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Stepwise migration of coordinated Pt(II) from the endocyclic N1 site to the exocyclic amino group occurs in the bis(9-methyladenine-N1) complex of cis-Pt(II)(NH(3))(2) in basic solution, whereafter deamination of the 9-methyladenine still coordinated at N-1 competes with a second migration step. 相似文献