Preparation and Crystal Structure of Hetero—metal Clusters[η^5—C5H4C（O）CH2CH2C（O）OCH3]FeCoM（μ3—S）（CO）8（M=Mo or W）

1 INTRODUCTIONTransition metal clusters have been attracting intensive attention largely because they are suggested as active catalysts in a variety of homogeneous catalyzed reactions. However, no unequivocal proof exists that metal clusters themselves serve as the true catalysts among the catalytic process. In many cases it is known that fragments of the original clusters are the actual catalytic species. The unambiguous proof would be the use of a rigid chiral cluster to catalyze an asy…     

Synthesis and Crystal Structure of Fe（aapo）2Cl3 （aapo=2—Acetylamino Pyridine N—Oxide

1INTRODUCTIONComplexesofpyridineN-oxideligandshavereceivedmoreandmoreattention,andwehavereportedsomeofthemcontainingadonorsubstituteatthe2-positioninanattempttobroadentherangeofpyridineN-oxidecomplexes[1,2].MostcrystalstructuresofpyridineN-oxidesreportedareaboutdivalenttransitionmetalionsM(Ⅱ)[1～4],withonlyaveryfewontrivalenttransitionmetalionsM(Ⅲ)[5].Asthecontinuingworkofsystematicresearch,herewewillpresentthesynthesisandstructureofthetitlecompound.Toourknowledge,itisthefirstexamplet…     

Cleavage of the Fe—Fe Bond of （Me2SiSiMe2） [η^5－C5H4Fe（CO）2]2 with Na／Hg and Molecular Structure of the Ring－Opened Complex

The reaction of the rifle cyclic complex (1) with sodium amalgam in THF resulted in the expected cleavage of the Fe-Fe bond to afford his-sodium salt ( Me2SiSiMe2 ) [η^5-C5H4Fe(CO)2]2 (4). The latter was not isolated and was used directly to react with MeI, PhCH2Cl, CH3C(O)Cl, PhC(O)Cl,Cy3SnCl (Cy= cyclohexyl) or Ph3SnCl to afford corresponding ring-opened derivatives (Me2SiSiMe2) [η^5-C5H4Fe(CO)2]2 [5, R=Me; 6, R=PhCH2; 7, R=CH3C(O); 8, R=PhC(O); 9, R = Cy3Sn or 10, R = Ph3Sn ]. The crystal and molecular structures of 10 were determined by X-ray diffraction analysis. The molecule took the desired ant/ conformation around the Si-Si bond. The length of the Si--Si bond is 0.2343(3)nm, which is essentially identical to that in the cyclic structure of 1[0.2346(4) tun]. This result unambiguously demonstrates that the Si--Si bond in the cyclic structure of 1 is not subject to obvious strain.     

Synthesis, Structure and Optical Limiting （OL） Properties of a Novel Incomplete Cubane-like Cluster [PPh4][η^5-C5Me5） WS3-（CuBr） （CuI）2 （μ-dppm）]

IntroductionTetrathiometallateanions [MS4 ]2 - (M =Mo ,W )andtheirclusterswithvarioustransitionmetalsarewell knownfortheirrichcoordinationchemistry ,1 7andtheirrelationtoindustrialcatalysisprocess ,8biologicalsystems ,9andNLOmaterials .10 12 However,thechemistryoftheorganometallictrisulfidecomplexes [PPh4 ][(η5 C5Me5) MS3](M =Mo ,13W14 )andtheirrelatedmixed metalclus tershavebeenlessinvestigated .15,16 Inordertoextendourknowledgeaboutthechemistryof [PPh4 ][(η5 C5Me5) MS3]andconti…     

Synthesis and Structure of [Cu（OH）2（H2O）2（4—C5H4N—COOH）2]

1 INTRODUCTION Supramolecular chemistry and crystal engineering of coordination compounds have attracted considerable interests nowadays owing to the fascinating structural diversity and potential applications as functional materials[1,2]. Generally, architectures of supramolecules are formed through hydrogen bonds, ?- ?stacking interaction or other weak interactions between the molecules. Recently, many supramolecular compounds containing silver(I) and copper(II) species have been re-…     

Synthesis and 2D H-bonded Cd（ Ⅱ ） Network Structure of [Cd（C10H15N3）Cl2]

1 INTRODUCTION Transition metal Schiff base complexes have been extensively studied in the past two decades for their various crystallographic features, enzymatic reactions, steric effects[1～4], catalysis and magnetic properties[5, 6] as well as their important role in organisms[7, 8]. Most of these first-row materials are biologically essential with a number of their complexes showing bioactivities[9, 10]. Herein we describe the synthesis and X-ray structure of the cadmium (Ⅱ) compl…     

Syntheses and Anti—inflammatory Actiobn of （η—C5H5）2Ti （Cin）2 and （η—C5H5）2Ti（Tzea）2

Two new Complexes(Cp)2Ti(Cin)2and (CP2)Ti(Tzea)2(CP=Cyclopentadienyl η^5-C5H5)have been synthesized in THF by the reaction of HCin(Cincofen,2-phenylquinoline-4-carboxylic acid)or HTzea(5-phenyltetrazolyl-2-ethanoic acid)with(Cp)2TiCl2,and characterized by elemental analyses,IR,1H NMR and 13C NMR,UV spectra,molar conductivity,TGDTA.In the complexes the carboxyl groups are coordinated to Ti(IV)in a monodentate manner,The inhibitory actions of the complexes on mice ear tumefaction caused by croton oil and the rat foot granulation growth produced by cotton wool are higher than those of the corresponding ligands HCin,HTzea and [(Cp)2TiCl2],while their toxicities are lower than those of the free ligands.ηη     

Synthesis and Crystal Structure of [H-amp]4[Mo8O26（DMF）2].2H2O（amp = 2-Amino-6-methyl-pyridine）

1INTRODUCTIONMetal-oxoclusterchemistryhasbeenactivelypurchasedduetotheinterestinchemistryitselfanditsvariousapplicationsinfieldssuchascatalysis,electronicconductivity,magnetism,nonlinearopti-calpropertiesandmedicine[1～3].Recently,anim-portantadvanceinmet…     

Synthesis and Structure of Dimolybdenum Carbonyl Thiolate Compound [Et4N]2[Mo2（CO）8（SC6H4—CH3—m）2]

1 INTRODUCTION In 1984, thiolate ligand was successfully introduced into molybdenum carbonyl compound by the reaction of Mo(CO)6 with [Et4N]SR( R = C6H5, But) in a moderate condition[1]. From then on, a series of dinuclear molybdenum(0) carbonyl thiolate compounds have been synthesized and characterized by using a variety of thiolate ligands in our research group. It was found that a planar Mo2S2 unit is in the compound [Et4N]2[Mo2(CO)8(SC6H4-CH_3-p)2][2] (2) and a "butterfly" t…     

Synthesis and Crystal Structure of a Novel Two-dimensional Layered Polymer [Zn（μ-O2CCH=CHCO2）（C3H4N2）（H2O）]n

1 INTRODUCTION More than 200 known metalloenzymes of a wide variety of types have been shown to contain zinc centers at their active sites (such as hydrolases, ligases and anhydrases)[1～3]. The active zinc centers in biological systems are usually surro…     

Syntheses and Crystal Structure of [Cu（pyr）3].Hg2I6

1INTRODUCTIONThepolynucleard10metalcomplexesarepotentialluminescentsensormaterialsduetotheirattractivephotochemicalandphotophysicalpro-perties[1,2].Lowdimensionalmetal-organichalidecomplexeshavereceivedever-interestingattentioninrecentyearsfortheirpotentialapplicationsaselectronicandcatalyticmaterials[3,4].RecentlyHomo-metaloligomersandthechainsofcopperhavebeenreportedbyZubietaandthecoworkersviahydrothermalsyntheses[5,6].Theexistingexamplesofcopperwithmercuryareextremelyrare[7].Intherece…     

Synthesis and Crystal Structure of Cadmium（Ⅱ） Complex [Cd（H2O）（CH3OC6H4COO）2]n

1 INTRODUCTION Cadmium (Ⅱ) complexes have been exten- sively studied from both chemical and structural views, mainly due to the capability of cadmium (Ⅱ) (shared by most d10 metal ions) to adopt different modes of coordination determined by the consideration of size, as well as electrostatic and covalent bonding forces[1]. And the field of coordination polymers has witnessed tremendous growth over the last decade[2]. Many coordination polymeric networks have been shown to posses intere…     

Synthesis of Substituted Indenyl Lanthanide Chloride and Molecular Structure of[（C5H9C9H6）2Yb（μ—Cl）2Li（Et2O）2]

Reaction of anhydrous ytterbium trichlorides with 2 equiv.of cyclopentylindenyl lithium in THF solution,followed by removal of the solvent and crystallization of the porduct from diethyl ether,affords a crystal complex of the composition(C5H9C9H6)2Yb(μ-Cl)2Li(Et2O)2.Crystallographic analysis shows that the ytterbium coordinated by two cyclopentylindenly rings and lithium surrounded by two ether molecules are bridged by the two chlorine atoms and Yb,Li and two chlorine atoms form a plane.     

Hydrothermal Synthesis and Crystal Structure of [（CH3CH2）4N]4[（La12（OH）12MoO29）],A Novel Cluster Compound with a MoO5 Hexahedron Center surrounded by La—O Octahedron

IntroductionRecently,the molecular designs of polyox-ometalates( POM) with basic oxometal clusterbuilding blocks are of great interest[1,2 ] . Hy-drothermal synthesis,with the characteristic ofone- pot reaction,provides a convenient method toobtain novel structures of POM compounds[3— 6] . Inthe Ln/Mo/O system ( Ln=rare earth) ,somecompounds containing La and Mo elements havebeen reported[7— 17] . However,these compoundshave all been synthesized under the highly restrict-ed synthetic co…     

Synthesis, Crystal Structure, UV-vis and EPR Studies of（ NH3CH2CH2NH2 ） 2.5 [ Mo0.5^（V）W0.5^（VI）O2 （ OC6H4O ） 2]

Cis-dioxo-metal complex ( NH3CH2CH2NH2 ) 2.5 [ Mo0.5^(V)W0.5^(VI)O2 ( OC6H4O ) 2] 1 was obtained by the reaction of tetra-butyl ammonium hexamolybdotungstate with 1, 2-dihydroxybenzene in the mixed solvent of CH3OH, CH3CN and ethylenediamine,and characterized by X-ray diffraction, UV-vis and EPR analysis. Compared with its analogous complexes (NH3CH2CH2NH2)3[Mo^(V)O2(OC6H40)2] 2 and (NH3CH2CH2NH2)2[W^(VI)O2(OC6H4O)2] 3, the results show that tungsten(VI) is less active in redox than molybdenum (VI) and that the change of the valence induced by substitution of W(VI) for Mo(V) in EMO2(OC6H40)2]n- does not influence the coordination geometry of the complex anion in which the metal center exhibits distorted octahedral coordination with cis-dioxo catechol. The responses to EPR of complexes 1 and 2 are active but complex 3 is silent,and the UV-vis spectra exhibited by the three complexes are obvious different because of the different electronic configuration between the central Mo(V) and W(VI) ions in the complexes.It is noteworthy that complexes 1 and 2 have the similar EPR signal to flavoenzyme, suggesting that the three complexes have the same coordination geometry feature with the co-factor of flavoenzyme.     

Synthesis and Crystal Structures of Three Ladder Distannoxane Dimers [（PhCH2）2（Cl）SnOSn（X）（CH2Ph）2]2（X=Cl,OMe,OEt）

Three distannoxane dimers[(PhCH2)2(Cl)SnOSn(X)(CH2Ph)2]2(X=Cl,OMe,OEt)were prepared by the hydrolytic reaction of (PhCH2)2SnCl2 with sodium alkoxides.The compounds are assigned tetranuclear distannoxane structures in solid state.which contain the so-called ladder arrangement with a central planar Sn2O2 four-membered ring.The endo-and exo-cyclic Sn atoms are both five-coordinate,and have distorted trigonal bipyramidal geometries.A variety of hydrolyses of(PhCH2)2SnCl2 were performed and these dimers were characterized by IR,^1H NMR spectroscopy and X-ray diffraction analysis.     

Syntheses of Two Chiral Clusters [η5—C5H4C（NR）CH3]—RuNiM（CO）5（μ3—S）（R=NH—C6H3—2,4—（NO2）2,M=Mo,3;M=W,4）and the Single—crystal Structure of Cluster 3

1 INTRODUCTION The synthesis of chiral clusters containing four different atoms at the vertexes of the tetrahedron has been extensively studied because the chiral cluster can induce an asymmetric catalysis potentially[1]. Until now, many tetrahedron-type chiral clusters have been reported, but only a few of the reactions about the organic group in these clusters were investi- gated[2～4]. In this paper, we described the syntheses of clusters 3 and 4, and the structure of the former. 2 …