16.
The macroscopic cross-section Σ and average neutron fluence in matter Φ are usable factors to comment neutron shielding property of samples. In this paper, we have used MgB2, NaBH4 and KBH4 samples including different percentages of boron. Neutron macroscopic cross-section measurements of them have been done by using a source of mono-energetic neutrons (E eff = 4.5 MeV 241Am–Be). Average neutron fluence values and double differential fast neutron flux distributions of each samples calculated by using FLUKA Monte Carlo code. Also half value layers (HVLs) of samples are compared to paraffin which is one of the most neutron moderators. As a result, growing boron concentration can raise neutron shielding property of materials.  相似文献   

17.
The well-tempered Gaussian basis sets (14s 10p) for atoms from lithium to neon were contracted and used in restricted Hartree–Fock calculations on 13 systems: Li2(Σ), B2(Σ), C2(Σ), N2(Σ), O2(Σ), F2(Σ), Ne2(Σ), LiF(Σ), BeO(Σ), BF(Σ), CN?(Σ), CO(Σ), and NO+(Σ). Spectroscopic constants (Re, ωe, ωexe, Be, αe, and ke) and one-electron properties (dipole, quadrupole, and octupole moments at the center of mass and electric field, electric field gradient, potential, and electron density at the nuclei) were evaluated and compared with the Hartree–Fock results. The largest contracted basis set (7s6p3d) gives results very close to the Hartree–Fock values; the remaining differences are attributed to the absence of the f functions in the present basis sets. For Ne2, the interaction energy was calculated; the magnitude of the basis-set superposition error was found to be very small (less than 3 μEh at 2.8 a0 and less than 2 μEh at 5.0 a0).  相似文献   

18.
Matrix isolation is an experimental method in chemistry that is widely used for the preparation of samples for spectroscopic studies. It makes it possible to stabilize species which are unstable at room temperature, to isolate molecules in solids from each other, and to carry out molecular spectroscopy at low temperatures. Matrix isolated molecules are studied by a variety of techniques. In this paper the application of inelastic neutron scattering (INS) to matrix isolation is reviewed. Molecules that contain hydrogen atoms are diluted in inert gases such as argon, krypton and nitrogen, and then condensed inside a liquid helium cryostat of the type that is in use at many neutron spectrometers. For this work we developed a technique for the vapor deposition of inert gases with dopants that have low vapor pressure. INS focuses on some aspects of matrix isolation which are not appropriately covered by other spectroscopies, mainly solid state aspects of matrix isolated molecular aggregates and of the matrix itself. Neutron scattering is used to observe optically forbidden excitations such as methyl librations, tunnelling transitions, phonons, and rotational transitions involving a nuclear spin flip. Moreover, a direct correlation of spectroscopic data with the powder diffraction pattern of the matrix is possible with this technique. Localized modes and phonon densities of states can be observed in the same sample and may then be related to the respective diffraction pattern. The vapor deposited samples can be characterized in this way, and possible structural faults in rare-gas lattices revealed which are not usually recognized by other techniques. The structure of molecular aggregates has been elucidated by neutron spectroscopy of their low frequency internal intermolecular modes. HCN forms long linear chains, CH3CN antiparallel dimers. Both species may, be understood as intermediates for the formation of the respective crystals. The structure of the matrix cages, in which single molecules are embedded, is explored by recording rotational and translational localized modes of these molecules. The single particle rotations of HCl, H2O, NH3, and CH4 were studied directly. Tunnel splittings and librational spectra were recorded from molecules with methyl groups [CH3CN, CH3I, CH3COCH3, C3H8, C4H10, Sn(CH3)4, and others]. The mutual influence of translational modes of the guest and phonons of the host can be studied, since the neutron spectra are directly connected with the phonon density of states of the system. The librational spectrum of N2 in Ar and a local mode of H2 in solid D2 are presented and compared with theoretical calculations.  相似文献   

19.
Summary Results are presented of studies of packings containing copper (II) acetylacetonate (acac), hexafluoroacetylacetonate (hfac), and chloride, chemically bonded via β-dik-etonate groups. The retention parameters retention factor (k) specific retention volume (V g), and molecular retention index (M e) were measured and used to calculate the thermodynamic parameters free energy of adsorption (ΔG a) heat of adsorption (−ΔH a), and entropy of adsorption (ΔS a). These parameters enable, characterization of specific interactions between aromatic and cyclic hydrocarbons, ethers and thioethers and metal complexes chemically bonded, to a silica surface.  相似文献   

20.
The molecular and electronic structure of hypothetical metallofullerenes In5C55 (1a) and In10C60 (2a) were simulated by the MNDO/PM3 method. Formally, heterofullerene1a is obtained from the C60 cluster by replacement of the carbon atoms at α-positions relative to one of the pentagons by In atoms, and cluster2a is obtained from the C70 cluster by replacement of the carbon atoms framing the polar pentagons of this fullerene by In atoms. Along with clusters1a and2a, their η5-π-complexes ln(η5-1a (1b) and ln2(2η5-2a) (2b) with one (1b) and two (2b) exohedral In atoms coordinated to the pentagons (pent *) isolated by In atoms were also studied. The energies of the In—pent * bonds in1b and2b are approximately equal to 104 kcal mol−1. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 880–883, May, 1998.  相似文献   

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