Elemental composition of β-Sic(001) surface phases studied by medium energy ion scattering

β-SiC surfaces have been investigated in terms of surface composition and reconstruction by medium energy ion scattering (MEIS), Auger electron spectroscopy (AES), and low energy electron diffraction (LEED). A (3 × 2) phase is produced by evaporating Si on a β-SiC surface. Heat treatment at 1065°C causes consecutive transformation into (5 × 2), c(4 × 2), (2 × 1), (1 × 1) and c(2 × 2) phases. Quantitative analysis of MEIS spectra shows that the c(4 × 2) surface has a full silicon topmost layer, whereas the c(2 × 2) surface has a full carbon topmost layer. The (3 × 2) and (5 × 2) phases are believed to originate from additional Si dimer rows on top of a Si terminated crystal.     

The coadsorption of I and Cl on Pt(111)

Using LEED and AES, the coadsorption of iodine and chlorine on Pt(111) was studied. Five surface structures were observed: (1 × 1), (√3 × √3)R30°, (√7 × √7)R±19.1°, (3 × 3) and c(2 × 4). Fractional monolayer coverages for both Cl and I are assigned to these structures. The importance of the adatom-adatom steric interactions is discussed.     

Dynamical behaviour of PtRh(100) alloy surface during dissociative adsorption of NO and reaction of NO with H2

When a clean Pt-Rh(100) alloy surface was exposed to NO at T > 440 K, the LEED pattern changed sequentially as p(1 × 1) → c(2 × 2) → c(2 × 2) + p(3 × 1) → p(3 × 1), where the c(2 × 2) pattern appeared immediately after the exposure to NO. In contrast to this, the appearance time for the p(3 × 1) depends strongly on the initial Rh concentration on the surface adjusted by annealing. When the p(3 × 1) surface was exposed to H₂ by mixing H₂ into NO gas, the AES intensity of O(a) decreased and of N(a) increased markedly and the LEED pattern changed from p(3 × 1) to c(2 × 2). These results suggest that N(a) has equal affinity to Pt and Rh atoms so that the N(a) does not distinguish the Pt and Rh sites on the alloy surface. On the other hand, O(a) makes a stronger bond with Rh atoms so that Rh atom segregation onto the surface is induced. By reacting randomly distributed Rh atoms on the Pt-Rh(100) surface with oxygen, a surface compound in a p(3 × 1) arrangement is built on the surface.     

Cyclic cluster study of water adsorption structures on the MgO(1 0 0) surface

Cyclic cluster calculations were performed with the quantum chemical method MSINDO to elucidate the relative stabilities of c(4 × 2), p(3 × 2) and (1 × 1) overlayer structures of water molecules on the MgO(1 0 0) surface. For the c(4 × 2) and p(3 × 2) structures both molecular adsorption and partially dissociated adsorption were considered. In agreement with earlier theoretical studies partial dissociation was found to be more stable than molecular adsorption. For the c(4 × 2) structure both monolayer and double layer coverage were studied. Adsorption was found to be more stabilized with increasing degree of dissociation until 50% of the water molecules were dissociated. In the case of 50% dissociated water molecules we found that one quarter of the Mg atoms were pulled out of the MgO surface when surface relaxation was taken into account. A new structure for the fully dissociated (1 × 1) water monolayer was found which is considerably more stable than previously studied arrangements. In all cases surface relaxation was found to be important. The most stable structures of c(4 × 2), p(3 × 2) and (1 × 1) symmetry have adsorption energies which differ by no more than 13 kJ/mol. This offers an explanation of phase transitions of overlayer structures found by experiments between 180 and 300 K.     

Atomic structure of Cu{0 0 1}c(2 × 2)-Cl

A LEED intensity analysis of Cu{0 0 1}c(2 × 2)-Cl has given an excellent fit of theory to experiment with Cl in the fourfold symmetrical hollows in a simple overlayer structure with a Cu-Cl bond length of 2.38 Å. This structure is consistent with an analysis of angle-resolved photoemission measurements made in the same experiments and published elsewhere. These results help confirm the LEED analysis of the analogous system Ag{0 0 1}c(2 × 2)-Cl which gave the same structure, but had been rejected by an independent photoemission analysis.     

B^0 - \bar B^0 mixing in a supersymmetric model without at-quark

A model based on a low energySU(3)_c×SU(2)₁×SU(2)₂×U(1) _H gauge group is considered. Theb-quark couples mainly to thec-quark via a new heavyW-boson and thet-quark is omitted altogether. The model is shown to be compatible with low energy charged current data. \(B_d^0 - \bar B_d^0 \) mixing occurs through the exchange of the heavyW-boson and through gluino exchange in the supersymmetric version of the model. The calculated mixing is much smaller in both cases than the observed effect and the model is, therefore, ruled out.     

A perturbation theory study of H2 on LiF(0 0 1)

In response to recent helium atom scattering (HAS) results, Monte Carlo (MC) simulations and perturbation theory have been performed for H₂ on LiF(0 0 1). MC simulations predict that H₂ molecules form a series of structures, p(2 × 2), p(8 × 2), p(4 × 2) with coverages Θ = 0.5, 0.625 and 0.75, respectively, that are stable up to 8 K. This is in partial agreement with the HAS results that report c(2 × 2) and c(8 × 2) structures; they agree in terms of coverage and stability, but disagree in terms of symmetry. To reconcile the results of the simulations and experiments, the orientation of the adsorbed H₂ molecules was studied using perturbation theory. These calculations show that the adsorbed H₂ molecules are azimuthally delocalized and that the structures are c-type rather then p-type. The calculations also indicate that p-H₂ and helicoptering o-H₂ prefer cationic sites, while cartwheeling o-H₂ prefers anionic sites.     

The GaAs (001)−c(4×4) and (2×4) reconstructions: A comparative photoemission study

Surface sensitive photoemission measurements of As(3d) core levels give new experimental evidence that the MBE-grown GaAs (0 0 1)?c(4×4) surface is richer in As than the 2×4 surface and that it is produced by an As overlayer chemisorbed onto the As atoms terminating the polar GaAs(0 0 1) surface. A study of As thermal desorption shows that the c(4×4) structure persists over a broad range of surface stoichiometry.     

Phase transitions on clean Si(110) surfaces

The properties of the structure of clean Si(110) surfaces have been investigated by LEED. The phase transitions between surface structures Si(110)?(4 × 5), Si(110)?(2 × 1) and Si(110)(5 × 1) take place at about 600 and 750°C. The time of reconstruction from the high temperature phase to the low temperature phase may exceed the time of the sample cooling. That explains why the Si(110)?(2 × 1) and the Si(110)?(5 × 1) superstructures may be seen at room temperature. Surface defects favour the retaining of high temperature phases on the surface at room temperature. The transition from the Si(110)?(5 × 1) structure to the Si(110)?(2× 1) structure and conversely in the temperature range of 720–750°C apparently occurs through formation of the intermediate structures Si(110)?(7 × 1) and Si(110)?(9 × 1). The models are given of superstructures observed by LEED.     

Vibrational excitations of p(2×2) oxygen and c(2×2) hydrogen on Pd(100)

The p(2×2) oxygen and c(2×2) hydrogen structures on Pd(100) have been investigated by angle-resolved high-resolution electron energy loss spectroscopy. Dipole excited vibrational modes are observed at 44 and 64 meV for the oxygen and hydrogen structures respectively and are interpreted to correspond to atomic adsorption in the hollow site.     

D2 layers on MgO(0 0 1): Simulation study

In response to recent helium atom scattering (HAS) and neutron scattering results, Monte Carlo simulations and perturbation theory calculations have been performed for D₂ on MgO(0 0 1). Monte Carlo simulations predict that D₂ molecules form a series of interesting structures, p(2 × 2) → p(4 × 2) → p(6 × 2), with coverages Θ = 0.5, 0.75, 0.83 respectively, and followed by a formation of a top layer of p(6 × 2) unit cell symmetry. The three types of mono-layers are stable up to 13 K, whereas the top layer still exists up to 10 K. This is in partial agreement with the neutron scattering and HAS results that report c(2 × 2), c(4 × 2) and c(6 × 2); they agree in terms of coverage and stability, but disagree in terms of symmetry. A quantum mechanical examination of the D₂ molecules’ rotational motion shows the molecular axes are azimuthally delocalized and hence the simulated structures are c-type rather than p-type. These calculations also indicate that ortho-D₂ and helicoptering para-D₂ prefer cationic sites, while cartwheeling para-D₂ prefers anionic sites.     

RHEED study of In-induced superstructures on Ge(111) surfaces

When submonolayer and monolayer amounts of indium were deposited onto clean Ge(111) surfaces at room temperature and then heated, (13 × 2√3), (12 × 2√3), (11 × 2√3), (10 × 2√3), (4√3 × 4√3) R30°-related, (√31 × √31) R(±9°), (√61 × √61) R(30 ± 4°) and (4.3 × 4.3) structures appeared on the surfaces at fixed In coverages and at fixed surface temperatures. General intensity features of superlattice reflections are derived from intensity estimations by eye of superlattice spots in their RHEED patterns, and some structural characteristics of the superstructures are clarified from the analysis of the general intensity features. The former four superstructures are long-period (2 × 2)-related antiphase structures whose period changes, depending on the coverage. The wavevector characterizing the (13 × 2√3) structure, which appears at the smallest coverage, almost coincides with those of structural fluctuation emerging at the clean Ge(111) (1 × 1) surface around 350°C. The coincidence suggests that the longperiod (2 × 2)-related antiphase structures have a close relationship to the structural fluctuation and, besides, to the (2 × 8) structure in their origin.     

Nonabelian electric and magnetic flux in unified SU(5) gauge theory

We study the long-distance behaviour of pure unified SU(5) gauge theory in the limit when the electroweak subgroup is unbroken. We show that the symmetry breaking pattern SU(5)→SU(3)_c×SU(2)×U(1)_Y, with SU(3)_c and SU(2) ×U(1)_Y realized, respectively, in confining and coulombic phases, is a possible dynamical phase of the SU(5) theory. The proof relies on showing that the duality equation of 't Hooft, relating the electric and magnetic flux, is exactly satisfied for the above symmetry breaking pattern. The infrared structure of SU(5), broken down to SU(3)_c×SU(2)×U(1)_Y, is not self-dual.     

Construction of grand unified models under maximal subalgebras

A construction of grand unified models of the strong, weak and electromagnetic interactions is described based on the transformation properties of the group generators under a maximal subgroup decomposition without recourse to large representation matrices or to the specific algebraic structures of some classical Lie-groups, such as the Clifford algebra associated with the orthogonal groups or the octonionic structure of the exceptional groups. To illustrate the procedure an explicit construction is given of the SU(5) model useful in the discussion of higher rank groups, of SO(10) under the maximal subalgebras SU(2)_L × SU(2)_R × SU(4)_c and SU(5) × U(1)_r and of the exceptional group E₆ under SU(3)_L × SU(3)_R × SU(3)_c and SO(10) × U(1)_t. The construction procedure can be used as well with any classical Lie-group.     

Phase portrait ofSU(5) model. II intermediate phasesSU(3)×[U(1)]2 and [SU(2)]2×[U(1)]2

The effective potential of the scalar field in theSU(5) model has extrema with symmetry:SU(5),SU(4)×U(1),SU(3)×SU(2)×U(1),SU(3)×[U(1)]², [SU(2)]²×[U(1)]². In our recent paper it was shown that theSU(4)×U(1) phase as well asSU(3)×SU(2)×U(1) phase were stable at the nonzero temperature in a vast region of parameters. In the present paper it is found that the [SU(2)]²×[U(1)]² symmetric vacuum is unstable and theSU(3)×[U(1)]² symmetric vacuum can be metastable in the certain interval of the temperature. Domains of the three phases:SU(4)×U(1),SU(3)×SU(2)×U(1),SU(3)×[U(1)]²-could co-exist in the early. Universe.     

Determination of the Co(001)c(2 × 2)-S superstructure by comparison of LEED intensity data

A cross-comparison of LEED intensity data for Co(001)c(2 × 2)-S and Ni(001)c(2 × 2)-S gives evidence that the sulfur atoms are chemisorbed on Co(001) in a fourfold site, at 1.3 Å from the first substrate layer.     

A low composite scale preon model with complementarity

We have constructed the first “realistic candidate” preon model with low composite scale satisfying complementarity between the Higgs and confining phases. The model is based onSU(4) metacolor and predicts four generations of ordinary quarks and leptons together with heavy neutrinos at the level of the standard gauge groupSU(3) _c ×SU(2) _L ×U(1) _Y . There are no exotic massless fermions. The global family group isSU(2)×U(1).     

Search for a new light gauge boson in π0, η and η′ decays

Upper limits for the production of new light gauge bosons in π⁰, η and η′ decays have been obtained with the Crystal Barrel detector. The kinematically well-constrained reactions p?p → π⁰π⁰ P have been studied, where P ? π ⁰, η, η′ decays through the emission of a single photon recoiling against a missing state X. X can be a long-lived weakly interacting particle or it decays into ???. The resulting branching ratio upper limits (90 % C.L.) are: 6 × 10^?5 for masses M _X of the missing particle X lying between 65 MeV/c² and 125 MeV/c² (π⁰ decay), 6 × 10^?5 for M _X between 200 MeV/c² and 525 MeV/c² (gh decay), and 4 × 10^?5 for M _X between 50 MeV/c² and 925 MeV/c² (η′ decay). The π⁰-decay limit represents an improvement by a factor of 4 to 8 (depending on M _X) when compared to the existing limit, whereas the η and η′ decay limits have been measured for the first time, thereby extending the M _X range from 125 MeV/c² up to 925 MeV/c².     

LEED investigation of mixed layers of carbon and sulfur on cobalt

The structure of mixed layers of carbon and sulfur on the Co(001) face was investigated by LEED as a function of composition. The results indicate that C and S atoms do not form seperate islands, but are present in the same domains on neighbor sites. Several models are discussed, on the basis of the Structure of the pure phases c(2×2)-S, p(2×2)-S and p(2×2)-C on Co(001), which are shown to be nearly the same as those reported for the Ni(001) face.     

Phase portrait ofSU(5) grand unified model

The one-loop effective potential of theSU(5) model is investigated both in high and low temperature approximation. We find the regions of values of coupling constants and temperatures where theSU(5), theSU(4)×U(1) and theSU(3)×SU(2)×U(1) symmetric states are metastable. A general method of such an investigation is proposed. We observe that the domain structure of the Universe with the simultaneous existence of the gauge symmetriesSU(4)×U(1) andSU(3)×SU(2)×U(1) in different domains could take place.