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Alfonso Castiñeiras Cristina Molleda José R. Masaguer Victoria Coto 《Transition Metal Chemistry》1983,8(3):129-131
Summary Several cobalt(II) halide complexes derived from 1,8-bis(2-pyridyl)-3,6-dithiaoctane (bpdto) are described. Chemical analysis suggests their formulae to be: Co(bpdto)X2 (X=Cl–, Br–, or I–). Electrolytic conductivities in acetonitrile, magnetic moments at different temperatures, solid state i.r. and u.v.-visible spectra support a tetrahedral stereochemistry around the cobalt(II). The ligand is bidentate andN-bonded in all cases.This work was presented in the Fifth Annual Meeting of the Portuguese Chemical Society, Porto (Portugal), March 1982. 相似文献
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O. Kristiansson 《Acta Crystallographica. Section C, Structural Chemistry》1999,55(5):IUC9900038-IUC9900038
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Ki-Young Choi Nack-Do Sung Ki-Seob Yun Young-Soo Park Jin-Gyu Kim Il-Hwan Suh 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(1):47-48
The title compound, [CuCl(C16H14N4)2]ClO4, consists of a mononuclear complex cation and a perchlorate anion. The coordination of the copper(II) ion exhibits a trigonal bipyramidal geometry, where the equatorial plane is composed of the Cl atom and two N atoms of the two pyridazine rings, and the axial positions are occupied by the N atoms of two methylpyridine rings. 相似文献
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